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    • 5. 发明授权
    • Photothermographic material comprising an infra-red sensitizer
    • 光热成像材料包括红外线敏化剂
    • US6074814A
    • 2000-06-13
    • US889411
    • 1997-07-08
    • Geert DerooverHerman UytterhoevenPaul CallantJohan Loccufier
    • Geert DerooverHerman UytterhoevenPaul CallantJohan Loccufier
    • G03C1/28G03C1/498G03C1/490
    • C09B23/0066C09B23/0075C09B23/086C09B23/148G03C1/49854G03C1/49863G03C1/28
    • A photothermographic recording material comprising a photo-addressable thermally developable element including a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, in a quantity of 0.1 to 35 mol % relative to the organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder comprises a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer and the dye is represented by formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.17 are independently each an alkyl or sulfo-alkyl group which may be substituted with at least one fluorine, chlorine, bromine, iodine or an alkoxy-, aryloxy- or ester-group; and X represents an anion.
    • 一种光热记录材料,其包含可光寻址的热显影元件,其包含基本上不光敏的有机银盐,相对于基本上不光敏的有机银盐催化缔合的感光卤化银,其量相对于 有机银盐,用染料对红外线进行光谱敏化,染料用超增敏剂,与基本上不透光的有机银盐和粘合剂的热加工关系的还原剂,其中粘合剂包含水溶性聚合物, 水分散性聚合物或水溶性聚合物和水分散性聚合物,染料由式(I)表示:其中Z1和Z2独立地表示S,O或Se; R 1和R 17各自独立地为可以被至少一个氟,氯,溴,碘或烷氧基 - ,芳氧基或酯基取代的烷基或磺基 - 烷基; X表示阴离子。
    • 6. 发明授权
    • Photothermographic material comprising at least one dye absorbing
electromagnetic radiation in the wavelength range 700 to 1100NM
    • 光热成像材料包含至少一种吸收波长在700至1100NM范围内的电磁辐射的染料
    • US5851755A
    • 1998-12-22
    • US889404
    • 1997-07-08
    • Herman UytterhoevenJohan LoccufierGeert DerooverPaul Callant
    • Herman UytterhoevenJohan LoccufierGeert DerooverPaul Callant
    • G03C1/28G03C1/498G03C5/16G03C1/494
    • G03C1/49854G03C1/28G03C5/164Y10S430/145
    • A photothermographic recording material comprising a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder includes a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer; the dye absorbs electromagnetic radiation in the wavelength range from 700 to 1100 nm; and the supersensitizer is a stilbene compound represented by general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups; and R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.sup.12 are independently hydrogen and alkyl, alkoxy, carboxy or sulfo groups; a production process therefor and a photothermographic recording process therewith.
    • 一种光热记录材料,其包含光可寻址热显影元件,其含有基本上不受光敏的有机银盐,与基本上不光敏的有机银盐催化缔合的感光卤化银和用染料对红外光进行光谱敏化, 用于染料的超敏剂,与基本上不透光的有机银盐和粘合剂的热加工关系的还原剂,其中粘合剂包括水溶性聚合物,水分散性聚合物或水溶性聚合物和水分散性聚合物 ; 染料吸收700〜1100nm波长范围内的电磁辐射; 超敏剂是由通式(I)表示的芪化合物:其中R 1,R 2,R 3和R 4独立地为氢或烷基,芳基,芳烷基,烷芳基,烷氧基或芳氧基; 且R 5,R 6,R 7,R 8,R 9,R 10,R 11和R 12独立地为氢和烷基,烷氧基,羧基或磺基; 其制备方法及其光热记录方法。
    • 7. 发明授权
    • Diagnostic radiographic silver halide photographic film material
    • 诊断射线照相卤化银摄影胶片材料
    • US06733947B2
    • 2004-05-11
    • US10609880
    • 2003-06-30
    • Leo De BieJohan LoccufierLudo JolyMarc Van den ZegelPaul Callant
    • Leo De BieJohan LoccufierLudo JolyMarc Van den ZegelPaul Callant
    • G03C1295
    • G03C1/061G03C1/035G03C5/17G03C2001/03511G03C2001/03541Y10S430/167
