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1. 发明授权

US5691121A Method for making negative lith images direct positive images 失效
标题翻译：制造负像图像的方法直接呈现正像
公开(公告)号：US5691121A
公开(公告)日：1997-11-25
申请号：US680358
申请日：1996-07-15
申请人： Jean-Marie Dewanckele , David Terrell , Hieronymus Andriessen , Kris Viaene
发明人： Jean-Marie Dewanckele , David Terrell , Hieronymus Andriessen , Kris Viaene
IPC分类号： G03C1/06 , G03C1/485 , G03C1/73
CPC分类号： G03C1/48546 , G03C1/067 , Y10S430/141
摘要： A photographic light-sensitive silver halide material is provided for making negative lithographic images or direct-positive images, said material comprising a support, at least one internal latent image-type silver halide emulsion layer (in the case of direct-positive materials) or surface latent image-type silver halide emulsion layer (in the case of lithographic materials) and development-nucleating amounts of a compound or a precursor thereof, said compound having at least one quaternary heterocyclic ring system comprising at least three rings including a tetrahydropyridinium ring wherein carbon-nitrogen and carbon-carbon double bonds are also part of an aromatic ring being one of said three rings and wherein said double bonds and nitrogen atom in said tetrahydropyridinium ring are incorporated into annelated conjugated ring systems. Developing said photographic material after exposure in an alkaline surface developer rapidly converts said precursor into a ring system as defined hereinbefore.
摘要翻译：提供摄影感光卤化银材料，用于制作负性平版印刷图像或直接正像，所述材料包括载体，至少一个内部潜像型卤化银乳剂层（在直接正极材料的情况下）或表面潜像型卤化银乳剂层（在平版印刷材料的情况下）和显影成核量的化合物或其前体，所述化合物具有至少一个四元杂环系统，其包含至少三个包括四氢吡啶鎓环的环，其中碳 - 氮和碳 - 碳双键也是作为所述三个环之一的芳香环的一部分，并且其中所述四氢吡啶鎓环中的所述双键和氮原子并入到环状共轭环体系中。在碱性表面显影剂中曝光后显影所述照相材料快速地将所述前体转化成如上所定义的环系。

2. 发明授权

US5480770A Method for making direct-positive photographic images 失效
标题翻译：制作直摄摄影图像的方法
公开(公告)号：US5480770A
公开(公告)日：1996-01-02
申请号：US267505
申请日：1994-06-29
申请人： Jean-Marie Dewanckele , David Terrell , Kris Viaene
发明人： Jean-Marie Dewanckele , David Terrell , Kris Viaene
IPC分类号： G03C1/295 , C07C329/16 , C07C333/20 , G03C1/485 , G03C5/50 , G03C5/305
CPC分类号： G03C1/48561 , C07C329/16 , C07C333/20
摘要： The present invention provides a method for making direct-positive photographic images comprising the steps of image-wise exposing a photographic light-sensitive silver halide material comprising a support and a layer of an internal latent image-type silver halide emulsion the pAg of which has been adjusted to a value of at least 8.5 before coating, and developing said exposed photographic silver halide material in a surface developer in the presence of at least one development nucleator which is not able to react with but which is able to adsorb weakly on the surface of the silver halide emulsion crystals prior to development, but which contains a group protected against reaction with silver halide and which is transformed during development in a nucleating derivative with an enhanced reactivity for the silver halide crystals. Photographic materials comprising these novel development nucleators are also described.
摘要翻译：本发明提供一种制造直接正性照相图像的方法，包括以下步骤：将包含支持体的照相感光卤化银材料和其pAg的内部潜像型卤化银乳剂层成像曝光在涂覆之前调节至少为8.5，并且在存在至少一种显影成核剂的情况下在表面显影剂中显影所述曝光的照相卤化银材料，所述显影成核剂不能与表面上的弱吸收而不能反应的卤化银乳液晶体，但是其含有保护不与卤化银反应的基团，并且在显影期间在具有增强的卤化银晶体的反应性的成核衍生物中转化。还描述了包含这些新型显影成核剂的照相材料。

