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    • 1. 发明授权
    • Silicon nitride composite sintered body and process for producing the
same
    • 氮化硅复合烧结体及其制造方法
    • US5384292A
    • 1995-01-24
    • US220457
    • 1994-03-31
    • Jin-Joo MatsuiOsamu KomuraAkira YamakawaMasaya Miyake
    • Jin-Joo MatsuiOsamu KomuraAkira YamakawaMasaya Miyake
    • C04B35/584C04B35/58
    • C04B35/584
    • A silicon nitride composite sintered which comprises crystal grains of silicon nitride and/or sialon having an average minor axis length of 0.05 to 3 .mu.m and an aspect ratio of 10 or less and foreign particles dispersed in the crystal grains and/or the grain boundary phase, said particles having a thermal expansion coefficient of 5.times.10.sup.-6 /.degree.C. or more and an average particle size of 1 to 500 nm. The sintered body is produced by wet mixing silicon nitride powder, at least two sintering aids selected from among Y.sub.2 O.sub.3, Al.sub.2 O.sub.3, AlN and MgO and at least one compound selected from among the oxides, nitrides, carbides and silicides of the elements, excluding Si and C, of the groups IIa, IIIa, IVa, Va, VIa, IIb, IIIb and IVb of the Periodic Table to form a molding; and heat treating under the specified conditions. The sintered body can also be obtained by coating the surfaces of silicon nitride crystal grains with an organometallic compound convertible to the above foreign particles, heat treating and sintering with the sintering aid.
    • 一种氮化硅复合材料,其包含平均短轴长度为0.05〜3μm,长径比为10以下的氮化硅和/或赛隆的晶粒和分散在晶粒和/或晶界中的异物的氮化硅复合体 所述颗粒的热膨胀系数为5×10 -6 /℃以上,平均粒径为1〜500nm。 烧结体通过湿式混合氮化硅粉末,至少两种选自Y 2 O 3,Al 2 O 3,AlN和MgO的烧结助剂和选自元素的氧化物,氮化物,碳化物和硅化物中的至少一种化合物,除Si和 C,元素周期表IIa,IIIa,IVa,Va,VIa,IIb,IIIb和IVb族中的一种,形成一个成型体; 并在规定条件下进行热处理。 烧结体也可以通过用可转化为上述外来颗粒的有机金属化合物涂覆氮化硅晶粒表面,用烧结助剂进行热处理和烧结来获得。
    • 4. 发明授权
    • Composite bearing structure
    • 复合轴承结构
    • US5675201A
    • 1997-10-07
    • US295623
    • 1994-08-24
    • Osamu KomuraTetsuya KatayamaAkira YamakawaKenji MatsunumaNorio YasuokaMatsuo HiguchiMasaya Miyake
    • Osamu KomuraTetsuya KatayamaAkira YamakawaKenji MatsunumaNorio YasuokaMatsuo HiguchiMasaya Miyake
    • F16C17/02F16C32/00F16C32/04F16C33/10F16C33/24F16C39/06H02K7/08H02K7/09
    • F16C32/0427F16C17/107F16C32/0431F16C33/107F16C39/063
    • A composite bearing structure that has a high rotational accuracy and that can withstand high-speed rotation comprises first bearing means, second bearing means, third bearing means and fourth bearing means. The first bearing means supports a radial impact force which is applied to a rotator during rotation, and is formed by an inner ring (1) and an outer ring (2) consisting of silicon nitride ceramics sintered bodies. The second bearing means supports an axial load which is applied to the rotator while maintaining a prescribed clearance with the rotator, and is formed by a magnetic bearing body of two permanent magnets (12) and (13) which are thrust-directionally opposed to each other. The third bearing means maintains the radial rotational accuracy of the rotator, and is formed by a radial dynamic pressure producing groove (5) which is formed in a cylindrical surface of the inner ring (1). The fourth bearing means maintains the thrust-directional rotational accuracy of the rotator, and is formed by an air dome portion (100) which is confined in a semi-closed state by the inner ring (1), the outer ring (2) and a cover (4).
