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1. 发明授权

US6013844A Preparation of catechol monoethers and catechols 失效
标题翻译：儿茶酚单醚和儿茶酚的制备
公开(公告)号：US6013844A
公开(公告)日：2000-01-11
申请号：US115803
申请日：1998-07-15
申请人： Daniel Heineke , Uwe Dingerdissen , Joachim Wulff-Doring , Michael Hesse
发明人： Daniel Heineke , Uwe Dingerdissen , Joachim Wulff-Doring , Michael Hesse
IPC分类号： B01J23/44 , C07B61/00 , C07C33/26 , C07C37/00 , C07C37/055 , C07C37/06 , C07C37/07 , C07C37/50 , C07C39/08 , C07C41/18 , C07C41/28 , C07C43/205 , C07C43/23 , C07C41/00
CPC分类号： B01J35/1014 , B01J21/066 , B01J23/44 , B01J27/045 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0036 , C07C37/50 , C07C41/26 , C07C41/28
摘要： A process for preparing catechol monoethers or catechols of the formula Ia or Ib ##STR1## where R.sup.1 and R.sup.2 are, independently of one another, hydrogen or C.sub.1 -C.sub.8 hydrocarbon radicals, and R.sup.3 is a C.sub.1 -C.sub.8 hydrocarbon radical, which comprises a 2-hydroxycyclohexanone dialkyl ketal of the formula II or a 2-alkoxycyclohexanone of the formula III ##STR2## a) being reacted in the gas phase in the presence of palladium on zirconium oxide as catalyst to obtain compounds Ia orb) carrying out stage a) in the presence of water to obtain compounds Ib.
摘要翻译：制备式Ia或Ib的邻苯二酚单醚或邻苯二酚的方法，其中R 1和R 2彼此独立地为氢或C 1 -C 8烃基，R 3为C 1 -C 8烃基，其包含2-羟基环己酮二烷基式II的缩酮或式IIIa的2-烷氧基环己酮在气相中在作为催化剂的氧化锆上的钯的存在下反应，得到化合物Ia或b）在水存在下进行阶段a）得到化合物Ib。

2. 发明授权

US6063939A Process for preparing unsaturated cyclic ethers 失效
标题翻译：不饱和环醚的制备方法
公开(公告)号：US6063939A
公开(公告)日：2000-05-16
申请号：US226144
申请日：1999-01-07
申请人： Carsten Groning , Michael Hesse , Daniel Heineke , Heinz-Josef Kneuper , Gerhard Fritz
发明人： Carsten Groning , Michael Hesse , Daniel Heineke , Heinz-Josef Kneuper , Gerhard Fritz
IPC分类号： B01J23/89 , B01J27/045 , C07D309/18 , C07D507/02 , C07D309/00 , C07D319/12
CPC分类号： B01J27/045 , B01J23/8913 , C07D309/18
摘要： Unsaturated cyclic ethers of the formula I ##STR1## whereZ is --(CHR.sup.4).sub.q -- or --(CHR.sup.4).sub.q --O--,q is 0, 1, 2 or 3 andR.sup.1,R.sup.2,R.sup.3,R.sup.4 are hydrogen or C.sub.1 -C.sub.4 -alkylare prepared by reacting diols of the formula II ##STR2## where Z, R.sup.1, R.sup.2 and R.sup.3 are as defined above, in the liquid phase at from 150 to 300.degree. C. in the presence of a cobalt-containing supported catalyst which has not been activated by reduction before use and comprises cobalt and a noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, ruthenium, osmium, rhenium or a mixture thereof applied by sol impregnation on an inert support, wherein the supported catalyst is doped with sulfur. Sulfur-doped supported catalysts comprising cobalt and noble metals are also provided.
摘要翻译： Z为 - （CHR 4）q-或 - （CHR 4）q O - ，q为0,1,2或3且R 1，R 2，R 3，R 4为氢或C 1 -C 4烷基的式I的不饱和环醚为通过使其中Z，R 1，R 2和R 3如上所定义的式II的二醇在150-300℃的液相中，在没有被还原活化的含钴担载催化剂存在下反应制备并且包括钴和选自铂，钯，铑，铱，钌，锇，铼的贵金属或其通过溶胶浸渍施加到惰性载体上的混合物，其中负载型催化剂掺杂有硫。还提供了包含钴和贵金属的硫掺杂负载型催化剂。

