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1. 发明授权

US06461425B2 Cementitious dry cast mixture 有权
标题翻译：水泥干混合物
公开(公告)号：US06461425B2
公开(公告)日：2002-10-08
申请号：US09847693
申请日：2001-05-02
申请人： Heath Brown , Jeffrey R. Bury , Lan Huang , Runhai Lu , Jesse Osborne , Ken Sroka , Thomas M. Vickers, Jr.
发明人： Heath Brown , Jeffrey R. Bury , Lan Huang , Runhai Lu , Jesse Osborne , Ken Sroka , Thomas M. Vickers, Jr.
IPC分类号： C04B2412
CPC分类号： C04B24/2647 , C04B24/163 , C04B24/243 , C04B24/26 , C04B24/2641 , C04B24/2652 , C04B24/2664 , C04B24/267 , C04B24/2688 , C04B24/2694 , C04B2103/408 , C04B2111/00068
摘要： The present invention is directed to cementitious dry cast mixtures for forming cementitious articles, particularly a cementitious dry cast mixture containing a dispersant, wherein said dispersant is a derivatized polycarboxylate dispersant which is a polymer comprising units derived from at least a substituted carboxylic acid monomer or substituted ethylenically unsaturated monomer, and optionally including at least one of an unsaturated hydrocarbon, an N-polyoxyalkylene maleimide, and a condensation product of an unsubstituted carboxylic acid monomer and an alkoxypolyoxyalkylene primary amine substituted carboxylic acid monomer. The cementitious dry cast mixture has a reduced effective dose of dispersant; compacts and consolidates in response to vibration energy; reduces the cycle time in the production of articles manufactured from dry cast mixtures; provides for increased green strength, density, and early compressive strength; and improves the surface aesthetics of articles manufactured from dry cast mixtures. Additionally, a surface active agent/air entraining agent can be included in combination with the dispersant to provide for increased swipe effect.
摘要翻译：本发明涉及用于形成水泥质制品的水泥质干法浇铸混合物，特别是含有分散剂的水泥质干浇注混合物，其中所述分散剂是衍生化的聚羧酸酯分散剂，其是包含衍生自至少取代的羧酸单体或取代的单体的聚合物烯键式不饱和单体，并且任选地包括不饱和烃，N-聚氧化烯马来酰亚胺和未取代的羧酸单体和烷氧基聚氧化烯伯胺取代的羧酸单体的缩合产物中的至少一种。水泥质干法浇注混合物的分散剂有效剂量降低; 响应于振动能量紧凑和整合; 减少了由干式混合物制造的制品生产中的循环时间; 提供增加的生坯强度，密度和早期抗压强度; 并且改善了由干式混合物制造的制品的表面美观性。此外，表面活性剂/加气剂可以与分散剂结合使用以提供增加的擦拭效果。

2. 发明授权

US06267814B1 Cementitious dry cast mixture 有权
标题翻译：水泥干混合物
公开(公告)号：US06267814B1
公开(公告)日：2001-07-31
申请号：US09369562
申请日：1999-08-06
申请人： Jeffrey R. Bury , Jesse Osborne , Thomas M. Vickers, Jr. , Ken Sroka , Runhai Lu , Lan Huang , Heath Brown
发明人： Jeffrey R. Bury , Jesse Osborne , Thomas M. Vickers, Jr. , Ken Sroka , Runhai Lu , Lan Huang , Heath Brown
IPC分类号： C04B2412
CPC分类号： C04B24/2647 , C04B24/163 , C04B24/243 , C04B24/26 , C04B24/2641 , C04B24/2652 , C04B24/2664 , C04B24/267 , C04B24/2688 , C04B24/2694 , C04B2103/408 , C04B2111/00068
摘要： The present invention is directed to cementitious dry cast mixtures for forming cementitious articles, particularly a cementitious dry cast mixture containing a dispersant, wherein said dispersant is a derivatized polycarboxylate dispersant which is a polymer comprising units derived from at least a substituted carboxylic acid monomer or substituted ethylenically unsaturated monomer, and optionally including at least one of an unsaturated hydrocarbon, an N-polyoxyalkylene maleimide, and a condensation product of an unsubstituted carboxylic acid monomer and an alkoxypolyoxyalkylene primary amine substituted carboxylic acid monomer. The cementitious dry cast mixture has a reduced effective dose of dispersant; compacts and consolidates in response to vibration energy; reduces the cycle time in the production of articles manufactured from dry cast mixtures; provides for increased green strength, density, and early compressive strength; and improves the surface aesthetics of articles manufactured from dry cast mixtures. Additionally, a surface active agent/air entraining agent can be included in combination with the dispersant to provide for increased swipe effect.
摘要翻译：本发明涉及用于形成水泥质制品的水泥质干法浇铸混合物，特别是含有分散剂的水泥质干浇注混合物，其中所述分散剂是衍生化的聚羧酸酯分散剂，其是包含衍生自至少取代的羧酸单体或取代的单体的聚合物烯键式不饱和单体，并且任选地包括不饱和烃，N-聚氧化烯马来酰亚胺和未取代的羧酸单体和烷氧基聚氧化烯伯胺取代的羧酸单体的缩合产物中的至少一种。水泥质干法浇注混合物的分散剂有效剂量降低; 响应于振动能量紧凑和整合; 减少了由干式混合物制造的制品生产中的循环时间; 提供增加的生坯强度，密度和早期抗压强度; 并且改善了由干式混合物制造的制品的表面美观性。此外，表面活性剂/加气剂可以与分散剂结合使用以提供增加的擦拭效果。