    • A single-side coated silver halide photographic film material has been disclosed, said film material comprising a support, at least one light-sensitive emulsion layer and a substantially light-insensitive protective hydrophilic colloid layer farther away from said support than said emulsion layer, wherein said emulsion layer contains a silver halide emulsion rich in silver bromide with cubic crystals having an average numerical diameter in the range from 0.4 up to 0.8 &mgr;m, wherein at least 95 mole % of bromide ions are present, and wherein said hydrophilic colloid layer or another substantially light-insensitive hydrophilic colloid layer essentially comprises a hydrazide represented by the general formula (I) having a silver halide adsorbing group or a masked silver halide adsorbing group; besides a method for forming a diagnostic image comprising the steps of contacting said photographic film material with an intensifying screen, forming a film/screen assembly, and exposing said assembly to X-ray radiation with an energy lower than or equal to 70 kVp, and processing said film material during a time of 90 seconds or less in a processing cycle following the steps of developing, fixing, rinsing and drying, and wherein the developing proceeds in a radiographic developer composition essentially comprising a hydroquinone and a phenidone (a 1-phenyl-3-pyrazolidine-1-one compound) as a developing agent and a heteroatomic nitro-indazol.
    • 已经公开了单面涂覆的卤化银照相胶片材料,所述胶片材料包括载体,至少一种感光乳剂层和比所述乳剂层更远离所述载体的基本上不光敏的保护性亲水胶体层,其中 所述乳剂层含有富含溴化银的卤化银乳剂,其立方晶体的平均数值范围为0.4至0.8μm,其中存在至少95mol%的溴离子,并且其中所述亲水胶体层或另一种 基本上不透光的亲水胶体层基本上包含具有卤化银吸附基团或掩蔽的卤化银吸附基团的由通式(I)表示的酰肼; 除了用于形成诊断图像的方法之外,包括以下步骤:使所述照相胶片材料与增强屏幕接触,形成膜/屏幕组件,并将所述组件暴露于具有低于或等于70kVp的能量的X射线辐射,以及 在显影,固定,漂洗和干燥的步骤之后的处理循环中,在90秒或更短的时间内处理所述薄膜材料,并且其中显影在基本上包含氢醌和菲尼酮(1-苯基 -3-吡唑烷-1-酮化合物)和杂原子硝基 - 吲唑。
    • 9. 发明授权
    • Colour laser marking methods of security document precursors
    • 安全文件前体的彩色激光打标方法
    • US09067450B2
    • 2015-06-30
    • US14241115
    • 2012-09-04
    • Bart WaumansPaul CallantIngrid Geuens
    • Bart WaumansPaul CallantIngrid Geuens
    • B41J2/435G03C8/00B41M3/14B41M5/26B41M5/323B41M5/34
    • B41M3/14B41M3/142B41M5/267B41M5/323B41M5/34
    • A method of color laser marking a security document precursor including at least: a transparent biaxially stretched polyethylene terephthalate foil; at least one colorless color forming layer for generating a color different from black containing at least an infrared absorber a color forming compound and a polymeric binder; and a laser markable polymeric support or a laser markable layer for generating a black color; comprising the steps of: laser marking the colorless color forming layer through the transparent polymeric foil with a infrared laser used in continuous wave mode to generate a color different from black; and laser marking the laser markable polymeric support or the laser markable layer through the transparent polymeric foil with the same infrared laser but used in a pulsed mode to generate a black color.
    • 一种彩色激光标记安全文件前体的方法,至少包括:透明双轴拉伸聚对苯二甲酸乙二醇酯箔; 至少一个无色颜色形成层,用于产生不同于至少含有红外线吸收剂的成色化合物和聚合物粘合剂的黑色; 以及用于产生黑色的可激光标记聚合物支撑体或激光可标记层; 包括以下步骤:通过使用连续波模式的红外激光通过透明聚合物箔激光标记无色成色层以产生不同于黑色的颜色; 并且通过具有相同红外激光器的透明聚合物箔片激光标记可激光标记聚合物支持体或激光可标记层,但以脉冲模式使用以产生黑色。