    • PCT No.PCT / JP94 / 00002 Sec。 371日期:1994年8月24日 102(e)日期1994年8月24日PCT 1994年1月4日PCT PCT。 公开号WO94 / 16233 PCT 日期1994年7月21日具有高旋转精度并能承受高速旋转的复合轴承结构包括第一轴承装置,第二轴承装置,第三轴承装置和第四轴承装置。 第一轴承装置支撑在旋转期间施加到旋转器的径向冲击力,并且由内环(1)和由氮化硅陶瓷烧结体组成的外圈(2)形成。 第二轴承装置支撑轴向载荷,该轴向载荷与旋转体保持规定的间隙,并且由两个永磁体(12)和(13)的磁轴承体形成,该永磁体与每个 其他。 第三轴承装置维持旋转体的径向旋转精度,并且由形成在内圈(1)的圆柱形表面中的径向动压产生槽(5)形成。 第四轴承装置保持旋转体的推力定向旋转精度,并且由内圈(1),外圈(2)和外圈(1)限定在半闭合状态的空气圆顶部(100)形成, 盖(4)。
    • 6. 发明授权
    • Silicon nitride composite sintered body and process for producing same
    • 氮化硅复合烧结体及其制造方法
    • US5352641A
    • 1994-10-04
    • US956887
    • 1992-12-14
    • Jin-Joo MatsuiAkira Yamakawa
    • Jin-Joo MatsuiAkira Yamakawa
    • C04B35/584C04B35/58
    • C04B35/584
    • A composite silicon nitride sintered body formed of silicon nitride as a matrix and silicon carbide having particle sizes of 5 to 500 nm as a phase dispersed in the sintered body, wherein the total amount of dispersed silicon carbide is 1 to 40% by volume based on the sintered body, the proportion by volume of the silicon carbide dispersed in the silicon nitride particles is 5 to 99% based on the total amount dispersed, the remainder being present only in the grain boundary of the silicon nitride, and a process for producing a silicon nitride composite sintered body which includes the steps of adding a sintering aid to amorphous composite powders as starting materials consisting of silicon, nitrogen and carbon to form a green compact; firing the green compact in a nitrogen atmosphere at 1350.degree. to 1650.degree. C. as the primary sintering; firing the same at 1600.degree. to 1900.degree. C. as the secondary sintering; and firing the same at 1800.degree. to 2200.degree. C. to transfer the silicon carbide precipitated in the particles of silicon nitride to the grain boundaries thereof.
    • PCT No.PCT / JP92 / 01032 Sec。 371日期:1992年12月14日 102(e)日期1992年12月14日PCT提交1992年8月12日PCT公布。 出版物WO93 / 0401200 日期:1993年3月4日。作为基体的氮化硅形成的复合氮化硅烧结体和粒径为5〜500nm的碳化硅作为分散在烧结体中的相,其中分散碳化硅的总量为1 至基于烧结体的40体积%,分散在氮化硅颗粒中的碳化硅的体积比例相对于分散的总量为5〜99%,余量仅存在于氮化硅的晶界 以及制造氮化硅复合烧结体的方法,包括以下步骤:将无定形复合粉末作为起始材料添加到由硅,氮和碳组成的烧结助剂以形成生坯; 在1350〜1650℃的氮气氛中烧成生坯,作为一次烧结; 在1600℃〜1900℃下烧成二次烧结; 并在1800〜2200℃下烧成,将在氮化硅粒子中析出的碳化硅转移至其晶界。
    • 7. 发明授权
    • Silicon nitride sintered body and process for producing the same
    • 氮化硅烧结体及其制造方法
    • US5369065A
    • 1994-11-29
    • US118023
    • 1993-09-08
    • Masashi YoshimuraJin-Joo MatsuiTakehisa YamamotoAkira Yamakawa
    • Masashi YoshimuraJin-Joo MatsuiTakehisa YamamotoAkira Yamakawa
    • C04B35/584C04B35/593C04B35/58
    • C04B35/5935
    • A silicon sintered body comprising a matrix phase consisting of silicon nitride and a grain boundary phase in which the silicon nitride consists of 66 to 99% by volume of .beta.-Si.sub.3 N.sub.4 and/or .beta.'-sialon with the balance being .alpha.-Si.sub.3 N.sub.4 and/or .alpha.'-sialon, the .beta.-Si.sub.3 N.sub.4 and/or .beta.'-sialon consisting of hexagonal rod-like grains having a diameter of 500 nm or less in the minor axis and an aspect ratio 5 to 25, the .alpha.-Si.sub.3 N.sub.4 and/or .alpha.'-sialon consisting of equi-axed grains having an average diameter of 300 nm or less, and titanium compounds are contained within the grains of the matrix phase and in the grain boundary phase. The sintered body is produced by mixing (1) 100 parts by weight of .alpha.-Si.sub.3 N.sub.4 powder, (2) 0.1 to 10 parts by weight of titanium oxide having an average particle size of 100 nm or less and (3) 2 to 15 parts by weight, in total, of specified sintering aids; molding the resultant powder mixture into a green compact; subjecting the green compact to primary sintering and secondary sintering under the prescribed conditions.
