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1. 发明授权

US6162928A Preparation of pyrroles 有权
标题翻译：吡咯的制备
公开(公告)号：US6162928A
公开(公告)日：2000-12-19
申请号：US553254
申请日：2000-04-20
申请人： Joachim Wulff-Doring , Joachim Simon , Michael Hesse , Peter Wahl
发明人： Joachim Wulff-Doring , Joachim Simon , Michael Hesse , Peter Wahl
IPC分类号： B01J23/44 , B01J23/63 , C07B61/00 , C07D207/32 , C07D207/323
CPC分类号： C07D207/323 , B01J23/44 , B01J23/63
摘要： A process for preparing pyrroles of the formula I: ##STR1## where R.sub.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen atoms, alkyl groups having from 1 to 12 carbon atoms or cycloalkyl groups having from 3 to 12 carbon atoms, by dehydrogenation of pyrrolidines of the formula II: ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, in the presence of a supported noble metal catalyst is described. In this process, the dehydrogenation is carried out at from 150 to 300.degree. C. and pressures of from 0.01 to 50 bar and the noble metal catalyst comprises from 30 to 100% by weight of:a) palladium on an oxide of a rare earth or an oxide of an element of the 4.sup.th group (transition group IV) of the Periodic Table, orb) a platinum/palladium mixture on aluminum oxide, an oxide of a rare earth or an oxide of an element of the 4.sup.th groupand from 0 to 70% by weight of alkali metal oxide or alkaline earth metal oxide.
摘要翻译：制备式I的吡咯的方法：其中R 1，R 2，R 3和R 4相同或不同，为氢原子，具有1至12个碳原子的烷基或具有3至12个碳原子的环烷基，通过脱氢描述了在负载的贵金属催化剂的存在下，式II的吡咯烷（其中R 1，R 2，R 3和R 4如上定义）。在该方法中，脱氢在150-300℃，压力为0.01至50巴，贵金属催化剂包含30-100重量％的：a）在稀土氧化物上的钯或元素周期表第4族元素（过渡组IV）的氧化物，或b）在氧化铝上的铂/钯混合物，稀土的氧化物或第4族元素的氧化物， 0〜70重量％的碱金属氧化物或碱土金属氧化物。

2. 发明授权

US6057442A Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US6057442A
公开(公告)日：2000-05-02
申请号：US159089
申请日：1998-09-23
申请人： Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
发明人： Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
IPC分类号： C07D295/02 , B01J23/755 , B01J23/889 , C07B61/00 , C07C209/16 , C07D295/023
CPC分类号： C07D295/023 , B01J23/755 , B01J23/8892 , C07C209/16 , B01J23/8898 , Y02P20/582
摘要： Amines are prepared from primary or secondary alcohols and nitrogen compounds selected from the group of ammonia, primary and secondary amines, at from 80 to 250.degree. C. under pressures from 0.1 to 40 MPa with hydrogen in the presence of a catalyst comprising zirconium, copper and nickel, wherein the catalytically active composition comprises20-85% by weight of oxygen-containing zirconium compounds, calculated as ZrO.sub.2,1-30% by weight of oxygen-containing copper compounds, calculated as CuO,14-70% by weight of oxygen-containing nickel compounds, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,0-10% by weight of oxygen-containing aluminum and/or manganese compounds, calculated as Al.sub.2 O.sub.3 and/or MnO.sub.2,and no oxygen-containing cobalt or molybdenum compounds.
摘要翻译：在含有锆，铜和铜的催化剂存在下，在氢气压力为0.1至40MPa的压力下，从伯，仲醇和选自氨，伯胺和仲胺的氮化合物制备胺。和镍，其中催化活性组合物包含20-85重量％的以ZrO 2计算的含氧锆化合物，1-30重量％的以CuO计的含氧铜化合物，14-70重量％以NiO计算的含氧镍化合物，其中镍与铜的摩尔比大于1-10重量％，以Al 2 O 3和/或MnO 2计算的含氧铝和/或锰化合物为0-10重量％含氧钴或钼化合物。

