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1. 发明申请

US20080249261A1 Method of preparing polymethylene-polyphenyl-polyamine 有权
标题翻译：聚亚甲基 - 多苯基多胺的制备方法
公开(公告)号：US20080249261A1
公开(公告)日：2008-10-09
申请号：US11873056
申请日：2007-10-16
申请人： Jiansheng Ding , Jianfeng Chen , Hongke Zhang , Haikui Zou , Weiqi Hua , Pengyuan Zhang , Shuchang Sun , Guangwen Chu , Limin Xu
发明人： Jiansheng Ding , Jianfeng Chen , Hongke Zhang , Haikui Zou , Weiqi Hua , Pengyuan Zhang , Shuchang Sun , Guangwen Chu , Limin Xu
IPC分类号： C08F2/01
CPC分类号： C08G73/0266 , C08L79/02
摘要： The present invention provides a method of preparing polymethylene-polyphenyl-polyamine (briefly referred to as polyamine, DAM), in which a high gravity rotating bed is used as the mixing reactor of formaldehyde and aniline hydrochloride, the mixing solution of aniline hydrochloride and circulation solution and the formaldehyde are fed into the high gravity rotating bed reactor proportionally to carry out mixing and condensation reaction under a condition of a very high gravity; the materials leaving the high gravity rotating bed reactor is introduced into a stirred vessel to proceed with the pre-condensation reaction and obtain a condensation solution; and the process steps of heating, molecular rearrangement, neutralization, water washing and purification, etc. are completed to obtain the refined DAM. With the method according to the present invention, the main by-products is obviously reduced in the condensation process, the phenomenon of deposit attaching to the inner walls of circulation pipes and heat exchanger and blockage are prevented in the condensation process, the impurity content is low in the refined DAM, and the subsequent product MDI has a lighter color, the product quality is stable and may be improved to a certain extent.
摘要翻译：本发明提供了使用高重力旋转床作为甲醛和苯胺盐酸盐的混合反应器的多亚甲基 - 多苯基多胺（简称为多胺，DAM）的制备方法，盐酸苯胺和循环的混合溶液溶液和甲醛按比例进料到高重力旋转床反应器中，以在非常高的重力条件下进行混合和缩合反应; 将离开高重力旋转床反应器的材料引入搅拌容器中以进行预缩合反应并获得缩合溶液; 完成加热，分子重排，中和，水洗净化等工艺步骤，得到精制DAM。根据本发明的方法，冷凝过程中主要副产物明显减少，在冷凝过程中防止了附着在循环管内壁和热交换器上的沉积现象，堵塞现象，杂质含量为精炼DAM低，后续产品MDI颜色较浅，产品质量稳定，可在一定程度上提高。

2. 发明授权

US07893301B2 Method of preparing polymethylene-polyphenyl-polyamine 有权
标题翻译：聚亚甲基 - 多苯基多胺的制备方法
公开(公告)号：US07893301B2
公开(公告)日：2011-02-22
申请号：US11873056
申请日：2007-10-16
申请人： Jiansheng Ding , Jianfeng Chen , Hongke Zhang , Haikui Zou , Weiqi Hua , Pengyuan Zhang , Shuchang Sun , Guangwen Chu , Limin Xu
发明人： Jiansheng Ding , Jianfeng Chen , Hongke Zhang , Haikui Zou , Weiqi Hua , Pengyuan Zhang , Shuchang Sun , Guangwen Chu , Limin Xu
IPC分类号： C07C211/00
CPC分类号： C08G73/0266 , C08L79/02
摘要： The present invention provides a method of preparing polymethylene-polyphenyl-polyamine (briefly referred to as polyamine, DAM), in which a high gravity rotating bed is used as the mixing reactor of formaldehyde and aniline hydrochloride, the mixing solution of aniline hydrochloride and circulation solution and the formaldehyde are fed into the high gravity rotating bed reactor proportionally to carry out mixing and condensation reaction under a condition of a very high gravity; the materials leaving the high gravity rotating bed reactor is introduced into a stirred vessel to proceed with the pre-condensation reaction and obtain a condensation solution; and the process steps of heating, molecular rearrangement, neutralization, water washing and purification, etc. are completed to obtain the refined DAM. With the method according to the present invention, the main by-products is obviously reduced in the condensation process, the phenomenon of deposit attaching to the inner walls of circulation pipes and heat exchanger and blockage are prevented in the condensation process, the impurity content is low in the refined DAM, and the subsequent product MDI has a lighter color, the product quality is stable and may be improved to a certain extent.
摘要翻译：本发明提供了使用高重力旋转床作为甲醛和苯胺盐酸盐的混合反应器的多亚甲基 - 多苯基多胺（简称为多胺，DAM）的制备方法，盐酸苯胺和循环的混合溶液溶液和甲醛按比例进料到高重力旋转床反应器中，以在非常高的重力条件下进行混合和缩合反应; 将离开高重力旋转床反应器的材料引入搅拌容器中以进行预缩合反应并获得缩合溶液; 完成加热，分子重排，中和，水洗净化等工艺步骤，得到精制DAM。根据本发明的方法，冷凝过程中主要副产物明显减少，在冷凝过程中防止了附着在循环管内壁和热交换器上的沉积现象，堵塞现象，杂质含量为精炼DAM低，后续产品MDI颜色较浅，产品质量稳定，可在一定程度上提高。

