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1. 发明申请

US20080237907A1 Process for the preparation of a polymerizable dental composition 审中-公开
标题翻译：制备可聚合牙科组合物的方法
公开(公告)号：US20080237907A1
公开(公告)日：2008-10-02
申请号：US12156794
申请日：2008-06-04
申请人： Joachim E. Klee , Uwe Walz , Andreas Facher , Christoph Weber , Rolf Mulhaupt , Holger Frey , Ekkehard Muh
发明人： Joachim E. Klee , Uwe Walz , Andreas Facher , Christoph Weber , Rolf Mulhaupt , Holger Frey , Ekkehard Muh
IPC分类号： A61C13/20
CPC分类号： A61K6/083 , A61K6/093 , C08L33/00 , C08L83/10
摘要： A process for the preparation of a polymerizable dental composition comprising the steps of (a) preparing a liquid mixture comprising (i) 1 to 99% w/w of a hybrid monomer component containing at least one hybrid monomer compound having one hydrolysable siloxane group and at least one polymerizable organic moiety, and (ii) 99 to 1% w/w of a monomer component polymerizable with the polymerizable organic moiety of the hybrid monomer compounds; and (b) adding at least a stoichiometrically sufficient amount of water to the mixture to hydrolyse the hydrolysable siloxane group of the hybrid monomer compound and to form spherical polymerizable nanoparticles having an average particle size of from 1 to 100 nm dispersed in the monomer component, whereby the nanoparticles have a structure with Si—O—Si bonds and peripherally exposed polymerizable organic moieties.
摘要翻译：一种制备可聚合牙科用组合物的方法，包括以下步骤：（a）制备液体混合物，其包含（i）1至99％w / w的含有至少一种具有一个可水解硅氧烷基团的杂化单体化合物的杂化单体组分和至少一个可聚合的有机部分，和（ii）99-1％w / w的可与所述杂化单体化合物的可聚合有机部分聚合的单体组分; 和（b）向所述混合物中加入至少一种化学计量的足够量的水以水解所述杂化单体化合物的可水解硅氧烷基团并形成分散在单体组分中的平均粒度为1至100nm的球形可聚合纳米颗粒，由此纳米颗粒具有具有Si-O-Si键和外围暴露的可聚合有机部分的结构。

2. 发明授权

US06339114B1 Liquid crystalline (meth)acrylate compounds, composition and method 失效
公开(公告)号：US06339114B1
公开(公告)日：2002-01-15
申请号：US09391539
申请日：1999-09-08
申请人： Joachim E. Klee , Holger Frey , Dirk Holter , Rolf Mulhaupt
发明人： Joachim E. Klee , Holger Frey , Dirk Holter , Rolf Mulhaupt
IPC分类号： A61K6083
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0038 , A61K6/083 , A61K6/09 , C07C69/712 , C07C255/54 , C08F290/06 , C08F290/061 , C08F290/064 , C08G18/835 , C08G59/10 , C08G59/12 , C08G59/1466 , C08G59/1494 , C08G59/4292 , C08G63/52 , C08G2270/00 , C08L67/07 , C09K19/2028 , C09K19/3068 , C09K2019/0448 , C08L33/00 , C08L75/16 , C08L43/02
摘要： Liquid crystalline (meth)acrylates of the invention include at least three rigid rod-like moieties. One of these moieties is comprised between the (meth)acrylate rests and further two moieties are bonded as side chains. The liquid crystalline (meth)acrylates polymerizable using redox initiators and/or photo initiators. The (meth)acrylates of the invention polymerize quantitative and with very low volume shrinkage of less than 2.5 percent. The invention provides a polymerizable compound within the scope of the general formula: wherein R1 is a group of the general formula —A—, —A—Y1—B—, —A—Y1—B—Y2—C—, or a steroidal moiety, preferably selected of the group of cholesteryl compounds, wherein each A, B and C independently is a substituted or unsubstituted aromatic moiety having 6 to 24 carbon atoms, a substituted or unsubstituted heteroaromatic moiety having 2 to 24 carbon atoms or a substituted or unsubstituted cycloalkylene moiety having 5 to 30 carbon atoms, a substituted or unsubstituted alkylene moiety having 2 to 20 carbon atoms, each Y1 and Y2 independently is a covalent bond, OCO, N═N, CH═N, C═C, CO, O, S, SO2, O(CO)O, OCS, CH2—O, CH2—S, each L1 and L2 independently is a hydrogen, a alkylene having 1 to 20 carbon atoms or CN, R3 is a covalent bond or a substituted or unsubstituted alkylene having 1 to 20 carbon atoms, oxyalkylene having 1 to 20 carbon atoms, thioalkylene having 1 to 20 carbon atoms or a carboxyalkylene having 1 to 20 carbon atoms, R4 is hydrogen, a substituted or an unsubstituted alkyl having 1 to 20 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, or aryl rest having 6 to 20 carbon atoms, M is a mesogenic group of the general formula —A—Z, —A—Y1—B—Z, —A—Y1—B—Y2—C—Z, or a steroidal moiety, preferably selected of the group of cholesteryl compounds, wherein each A, B and C independently is a substituted or unsubstituted aromatic moiety having 6 to 24 carbon atoms, a substituted or unsubstituted heteroaromatic moiety having 2 to 24 carbon atoms or a substituted or unsubstituted cycloalkylene moiety having 5 to 30 carbon atoms, each Y1 and Y2 independently is a covalent bond, OCO, N═N, CH═N, C═C, CO, O, S, SO2, O(CO)O, OCS, CH2—O, CH2—S, each L1 and L2 independently is a hydrogen, a alkylene having 1 to 20 carbon atoms or CN, Z is a hydrogen, halogen, CN, —OR, COOR, NO2, a halogen substituted or unsubstituted alkylene or alkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted oxyalkylene or oxyalkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted thioalkylene or thioalkenyl having 1 to 20 carbon atoms, a halogen substituted or unsubstituted carboxyalkylene or alkanoylenoxy having 1 to 20 carbon atoms, X is a covalent bond, CO, NHCO, OCO and n is an integer from 1 to 10. These compounds are used in dental compositions and methods of use thereof.

