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    • 3. 发明授权
    • Copolymers formed from polymerization of
N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine and their utility
as calcium carbonate scale inhibitors
    • 由N,N-二烯丙基-N-烷基-N-(磺基烷基)铵甜菜碱的聚合形成的共聚物及其作为碳酸钙垢抑制剂的用途
    • US5788866A
    • 1998-08-04
    • US715778
    • 1996-09-19
    • Dodd W. FongCharles F. MarthRonald V. Davis
    • Dodd W. FongCharles F. MarthRonald V. Davis
    • C02F5/12C08F220/04C08F226/04C08G73/06C23F14/02C02F1/00
    • C08G73/0611C02F5/12
    • The invention is a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of an N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine of the formula: ##STR1## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups, and an anionic monomer. The invention is also a method of inhibiting the precipitation and deposition of scale on metal surfaces in contact with industrial cooling waters comprising the addition of an effective, scale-inhibiting amount of a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of a betaine of the formula: ##STR2## wherein R is selected from the group consisting of alkyl and aryl groups, and R.sub.1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups, and an anionic monomer. A preferred polymer is a water-soluble copolymer of N,N-diallyl-N-methyl-N-(2-sulfoethyl) ammonium betaine and acrylic acid.
    • 本发明是一种水溶性N,N-二烯丙基-N-烷基-N-(磺基烷基)铵甜菜碱共聚物,其中所述共聚物是由N,N-二烯丙基-N-烷基-N-( 磺基烷基)铵甜菜碱,其结构式如下:其中R选自烷基和芳基,R 1选自烷基,芳基和烷基芳基,和阴离子单体。 本发明还是一种抑制与工业冷却水接触的金属表面沉淀和沉积的方法,包括加入有效的阻垢量的水溶性N,N-二烯丙基-N-烷基-N - (磺基烷基)铵甜菜碱的共聚物,其中所述共聚物由下式的甜菜碱的聚合形成:其中R选自烷基和芳基,R 1选自由以下组成的组: 烷基,芳基和烷芳基,以及阴离子单体。 优选的聚合物是N,N-二烯丙基-N-甲基-N-(2-磺乙基)铵甜菜碱和丙烯酸的水溶性共聚物。
    • 4. 发明授权
    • Method of preparing a synthetic fuel from coal
    • 从煤制备合成燃料的方法
    • US06641624B1
    • 2003-11-04
    • US10042747
    • 2002-09-11
    • Donald E. GovoniRonald V. Davis
    • Donald E. GovoniRonald V. Davis
    • C10L500
    • C10L5/14
    • A method of preparing a synthetic fuel from coal comprising reacting the coal with a polymer composition comprising an aqueous solution or an aqueous emulsion of one or more reactive polymers, the reactive polymers selected from the group consisting of ethylene/vinyl acetate copolymers, ethylene/vinyl alcohol copolymers, poly(acrylic acid), poly(vinyl alcohol), vinyl alcohol/vinyl acetate copolymers, poly(vinyl acetate), vinyl acetate/acrylic acid copolymers, poly(vinyl acetate/acrylic acid/ethylene), acrylic acid/acrylamide copolymers and poly(acrylamide).
    • 一种从煤制备合成燃料的方法,包括使煤与包含一种或多种反应性聚合物的水溶液或水乳液的聚合物组合物反应,所述反应性聚合物选自乙烯/乙酸乙烯酯共聚物,乙烯/乙烯基 醇类共聚物,聚(丙烯酸),聚(乙烯醇),乙烯醇/乙酸乙烯酯共聚物,聚乙酸乙烯酯,乙酸乙烯酯/丙烯酸共聚物,聚(乙酸乙烯酯/丙烯酸/乙烯),丙烯酸/丙烯酰胺 共聚物和聚(丙烯酰胺)。
    • 6. 发明授权
    • Method of preparing a synthetic fuel from coal
    • 从煤制备合成燃料的方法
    • US06964691B1
    • 2005-11-15
    • US10667619
    • 2003-09-22
    • Donald E. GovoniRonald V. Davis
    • Donald E. GovoniRonald V. Davis
    • C10L5/00C10L5/14
    • C10L5/14
    • A method of preparing a synthetic fuel from coal comprising applying to the coal an aqueous emulsion of one or more reactive polymers and thoroughly mixing the coal to yield a complete reaction of the coal with the reactive polymers, wherein the reactive polymers are selected from the group consisting of ethylene/vinyl acetate copolymers, ethylene/vinyl alcohol copolymers, poly(acrylic acid), poly(vinyl alcohol), vinyl alcohol/vinyl acetate copolymers, poly(vinyl acetate), vinyl acetate/acrylic acid copolymers, poly(vinyl acetate/acrylic acid/ethylene), acrylic acid/acrylamide copolymers and poly(acrylamide).