3. 发明授权

US09802848B2 Method for treating waste saline water produced in production process of diphenylmethane diisocyanate (MDI) 有权
公开(公告)号：US09802848B2
公开(公告)日：2017-10-31
申请号：US13496872
申请日：2009-09-17
申请人： Hongke Zhang , Weiqi Hua , Xiaogao Liu , Zhenhua Zhao , Shuchang Sun , Jiansheng Ding , Jianfeng Chen , Pengyuan Zhang , Haikui Zou , Guangwen Chu , Limin Xu
发明人： Hongke Zhang , Weiqi Hua , Xiaogao Liu , Zhenhua Zhao , Shuchang Sun , Jiansheng Ding , Jianfeng Chen , Pengyuan Zhang , Haikui Zou , Guangwen Chu , Limin Xu
IPC分类号： C02F1/26 , C02F9/00 , C01D3/16 , C01D3/18 , C02F1/20 , C02F1/28 , C02F1/38 , C02F1/72 , C02F1/74 , C02F103/36
CPC分类号： C02F9/00 , C01D3/16 , C01D3/18 , C02F1/20 , C02F1/265 , C02F1/283 , C02F1/38 , C02F1/72 , C02F1/74 , C02F2103/36
摘要： The invention relates to a method of circular use of waste brine produced in the manufacture process of MDI, comprising the following steps: (1) the waste brine produced in the manufacture process of MDI is subjected to a high-gravity extraction and then to a column extraction, wherein said waste brine contains aniline, diaminodiphenylmethane and polyamine; (2) the waste brine from step (1) is transmitted to a stripping tower for steam stripping; (3) the waste brine from the stripping tower of step (2) and a chemical oxidant are transmitted to an oxidation reactor to which air is blown for aeration; (4) the waste brine after the treatment of step (3) is transmitted to an absorption tower for absorption. The invention makes the salt water have TOC of less than 8 ppm and TN of less than 2.5 ppm and achieves regeneration of resources in the waste brine such as sodium chloride and water and the like for circular use.