3. 发明授权

US5449595A Method for making direct-positive photographic images 失效
标题翻译：制作直摄摄影图像的方法
公开(公告)号：US5449595A
公开(公告)日：1995-09-12
申请号：US267410
申请日：1994-06-29
申请人： Jean-Marie Dewanckele , David Terrell , Kris Viaene
发明人： Jean-Marie Dewanckele , David Terrell , Kris Viaene
IPC分类号： G03C1/295 , C07D487/04 , G03C1/485 , G03C5/50
CPC分类号： C07D487/04 , G03C1/48538 , G03C1/48561 , Y10S430/141
摘要： The present invention relates to a method for making direct-positive photographic images by developing light-sensitive materials in the presence of development nucleators which do not cause loss of sensitivity during exposure or unevenness of development. More specifically the invention relates to the formation of direct-positive images having a high maximum density and high exposure latitude and to photographic materials for use in said formation, which is accomplished by a method for making direct-positive images comprising:image-wise exposing a photographic light-sensitive silver halide material comprising a support and a layer of an internal latent image-type silver halide emulsion, the pAg of which has been adjusted to a pAg-value between 9.0 and 10.5 inclusive before coating, anddeveloping said exposed photographic silver halide material in a surface developer in the presence of a development nucleator with a group promoting adsorption to silver halide.It has been found that in a particular embodiment of this invention a development-nucleating amount of a hydrazine compound with a 7-hydroxy-s-triazolo-[1,5-a]-pyrimidine group as group promoting adsorption to silver halide is very useful.
摘要翻译：本发明涉及通过在显影成核剂的存在下开发感光材料来制造直接正性照相图像的方法，其不会在曝光或显影不均匀期间引起敏感性的损失。更具体地，本发明涉及形成具有高最大密度和高曝光宽容度的直接正像，以及用于所述地层中的照相材料，其通过用于制造直接正像的方法来实现，包括：图像曝光一种照相感光卤化银材料，其包含载体和一层内部潜像型卤化银乳剂，其pAg已被调节至涂覆前的9.0和10.5之间的pAg值，并显影所述曝光的照相卤化银材料在显影成核剂存在下在表面显影剂中具有促进对卤化银吸附的基团。已经发现，在本发明的一个具体实施方案中，显影成核量的具有7-羟基-s-三唑并 - [1,5-a] - 嘧啶基的肼化合物作为促进对卤化银吸附的基团是非常有用。