    • 一种从煤制备合成燃料的方法,包括向煤施加一种或多种反应性聚合物的水性乳液,并充分混合煤以产生煤与反应性聚合物的完全反应,其中反应性聚合物选自 由乙烯/乙酸乙烯酯共聚物,乙烯/乙烯醇共聚物,聚(丙烯酸),聚(乙烯醇),乙烯醇/乙酸乙烯酯共聚物,聚(乙酸乙烯酯),乙酸乙烯酯/丙烯酸共聚物,聚(乙酸乙烯酯 /丙烯酸/乙烯),丙烯酸/丙烯酰胺共聚物和聚(丙烯酰胺)。
    • 7. 发明授权
    • Autocycle control of cooling water systems
    • 自动循环控制冷却水系统
    • US06280635B1
    • 2001-08-28
    • US09562603
    • 2000-05-01
    • Barbara E. MoriartyDennis P. BakalikRonald V. DavisJohn E. HootsRobert W. Shiely
    • Barbara E. MoriartyDennis P. BakalikRonald V. DavisJohn E. HootsRobert W. Shiely
    • C02F100
    • G01N17/008C02F1/008C02F5/08C02F2103/023C02F2209/40C02F2303/08C02F2303/20G01N33/18G01N33/1853G01N33/1866Y10T137/0329
    • An autocycle method to control a cooling water system comprising the steps of: a) adding a treatment product to said cooling water system, with said treatment product comprising inert tracer and tagged treatment polymer in a set proportion; b) providing a sufficient number of fluorometers, c) using said sufficient number of fluorometers to measure the fluorescent signal of said inert tracer and the fluorescent signal of said tagged treatment polymer in the water from the cooling water system; d) using these measured fluorescent signals from step c) to determine the amount of said tagged treatment polymer present in said cooling water system; e) comparing the amount of said tagged treatment polymer present to the amount of tagged treatment polymer being fed into the system to determine the consumption of said tagged treatment polymer; and f) using said consumption of said tagged treatment polymer to control the concentration cycles of said cooling water system, with the proviso that said control is implemented by linking any or all of the following parameters i) the flowrate of the make-up water to the cooling water system; ii) the flowrate of the treatment product comprising inert tracer and tagged treatment polymer, iii) frequency and amount of blowdown flowrate from the cooling water system; iv) overall water flowrate through the cooling tower; v) overall volume of water in the cooling tower; and vi) composition of makeup water; to the consumption of said tagged treatment polymer, with the provisos that: &agr;) the minimum flowrate of treatment product comprising inert tracer and tagged treatment polymer must be sufficient to supply the cooling water system with the requisite amount of tagged treatment product; and &bgr;) when control is implemented by linking flowrates, the flowrates are balanced.