3. 发明授权

US06716789B1 Method for producing oxidic catalysts containing copper with oxidation number>0 失效
标题翻译：生产含氧化值> 0的铜的氧化催化剂的方法
公开(公告)号：US06716789B1
公开(公告)日：2004-04-06
申请号：US09581988
申请日：2000-06-21
申请人： Daniel Heineke , Ruprecht Meissner , Michael Hesse , Henning-Peter Gehrken
发明人： Daniel Heineke , Ruprecht Meissner , Michael Hesse , Henning-Peter Gehrken
IPC分类号： B01J2108
CPC分类号： C07C45/002 , B01J23/72 , B01J37/0203 , C07C49/403
摘要： The disclosure is directed to a process for preparing an oxidic catalyst comprising copper in an oxidation state >0, which comprises treating a solid oxidic support material with an aqueous solution comprising at least one copper salt and at least one organic water soluble polymer which binds copper ions coordinatively in a concentration of from 0.1 to 100 g/l and then calcining, to the catalyst obtainable by this process and also to a process for dehydrogenating secondary alcohols to ketones using the catalysts, especially for dehydrogenating cyclohexanol.
摘要翻译：本发明涉及制备氧化态> 0的铜的氧化催化剂的方法，该方法包括用包含至少一种铜盐和至少一种与铜结合的有机水溶性聚合物的水溶液处理固体氧化载体材料离子以0.1至100g / l的浓度配位，然后煅烧至可通过该方法获得的催化剂，并且还涉及一种使用催化剂，特别是用于使环己醇脱氢来将仲醇脱氢成酮的方法。

4. 发明授权

US5817592A Process for the preparation of a hydrogenation catalyst 失效
标题翻译：制备氢化催化剂的方法
公开(公告)号：US5817592A
公开(公告)日：1998-10-06
申请号：US590455
申请日：1996-01-23
申请人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J23/96 , B01J37/16 , B01J38/64 , C01B21/14 , B01J21/18 , B01J23/16 , B01J27/185
CPC分类号： B01J23/42 , B01J37/16 , C01B21/1418
摘要： A process for the preparation of a hydrogenation catalyst by reduction of platinum in an oxidation stage of not less than 2 in an aqueous medium in the presence of a carboniferous support, optionally following partial poisoning with a sulfur, arsenic, tellurium, or antimony-containing compound, using a reducing agent, in which the reducing agent used is an ammonium or phosphonium salt of the general formula I �XR.sup.4 !.sub.n Y I in which X stands for N or P, R stands for hydrogen, C.sub.1 --C.sub.18 alkyl, C.sub.5 --C.sub.10 cycloalkyl, phenyl radical, and also a C.sub.1 --C.sub.4 alkyl radical substituted by phenyl, the phenyl radicals being mono-to tri-substituted by C.sub.1 --C.sub.6 alkyl, halogen, nitro or amino, if desired, provided that the radicals R may be the same or different but cannot simultaneously denote hydrogen, if X is P, n is an integer of 1 to 3, and Y is an organic anion which can reduce platinum in an oxidation stage other than zero to platinum in the oxidation stage of zero.
摘要翻译：一种通过在含水载体的存在下在水性介质中在不少于2的氧化阶段还原铂的氢化催化剂的方法，任选地在用硫，砷，碲或含锑的部分中毒后化合物，使用还原剂，其中所用的还原剂是通式I [XR4] nYinin的铵盐或鏻盐，其中X代表N或P，R代表氢，C1-C18烷基，C5-C10环烷基苯基，以及被苯基取代的C1-C4烷基，如果需要，苯基由C1-C6烷基，卤素，硝基或氨基单取代至三取代，条件是基团R可以相同或不同，但不能同时表示氢，如果X为P，n为1至3的整数，Y为有机阴离子，在氧化阶段为零的情况下，铂可以在除氧以外的氧化阶段中还原为铂。