4. 发明申请

US20120168375A1 METHOD FOR TREATING WASTE SALINE WATER PRODUCED IN PRODUCTION PROCESS OF DIPHENYLMETHANE DIISOCYANATE (MDI) 有权
标题翻译：二氯甲烷二异氰酸酯（MDI）生产过程中生产的废水的处理方法
公开(公告)号：US20120168375A1
公开(公告)日：2012-07-05
申请号：US13496872
申请日：2009-09-17
申请人： Hongke Zhang , Weiqi Hua , Xiaogao Liu , Zhenhua Zhao , Shuchang Sun , Jiansheng Ding , Jianfeng Chen , Pengyuan Zhang , Haikui Zou , Guangwen Chu , Limin Xu
发明人： Hongke Zhang , Weiqi Hua , Xiaogao Liu , Zhenhua Zhao , Shuchang Sun , Jiansheng Ding , Jianfeng Chen , Pengyuan Zhang , Haikui Zou , Guangwen Chu , Limin Xu
IPC分类号： C02F9/08 , C02F1/76 , C02F1/72 , C02F1/78 , C02F1/26 , C02F1/28
CPC分类号： C02F9/00 , C01D3/16 , C01D3/18 , C02F1/20 , C02F1/265 , C02F1/283 , C02F1/38 , C02F1/72 , C02F1/74 , C02F2103/36
摘要： The invention relates to a method of circular use of waste brine produced in the manufacture process of MDI, comprising the following steps: (1) the waste brine produced in the manufacture process of MDI is subjected to a high-gravity extraction and then to a column extraction, wherein said waste brine contains aniline, diaminodiphenylmethane and polyamine; (2) the waste brine from step (1) is transmitted to a stripping tower for steam stripping; (3) the waste brine from the stripping tower of step (2) and a chemical oxidant are transmitted to an oxidation reactor to which air is blown for aeration; (4) the waste brine after the treatment of step (3) is transmitted to an absorption tower for absorption. The invention makes the salt water have TOC of less than 8 ppm and TN of less than 2.5 ppm and achieves regeneration of resources in the waste brine such as sodium chloride and water and the like for circular use.
摘要翻译：本发明涉及在MDI制造工艺中生产的废盐水的循环使用方法，包括以下步骤：（1）在MDI制造过程中生产的废盐水经受高重力萃取，然后进行柱提取，其中所述废盐水包含苯胺，二氨基二苯基甲烷和多胺; （2）来自步骤（1）的废盐水被传送到用于汽提的汽提塔; （3）将来自步骤（2）的汽提塔的废盐水和化学氧化剂输送到氧化反应器，吹入空气进行曝气; （4）步骤（3）处理后的废盐水被传送到吸收塔进行吸收。本发明使得盐水的TOC小于8ppm，TN小于2.5ppm，实现了循环使用的氯化钠，水等废盐水的再生。

5. 发明授权

US07485367B2 CaCO3/SiO2.nH2O nanocomposite particles and SiO2.nH2O hollow-structures nanomaterials and synthesizing method 有权
标题翻译： CaCO3 / SiO2.nH2O纳米复合颗粒和SiO2.nH2O中空结构纳米材料及其合成方法
公开(公告)号：US07485367B2
公开(公告)日：2009-02-03
申请号：US10945299
申请日：2004-09-20
申请人： Jianfeng Chen , Runjing Liu , Yun Jimmy , Zhigang Shen , Haikui Zou , Fen Guo
发明人： Jianfeng Chen , Runjing Liu , Yun Jimmy , Zhigang Shen , Haikui Zou , Fen Guo
IPC分类号： B32B5/16 , B05D7/00
CPC分类号： C01F11/185 , C01P2002/72 , C01P2004/04 , C01P2004/80 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： The invention provides CaCO3/SiO2.nH2O nanocomposite particles and method of producing the same. A template nucleus is used calcium carbonate and the surface of nucleus is encapsulated by a SiO2.nH2O nanolayer. The invention also provides a CaCO3/SiO2.nH2O nanocomposite particles having hollow structure, in which n=0-2. The nanocomposite particles according to the invention have a number of uses.
摘要翻译：本发明提供CaCO 3 / SiO 2·nH 2 O纳米复合颗粒及其制备方法。模板核使用碳酸钙，核表面被SiO2.nH2O纳米层包裹。本发明还提供了具有中空结构的CaCO 3 / SiO 2·nH 2 O纳米复合材料颗粒，其中n = 0-2。根据本发明的纳米复合颗粒具有许多用途。

