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1. 发明授权

US06307095B1 Process for the preparation of vinylesters 失效
标题翻译：制备乙烯基酯的方法
公开(公告)号：US06307095B1
公开(公告)日：2001-10-23
申请号：US08950427
申请日：1997-10-15
申请人： Johannes Jacobus Keijsper , Jean-Paul Lange , Brendan Dermot Murray
发明人： Johannes Jacobus Keijsper , Jean-Paul Lange , Brendan Dermot Murray
IPC分类号： C07C6704
CPC分类号： C07C67/04 , C07C69/01 , C07C69/24
摘要： A process for the catalytic conversion of carboxylic acids with acetylene to vinylesters. At least one, preferably saturated, secondary carboxylic ester and/or at least one, preferably tertiary carboxylic acid is (are) passed in the gas phase together with acetylene at an elevated temperature, preferably in the range of from 150 to 400° C., over a catalyst comprising zinc and a solid inert oxidic carrier, preferably alumina. The carboxylic acids have advantageously the following formula: in which R1 is H or an alkyl group and R2 and R3 are alkyl groups, the total number of C-atoms of R1+R2+R3 being in the range of from 3 to 18. These vinylesters have a good stability and are particularly useful components in emulsion paints and as modifiers in alkyd and epoxy resin.
摘要翻译：将羧酸与乙炔催化转化成乙烯基酯的方法。在高温下，将至少一种优选饱和的仲羧酸酯和/或至少一种优选叔羧酸与乙炔一起通入气相中温度，优选在150-400℃的范围内，在包含锌和固体惰性氧化载体的催化剂，优选氧化铝中。羧酸有利地具有下式：其中R 1是H或烷基，R 2 并且R 3是烷基，R 1 + R 2 + R 3的C原子总数在3至18的范围内。这些乙烯基酯具有良好的稳定性，并且在乳液漆中和作为醇酸树脂和环氧树脂中的改性剂是特别有用的组分树脂。

2. 发明授权

US09365778B2 Process for liquefying a cellulosic material and its products 有权
标题翻译：液化纤维素材料及其制品的方法
公开(公告)号：US09365778B2
公开(公告)日：2016-06-14
申请号：US13106553
申请日：2011-05-12
申请人： Klaas Lambertus Von Hebel , Jean-Paul Lange
发明人： Klaas Lambertus Von Hebel , Jean-Paul Lange
IPC分类号： C10G1/06 , C08H8/00
CPC分类号： C10G1/002 , C08H8/00 , C10G1/065 , C10G3/50 , C10G2300/1014 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/04 , C10L2200/0469 , C10L2290/544 , Y02E50/13 , Y02P30/20
摘要： A process for liquefying a cellulosic material to produce a liquefied product from cellulosic material is provided. Products obtained from such process and use of such products to prepare biofuels is also provided.
摘要翻译：提供了一种用于液化纤维素材料以从纤维素材料生产液化产物的方法。还提供从这种方法获得的产品和使用这些产品来制备生物燃料。

3. 发明授权

US09012680B2 Process for preparing an ester 有权
标题翻译：制备酯的方法
公开(公告)号：US09012680B2
公开(公告)日：2015-04-21
申请号：US13389300
申请日：2010-04-29
申请人： Rene Johan Haan , Jean-Paul Lange
发明人： Rene Johan Haan , Jean-Paul Lange
IPC分类号： C07C67/00 , C07C67/08
CPC分类号： C07C67/08 , C07C67/00 , C07C69/24
摘要： A process for preparing an ester of formula (I): R3CH2—(CR1R2)n—CH2—O—CO—(CR1R2)n—CH2R3 (I) wherein n is 1-3 and R1 and R2 are each, independently, a hydrogen atom or a carbon-linked organic group and R3 is a carbon-linked organic group, is provided by hydrogenation of a certain lactone, carboxylic acid or its ester reactant.
摘要翻译：制备式（I）的酯的方法：R 3 -CH 2 - （CR 1 R 2）n -CH 2 -O-CO-（CR 1 R 2）n -CH 2 R 3（I）其中n为1-3，并且R 1和R 2各自独立地为氢原子或碳连接的有机基团，并且R 3是碳连接的有机基团，通过某些内酯，羧酸或其酯反应物的氢化提供。

4. 发明申请

US20110184195A1 PROCESS FOR THE HYDROGENOLYSIS OF FURFURYL DERIVATIVES 审中-公开
标题翻译：呋喃衍生物氢化方法
公开(公告)号：US20110184195A1
公开(公告)日：2011-07-28
申请号：US12999445
申请日：2009-06-24
申请人： Jean-Paul Lange , Jeroen Van Buijtenen
发明人： Jean-Paul Lange , Jeroen Van Buijtenen
IPC分类号： C07D307/36
CPC分类号： C07D307/36 , Y02P20/127
摘要： The present invention relates to a process for the hydrogenolysis of a furfuryl derivative to 2-methylfuran derivative, comprising: (a) contacting under liquid phase conditions a solution of the furfuryl derivative in a solvent having a boiling point above the boiling point of furfuryl derivative with hydrogen in the presence of a catalyst comprising a hydrogenation compound to form a 2-methylfuran derivative and water, at a temperature and pressure suitable to maintain the furfuryl derivative in the solvent in the liquid phase, and (b) continuously distilling the 2-methylfuran derivative from the reaction mixture.
摘要翻译：本发明涉及糠基衍生物氢解成2-甲基呋喃衍生物的方法，包括：（a）在液相条件下使糠基衍生物在沸点高于糠基衍生物的沸点的溶剂中接触在含有氢化化合物的催化剂存在下，使氢气在适于将糠基衍生物保持在溶剂中的温度和压力下形成2-甲基呋喃衍生物和水，和（b）连续蒸馏2- 甲基呋喃衍生物。