5. 发明授权

US06989346B2 Preparation of olefins, particularly of propylene, by dehydrogenation 失效
标题翻译：通过脱氢制备烯烃，特别是丙烯
公开(公告)号：US06989346B2
公开(公告)日：2006-01-24
申请号：US10340282
申请日：2003-01-13
申请人： Daniel Heineke , Michael Baier , Dirk Demuth , Klaus Harth
发明人： Daniel Heineke , Michael Baier , Dirk Demuth , Klaus Harth
IPC分类号： B01J23/00 , B01J23/40 , B01J23/42 , B01J23/58 , B01J23/60
CPC分类号： C07C5/3335 , B01J21/063 , B01J21/066 , B01J23/14 , B01J23/24 , B01J23/26 , B01J23/36 , B01J23/40 , B01J23/626 , C07C5/3332 , C07C5/3337 , C07C2521/06 , C07C2523/26 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , Y02P20/52 , C07C11/02
摘要： Olefinically unsaturated hydrocarbons are prepared from corresponding paraffinic hydrocarbons, in particular propylene is prepared from propane, by dehydrogenation over a catalyst comprising an oxide of a transition metal of group IV B of the Periodic Table, eg. TiO2 or ZrO2, and possibly at least one element selected from among elements of transition group VIII, eg. palladium, platinum or rhodium, and/or an element of transition group VI, eg. chromium, molybdenum or tungsten, and/or rhenium and/or tin and possibly a compound of an alkali metal or alkaline earth metal, a compound of main group III or transition group III or zinc.
摘要翻译：由相应的链烷烃制备烯属不饱和烃，特别是丙烯由丙烷制备，通过在包含元素周期表IVB族过渡金属的氧化物的催化剂上脱氢制备。 TiO 2或ZrO 2，以及可能的至少一种选自过渡族VIII的元素的元素，例如。钯，铂或铑，和/或过渡族VI的元素，例如。铬，钼或钨，和/或铼和/或锡以及可能的碱金属或碱土金属的化合物，主要III族或过渡族III的化合物或锌。

6. 发明授权

US06670303B1 Catalyst having a bimodal pore radius distribution 有权
标题翻译：具有双峰孔半径分布的催化剂
公开(公告)号：US06670303B1
公开(公告)日：2003-12-30
申请号：US09625485
申请日：2000-07-25
申请人： Daniel Heineke , Klaus Harth , Uwe Stabel
发明人： Daniel Heineke , Klaus Harth , Uwe Stabel
IPC分类号： B01J2302
CPC分类号： B01J21/066 , B01J23/02 , B01J23/08 , B01J23/70 , B01J35/10 , B01J35/109 , B01J37/0018 , C07C5/325 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/14 , C07C2523/42
摘要： Catalysts having a bimodal pore radius distribution comprise a) from 10 to 99.9% by weight of zirconium dioxide and b) from 0 to 60% by weight of aluminum oxide, silicon dioxide and/or titanium dioxide and c) from 0.1 to 10% by weight of at least one element of main group I or II, an element of transition group III, an element of transition group VIII, of the Periodic Table of the Elements, lanthanum and/or tin, with the proviso that the sum of the percentages by weight is 100.
摘要翻译：具有双峰孔半径分布的催化剂包括a）10至99.9重量％的二氧化锆和b）0至60重量％的氧化铝，二氧化硅和/或二氧化钛，和c）0.1至10重量％的主要组I或II的至少一个元素，过渡组III的元素，元素周期表的过渡组VIII的元素，镧和/或锡，条件是重量百分比之和为 100。