6. 发明申请

US20050170178A1 CaCO3/SiO2.nH2O nanocomposite particles and SiO2.nH2O hollow-structures nanomaterials and synthesizing method 有权
标题翻译： CaCO3 / SiO2.nH2O纳米复合颗粒和SiO2.nH2O中空结构纳米材料及其合成方法
公开(公告)号：US20050170178A1
公开(公告)日：2005-08-04
申请号：US10945299
申请日：2004-09-20
申请人： Jianfeng Chen , Runjing Liu , Yun Jimmy , Zhigang Shen , Haikui Zou , Fen Guo
发明人： Jianfeng Chen , Runjing Liu , Yun Jimmy , Zhigang Shen , Haikui Zou , Fen Guo
IPC分类号： C01F11/18 , B32B18/00 , B05D7/00
CPC分类号： C01F11/185 , C01P2002/72 , C01P2004/04 , C01P2004/80 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： The invention provides CaCO3/SiO2.nH2O nanocomposite particles and method of producing the same. A template nucleus is used calcium carbonate and the surface of nucleus is encapsulated by a SiO2.nH2O nanolayer. The invention also provides a CaCO3/SiO2.nH2O nanocomposite particles having hollow structure, in which n=0-2. The nanocomposite particles according to the invention have a number of uses.
摘要翻译：本发明提供了CaCO 3 / SiO 2·nH 2 O 2纳米复合颗粒及其制备方法。模板核使用碳酸钙，并且核的表面被SiO 2纳米N 2 O 3纳米层包封。本发明还提供了具有中空结构的CaCO 3 / SiO 2·nH 2 O 2纳米复合材料颗粒，其中n = 0-2。根据本发明的纳米复合颗粒具有许多用途。

7. 发明申请

US20060120941A1 Silica support material, its application in a polyalkene catalyst, and its preparation process 审中-公开
标题翻译：二氧化硅载体材料，其在聚烯烃催化剂中的应用及其制备方法
公开(公告)号：US20060120941A1
公开(公告)日：2006-06-08
申请号：US11291154
申请日：2005-12-01
申请人： Jianfeng Chen , Jirui Song , Haikui Zou , Lixiong Wen
发明人： Jianfeng Chen , Jirui Song , Haikui Zou , Lixiong Wen
IPC分类号： C01B33/12
CPC分类号： C01B33/193 , B01J21/08 , B01J35/08 , B01J37/0018 , B01J37/0072 , C08F4/65916 , C08F10/00 , C08F4/025
摘要： An SiO2 support material used in a polyolefin catalyst, which consists of a hollow silica particle having a wall of some thickness and a process to prepare the silica mesoporous material above and the agglomerated hollow silica particulate, comprising the steps of: taking nanometer-sized calcium carbonate as inorganic template, or taking PMMA, PS, PU as organic template, then making silica grow and synthesize on the surface of the template, and obtaining the hollow silica material by removing the template. The above hollow silica can be used as raw material to prepare an agglomerated hollow silica particulate by particle shaping. Such material has a certain specific surface area, a wide pore size distribution and a large pore volume, and a uniform particle size distribution, so it can be used in many applications such as adsorption material, catalyst material, wave-absorbing material, ceramic material, sensitive material, magnetic material and the like, especially widely used in the polyolefin catalyst.
摘要翻译：用于聚烯烃催化剂中的SiO 2支撑材料，其由具有一定厚度的壁的中空二氧化硅颗粒和制备上述二氧化硅介孔材料的方法和团聚的中空二氧化硅颗粒组成，包括步骤：以纳米级碳酸钙为无机模板，或以PMMA，PS，PU为有机模板，然后在模板表面生成二氧化硅并合成，并通过去除模板获得中空二氧化硅材料。可以使用上述中空二氧化硅作为原料，通过粒子成型制备凝聚的中空二氧化硅颗粒。这种材料具有一定的比表面积，宽孔径分布和孔体积大，粒径分布均匀的特点，可用于吸附材料，催化剂材料，吸波材料，陶瓷材料等众多领域，敏感材料，磁性材料等，特别广泛用于聚烯烃催化剂中。