5. 发明申请

US20090101584A1 Reverse flow reactor with integrated separation and process for the employing this reactor 失效
标题翻译：具有集成分离的反流反应器和使用该反应器的方法
公开(公告)号：US20090101584A1
公开(公告)日：2009-04-23
申请号：US11666074
申请日：2005-10-24
申请人： Alouisius Nicolaas Renee Bos , Girish Rajkumar Kabra , Jean-Paul Lange
发明人： Alouisius Nicolaas Renee Bos , Girish Rajkumar Kabra , Jean-Paul Lange
IPC分类号： B01J8/04 , B01D53/68 , B01D53/48 , B01D53/14
CPC分类号： B01D51/10 , B01D53/02 , B01D2253/10 , B01D2253/202 , B01D2257/204 , B01D2257/30 , B01D2257/80 , B01J8/0446 , B01J2208/00106 , B01J2208/00699 , B01J2208/00707 , B01J2208/025
摘要： The present invention pertains to a reverse-flow reactor comprising at least one catalyst bed which is preceded and followed by at least one bed containing selectively adsorbing material, and its application for in a process for the removal of contaminants from a process stream.
摘要翻译：本发明涉及一种反流反应器，其包含至少一个催化剂床，其前面和后面是至少一个含有选择性吸附材料的床，以及其在从工艺流中除去污染物的方法中的应用。

6. 发明申请

US20070208183A1 HYDROGENATION PROCESS FOR THE CONVERSION OF A CARBOXYLIC ACID OR AN ESTER HAVING A CARBONYL GROUP 审中-公开
标题翻译：羧基酸转化反应的氢化方法
公开(公告)号：US20070208183A1
公开(公告)日：2007-09-06
申请号：US11680437
申请日：2007-02-28
申请人： Rene Haan , Jean-Paul Lange , Leonardus Petrus , Catharina Petrus-Hoogenbosch
发明人： Rene Haan , Jean-Paul Lange , Leonardus Petrus , Catharina Petrus-Hoogenbosch
IPC分类号： C07D305/12 , C07C69/66
CPC分类号： C07D307/33 , C07C51/367 , C07D309/30 , C07C59/01
摘要： A hydrogenation process for the conversion of a reactant selected from the group consisting of a carboxylic acid having a carbonyl group and an ester of a carboxylic acid having a carbonyl group to form a carboxylic acid or an ester with a hydroxyl group or a lactone, wherein the reactant is contacted with a heterogeneous catalyst comprising a hydrogenating compound, in the presence of formic acid, at a temperature in the range of from 150 to 400° C. and a pressure in the range of from 1.0 to 150 bar (absolute).
摘要翻译：用于将选自具有羰基的羧酸和具有羰基的羧酸的酯的反应物转化以形成羧酸或具有羟基或内酯的酯的氢化方法，其中反应物在含有氢化化合物的非均相催化剂的存在下，在甲酸存在下，在150-400℃的温度和1.0-150巴（绝对压力）的范围内接触。

7. 发明授权

US06897343B2 Process for the preparation of propanediol 失效
标题翻译：制备丙二醇的方法
公开(公告)号：US06897343B2
公开(公告)日：2005-05-24
申请号：US10742361
申请日：2003-12-19
申请人： Klaas Lambertus Von Hebel , Jean-Paul Lange
发明人： Klaas Lambertus Von Hebel , Jean-Paul Lange
IPC分类号： C07C29/12 , C07C31/20 , C07C68/06 , C07C69/96 , C07D317/36 , C07C29/48 , C07C29/00 , C07C29/132 , C07C29/15 , C07C29/16 , C07C27/041
CPC分类号： C07C68/065 , C07C29/12 , C07C69/96 , C07C31/205
摘要： The invention relates to a process for the preparation of 1,2-propanediol from propylene oxide, which process involves contacting propylene oxide with carbon dioxide in the presence of a homogeneous phosphorus containing catalyst to obtain propylene carbonate, optionally removing at least part of the carbon dioxide, adding water and/or an alcohol to the reaction product containing propylene carbonate and phosphorus containing catalyst and contacting the mixture with a heterogeneous catalyst to obtain 1,2-propanediol in combination with dialkylcarbonate and/or carbon dioxide, and separating 1,2-propanediol from the reaction product obtained.
摘要翻译：本发明涉及一种由环氧丙烷制备1,2-丙二醇的方法，该方法包括在均相含磷催化剂存在下使环氧丙烷与二氧化碳接触，得到碳酸亚丙酯，任选地除去至少部分碳二氧化碳，向含有碳酸亚丙酯和含磷催化剂的反应产物中加入水和/或醇，并将该混合物与多相催化剂接触，得到与二烷基碳酸酯和/或二氧化碳组合的1,2-丙二醇，并分离1,2- - 丙二醇。