3. 发明授权

US5998499A Liquid crystalline (meth)acrylate compounds, composition and method 失效
标题翻译：液晶（甲基）丙烯酸酯化合物，组成和方法
公开(公告)号：US5998499A
公开(公告)日：1999-12-07
申请号：US723443
申请日：1996-10-07
申请人： Joachim E. Klee , Holger Frey , Dirk Holter , Rolf Mulhaupt
发明人： Joachim E. Klee , Holger Frey , Dirk Holter , Rolf Mulhaupt
IPC分类号： G02F1/13 , A61K6/00 , A61K6/083 , A61K6/087 , A61K6/09 , C07C69/54 , C07C69/712 , C07C255/54 , C08F290/06 , C08G18/83 , C08G59/10 , C08G59/12 , C08G59/14 , C08G59/17 , C08G59/42 , C08G63/52 , C08L67/07 , C09K19/20 , C09K19/30 , C09K19/38
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0038 , A61K6/083 , A61K6/09 , C07C255/54 , C07C69/712 , C08F290/06 , C08F290/061 , C08F290/064 , C08G18/835 , C08G59/10 , C08G59/12 , C08G59/1466 , C08G59/1494 , C08G59/4292 , C08G63/52 , C08L67/07 , C09K19/2028 , C09K19/3068 , C08G2270/00 , C09K2019/0448
摘要： A liquid crystalline compound, a polymeric product formed by polymerization of the liquid crystalline compound, a dental composition including the liquid crystalline compound and method of using the dental composition. Polymerization of the liquid crystalline compound results in an low volume percent shrinkage and a high conversion to polymer. The composition of the invention is useful for dental adhesive, primer, cement, pit and fissure sealant and restorative.
摘要翻译：液晶化合物，通过液晶化合物的聚合形成的聚合物，包含液晶化合物的牙科用组合物和使用该牙科用组合物的方法。液晶化合物的聚合导致收缩率低，聚合物转化率高。本发明的组合物可用于牙科粘合剂，底漆，水泥，凹坑和裂缝密封剂和修复剂。