8. 发明申请

US20050019248A1 High-gravity reactive precipitation process for the preparation of barium titanate powders 有权
标题翻译：用于制备钛酸钡粉末的高重力反应沉淀法
公开(公告)号：US20050019248A1
公开(公告)日：2005-01-27
申请号：US10624944
申请日：2003-07-21
申请人： Jianfeng Chen , Xiaolin Liu , Zhigang Shen , Guangwen Chu
发明人： Jianfeng Chen , Xiaolin Liu , Zhigang Shen , Guangwen Chu
IPC分类号： B01J8/10 , C01G23/00 , C01G23/04
CPC分类号： B82Y30/00 , B01J8/10 , B01J2219/00006 , C01G23/006 , C01P2002/72 , C01P2004/04 , C01P2004/62 , C01P2004/64 , C01P2006/40
摘要： The invention relates to a process for the preparation of fine barium titanate (BaTiO3) powders. The process comprises introducing an aqueous solution (I) containing salts of barium and titanium, and an aqueous basic solution (II) containing an inorganic or organic base separately and simultaneously into a high-gravity reactor with the high-gravity level of 1.25G to 12,500G and performing the reaction of the solution (I) with the solution (II) at a temperature of from 60 to 100° C. The solution (I) is preheated to a temperature ranging from 60° C. to 65° C. and the solution (II) is preheated to a temperature ranging from 60° C. to 100° C. respectively prior to the reaction, in which the Ba/Ti molar ratio in the solution (I) is more than 1 and the concentration of the base in the solution (II) is such that the reaction mixture is maintained at a constant OH− concentration, preferably a pH value of about 14. The reaction product is separated by filtering and washed with deionized water to remove the impurity ions and excessive barium ions, and then dried to obtain BaTiO3 powders. Said powders consist essentially of crystalline, primary particles having a uniform particle size ranging from 5 to 200 nm, an approximately spherical morphology and a high sintering activity.
摘要翻译：本发明涉及一种制备精细钛酸钡（BaTiO3）粉末的方法。该方法包括将含有钡和钛的盐的水溶液（I）和含有无机或有机碱的碱性水溶液（II）分别并入同时进入高重力水平为1.25G的高重力反应器中 12,500G，并在60〜100℃的温度下进行溶液（I）与溶液（II）的反应。将溶液（I）预热至60℃至65℃的温度。并且溶液（II）分别在反应之前预热至60℃至100℃的温度，其中溶液（I）中的Ba / Ti摩尔比大于1，浓度溶液（II）中的碱使得反应混合物保持恒定的OH - 浓度，优选pH值为约14.反应产物通过过滤分离并用去离子水洗涤以除去杂质离子和过量的钡离子，然后干燥得到BaTiO3粉末呃所述粉末基本上由具有5至200nm的均匀粒度的晶体初级粒子，近似球形的形态和高烧结活性组成。

9. 发明授权

US08540908B2 Method of preparing nano-dispersed high-all-trans-carotenoid microcapsules 有权
标题翻译：制备纳米分散高全反式类胡萝卜素微胶囊的方法
公开(公告)号：US08540908B2
公开(公告)日：2013-09-24
申请号：US13259291
申请日：2010-03-18
申请人： Zhirong Chen , Jianfeng Chen , Hong Yin , Hong Zhao , Dan Qiu , Lifang Shi , Jiandong Li , Guangwen Chu , Lei Shao
发明人： Zhirong Chen , Jianfeng Chen , Hong Yin , Hong Zhao , Dan Qiu , Lifang Shi , Jiandong Li , Guangwen Chu , Lei Shao
IPC分类号： B01J13/04
CPC分类号： B01J13/043 , A23K20/179 , A23L5/44 , A23L33/10 , A23L33/105 , A23P10/30 , A23V2002/00 , A61K8/0241 , A61K8/11 , A61K8/31 , A61K8/35 , A61K31/01 , A61K31/122 , A61K2800/412 , A61Q19/00 , C09B61/00 , C09B67/0097 , A23V2250/211 , A23V2200/224
摘要： A method of preparing nano-dispersed high-all-trans-carotenoid microcapsules is provided, comprising: preparing 10-20% carotenoid suspension by milling the high-all trans-carotenoid crystals with dichloromethane until the particle size thereof is in the range of 2-5 μm, then supplying the suspension together with preheated dichloromethane of another pass into a dissolving tank to obtain a solution of 0.5-2%; delivering the solution together with ethanol or isopropanol into a crystallization device having high gravity rotating packed bed simultaneously and continuously, and then into a wiped-film evaporator for desolvation until the solid content is 10-20%, then a transparent alcohol dispersion of carotenoid is obtained; mashing the alcohol dispersion together with an aqueous solution containing an antioxidant and protective colloid and spray drying to obtain nano-dispersed high-all-trans-carotenoid microcapsules. As the crystals are nano-dispersed and the content of trans-isomer is more than 90%, the carotenoid microcapsules of present inventions exhibit high bioavailability.
摘要翻译：提供了一种制备纳米分散高全反式类胡萝卜素微胶囊的方法，包括：通过用二氯甲烷研磨高全反式类胡萝卜素晶体制备10-20％的类胡萝卜素悬浮液，直到其粒径在2 -5μm，然后将悬浮液与另一道次的预热二氯甲烷一起供入溶解槽中，得到0.5-2％的溶液; 将溶液与乙醇或异丙醇一起输送到具有高重力旋转填充床的结晶装置中，同时且连续地进行，然后进入擦膜蒸发器进行去溶剂化直到固体含量为10-20％，然后将类胡萝卜素的透明醇分散体获得; 将醇分散体与含有抗氧化剂和保护胶体的水溶液一起糖化并喷雾干燥，得到纳米分散的高全反式类胡萝卜素微胶囊。由于晶体是纳米分散的并且反式异构体的含量大于90％，本发明的类胡萝卜素微胶囊显示出高的生物利用度。