3. 发明授权

US06310143B1 Derivatized polycarboxylate dispersants 失效
标题翻译：衍生的聚羧酸酯分散剂
公开(公告)号：US06310143B1
公开(公告)日：2001-10-30
申请号：US09212652
申请日：1998-12-16
申请人： Thomas M. Vickers, Jr. , Rainer Packe-Wirth , Jeffrey R. Bury , Jesse Osborne , Runhai Lu , John Moreau , Lynn E. Brower , Samy M. Shendy , John Pickett
发明人： Thomas M. Vickers, Jr. , Rainer Packe-Wirth , Jeffrey R. Bury , Jesse Osborne , Runhai Lu , John Moreau , Lynn E. Brower , Samy M. Shendy , John Pickett
IPC分类号： B01F1734
CPC分类号： C04B24/267 , C04B28/04 , C04B2103/0059 , C04B2103/408 , C04B2103/50 , C08F8/44 , Y02W30/92 , Y02W30/94 , Y10S516/912 , Y10S516/915 , Y10S525/919 , Y10S526/932 , C04B18/08 , C04B18/146 , C04B2103/10 , C04B14/106 , C08F8/32 , C08F212/08 , C08F222/06
摘要： The present invention is directed to derivatized polycarboxylate dispersants for cementitious mixtures, including those mixtures with high percentages of pozzolan cement replacement and dry cast applications. In particular, the invention is directed to a cementitious mixture comprising cement, including cements with high percentages of pozzolan cement replacement, water, coarse aggregate, fine aggregate, and including a dispersant, wherein said dispersant is a derivatized polycarboxylate dispersant, or combination of polycarboxylate dispersants, which is a derivatized polymer comprising a backbone having moieties derived from (a) an unsaturated hydrocarbon; (b) at least one of a substituted carboxylic acid monomer, a substituted ethylenically unsaturated monomer, and maleic anhydride; and (c) optionally including an N-polyoxyalkylene succinimide; and wherein derivative moieties are pendant to the backbone monomer by at least one ester linkage and at least one amide linkage. The derivatized polycarboxylate dispersant provides for a longer shelf life dispersant, improved dispersability of cementitious mixtures, water reduction in cementitious mixtures, and is an effective dispersant in high pozzolan replaced cementitious mixtures.
摘要翻译：本发明涉及用于水泥混合物的衍生的聚羧酸酯分散剂，包括具有高百分比的火山灰水泥替代物和干浇注应用的那些混合物。特别地，本发明涉及包含水泥的水泥混合物，包括具有高百分比的火山灰水泥替代物的水泥，水，粗骨料，细骨料，并且包括分散剂，其中所述分散剂是衍生化的聚羧酸酯分散剂，或多羧酸盐组合分散剂，其是衍生的聚合物，其包含具有衍生自（a）不饱和烃的部分的主链; （b）取代的羧酸单体，取代的烯属不饱和单体和马来酸酐中的至少一种; 和（c）任选地包括N-聚氧化烯琥珀酰亚胺; 并且其中衍生部分通过至少一个酯键和至少一个酰胺键垂饰于主链单体。衍生化的聚羧酸酯分散剂提供更长的保质期分散剂，改善水泥混合物的分散性，水泥混合物中的水分降解，并且是高火山灰替代水泥混合物中的有效分散剂。

