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    • 5. 发明授权
    • Method for making a heat-shrinkable film containing a layer of crystalline polyamides
    • 制备含有结晶聚酰胺层的热收缩膜的方法
    • US06203750B1
    • 2001-03-20
    • US08789528
    • 1997-01-27
    • Kelly R. AhlgrenRam K. Ramesh
    • Kelly R. AhlgrenRam K. Ramesh
    • B29C4788
    • B32B27/34A22C13/0013A22C2013/002A22C2013/0053A22C2013/0059A22C2013/0083A22C2013/0086B29C47/0026B29C47/061B29C55/28B29K2077/00B29K2995/0049B29L2009/00B29L2031/712C08L77/00C08L77/02C08L77/06C08L23/00
    • A process of making a biaxially-oriented multilayer film, comprises extruding a tubular multilayer tape and inflating the tape so that the tape is biaxially oriented by stretching in the transverse direction and machine direction at the same time, so that a tubular multilayer film is formed. The tubular multilayer tape comprises: (i) a first layer comprising a composition comprising a first polyamide and at least one member selected from the group consisting of a first polyolefin and a second polyamide, wherein the first polyamide comprises at least one member selected from the group consisting of nylon 6, nylon 66, and nylon 6/66, and wherein the first polyolefin and the second polyamide each has a different crystal structure than the first polyamide, and wherein the first layer has a thickness of less than about 15 percent, based on a total thickness of the tape; (ii) a second layer comprising a second polyolefin; (iii) a third layer which is an O2-barrier layer comprising at least one member selected from the group consisting of ethylene/vinyl alcohol copolymer, polyvinylidene chloride, and polyalkylene carbonate, the third film layer having a thickness of less than about 15 percent, based on a total thickness of the tape; and (iv) a fourth layer comprising a third polyolefin.
    • 制造双轴取向多层膜的方法包括挤出管状多层带并使带充气,从而使带通过沿横向和机器方向同时拉伸双轴取向,从而形成管状多层膜 。 管状多层胶带包括:(i)第一层,其包含包含第一聚酰胺和至少一种选自第一聚烯烃和第二聚酰胺的成分的组合物,其中所述第一聚酰胺包含至少一种选自 由尼龙6,尼龙66和尼龙6/66组成的组,其中第一聚烯烃和第二聚酰胺各自具有与第一聚酰胺不同的晶体结构,并且其中第一层的厚度小于约15% 基于胶带的总厚度; (ii)包含第二聚烯烃的第二层; (iii)第三层,其是包含选自乙烯/乙烯醇共聚物,聚偏二氯乙烯和聚亚烷基碳酸酯中的至少一种的O 2阻挡层,第三膜层的厚度小于约15% ,基于胶带的总厚度; 和(iv)包含第三聚烯烃的第四层。