4. 发明授权

US5622803A Negatively charged toner for use in electrostatography 失效
标题翻译：用于静电放电的负电荷调色剂
公开(公告)号：US5622803A
公开(公告)日：1997-04-22
申请号：US356236
申请日：1994-12-14
申请人： Serge Tavernier , Werner Op de Beeck , Jean-Marie Dewanckele , Peter Van Rompuy
发明人： Serge Tavernier , Werner Op de Beeck , Jean-Marie Dewanckele , Peter Van Rompuy
IPC分类号： G03G9/08 , G03G9/087 , G03G9/097
CPC分类号： G03G9/08759 , G03G9/0823 , G03G9/08797 , G03G9/09741 , G03G9/0975 , G03G9/09758
摘要： A dry toner powder the toner particles of which are triboelectrically negatively charged and are suited for development of an electrostatic charge pattern, wherein said toner particles contain:(1) at least one triboelectrically negatively chargeable thermoplastic resin serving as binder having a volume resistivity of at least 10.sup.13 .OMEGA.-cm, and(2) at least one resistivity lowering substance being an onium compound having a volume resistivity lower than the volume resistivity of said binder, and said toner particles are free from non-resinous charge-controlling agent(s) providing negative triboelectric chargeability,wherein said substance(s) (2) is (are) capable of lowering the volume resistivity of said binder by a factor of at least 3.3 when present in said binder in a concentration of 5% by weight relative to the weight of said binder, andwherein said toner powder containing toner particles including a mixture of said ingredients (1) and (2) under triboelectric charging conditions is capable of obtaining an absolute median (q/d) charge/diameter value (x) lower than 10 fC/10 .mu.m but not lower than 1 fC/10 .mu.m, and said toner powder under the same triboelectric charging conditions but free from said substance(s) (2) then has an absolute median q/d value (x) at least 50% higher than when said substance(s) (2) is (are) present, and wherein the distribution of the charge/diameter values of the individual toner particles is characterized by a coefficient of variation .nu..ltoreq.0.33.
摘要翻译： PCT No.PCT / EP94 / 01310 Sec。 371日期1994年12月14日第 102（e）日期1994年12月14日PCT 1994年4月25日PCT PCT。 WO94 / 27191 PCT出版物日期1994年11月24日一种其调色剂颗粒为摩擦带电带电并适于显影静电荷图案的干燥调色剂粉末，其中所述调色剂颗粒包含：（1）至少一种用作粘合剂的摩擦带电性带负电荷的热塑性树脂，体积电阻率为至少1013欧姆 - 厘米，和（2）至少一种电阻率降低物质是体积电阻率低于所述粘合剂的体积电阻率的鎓化合物，并且所述调色剂颗粒不含非树脂电荷 - 提供负摩擦带电性的控制剂，其中所述物质（2）当以5％的浓度存在于所述粘合剂中时能够将所述粘合剂的体积电阻率降低至少3.3倍，，并且其中所述调色剂粉末含有包含所述成分（1）和（2）的混合物的调色剂颗粒在摩擦电充电条件能够获得低于10fC /10μm但不低于1fC /10μm的绝对中值（q / d）电荷/直径值（x），并且所述调色剂粉末在相同的摩擦带电条件但没有所述物质（2）的绝对中值q / d值（x）比所述物质（2）存在时高出至少50％，并且其中单个调色剂颗粒的电荷/直径值的特征在于变异系数nu <0.33。

5. 发明授权

US5362620A Photographic material containing a mixture of silver halide emulsions 失效
标题翻译：含有卤化银乳剂混合物的照相材料
公开(公告)号：US5362620A
公开(公告)日：1994-11-08
申请号：US140474
申请日：1993-10-25
申请人： Johan Lamotte , Jean-Marie Dewanckele
发明人： Johan Lamotte , Jean-Marie Dewanckele
IPC分类号： G03C1/035 , G03C1/12 , G03C1/34 , G03C8/06 , G03C8/28 , G03C8/36 , G03C1/00
CPC分类号： G03C1/346 , G03C1/035 , G03C8/06
摘要： The present invention discloses a photographic material comprising on a support a photosensitive layer containing a mixture of silver halide emulsions at least one of which is spectrally sensitized and at least one of which is not spectrally sensitized characterized in that the surface of the silver halide particles of the silver halide emulsion not being spectrally sensitized is loaded with a stabilizer having a mercapto group or the tautomeric thione group thereof such that the surface covered by one molecule of stabilizer is between 10 .ANG..sup.2 and 70 .ANG..sup.2. The loss of speed due to migration of the spectral sensitizer from the sensitized emulsion to the non sensitized emulsion is reduced and can even be inhibited.
摘要翻译：本发明公开了一种照相材料，其在载体上包含含有卤化银乳剂的混合物的感光层，所述卤化银乳剂的至少一种是光谱增感的，其中至少一种不受光谱增感，其特征在于，卤化银颗粒的表面没有光谱敏化的卤化银乳剂装载有具有巯基或其互变异构硫酮基团的稳定剂，使得被一分子稳定剂覆盖的表面在10埃至2埃到7埃之间。由于迁移而导致的速度损失的光敏剂从致敏乳液到非致敏乳液的降低，甚至可以被抑制。

