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1. 发明授权

US6147163A Acrylic oligomeric and polymeric durability enhancing agents, method therefore and cured coating compositions containing the same 失效
标题翻译：丙烯酸低聚物和聚合物耐久性增强剂，因此其方法和含有它们的固化涂料组合物
公开(公告)号：US6147163A
公开(公告)日：2000-11-14
申请号：US769289
申请日：1996-12-18
申请人： John E. Boisseau , Donald L. St. Aubin , Patricia K. Oberg , John W. Rehfuss
发明人： John E. Boisseau , Donald L. St. Aubin , Patricia K. Oberg , John W. Rehfuss
IPC分类号： C08F2/00 , C08K5/00 , C09D7/12 , C07D251/00 , C07D211/92 , C07D211/26 , C07D249/16
CPC分类号： C08K5/005 , C09D7/1241 , C08K5/07 , C08K5/3435 , C08K5/3475 , C08K5/34926
摘要： A durability enhancing agent comprising the reaction product of an acrylic oligomer or acrylic polymer and an ultraviolet light absorbing compound, a hindered amine light stabilizer or mixture thereof, said durability enhancing agent further comprising more than one carbamate functional group, or group convertible to a carbamate group, and optionally, including other reactive functionality capable of undergoing a crosslinking reaction. Also included is a curable coating composition comprising the durability enhancing agent, a method for obtaining a coated substrate and the coated article obtained thereby.
摘要翻译：一种耐久性增强剂，其包含丙烯酸类低聚物或丙烯酸类聚合物与紫外线吸收性化合物的反应产物，受阻胺光稳定剂或其混合物，所述耐久性增强剂还包含多于一个氨基甲酸酯官能团或可转化为氨基甲酸酯的基团并且任选地包括能够经历交联反应的其它反应性官能团。还包括含有耐久性增强剂的可固化涂料组合物，获得涂布基材的方法和由此得到的涂布制品。

2. 发明授权

US06180240B2 Acrylic ogligomeric and polymeric durability enhancing agents, method therefore and cured coating composition containing the same 有权
标题翻译：丙烯酸低聚物和聚合物耐久性增强剂，因此方法和含有其的固化涂料组合物
公开(公告)号：US06180240B2
公开(公告)日：2001-01-30
申请号：US09271784
申请日：1999-03-18
申请人： Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , Patricia K. Oberg
发明人： Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , Patricia K. Oberg
IPC分类号： B32B2738
CPC分类号： C08K5/005 , C08K5/07 , C08K5/3435 , C08K5/3475 , C08K5/34926 , C09D7/48 , Y10T428/31507
摘要： A durability enhancing agent comprising the reaction product of an acrylic oligomer or acrylic polymer and an ultraviolet light absorbing compound, a hindered amine light stabilizer or mixture thereof, said durability enhancing agent further comprising more than one carbamate functional group, or group convertible to a carbamate group, and optionally, including other reactive functionality capable of undergoing a crosslinking reaction. Also included is a curable coating composition comprising the durability enhancing agent, a method for obtaining a coated substrate and the coated article obtained thereby.
摘要翻译：一种耐久性增强剂，其包含丙烯酸类低聚物或丙烯酸类聚合物与紫外线吸收性化合物的反应产物，受阻胺光稳定剂或其混合物，所述耐久性增强剂还包含多于一个氨基甲酸酯官能团或可转化为氨基甲酸酯的基团并且任选地包括能够经历交联反应的其它反应性官能团。还包括含有耐久性增强剂的可固化涂料组合物，获得涂布基材的方法和由此得到的涂布制品。

3. 发明授权

US6166148A Durability enhancing agents, method therefore and cured coating compositions containing the same 失效
标题翻译：耐久性增强剂，因此的方法和包含其的固化涂料组合物
公开(公告)号：US6166148A
公开(公告)日：2000-12-26
申请号：US769245
申请日：1996-12-18
申请人： Walter H. Ohrbom , Donald L. St. Aubin , John E. Boisseau , Patricia K. Oberg , John W. Rehfuss
发明人： Walter H. Ohrbom , Donald L. St. Aubin , John E. Boisseau , Patricia K. Oberg , John W. Rehfuss
IPC分类号： C08K5/00 , C09D7/12 , C08F26/06
CPC分类号： C08K5/005 , C09D7/48
摘要： A durability enhancing agent which is an ultraviolet light absorbing compound or hindered amine light stabilizer covalently bonded to a monomeric, oligomeric or polymeric component. The durability enhancing agent includes more than one carbamate functional group, group convertible to a carbamate group, or group that is crosslinked via a carbamate group. The durability enhancing agent may also have other reactive functionality thereon. Also included is a coating composition including the durability enhancing agent.
摘要翻译：耐久性增强剂，其是共价键合到单体，低聚物或聚合物组分的紫外光吸收化合物或受阻胺光稳定剂。耐久性增强剂包括多于一个氨基甲酸酯官能团，可转化成氨基甲酸酯基的基团或经由氨基甲酸酯基团交联的基团。耐久性增强剂也可以具有其它反应性官能团。还包括含有耐久性增强剂的涂料组合物。