3. 发明授权

US6013844A Preparation of catechol monoethers and catechols 失效
标题翻译：儿茶酚单醚和儿茶酚的制备
公开(公告)号：US6013844A
公开(公告)日：2000-01-11
申请号：US115803
申请日：1998-07-15
申请人： Daniel Heineke , Uwe Dingerdissen , Joachim Wulff-Doring , Michael Hesse
发明人： Daniel Heineke , Uwe Dingerdissen , Joachim Wulff-Doring , Michael Hesse
IPC分类号： B01J23/44 , C07B61/00 , C07C33/26 , C07C37/00 , C07C37/055 , C07C37/06 , C07C37/07 , C07C37/50 , C07C39/08 , C07C41/18 , C07C41/28 , C07C43/205 , C07C43/23 , C07C41/00
CPC分类号： B01J35/1014 , B01J21/066 , B01J23/44 , B01J27/045 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0036 , C07C37/50 , C07C41/26 , C07C41/28
摘要： A process for preparing catechol monoethers or catechols of the formula Ia or Ib ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen or C.sub.1 -C.sub.8 hydrocarbon radicals, and R.sup.3 is a C.sub.1 -C.sub.8 hydrocarbon radical, which comprises a 2-hydroxycyclohexanone dialkyl ketal of the formula II or a 2-alkoxycyclohexanone of the formula III ##STR2## a) being reacted in the gas phase in the presence of palladium on zirconium oxide as catalyst to obtain compounds Ia orb) carrying out stage a) in the presence of water to obtain compounds Ib.
摘要翻译：制备式Ia或Ib的邻苯二酚单醚或邻苯二酚的方法，其中R 1和R 2彼此独立地为氢或C 1 -C 8烃基，R 3为C 1 -C 8烃基，其包含2-羟基环己酮二烷基式II的缩酮或式IIIa的2-烷氧基环己酮在气相中在作为催化剂的氧化锆上的钯的存在下反应，得到化合物Ia或b）在水存在下进行阶段a）得到化合物Ib。

4. 发明授权

US5679869A Preparation of aldehydes 失效
标题翻译：醛的制备
公开(公告)号：US5679869A
公开(公告)日：1997-10-21
申请号：US567749
申请日：1995-12-05
申请人： Werner Schnurr , Rolf Fischer , Joachim Wulff-Doring , Michael Hesse
发明人： Werner Schnurr , Rolf Fischer , Joachim Wulff-Doring , Michael Hesse
IPC分类号： B01J23/10 , B01J23/06 , C07B61/00 , C07C45/41 , C07C47/02 , C07C47/105 , C07C47/14 , C07C47/19 , C07C47/198 , C07C47/228 , C07C47/28
CPC分类号： B01J23/06 , C07C45/41
摘要： A process for preparing aldehydes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl, C.sub.7 -C.sub.12 -phenylalkyl and R.sup.1 and R.sup.2 are joined together to form a 3-, 4-, 5-, 6- or 7-membered cycloaliphatic ring, R.sup.1 and R.sup.3 are each C.sub.1 -C.sub.4 -alkoxy, phenoxy, methylamino, dimethylamino or halogen, and R.sup.1 is additionally hydroxyl or amino comprises reacting a carboxylic acid or ester of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 are each as defined above, and R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.12 -alkylphenyl or C.sub.7 -C.sub.12 -phenylalkyl, with hydrogen in the gas phase at temperatures from 200.degree. to 450.degree. C. and pressures from 0.1 to 20 bar in the presence of a catalyst whose catalytically active mass comprises from 60 to 99.9% by weight of zirconium oxide and from 0.1 to 40% by weight of one or more elements of the lanthanides.
摘要翻译：制备通式I（I）的醛的方法，其中R1，R2和R3各自为氢，C1-C6烷基，C3-C8-环烷基，芳基，C7-C12-烷基苯基，C7-C12- 苯基烷基和R 1和R 2连接在一起形成3-，4-，5-，6-或7-元环脂族环，R 1和R 3各自为C 1 -C 4 - 烷氧基，苯氧基，甲基氨基，二甲基氨基或卤素，R 1 另外羟基或氨基包括使通式II（II）的羧酸或酯与其中R 1，R 2和R 3各自如上所定义，R 4是氢，C 1 -C 6烷基，C 3 -C 8 - 环烷基，芳基，C 7 -C 12 - 烷基苯基或C 7 -C 12 - 苯基烷基，在气相中的氢气在200-450℃的温度和0.1至20巴的压力下，在催化剂存在下，其催化活性质量包含 60至99.9重量％的氧化锆和0.1至40重量％的一种或多种镧系元素。