    • 一种硅烧结体,包括由氮化硅和晶界相组成的基质相,其中氮化硅由66-99体积%的β-Si 3 N 4和/或β' - 赛隆组成,余量为α-Si 3 N 4和/ 或α' - 塞隆,β-Si 3 N 4和/或β'-Sialon由短轴具有500nm或更小直径的六角棒状晶粒和5至25的长宽比组成,α-Si 3 N 4和/ 或由平均直径为300nm以下的等轴晶粒组成的α'-Sialon,并且钛化合物包含在基质相的晶粒内和晶界相中。 烧结体通过混合(1)100重量份的α-Si 3 N 4粉末,(2)0.1〜10重量份的平均粒径为100nm以下的氧化钛和(3)2〜15重量份 总共为指定的烧结助剂; 将所得粉末混合物成型为生坯; 在规定的条件下对生坯进行一次烧结和二次烧结。
    • 9. 发明授权
    • Silicon nitride sintered body
    • 氮化硅烧结体
    • US5424256A
    • 1995-06-13
    • US138346
    • 1993-10-18
    • Masashi YoshimuraTakehisa YamamotoShinichi YamagataJin-Joo MatsuiAkira Yamakawa
    • Masashi YoshimuraTakehisa YamamotoShinichi YamagataJin-Joo MatsuiAkira Yamakawa
    • C04B35/593C04B35/599
    • C04B35/5935
    • Silicon nitride sintered bodies consisting of prismatic crystal grains of Si.sub.3 N.sub.4 and/or sialon, equi-axed crystal grains of Si.sub.3 N.sub.4 and/or sialon, a grain boundary phase existing among the prismatic and equi-axed crystal grains and dispersed particles in the grain boundary phase, in which the prismatic crystal grains have an average grain size of 0.3 .mu.m or less in minor axis and an average grain size of 5 .mu.m or less in major axis, the equi-axed crystal grains have an average grain size of 0.5 .mu.m or less and the dispersed particles have an average size of 0.1 .mu.m or less, the volume of the dispersed particles being 0.05% by volume or more based on the total volume of the rest of the sintered body. The silicon nitride sintered bodies have a strength sufficient for use as structural materials of machine parts or members, with a minimized scattering of the strength as well as high reliability, superior productivity and advantageous production cost.
    • 由Si 3 N 4和/或赛隆的棱柱状晶粒构成的氮化硅烧结体,Si 3 N 4等离子晶粒和/或赛隆,棱晶相和等轴晶粒中存在的晶界相和晶界相中的分散粒子 其中棱柱晶粒的短轴平均粒径为0.3μm以下,长轴的平均粒径为5μm以下,等轴晶粒的平均粒径为0.5μm m以下,分散粒子的平均粒径为0.1μm以下,相对于烧结体的其余部分的总体积,分散粒子的体积为0.05体积%以上。 氮化硅烧结体具有足以用作机械部件或部件的结构材料的强度,其强度的极小散射以及高可靠性,优异的生产率和有利的生产成本。