8. 发明授权

US06835858B1 Catalytic conversion of an organic carbonate 有权
标题翻译：有机碳酸盐的催化转化
公开(公告)号：US06835858B1
公开(公告)日：2004-12-28
申请号：US10659142
申请日：2003-09-10
申请人： Johannes Petrus De Jonge , Jean-Paul Lange
发明人： Johannes Petrus De Jonge , Jean-Paul Lange
IPC分类号： C07C3900
CPC分类号： C07C68/065 , B01J23/06 , B01J23/26 , B01J23/80 , C07C29/12 , C07C29/128 , C07C31/205 , C07C69/96
摘要： The invention relates to a method for the catalytic conversion of organic carbonate to the corresponding alcohol, wherein the organic carbonate is contacted with alcohol and/or water in the presence of a zinc supported catalyst.
摘要翻译：本发明涉及一种将有机碳酸酯催化转化成相应的醇的方法，其中有机碳酸酯在负载有锌的催化剂存在下与醇和/或水接触。

9. 发明授权

US08741002B2 Gasoline compositions 有权
标题翻译：汽油组成
公开(公告)号：US08741002B2
公开(公告)日：2014-06-03
申请号：US12787261
申请日：2010-05-25
申请人： Allison Felix-Moore , Jean-Paul Lange , Johanne Smith
发明人： Allison Felix-Moore , Jean-Paul Lange , Johanne Smith
IPC分类号： C10L1/18
CPC分类号： C10L10/08 , C10L1/023 , C10L1/19 , C10L10/10
摘要： An unleaded gasoline composition comprising: (i) a gasoline base fuel; and (ii) component A, wherein component A is an alkyl alkenoate compound, or a mixture of alkyl alkenoate compounds, selected from compounds of formula I: wherein R1 is a linear alkenyl group containing 3 to 5 carbon atoms, optionally substituted by a methyl group, and R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms. The gasoline composition of the present invention exhibits good lubricity. The gasoline composition of the invention in another aspect provides increased sensitivity.
摘要翻译：一种无铅汽油组合物，包括：（i）汽油基燃料; 和（ii）组分A，其中组分A是烷基烯酸酯化合物或选自式I化合物的烷基烯酸酯化合物的混合物：其中R 1是含有3至5个碳原子的直链烯基，任选被甲基并且R 2是含有1至6个碳原子的直链或支链烷基。本发明的汽油组合物表现出良好的润滑性。本发明的另一方面的汽油组合物提供了增加的灵敏度。

10. 发明申请

US20110173877A1 PROCESS FOR PREPARING A HYDROCARBON OR MIXTURE OF HYDROCARBONS 审中-公开
标题翻译：制备烃类或混合物的方法
公开(公告)号：US20110173877A1
公开(公告)日：2011-07-21
申请号：US12972170
申请日：2010-12-17
申请人： Jeroen Van Buijtenen , Jean-Paul Lange , Richard John Price
发明人： Jeroen Van Buijtenen , Jean-Paul Lange , Richard John Price
IPC分类号： C10L1/18 , C07D407/00
CPC分类号： C07D307/12 , C07D307/44
摘要： A process for preparing a hydrocarbon or mixture of hydrocarbons comprising the steps of (i) hydrogenating furfural, 5-hydroxymethylfurfural or a mixture of furfural and 5-hydroxymethylfurfural to provide furfuryl alcohol, 2,5-furandimethanol or a mixture of furfuryl alcohol and 2,5-furandimethanol; (ii) oligomerizing the alcohol or mixture of alcohols of step (i) in the presence of an acidic catalyst to provide a carbon-carbon coupled oligomer; and (iii) hydrogenating the oligomer of step (ii) is provided. The hydrocarbons are useful as fuel blending components. Processes for controlling the oligomerization of alcohol or mixture of alcohols to optimise the production of oligomers suitable for conversion to hydrocarbons useful as kerosene and diesel components are also provided.
摘要翻译：一种制备碳氢化合物或烃混合物的方法，包括以下步骤：（ⅰ）氢化糠醛，5-羟甲基糠醛或糠醛与5-羟甲基糠醛的混合物，得到糠醇，2,5-呋喃二甲醇或糠醇与2 ，5-呋喃二甲醇; （ii）在酸性催化剂存在下使步骤（ⅰ）的醇或醇的混合物低聚以提供碳 - 碳偶合的低聚物; 和（iii）氢化步骤（ⅱ）的低聚物。烃可用作燃料混合组分。还提供了用于控制醇或醇混合物的低聚的方法以优化适用于转化为用作煤油和柴油组分的烃的低聚物的生产。

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