4. 发明授权

US06391106B1 Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor 有权
公开(公告)号：US06391106B1
公开(公告)日：2002-05-21
申请号：US09912182
申请日：2001-07-24
申请人： John Moreau , Runhai Lu , Jeffrey R. Bury , Thomas M. Vickers, Jr.
发明人： John Moreau , Runhai Lu , Jeffrey R. Bury , Thomas M. Vickers, Jr.
IPC分类号： C04B2404
摘要： A cementitious mixture comprises a hydraulic cement; greater than about 10% by weight of a pozzolanic cement replacement selected from fly ash, slag, natural pozzolans, and mixtures thereof, based on the weight of said hydraulic cement and cement replacement; and a compatabilizing admixture, wherein the compatabilizing admixture comprises a compatabilizing derivatized polycarboxylate polymer dispersant capable of acting as a water reducer, in combination with an accelerator. The derivatized polycarboxylate dispersant, alone or in combination with other derivatized polycarboxylate dispersants, is a polymer comprising units derived from at least one of a substituted carboxylic acid monomer and a substituted ethylenically unsaturated monomer, at least one of an N-polyoxyalkylene maleimide and a condensation product of an unsubstituted carboxylic acid monomer and an alkoxypolyoxyalkylene primary amine substituted carboxylic acid monomer, and optionally including an unsaturated hydrocarbon. The derivatized polycarboxylate dispersant provides for a longer shelf life dispersant, improved dispersability of cementitious mixtures, water reduction in cementitious mixtures, and is an effective dispersant in high pozzolan replaced cementitious mixtures.

5. 发明授权

US06290770B1 Cementitious mixture containing high pozzolan cement replacement and compatabilizing admixtures therefor 有权
标题翻译：含有高火山灰水泥替代物的水泥混合物及其混合物
公开(公告)号：US06290770B1
公开(公告)日：2001-09-18
申请号：US09371627
申请日：1999-08-11
申请人： John Moreau , Runhai Lu , Jeffrey R. Bury , Thomas M. Vickers, Jr.
发明人： John Moreau , Runhai Lu , Jeffrey R. Bury , Thomas M. Vickers, Jr.
IPC分类号： C04B713
CPC分类号： C04B28/04 , C04B24/165 , C04B24/243 , C04B24/2658 , C04B24/267 , C04B24/2694 , C04B40/0039 , C04B2111/1062 , Y02W30/92 , Y02W30/94 , C04B14/10 , C04B14/106 , C04B14/14 , C04B18/08 , C04B18/141 , C04B18/146 , C04B2103/10 , C04B2103/408 , C04B2103/0088 , C04B2103/302
摘要： A cementitious mixture comprises a hydraulic cement; greater than about 10% by weight of a pozzolanic cement replacement selected from fly ash, slag, natural pozzolans, and mixtures thereof, based on the weight of said hydraulic cement and cement replacement; and a compatabilizing admixture, wherein the compatabilizing admixture comprises a compatabilizing derivatized polycarboxylate polymer dispersant capable of acting as a water reducer, in combination with an accelerator. The derivatized polycarboxylate dispersant, alone or in combination with other derivatized polycarboxylate dispersants, is a polymer comprising units derived from at least one of a substituted carboxylic acid monomer and a substituted ethylenically unsaturated monomer, at least one of an N-polyoxyalkylene maleimide and a condensation product of an unsubstituted carboxylic acid monomer and an alkoxypolyoxyalkylene primary amine substituted carboxylic acid monomer, and optionally including an unsaturated hydrocarbon. The derivatized polycarboxylate dispersant provides for a longer shelf life dispersant, improved dispersability of cementitious mixtures, water reduction in cementitious mixtures, and is an effective dispersant in high pozzolan replaced cementitious mixtures.
摘要翻译：水泥混合物包括水硬性水泥; 基于所述水硬性水泥和水泥替代物的重量，大于约10重量％的火山灰水泥替代物，其选自飞灰，矿渣，天然火山灰及其混合物; 和一种可配制的混合物，其中所述配混的混合物包括与促进剂组合的能够用作减水剂的可衍生的衍生的聚羧酸酯聚合物分散剂。衍生化的聚羧酸酯分散剂单独或与其它衍生化的聚羧酸酯分散剂组合是包含衍生自取代的羧酸单体和取代的烯键式不饱和单体中的至少一种的单体的聚合物，N-聚氧化烯马来酰亚胺和缩合物中的至少一种未取代的羧酸单体和烷氧基聚氧化烯伯胺取代的羧酸单体的产物，并且任选地包括不饱和烃。衍生化的聚羧酸酯分散剂提供更长的保质期分散剂，改善水泥混合物的分散性，水泥混合物中的水分降解，并且是高火山灰替代水泥混合物中的有效分散剂。