    • 一种用于控制冷却水系统的自动循环方法,包括以下步骤:a)向所述冷却水系统中加入处理产物,所述处理产物包含惰性示踪剂和标记处理聚合物,其设定比例; b)提供足够数量的荧光计 c)使用所述足够数量的荧光计测量来自冷却水系统的所述惰性示踪剂的荧光信号和所述标记的处理聚合物的荧光信号; d)使用来自步骤c)的这些测量的荧光信号来确定 存在于所述冷却水体系中的所述标记的处理聚合物的量; e)将所述标记的处理聚合物的存在量与进料到系统中的标记处理聚合物的量进行比较,以确定所述标记的处理聚合物的消耗; 以及f)使用所述标记的处理聚合物的所述消耗来控制所述冷却水系统的浓缩循环,条件是通过将补充水的流量与冷却水的任何或全部连接来实现所述控制 水系统; ii)包含惰性示踪剂和标记处理聚合物的处理产品的流量,iii)来自冷却水系统的排放流量的频率和量; iv)通过冷却塔的总体水流量; v)总体积的水 冷却塔; 和)维生素水的组成;对所述标记的处理聚合物的消耗,条件是:α)包含惰性示踪剂和带标签的处理聚合物的处理产物的最小流速必须足以向冷却水系统提供必需量的 标记治疗产品; andbeta)当通过连接流量来实现控制时,流量平衡。
    • 8. 发明申请
    • CHEMICAL ADDITIVES TO INHIBIT THE AIR OXIDATION AND SPONTANEOUS COMBUSTION OF COAL
    • 化学添加剂抑制空气氧化和煤炭的自发燃烧
    • US20120247006A1
    • 2012-10-04
    • US13438917
    • 2012-04-04
    • Ronald V. DavisStephen J. Blubaugh
    • Ronald V. DavisStephen J. Blubaugh
    • C10L5/00
    • C10L9/10
    • The invention is directed towards methods and compositions for treating piles of low-rank coal to inhibit its spontaneous combustion. The method involves applying to the low-rank coal a composition containing VAE and crude glycerin. The composition prevents water from evaporating out of the low-rank coal. This prevents the formation within the low-rank coal of hollow openings which are a huge factor in causing its spontaneous combustion. The composition has better performance than its ingredients do alone. In fact it is so effective that certain cumbersome low-rank coal-handling methods, such as FIFO recordkeeping and inventorying, not using pinch points, or only using elbow-free equipment can be disregarded when the composition is used.
    • 本发明涉及用于处理低级煤堆以抑制其自燃的方法和组合物。 该方法涉及向低等级煤应用含有VAE和粗甘油的组合物。 该组合物防止水从低等级煤中蒸发掉。 这防止了中空开口的低等级煤中的形成,这是引起其自燃的重要因素。 该组合物的成分比单独使用的成分具有更好的性能。 事实上,使用组合物时,某些繁琐的低等级煤处理方法(如FIFO记录保存和库存)不使用夹点或仅使用无弯管设备是非常有效的。
    • 9. 发明授权
    • Sulfobetaine-containing polymers and their utility as calcium carbonate scale inhibitors
    • 含有磺基甜菜碱的聚合物及其作为碳酸钙垢抑制剂的用途
    • US06225430B1
    • 2001-05-01
    • US09078463
    • 1998-05-14
    • Dodd W. FongCharles F. MarthRonald V. Davis
    • Dodd W. FongCharles F. MarthRonald V. Davis
    • C08F12204
    • C08G73/0611C02F5/12
    • The invention is a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of an N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine of the formula:  wherein R is selected from the group consisting of alkyl and aryl groups, and R1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups,  and an anionic monomer, and  the invention is also a method of inhibiting the precipitation and deposition of scale on metal surfaces in contact with industrial cooling waters comprising the addition of an effective, scale-inhibiting amount of a water-soluble N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine containing copolymer, wherein said copolymer is formed from the polymerization of a betaine of the formula:  wherein R is selected from the group consisting of alkyl and aryl groups, and R1 is selected from the group consisting of alkyl groups, aryl groups, and alkylaryl groups,  and an anionic monomer.
    • 本发明是一种水溶性N,N-二烯丙基-N-烷基-N-(磺基烷基)铵甜菜碱共聚物,其中所述共聚物是由N,N-二烯丙基-N-烷基-N-( 磺基烷基)铵甜菜碱,其中R选自烷基和芳基,R 1选自烷基,芳基和烷基芳基,和阴离子单体,本发明是 还有一种抑制与工业冷却水接触的金属表面沉淀和沉积的方法,包括加入有效的阻垢量的水溶性N,N-二烯丙基-N-烷基-N-(磺基烷基 )含铵甜菜碱的共聚物,其中所述共聚物由下式的甜菜碱的聚合形成:其中R选自烷基和芳基,R 1选自烷基,芳基, 和烷基芳基,a 和阴离子单体。