4. 发明授权

US08399523B2 Quarternization of the additive amino alkylmethacrylate copolymer E for improving permeability and solubility of pharmaceuticals 有权
标题翻译：氨基甲基丙烯酸烷基酯共聚物E的改性，用于提高药物的渗透性和溶解度
公开(公告)号：US08399523B2
公开(公告)日：2013-03-19
申请号：US12747722
申请日：2008-12-12
申请人： Peter Langguth , Stefan Grube , Holger Frey , Boris Obermeier
发明人： Peter Langguth , Stefan Grube , Holger Frey , Boris Obermeier
IPC分类号： A61K47/32 , C08F26/02
CPC分类号： A61K47/32 , C08F26/02 , C08F220/10 , C08F220/34
摘要： The present invention relates to a strategy for improving the permeability and solubility of pharmaceuticals, based on adding a chemically modified amino alkyl methacrylate copolymer E, wherein the chemical modification is the quaternization of a fraction of the existing amino alkyl groups.
摘要翻译：本发明涉及基于加入化学修饰的氨基甲基丙烯酸烷基酯共聚物E来提高药物的渗透性和溶解度的策略，其中化学修饰是一部分现有氨基烷基的季铵化。

5. 发明授权

US07875698B2 Polymeric initiators 有权
标题翻译：聚合引发剂
公开(公告)号：US07875698B2
公开(公告)日：2011-01-25
申请号：US11169249
申请日：2005-06-28
申请人： Luc Vanmaele , Johan Loccufoer , Yu Chen , Holger Frey
发明人： Luc Vanmaele , Johan Loccufoer , Yu Chen , Holger Frey
IPC分类号： C08F2/46 , C09D11/10
CPC分类号： C08F2/46
摘要： A novel polymeric initiator is disclosed comprising a dendritic polymer core with at least one initiating functional group as an end group. The dendritic polymeric core is preferably a hyperbranched polymer. The polymeric initiators are useful in radiation curable compositions such as varnishes, lacquers and printing inks and are especially useful in radiation curable inkjet inks.
摘要翻译：公开了一种新颖的聚合引发剂，其包含具有至少一个起始官能团作为端基的树枝状聚合物核。树枝状聚合物芯优选为超支化聚合物。聚合物引发剂可用于可辐射固化组合物如清漆，油漆和印刷油墨中，并且特别适用于可辐射固化的喷墨油墨。

6. 发明申请

US20060014849A1 Novel polymeric co-initiators 失效
标题翻译：新型聚合共引发剂
公开(公告)号：US20060014849A1
公开(公告)日：2006-01-19
申请号：US11169091
申请日：2005-06-28
申请人： Luc Vanmaele , Johan Loccufier , Yu Chen , Holger Frey
发明人： Luc Vanmaele , Johan Loccufier , Yu Chen , Holger Frey
IPC分类号： C08F2/46
CPC分类号： C08F2/46
摘要： A novel polymeric co-initiator is disclosed comprising a dendritic polymer core with at least one co-initiating functional group as an end group. The polymeric co-initiators are useful in radiation curable compositions such as varnishes, lacquers and printing inks and are especially useful in radiation curable inkjet inks. The dendritic polymeric core is preferably a hyperbranched polymer.
摘要翻译：公开了一种新颖的聚合共引发剂，其包含具有至少一个共起始官能团作为端基的树枝状聚合物核。聚合共引发剂可用于可辐射固化组合物如清漆，漆和印刷油墨中，并且在辐射固化喷墨油墨中特别有用。树枝状聚合物芯优选为超支化聚合物。

7. 发明授权

US07507773B2 Radiation curable compositions 有权
标题翻译：辐射固化组合物
公开(公告)号：US07507773B2
公开(公告)日：2009-03-24
申请号：US11170016
申请日：2005-06-29
申请人： Johan Loccufier , Luc Vanmaele , Roland Claes , Jaymes Van Luppen , Yu Chen , Holger Frey
发明人： Johan Loccufier , Luc Vanmaele , Roland Claes , Jaymes Van Luppen , Yu Chen , Holger Frey
IPC分类号： C08F2/46 , C08J3/28
CPC分类号： C09D11/101 , C08F2/46 , Y10S522/904 , Y10S522/909
摘要： A radiation curable composition comprising a novel photoreactive polymer is disclosed comprising a dendritic polymer core with at least one initiating functional group and at least one co-initiating functional group.Suitable radiation curable compositions are varnishes, lacquers, printing inks and radiation curable ink-jet inks. The dendritic polymeric core is preferably a hyperbranched polymer.
摘要翻译：公开了包含新型光反应性聚合物的可辐射固化组合物，其包含具有至少一个起始官能团和至少一个共起始官能团的树枝状聚合物核。合适的可辐射固化组合物是清漆，油漆，印刷油墨和可辐射固化喷墨油墨。树枝状聚合物芯优选为超支化聚合物。

