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    • 4. 发明授权
    • Method of forming multilayer titanium nitride film by multiple step chemical vapor deposition process and method of manufacturing semiconductor device using the same
    • 通过多步化学气相沉积工艺形成多层氮化钛膜的方法和使用其制造半导体器件的方法
    • US06207557B1
    • 2001-03-27
    • US09356928
    • 1999-07-19
    • Jang-eun LeeJu-hyuck ChungTae-wook Seo
    • Jang-eun LeeJu-hyuck ChungTae-wook Seo
    • H01L214763
    • H01L21/76856H01L21/28556H01L21/76843H01L21/76846
    • A method of forming a multilayer titanium nitride film hardly containing any Cl component by a multiple step chemical vapor deposition method, and a method of manufacturing a semiconductor device using the same are provided. In the present invention, a multilayer TiN film is formed by multiple step chemical vapor deposition (CVD) on a semiconductor substrate on which an underlayer is formed. In order to form the multilayer TiN film, an underlayer protective TiN film is formed by forming a first TiN film on the underlayer and NH3 annealing the first TiN film. A main TiN film is formed by forming a second TiN film on the underlayer protective TiN film and NH3 annealing the second TiN film. A source gas used in order to form the first TiN film has a smaller TiCl4 to NH3 gas flow ratio than a source gas for forming the second TiN film. In order to apply the multilayer TiN film to the fabrication of the semiconductor device, an insulating film having a contact hole is formed on a semiconductor substrate. A Ti film is formed on the inner wall of the contact hole. A multilayer TiN film is formed on the Ti film by the multiple step CVD method. A metal plug is formed on the multilayer TiN film.
    • 提供了通过多步化学气相沉积法形成几乎不含任何Cl成分的多层氮化钛膜的方法,以及制造使用其的半导体器件的方法。 在本发明中,通过在其上形成有底层的半导体衬底上进行多步化学气相沉积(CVD)形成多层TiN膜。 为了形成多层TiN膜,通过在底层上形成第一TiN膜,并对第一TiN膜进行NH 3退火,形成下层保护TiN膜。 通过在底层保护性TiN膜上形成第二TiN膜并使NH 3退火第二TiN膜来形成主TiN膜。 用于形成第一TiN膜的源气体与用于形成第二TiN膜的源气体相比具有较小的TiCl 4与NH 3气体流量比。 为了将多层TiN膜施加到半导体器件的制造中,在半导体衬底上形成具有接触孔的绝缘膜。 在接触孔的内壁上形成有Ti膜。 通过多步CVD法在Ti膜上形成多层TiN膜。 在多层TiN膜上形成金属塞。