6. 发明授权

US5283156A Method for making a lithographic printing plate according to the silver salt diffusion transfer process 失效
标题翻译：根据银盐扩散转移法制造平版印刷版的方法
公开(公告)号：US5283156A
公开(公告)日：1994-02-01
申请号：US986072
申请日：1992-12-04
申请人： Marcel Monbaliu , Rene De Keyzer , Jean-Marie Dewanckele , Jos Vaes , Ludo Van Rompuy
发明人： Marcel Monbaliu , Rene De Keyzer , Jean-Marie Dewanckele , Jos Vaes , Ludo Van Rompuy
IPC分类号： G03C8/06 , G03C8/36 , G03F7/06 , G03F7/07 , G03C8/32
CPC分类号： G03C8/06 , G03C8/365 , G03F7/066
摘要： The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a regulator according to one of the formulas as specified in the claims. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
摘要翻译：本发明提供了一种根据银盐扩散转移方法制备平版印刷版的方法，包括以下步骤：将包含在载体上的成像元件成像曝光，所述感光层包含卤化银乳剂和包含物理显影核和在显影剂和卤化银溶剂的存在下使用碱性处理液显影所述成像元件，其特征在于所述显影在根据指定的一种式中的调节剂存在下进行在权利要求中。本发明还提供了一种用于所述方法的成像元件和碱性处理液体。

7. 发明授权

US5665515A Method for obtaining a printing plate according to the silver salt diffusion transfer process 失效
标题翻译：根据银盐扩散转移方法获得印版的方法
公开(公告)号：US5665515A
公开(公告)日：1997-09-09
申请号：US544662
申请日：1995-10-18
申请人： Lode Deprez , Marcel Monbaliu , Jean-Marie Dewanckele
发明人： Lode Deprez , Marcel Monbaliu , Jean-Marie Dewanckele
IPC分类号： G03C8/36 , G03F7/06 , G03F7/07 , G03C8/44 , G03C8/32
CPC分类号： G03F7/066
摘要： The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process using a photographic material comprising on a support a silver halide emulsion layer and a layer containing physical development nuclei comprising the steps of:image-wise exposing said photographic material;developing a thus obtained image-wise exposed photographic material by guiding said image-wise exposed photographic material through an alkaline processing liquid comprising a hydrophobizing agent, in 15s or less andsubsequently guiding a thus obtained developed photographic material through a stabilizing liquid;characterized in that said stabilizing liquid comprises a compound having a mercapto-group having a pK.sub.a of 4.5 or less.
摘要翻译：本发明提供根据银盐扩散转移方法制备平版印刷版的方法，该方法使用包含载体上的卤化银乳剂层和含有物理显影核的层的照相材料，该方法包括以下步骤：将所述照相材料; 通过引导所述成像曝光的照相材料通过包含疏水化剂的碱性处理液在15秒或更短时间内，然后引导如此获得的显影的照相材料通过稳定液体，从而显影如此获得的图像曝光的照相材料; 其特征在于，所述稳定液体包含具有4.5K以下的pKa的巯基的化合物。

8. 发明授权

US5645971A Method for making a lithographic printing plate according to the silver salt diffusion transfer process 失效
标题翻译：根据银盐扩散转移法制造平版印刷版的方法
公开(公告)号：US5645971A
公开(公告)日：1997-07-08
申请号：US666053
申请日：1996-06-20
申请人： Ludo Van Rompuy , Rene De Keyzer , Jean-Marie Dewanckele , Marcel Monbaliu , Jos Vaes
发明人： Ludo Van Rompuy , Rene De Keyzer , Jean-Marie Dewanckele , Marcel Monbaliu , Jos Vaes
IPC分类号： G03C5/38 , G03C8/36 , G03F7/07 , G03C8/32 , G03C8/06
CPC分类号： G03C5/383 , G03C8/365 , G03F7/07
摘要： The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising a silver halide emulsion and an image receiving layer containing physical development nuclei and developing said imaging element in the presence of developing agent(s) and silver halide solvent(s) using an alkaline processing liquid characterized in that said development is carried out in the presence of a meso-ionic compound. The present invention further provides an imaging element and alkaline processing liquid for use in said method.
摘要翻译：本发明提供了一种根据银盐扩散转移方法制备平版印刷版的方法，包括以下步骤：将包含在载体上的成像元件成像曝光，所述感光层包含卤化银乳剂和包含物理显影核和在显影剂和卤化银溶剂的存在下使用碱性处理液显影所述成像元件，其特征在于所述显影在内消旋离子化合物的存在下进行。本发明还提供了一种用于所述方法的成像元件和碱性处理液体。