6. 发明授权

US6133347A Oligomeric dispersant 有权
公开(公告)号：US6133347A
公开(公告)日：2000-10-17
申请号：US350394
申请日：1999-07-09
申请人： Thomas M. Vickers, Jr. , Rainer Packe-Wirth , Michael Porsch , Samy M. Shendy , Lynn E. Brower , John Pickett , Runhai Lu , Frank Danko
发明人： Thomas M. Vickers, Jr. , Rainer Packe-Wirth , Michael Porsch , Samy M. Shendy , Lynn E. Brower , John Pickett , Runhai Lu , Frank Danko
IPC分类号： C04B24/00 , C04B24/16 , C04B24/24 , C04B24/26 , C04B24/32 , C04B24/42 , C04B28/02 , C04B103/40 , C08G65/333 , C08G65/335 , C08G65/336 , C08K3/00
CPC分类号： C04B24/243 , C04B24/006 , C04B24/161 , C04B24/2688 , C04B24/32 , C08G65/336 , C04B2103/408 , C08G2650/50
摘要： A cementitious formulation comprising a cement and an oligomeric dispersant is provided. The dispersant is a reaction product of two or three moieties. The first moiety (A) is a nonpolymeric, functional moiety that adsorbs onto a particle, and wherein one or more A moieties together contain at least two residues to provide attachment of the dispersant onto a particle to be dispersed. The second required moiety (C) is a linear or branched water soluble, nonionic polymer that provides the dispersing capability. A third moiety (B), if present, is a nonpolymeric moiety disposed between the first and second moiety, to connect the first and second moieties. A method is provided for dispersing a cementitious formulation comprising a cement in water, including providing in said cementitious formulation the above oligomeric dispersant. A combination of any cement dispersant with an oligomeric dispersant wherein at least one A moiety is blocked is also provided in a cementitious formulation and in a method of making such cementitious formulation.

7. 发明授权

US09212095B2 Use of HyperBranched polyether surfactant in cementitious systems 有权
标题翻译：在水泥体系中使用超支化聚醚表面活性剂
公开(公告)号：US09212095B2
公开(公告)日：2015-12-15
申请号：US13400198
申请日：2012-02-20
申请人： Jeffrey R. Bury , Thomas M. Vickers, Jr.
发明人： Jeffrey R. Bury , Thomas M. Vickers, Jr.
IPC分类号： C08K3/00 , C04B24/32 , C04B28/02 , C04B40/00 , C04B103/40
CPC分类号： C04B24/32 , C04B28/02 , C04B40/0039 , C04B2103/40 , C04B24/12 , C04B2103/408 , C04B2103/50 , C04B24/2647 , C04B20/0048 , C04B2103/0088 , C04B2103/12 , C04B2103/22 , C04B2103/302 , C04B2103/304 , C04B2103/44 , C04B2103/54 , C04B2103/58 , C04B2103/61 , C04B2103/65
摘要： A cementitious composition containing hydraulic cement, water, and a hyper-branched polyether surfactant. An aqueous admixture composition for cementitious compositions including a hyper-branched polyether surfactant, optionally a dispersant, optionally an additional surfactant or defoamer, and optionally a stabilizing agent. A method of making a cementitious composition including mixing cementitious material, water, a hyper-branched polyether surfactant, optionally a dispersant for cementitious compositions, optionally an additional surfactant or defoamer, and optionally a stabilizing agent.
摘要翻译：含有水硬性水泥，水和超支化聚醚表面活性剂的水泥组合物。用于水泥组合物的水性混合物组合物，包括超支化聚醚表面活性剂，任选的分散剂，任选的另外的表面活性剂或消泡剂，以及任选的稳定剂。制备水泥组合物的方法，包括混合水泥质材料，水，超支化聚醚表面活性剂，任选的水泥组合物的分散剂，任选的另外的表面活性剂或消泡剂，以及任选的稳定剂。