5. 发明授权

US5663438A Preparation of cyclic amines 失效
标题翻译：环胺的制备
公开(公告)号：US5663438A
公开(公告)日：1997-09-02
申请号：US516147
申请日：1995-08-17
申请人： Ulrich Kohler , Frank-Friedrich Pape , Matthias Irgang , Joachim Wulff-Doring , Michael Hesse , Peter Polanek
发明人： Ulrich Kohler , Frank-Friedrich Pape , Matthias Irgang , Joachim Wulff-Doring , Michael Hesse , Peter Polanek
IPC分类号： B01J23/40 , B01J23/42 , B01J23/58 , B01J23/63 , C07B61/00 , C07C209/16 , C07C209/68 , C07C211/45
CPC分类号： C07C209/68 , C07C209/16
摘要： A process for the preparation of a phenyl amine which may be substituted by alkyl or cycloalkyl in which the corresponding cyolohexylamine is reduced at temperatures of 150.degree. to 300.degree. C. and pressures of 0.01 to 50 bar in the presence of a heterogeneous dehydrogenation catalyst consisting essentially of palladium or a palladium/platinum mixture supported on carrier consisting of the oxides of rare earth metals and and metals of Group IVb of the Periodic Table of Elements, with the proviso that the palladium/platinum mixture may also be supported on an alumina carrier. The cyclohexylamine reactant can be advantageously prepared by reacting the corresponding phenol with ammonia and hydrogen at 100.degree. to 250.degree. C. in the presence of the same heterogeneous catalyst as a preliminary step to provide a two stage process using the same catalyst in both stages.
摘要翻译：制备苯基胺的方法，其可以被烷基或环烷基取代，其中相应的环己胺在150-300℃的温度和0.01至50巴的压力下在存在非均相脱氢催化剂的条件下还原，基本上由负载在由稀土金属的氧化物构成的载体上的钯或钯/铂混合物和元素周期表IVb族金属组成，条件是钯/铂混合物也可以负载在氧化铝载体上。环己胺反应物可以有利地通过在相同的非均相催化剂的存在下在100-250℃下使相应的苯酚与氨和氢反应来制备，以提供在两个阶段中使用相同催化剂的两阶段方法。

6. 发明申请

US20070037936A1 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US20070037936A1
公开(公告)日：2007-02-15
申请号：US10572816
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kolle , Joachim Wulff-Doring
IPC分类号： C08F2/00
CPC分类号： B01J19/1837 , B01J3/008 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , Y10S526/92 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150° C., but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体的方法，但低于待形成的聚合物的熔点，压力为5-100巴，其中所形成的聚合物存在于在液体或超临界悬浮介质中的悬浮液，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在轴向泵以外的区域中至少有一个变宽和变窄。

7. 发明授权

US5840986A Preparation with heterogeneous catalysis of N-alkyl-substituted aminoalkynes 失效
标题翻译：用N-烷基取代的氨基炔的多相催化制备
公开(公告)号：US5840986A
公开(公告)日：1998-11-24
申请号：US923557
申请日：1997-09-04
申请人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
发明人： Thomas Preiss , Jochem Henkelmann , Joachim Wulff-Doring , Susanne Stutz
IPC分类号： C07D295/04 , B01J31/26 , C07C209/60 , C07C211/08 , C07C211/23 , C07C211/25 , C07C211/26 , C07C211/43 , C07C211/54 , C07C209/26
CPC分类号： C07C209/60
摘要： A process for preparing N-alkyl-substituted aminoalkynes by reacting an alkyne with a carbonyl compound and an amine with heterogeneous catalysis in which an unsupported copper acetylide derived from malachite is used as the catalyst. The N-alkyl-substituted aminoalkyne have a wide variety of uses including their use as precursors for pharmaceuticals, their use in electroplating processes and their use as corrosion inhibitors.
摘要翻译：通过使炔与羰基化合物和胺与非均相催化反应制备N-烷基取代的氨基炔烃的方法，其中使用源自孔雀石的未负载的乙炔化铜作为催化剂。 N-烷基取代的氨基炔具有多种用途，包括它们作为药物前体的用途，它们在电镀方法中的应用及其作为腐蚀抑制剂的用途。

8. 发明授权

US5733838A Process for the production of a hydrogenation catalyst 失效
标题翻译：制备氢化催化剂的方法
公开(公告)号：US5733838A
公开(公告)日：1998-03-31
申请号：US767382
申请日：1996-12-16
申请人： Maximilian Vicari , Klemens Flick , Johann-Peter Melder , Werner Schnurr , Joachim Wulff-Doring
发明人： Maximilian Vicari , Klemens Flick , Johann-Peter Melder , Werner Schnurr , Joachim Wulff-Doring
IPC分类号： B01J25/00 , B01J25/02 , B01J37/00 , C07B31/00 , C07C253/30 , B01J23/00 , B01J23/56 , B01J23/72 , B01J31/00
CPC分类号： B01J37/0009 , B01J25/00 , B01J25/02 , B01J37/0018 , C07B31/00 , C07C253/30
摘要： A hydrogenation catalyst based on an alloy of aluminum and of a transition metal is prepared by preparing a kneaded material from the alloy and an assistant, converting the kneaded material into moldings, calcining the moldings and treating the calcined moldings with an alkali metal hydroxide, by a process in which the assistant used is (a) polyvinyl alcohol and water or (b) stearic acid, and the catalyst prepared according to the invention is used for hydrogenation and hydrogenolysis, in particular the partial hydrogenation of aliphatic alpha,omega-dinitriles to aliphatic alpha,omega-aminonitriles.
摘要翻译：通过从合金和助剂制备捏合材料制备基于铝合金和过渡金属的氢化催化剂，将捏合的材料转化成模制品，煅烧模制品并用碱金属氢氧化物处理煅烧的模制品，通过使用的助剂是（a）聚乙烯醇和水或（b）硬脂酸的方法，根据本发明制备的催化剂用于氢化和氢解，特别是将脂族α，ω-二腈部分氢化成脂肪族α，ω-氨基腈。