9. 发明授权

US5632930A Class of stabilizing compounds for phosphor screens 失效
标题翻译：荧光屏稳定化合物类别
公开(公告)号：US5632930A
公开(公告)日：1997-05-27
申请号：US654612
申请日：1996-05-29
申请人： Paul Leblans , Paul Lardon , Jean-Marie Dewanckele
发明人： Paul Leblans , Paul Lardon , Jean-Marie Dewanckele
IPC分类号： C09K11/02 , G21K4/00 , C09K11/61 , G01T1/10
CPC分类号： G21K4/00 , C09K11/025 , G21K2004/06 , G21K2004/08
摘要： A phosphor screen is provided, characterised in that said screen comprises at least one organozinc compound corresponding to the following general formula I: ##STR1## wherein: A=either carbon or phosphorusY=--OR.sup.6, --NR.sup.7 R.sup.8, alkyl or aryl, wherein R.sup.6, R.sup.7 and R.sup.8 each independently represent a substituted or unsubstituted alkyl- or aryl group, or wherein R.sup.7 and R.sup.8 together form a ringstructuren=1 when A is carbonn=2 when A is phosphorus.
摘要翻译：提供荧光屏，其特征在于所述屏幕包含至少一种对应于以下通式I的有机锌化合物：其中：A =碳或磷Y = -OR6，-NR7R8，烷基或芳基，其中 R6，R7和R8各自独立地表示取代或未取代的烷基或芳基，或当A是磷时，当A为碳时n = 2时，R7和R8一起形成环结构n = 1。

10. 发明授权

US5569576A Photographic materials containing polymeric compounds 失效
标题翻译：含有聚合物的摄影材料
公开(公告)号：US5569576A
公开(公告)日：1996-10-29
申请号：US395112
申请日：1995-02-27
申请人： Jean-Marie Dewanckele , Geert Vercruysse , Ralf B uscher
发明人： Jean-Marie Dewanckele , Geert Vercruysse , Ralf B uscher
IPC分类号： G03C5/26 , C07C323/12 , C07C323/44 , C08G65/34 , G03C1/00 , G03C1/035 , G03C1/04 , G03C1/043 , G03C1/12 , G03C1/295 , G03C1/46 , G03C5/30 , G03C7/00 , G03C7/26 , G03C7/392 , G03C7/407
CPC分类号： C07C323/12 , C07C323/44 , C08G65/34 , G03C1/043
摘要： A photographic material is disclosed containing on at least one side of the support at least one light-sensitive silver halide emulsion layer characterised in that the light-sensitive layer and/or at least one non-light sensitive layer in water-permeable relationship with the light-sensitive layer comprises at least one compound having the general formula (I)R[O--CH.sub.2 --CH.sub.2 --S--(LINK.sup.1 --S).sub.x --CH.sub.2 --CH.sub.2 --O--(LINK.sup.2)].sub.y --OR (I)wherein each of LINK.sup.1 and LINK.sup.2 which may be the same or different represents a divalent linking group; R represents H, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or an acyl group; x is 0, 1 or 2, and y varies from 2 to 20.
摘要翻译：公开了一种照相材料，其在载体的至少一侧上含有至少一种感光卤化银乳剂层，其特征在于，所述感光层和/或至少一种不透水的非光敏层与光敏层包含至少一种具有通式（I）R [O-CH 2 -CH 2 -S-（LINK1-S）x-CH2-CH2-O-（LINK2）] y-OR（I）的化合物，其中可以相同或不同的LINK1和LINK2中的每一个表示二价连接基团; R表示H，取代或未取代的烷基，取代或未取代的芳基或酰基; x为0,1或2，y为2〜20。

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