7. 发明授权

US06576804B1 Method and catalyst for producing olefins, in particular propylenes, by dehydrogenation 失效
标题翻译：通过脱氢生产烯烃，特别是丙烯的方法和催化剂
公开(公告)号：US06576804B1
公开(公告)日：2003-06-10
申请号：US09331052
申请日：1999-06-16
申请人： Daniel Heineke , Michael Baier , Dirk Demuth , Klaus Harth
发明人： Daniel Heineke , Michael Baier , Dirk Demuth , Klaus Harth
IPC分类号： C07C5333
CPC分类号： C07C5/3335 , B01J21/063 , B01J21/066 , B01J23/14 , B01J23/24 , B01J23/26 , B01J23/36 , B01J23/40 , B01J23/626 , C07C5/3332 , C07C5/3337 , C07C2521/06 , C07C2523/26 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , Y02P20/52 , C07C11/02
摘要： Olefinically unsaturated hydrocarbons are prepared from corresponding paraffinic hydrocarbons, in particular propylene is prepared from propane, by dehydrogenation over a catalyst comprising an oxide of a transition metal of group IV B of the Periodic Table, eg. TiO2 or ZrO2, and possibly at least one element selected from among elements of transition group VIII, eg. palladium, platinum or rhodium, and/or an element of transition group VI, eg. chromium, molybdenum or tungsten, and/or rhenium and/or tin and possibly a compound of an alkali metal or alkaline earth metal, a compound of main group III or transition group III or zinc.
摘要翻译：由相应的链烷烃制备烯属不饱和烃，特别是丙烯由丙烷制备，通过在包含元素周期表IVB族过渡金属的氧化物的催化剂上脱氢制备。 TiO 2或ZrO 2，以及可能的至少一种选自过渡族VIII的元素的元素，例如。钯，铂或铑，和/或过渡族VI的元素，例如。铬，钼或钨，和/或铼和/或锡以及可能的碱金属或碱土金属的化合物，主要III族或过渡族III的化合物或锌。

8. 发明授权

US06197720B1 Palladium clusters and their use as catalysts 失效
标题翻译：钯簇及其用作催化剂
公开(公告)号：US06197720B1
公开(公告)日：2001-03-06
申请号：US09197681
申请日：1998-11-23
申请人： Daniel Heineke , Ekkehard Schwab , Martin Fischer , Guenter Schmid , Monika Baeumle
发明人： Daniel Heineke , Ekkehard Schwab , Martin Fischer , Guenter Schmid , Monika Baeumle
IPC分类号： B01J2342
CPC分类号： B22F9/24 , B01J23/44 , B01J35/0013 , B22F1/0022 , B82Y30/00 , C07C5/03 , C07C5/09 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/18 , C07C2523/44 , C07C2529/035 , C07C2529/06 , C07C2531/22 , C07C2531/24 , C07C2531/28 , C07C11/107
摘要： The invention relates to colloidal palladium composed of palladium clusters with an average particle diameter 0.2 nm≦d≦2 nm with at least 80% of the palladium clusters having a particle diameter which differs by not more than 0.2 nm from the average particle diameter d, it being possible for the palladium clusters to have protective ligands on the surface. The invention further relates to a process for preparing a colloidal solution of palladium by reacting a palladium salt with a reducing agent in solution at from 0 to 300° C., employing a branched-chain alcohol as reducing agent and phosphines and/or aromatic nitrogen compounds as protective ligands. The invention further relates to palladium-containing heterogeneous catalysts comprising colloidal palladium applied to a carrier, and to a process for their preparation.
摘要翻译：本发明涉及由平均粒径为0.2nm <= d <= 2nm的钯簇构成的胶体钯，其中至少80％的钯簇的粒径与平均粒径不同不超过0.2nm d，钯簇可以在表面上具有保护配体。本发明还涉及一种通过钯盐与还原剂在0-300℃溶液中反应来制备钯的胶体溶液的方法。使用支链醇作为还原剂，以及膦和/或芳族氮化合物作为保护配体。本发明还涉及包含应用于载体的胶体钯的含钯非均相催化剂及其制备方法。