9. 发明申请

US20090023947A1 PROCESS FOR PREPARING TERTIARY ALKYL ESTERS OF (METH) ACRYLIC ACID HAVING AT LEAST 4 CARBON ATOMS IN THE ALKYL RADICAL 有权
标题翻译：用于制备具有至少四个碳原子的（甲基）丙烯酸的仲胺酸酯在碱性辐射中的方法
公开(公告)号：US20090023947A1
公开(公告)日：2009-01-22
申请号：US12168342
申请日：2008-07-07
申请人： Gunter Lipowsky , Joachim Wulff-Doring , Peter Zurowski , Jurgen Strasser
发明人： Gunter Lipowsky , Joachim Wulff-Doring , Peter Zurowski , Jurgen Strasser
IPC分类号： C07C69/54
CPC分类号： C07C67/54 , C07C67/04 , C07C67/62 , C07C69/54
摘要： A process for preparing tertiary alkyl esters of (meth)acrylic acid having at least 4 carbon atoms in the alkyl radical, comprising the steps of: (1) reacting (meth)acrylic acid with at least one olefin of the general formula I: in which R1 and R2 are an alkyl radical, and R3 is a hydrogen atom, an alkyl radical, a cycloalkyl radical, an aryl radical, an alkylcycloalkyl radical, an alkylaryl radical, a cycloalkylaryl radical, or an alkylcycloalkylaryl radical; in homogeneous phase in the presence of an acidic catalyst in a reactor, (2) discharging the resulting reaction mixture (1) from the reactor, (3) separating the discharged reaction mixture (2) into a mixture (3.1) which comprises the catalyst and a mixture (3.2) which comprises the tertiary alkyl ester of (meth)acrylic acid having at least 4 carbon atoms in the alkyl radical, and (4) removing the tertiary alkyl ester of (meth)acrylic acid having at least 4 carbon atoms in the alkyl radical from the mixture (3.2), wherein, (5) in process step (4), at least one compound S which comprises at least one N-oxyl group is added as a stabilizer.
摘要翻译：一种制备烷基中具有至少4个碳原子的（甲基）丙烯酸叔烷基酯的方法，包括以下步骤：（1）使（甲基）丙烯酸与至少一种通式Ⅰ的烯烃反应：其中R1和R2是烷基，R3是氢原子，烷基，环烷基，芳基，烷基环烷基，烷基芳基，环烷基芳基或烷基环烷基芳基; 在反应器中存在酸性催化剂的同时，（2）将反应混合物（1）从反应器中排出，（3）将排出的反应混合物（2）分离成包含催化剂的混合物（3.1）和包含烷基中具有至少4个碳原子的（甲基）丙烯酸叔烷基酯的混合物（3.2），和（4）除去具有至少4个碳原子的（甲基）丙烯酸的叔烷基酯在来自混合物（3.2）的烷基中，其中（5）在方法步骤（4）中，加入至少一种包含至少一个N-氧基的化合物S作为稳定剂。

10. 发明申请

US20050043170A1 Catalyst solid comprising pyrogenic silica for olefin polymerization 审中-公开
标题翻译：包含用于烯烃聚合的热解二氧化硅的催化剂固体
公开(公告)号：US20050043170A1
公开(公告)日：2005-02-24
申请号：US10497939
申请日：2002-12-17
申请人： Volker Fraaije , Markus Oberhoff , Nicola Paczkowski , Heike Gregorius , Roland Kratzer , Wolfgang Bidell , Joachim Wulff-Doring
发明人： Volker Fraaije , Markus Oberhoff , Nicola Paczkowski , Heike Gregorius , Roland Kratzer , Wolfgang Bidell , Joachim Wulff-Doring
IPC分类号： C08F4/02 , C08F4/44 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , B01J31/00
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F4/65916 , C08F4/025 , C08F2500/18 , C08F2500/24
摘要： A catalyst solid comprising: A) support particles having a mean particle diameter d50 of from 5 to 200 μm and a specific surface area of from 30 to 1 000 m2/g and obtainable by agglomeration of primary particles of a pyrogenic silica having a mean particle diameter dm of from 1 to 50 nm, and B) at least one organic transition metal compound, can be used for the polymerization or copolymerization of olefins.
摘要翻译：一种催化剂固体，其包括：A）平均粒径d50为5至200μm，比表面积为30至1000m 2 / g的载体颗粒，并且可通过将具有平均粒径dm为1〜50nm，B）至少一种有机过渡金属化合物可用于烯烃的聚合或共聚。

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