8. 发明申请

US20130123530A1 Hydrophilic Polyorganosiloxanes 审中-公开
标题翻译：亲水性聚有机硅氧烷
公开(公告)号：US20130123530A1
公开(公告)日：2013-05-16
申请号：US13643568
申请日：2011-04-20
申请人： Paul Boehm , Holger Frey , Tammo J. Menke
发明人： Paul Boehm , Holger Frey , Tammo J. Menke
IPC分类号： C07F7/08
CPC分类号： C07F7/0838 , C08G77/38 , C08G77/388 , C08G77/46 , C09D183/12
摘要： The invention relates to glycerol-modified polyorganosiloxane compounds with high hydrophilicity and their use.
摘要翻译：本发明涉及具有高亲水性的甘油改性聚有机硅氧烷化合物及其用途。

9. 发明授权

US07507785B2 Polymeric co-initiators 失效
标题翻译：聚合共引发剂
公开(公告)号：US07507785B2
公开(公告)日：2009-03-24
申请号：US11169091
申请日：2005-06-28
申请人： Luc Vanmaele , Johan Loccufoer , Yu Chen , Holger Frey
发明人： Luc Vanmaele , Johan Loccufoer , Yu Chen , Holger Frey
IPC分类号： C08G59/68
CPC分类号： C08F2/46
摘要： A novel polymeric co-initiator is disclosed comprising a dendritic polymer core with at least one co-initiating functional group as an end group. The polymeric co-initiators are useful in radiation curable compositions such as varnishes, lacquers and printing inks and are especially useful in radiation curable inkjet inks. The dendritic polymeric core is preferably a hyperbranched polymer.
摘要翻译：公开了一种新颖的聚合共引发剂，其包含具有至少一个共起始官能团作为端基的树枝状聚合物核。聚合共引发剂可用于可辐射固化组合物如清漆，漆和印刷油墨中，并且在辐射固化喷墨油墨中特别有用。树枝状聚合物芯优选为超支化聚合物。

10. 发明授权

US07045938B2 Reflector lamp and method for producing such a reflector lamp 失效
标题翻译：反射灯及其制造方法
公开(公告)号：US07045938B2
公开(公告)日：2006-05-16
申请号：US10474177
申请日：2002-08-07
申请人： Holger Frey , Georg Rosenbauer , Konrad Regler , Bernhard Ruhland , Thomas Sauerer , Anton Würmser
发明人： Holger Frey , Georg Rosenbauer , Konrad Regler , Bernhard Ruhland , Thomas Sauerer , Anton Würmser
IPC分类号： H01J5/16 , H01J61/40 , H01K1/26 , H01K1/30
CPC分类号： H01K1/465 , F21V19/0005
摘要： The invention relates to a reflector lamp and to a method for producing such a reflector lamp, especially a simplified method for fixing the lamp (2) in the reflector (1). The gasket (22) of the lamp base (21) is disposed in the cavity (13) of the reflector neck (12) in such a manner that the at least one power lead (71, 72) projects from the reflector neck (12) through a passage and the lamp base (21) is supported on the inner wall (13) of the reflector (1) perpendicular to the longitudinal axis (A). A fastening element (81, 82) is fastened on the power lead (71, 72) at an angle to the longitudinal axis (A) and rests against the outer wall of the reflector neck (12). The lamp (2) is thus fixated in the reflector (1) in the longitudinal direction (A) without play and without any additional spring elements.
摘要翻译：本发明涉及一种反射灯及其制造方法，特别是用于将灯（2）固定在反射器（1）中的简化方法。灯座（21）的垫圈（22）以这样的方式设置在反射器颈部（12）的空腔（13）中，使得至少一个电源引线（71,72）从反射器颈部（12）突出）并且灯座（21）被支撑在垂直于纵向轴线（A）的反射器（1）的内壁（13）上。紧固元件（81,82）以与纵向轴线（A）成一定角度紧固在动力引线（71,72）上并靠在反射器颈部（12）的外壁上。因此，灯（2）在纵向（A）上不经过播放而没有任何额外的弹簧元件固定在反射器（1）中。

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