4. 发明授权

US5872165A Coating composition and method for reducing ultraviolet light degradation 失效
标题翻译：降低紫外光降解的涂料组合物和方法
公开(公告)号：US5872165A
公开(公告)日：1999-02-16
申请号：US768829
申请日：1996-12-18
申请人： Patricia K. Oberg , Donald L. St. Aubin , John E. Boisseau , Walter H. Ohrbom
发明人： Patricia K. Oberg , Donald L. St. Aubin , John E. Boisseau , Walter H. Ohrbom
IPC分类号： C09D201/00 , C09D7/12 , C08K5/34
CPC分类号： C09D7/1241 , C08K5/132 , C08K5/3475 , C08K5/34926
摘要： The present invention relates to a coating composition containing a combination of ultraviolet light absorbing compounds, one or more of which is bound to a polymer, and a method for reducing degradation of coating compositions due to ultraviolet light exposure.
摘要翻译：本发明涉及含有与聚合物结合的紫外光吸收化合物的组合的涂料组合物，以及由于紫外线曝光而降低涂料组合物降解的方法。

5. 发明授权

US06160058A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US06160058A
公开(公告)日：2000-12-12
申请号：US184196
申请日：1998-11-02
申请人： Walter H. Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss
发明人： Walter H. Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss
IPC分类号： C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/00 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C09D201/025 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C08L61/20 , C09D133/06 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/06 , C08L2666/16 , C08L2666/14 , C08L2666/28 , C08L2666/02
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes an acrylic polymer comprising active hydrogen-containing functional groups reactive with the third component(c). Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的丙烯酸聚合物。涂料组合物的组分（c）是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

6. 发明授权

US06080825A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US06080825A
公开(公告)日：2000-06-27
申请号：US184197
申请日：1998-11-02
申请人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
发明人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
IPC分类号： C09D175/04 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/79 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C07D251/34 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/792 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/025 , C09D201/06 , C08L61/20
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes a polymer resin comprising active hydrogen-containing functional groups reactive with the third component (c). The resins is selected from polyester, polyurethane, or polyester-polyurethane copolymers Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的聚合物树脂。树脂选自聚酯，聚氨酯或聚酯 - 聚氨酯共聚物涂料组合物的组分（c）是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

7. 发明授权

US6037441A Non-acrylic durability enhancing agents, method therefore and cured coating compositions containing the same 失效
标题翻译：非丙烯酸类耐久性增强剂，因此使用的方法和包含其的固化涂料组合物
公开(公告)号：US6037441A
公开(公告)日：2000-03-14
申请号：US769622
申请日：1996-12-18
申请人： Walter H. Ohrbom , John E. Boisseau , Donald L. St. Aubin , John W. Rehfuss
发明人： Walter H. Ohrbom , John E. Boisseau , Donald L. St. Aubin , John W. Rehfuss
IPC分类号： C08K5/00 , C09D7/12 , C08G73/00 , C08K5/3492
CPC分类号： C09D7/1241 , C08K5/005 , C08K5/34926
摘要： A durability enhancing agent which comprises an ultraviolet light absorbing compound or hindered amine light stabilizer, or mixture thereof, bonded to a non-acrylic monomeric, oligomeric, or polymeric component, said agent comprising more than one carbamate functional group, group convertible to a carbamate group, or a group that crosslinks with a carbamate functional group. Also included is a coating composition including the durability enhancing agent for improved resistance to environmental etch.
摘要翻译：一种耐久性增强剂，其包含与非丙烯酸类单体，低聚物或聚合物组分结合的紫外光吸收化合物或受阻胺光稳定剂或其混合物，所述试剂包含多于一个氨基甲酸酯官能团，可转化为氨基甲酸酯基团基团或与氨基甲酸酯官能团交联的基团。还包括一种涂料组合物，其包括用于改善耐环境蚀刻性能的耐久性增强剂。