9. 发明授权

US5917023A Reductive coupling of nitrobenzene or nitrobenzenes substituted on the nucleus to give the corresponding azobenzenes and azoxybenzenes by means of redox catalysts 失效
标题翻译：在核上取代的硝基苯或硝基苯的还原偶联，通过氧化还原催化剂得到相应的偶氮苯和偶氮氧苯
公开(公告)号：US5917023A
公开(公告)日：1999-06-29
申请号：US869760
申请日：1997-06-05
申请人： Alfred Hagemeyer , Daniel Heineke , Guido Voit , Tom Witzel
发明人： Alfred Hagemeyer , Daniel Heineke , Guido Voit , Tom Witzel
IPC分类号： B01J23/18 , C07B61/00 , C07C245/08 , C07C291/08
CPC分类号： C07C245/08 , C07C291/08
摘要： Nitrobenzene or a nitrobenzene substituted on the nucleus is subjected to reductive coupling to give the corresponding azobenzene and azoxybenzene under heterogeneous catalysis with substantial avoidance of overreduction to aniline derivatives by means of a redox catalyst in its reduced or partly reduced form, the redox catalyst containing at least one active metal component capable of a change of oxidation state.
摘要翻译：在核上取代的硝基苯或硝基苯进行还原偶联，在非均相催化下得到相应的偶氮苯和偶氮氧苯，基本上避免了通过其还原或部分还原形式的氧化还原催化剂将苯胺衍生物过度还原，至少一种能够改变氧化态的活性金属组分。

10. 发明授权

US6083468A Method of manufacturing a hydrogenation catalyst 失效
标题翻译：制造氢化催化剂的方法
公开(公告)号：US6083468A
公开(公告)日：2000-07-04
申请号：US155908
申请日：1998-10-08
申请人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
发明人： Daniel Heineke , Gunther Achhammer , Heinz-Walter Schneider , Alfred Thome
IPC分类号： B01J23/42 , B01J37/20 , C01B21/14 , C01C1/00
CPC分类号： B01J23/42 , C01B21/1418
摘要： A hydrogenation catalyst is prepared by reduction of platinum in an oxidation state of not less than two using a reducing agent in an aqueous medium in the presence of a carbon-containing support after partial poisoning, where use is made of a compound of the general formula I ##STR1## where X, Y and Z can be identical or different and are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl, halogen, hydroxyl, C.sub.1 -C.sub.6 -alkoxy and --NR'R", where R, R' and R" can be identical or different and can be hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.5 -C.sub.10 -cycloalkyl. Such a hydrogenation catalyst can be used for preparing hydroxylammonium salts and the process for preparing the above catalysts can also be used for regenerating hydrogenation catalysts based on platinum.
摘要翻译： PCT No.PCT / EP97 / 01617 Sec。 371日期：1998年10月8日 102（e）日期1998年10月8日PCT 1997年4月1日PCT PCT。出版物WO97 / 37758 日期：1997年10月16日氢化催化剂是通过在部分中毒后在含碳载体存在下，在水性介质中使用还原剂还原不少于2的铂的氢化催化剂，其中使用其中X，Y和Z可以相同或不同，为氢，C 1 -C 18 - 烷基，C 5 -C 10 - 环烷基，卤素，羟基，C 1 -C 6 - 烷氧基和-NR'R“的通式I化合物，其中R，R'和R“可以相同或不同，并且可以是氢，C 1 -C 18 - 烷基或C 5 -C 10 - 环烷基。这种氢化催化剂可用于制备羟铵盐，并且制备上述催化剂的方法也可用于再生基于铂的氢化催化剂。

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