10. 发明申请

US20120037232A1 MICROCHANNEL DOUBLE PIPE DEVICE AND USAGE THEREOF 有权
标题翻译：微通道双管设备及其使用
公开(公告)号：US20120037232A1
公开(公告)日：2012-02-16
申请号：US13263833
申请日：2010-04-09
申请人： Zhigang Shen , Jimmy Sunglai Yun , Jianfeng Chen , Guangwen Chu
发明人： Zhigang Shen , Jimmy Sunglai Yun , Jianfeng Chen , Guangwen Chu
IPC分类号： F15D1/00 , F16L9/18
CPC分类号： B01F15/065 , B01F11/0266 , B01F13/0067 , B01F13/1027 , B01J19/0093 , B01J2219/00788 , B01J2219/00889 , B22F2998/00 , Y10T137/0318
摘要： A microchannel double pipe device comprises a channel for inner nozzle (4), a channel for outer nozzle (5) and a mechanical probe (8). The channel for outer nozzle (5) concentrically surrounds the channel for inner nozzle (4), and the channel for inner nozzle (4) concentrically surrounds the mechanical probe (8). Constricted at the outlet of the channel for inner nozzle (4), the channel for inner nozzle (4) extends to form an inner nozzle core (9). Constricted at the outlet of the channel for outer nozzle (5), the channel for outer nozzle (5) extends to form an outer nozzle core (10). The outer nozzle core (10) essentially concentrically surrounds the inner nozzle core (9), and the outlets of the inner nozzle core (9) and the outer nozzle core (10) are at the same level essentially. The mechanical probe (8) is configured to intermittently empty the inner nozzle core (9). The device can be used for microcosmic mixing and reaction, especially suitable for continuous preparation of inorganic, organic or medicine particles with nanostructure or micron-structure using liquid-liquid precipitation method.
摘要翻译：微通道双管装置包括用于内部喷嘴（4）的通道，用于外部喷嘴（5）的通道和机械探针（8）。外喷嘴（5）的通道同心地围绕用于内喷嘴（4）的通道，内喷嘴（4）的通道同心地围绕机械探头（8）。在内喷嘴（4）的通道的出口处被限制，内喷嘴（4）的通道延伸以形成内喷嘴芯（9）。在外喷嘴（5）的通道的出口处受限，外喷嘴（5）的通道延伸以形成外喷嘴芯（10）。外喷嘴芯（10）基本上同心地围绕内喷嘴芯（9），并且内喷嘴芯（9）和外喷嘴芯（10）的出口基本上处于相同的水平。机械探针（8）构造成间歇地排空内部喷嘴芯（9）。该装置可用于微观混合和反应，特别适用于使用液 - 液沉淀法连续制备具有纳米结构或微米结构的无机，有机或药物颗粒。

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