8. 发明授权

US06284867B1 Highly efficient cement dispersants 失效
标题翻译：高效水泥分散剂
公开(公告)号：US06284867B1
公开(公告)日：2001-09-04
申请号：US09592231
申请日：2000-06-12
申请人： Thomas M. Vickers, Jr. , Runhai Lu , Lynn E. Brower , Samy M. Shendy , Rainer Packe-Wirth , Hong Gao
发明人： Thomas M. Vickers, Jr. , Runhai Lu , Lynn E. Brower , Samy M. Shendy , Rainer Packe-Wirth , Hong Gao
IPC分类号： C08G6900
CPC分类号： C04B24/32 , C04B24/28 , C04B24/287 , C04B2103/0051 , C04B2103/0052 , C04B2103/0059 , C04B2103/302 , C04B2103/408 , C08G69/48 , C08G73/02 , C08G73/0233 , C08G73/028 , C08G73/1092
摘要： A substantially non-crosslinked polymer cementitious composition dispersant for the improvement of the fluidity of cementitious compositions comprising hydrophilic side chain substituted polyimide or polyamide backbone units, having at least some proportion of grafted oligomeric or polymeric hydrophilic side chains linking at least one of amides, esters, and thioesters, wherein the polymer cementitious composition is water soluble, and wherein crosslinking is such that in a statistical sampling there is greater than zero to less than 0.1 mole % of backbone units involved in crosslinking.
摘要翻译：一种基本上非交联的聚合物胶结组合物分散剂，用于改善包含亲水侧链取代的聚酰亚胺或聚酰胺主链单元的水泥组合物的流动性，其具有至少一部分连接至少一种酰胺，酯的接枝的低聚或聚合的亲水侧链和硫酯，其中聚合物胶结组合物是水溶性的，并且其中交联使得在统计学取样中，涉及交联的主链单元大于零至小于0.1摩尔％。

9. 发明授权

US07556684B2 Amine containing strength improvement admixture 有权
标题翻译：含有强力改善剂的胺
公开(公告)号：US07556684B2
公开(公告)日：2009-07-07
申请号：US11066930
申请日：2005-02-25
申请人： Jeffrey R. Bury , Thomas M. Vickers, Jr. , Bruce J. Christensen
发明人： Jeffrey R. Bury , Thomas M. Vickers, Jr. , Bruce J. Christensen
IPC分类号： C04B24/00
CPC分类号： C04B40/0039 , C04B28/02 , C04B24/121 , C04B24/2647 , C04B24/122 , C04B24/2658 , C04B24/12 , C04B24/267 , C04B2103/12 , C04B2103/22 , C04B2103/302 , C04B2103/304 , C04B2103/50 , C04B2103/54 , C04B2103/61 , C04B2103/67 , C04B2103/69
摘要： A strength improvement admixture composition is provided that increases the compressive strength of cementitious compositions without negatively increasing the setting time. The admixture comprises the components of a polycarboxylate dispersant and strength improvement additive.
摘要翻译：提供了一种增强混凝土组合物的抗压强度，而不会增加固化时间。该混合物包括聚羧酸酯分散剂和强度改进添加剂的组分。

10. 发明授权

US06569924B2 Solubilized defoamers for cementitious compositions 有权
公开(公告)号：US06569924B2
公开(公告)日：2003-05-27
申请号：US09732380
申请日：2000-12-07
申请人： Samy Shendy , Jeffrey R. Bury , John J. Luciano , Thomas M. Vickers, Jr.
发明人： Samy Shendy , Jeffrey R. Bury , John J. Luciano , Thomas M. Vickers, Jr.
IPC分类号： C08K300
CPC分类号： C04B40/0039 , B01D19/04 , B01D19/0404 , B01F17/0085 , B01F17/0092 , C04B24/2647 , C04B24/2688 , C04B24/2694 , C04B24/32 , C04B28/02 , C04B2103/408 , C04B2103/50 , C04B24/267 , C04B2103/304 , C04B24/023 , C04B24/02 , C04B24/34 , C04B24/085 , C04B24/20 , C04B24/003 , C04B24/2664 , C04B24/42 , B01D19/0409 , B01D19/0413 , B01D19/0418
摘要： Solubilizing agents are mixed with water insoluble defoamers and a dispersant for cementitious compositions to provide an admixture for cementitious compositions that is stable over time. Suitable solubilizing agents include alkoxylated moieties or particles. A cementitious composition is provided that includes cement, water, a water insoluble defoamer, a dispersant for cementitious compositions, and a solubilizing agent that solubilizes the water insoluble defoamer. A method is provided for making a cementitious composition that includes mixing cement, water, a water insoluble defoamer, a dispersant for cementitious compositions, and a solubilizing agent that solubilizes the water insoluble defoamer.

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