8. 发明授权

US6084038A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US6084038A
公开(公告)日：2000-07-04
申请号：US184195
申请日：1998-11-02
申请人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
发明人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
IPC分类号： C09D179/00 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/79 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C07D251/34 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/792 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/025 , C09D201/06 , C08L61/20
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) having at least one carbamate group or urea group and having a lactone or hydroxy carboxylic acid moiety. The second component (b) of the coating composition is one or more of three materials. First, the second component can be a polymer resin (b)(1) comprising active hydrogen-containing functional groups reactive with the third component(c). Secondly, the second component can be a compound (b)(2) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea. Finally, the second component can be a compound (b)(3) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The third component of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包含具有至少一个氨基甲酸酯基或脲基并具有内酯或羟基羧酸部分的组分（a）。涂料组合物的第二组分（b）是三种材料中的一种或多种。首先，第二组分可以是包含与第三组分（c）反应的含活性氢的官能团的聚合物树脂（b）（1）。其次，第二组分可以是具有至少一个根据本发明的氨基甲酸酯基或末端脲基并且具有至少两个氨基甲酸酯或脲的连接基团的化合物（b）（2）。最后，第二组分可以是具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的基团的化合物（b）（3）。涂料组合物的第三组分是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

9. 发明授权

US07538130B2 Hindered amine light stabilizer, methods of making, and compositions 失效
标题翻译：受阻胺光稳定剂，制备方法和组合物
公开(公告)号：US07538130B2
公开(公告)日：2009-05-26
申请号：US11234898
申请日：2005-09-26
申请人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom , John E. Boisseau
发明人： Donald H. Campbell , Donald L. St. Aubin , Walter H. Ohrbom , John E. Boisseau
IPC分类号： A61K31/421 , A61K31/5375 , C07D263/04 , C07D265/04
CPC分类号： C08K5/35
摘要： A compound in which n is 0, 1, 2, or 3; R1, R2, R7, and R8 are each independently alkyl group, including cycloalkyl, an alkylaryl group, or an aryl group, optionally with one or more heteroatoms, with the proviso that R1 and R2 can together form a cycloalkylene group and, independently, R7 and R8 can together form a cycloalkylene group; Y is an oxygen free radical, a sulfur free radical, OR9 or SR9; R3, R4, R5, R6, and R9 are each independently H or an alkyl group, a cycloalkyl group, an aryl group, or an alkylaryl group, optionally with one or more heteroatoms; and compositions, such as basecoat and clearcoat coating compositions, containing such compounds.
摘要翻译： n为0,1,2或3的化合物; R 1，R 2，R 7和R 8各自独立地为烷基，包括环烷基，烷基芳基或芳基，任选具有一个或多个杂原子，条件是R 1和R 2可以一起形成亚环烷基， R7和R8可以一起形成亚环烷基; Y是氧自由基，无硫自由基，OR9或SR9; R 3，R 4，R 5，R 6和R 9各自独立地为H或烷基，环烷基，芳基或烷基芳基，任选具有一个或多个杂原子; 以及含有这些化合物的组合物，如底漆和透明涂料涂料组合物。

10. 发明授权

US06391390B1 Curable coating composition with improved durability 有权
标题翻译：可固化涂料组合物具有改善的耐久性
公开(公告)号：US06391390B1
公开(公告)日：2002-05-21
申请号：US09532763
申请日：2000-03-22
申请人： John E. Boisseau , Donald L. St. Aubin , Walter H Ohrbom
发明人： John E. Boisseau , Donald L. St. Aubin , Walter H Ohrbom
IPC分类号： C09D13304
CPC分类号： C09D7/65 , C08L33/062
摘要： The present invention provides a curable coating composition that includes a film-forming polymer, a polymeric additive having at least one bound surface protecting group, and a crosslinker that is reactive with the film-forming polymer. The polymeric additive is substantially free of groups reactive with the crosslinker and has comonomer units with aryl groups, alkyl groups having, on average, four or more carbon atoms, or combinations of the aryl and alkyl groups. When the coating composition is cured to form a cured coating layer, the concentration of the polymeric additive in the upper about 50% of the cured coating layer thickness is at least about 10% higher than the concentration of the polymeric additive in the rest of the cured coating layer.
摘要翻译：本发明提供一种可固化涂料组合物，其包括成膜聚合物，具有至少一个结合表面保护基的聚合物添加剂和与成膜聚合物反应的交联剂。聚合物添加剂基本上不含与交联剂反应的基团，并且具有芳基，具有平均四个以上碳原子的烷基或芳基和烷基的组合的共聚单体单元。当涂料组合物固化以形成固化的涂层时，聚合物添加剂在固化涂层厚度的约50％的浓度比其余的聚合物添加剂的浓度高至少约10％固化涂层。

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