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1. 发明授权

US5591850A o-Hydroxyphenyl-s-triazines 失效
标题翻译：邻羟基苯基-s-三嗪
公开(公告)号：US5591850A
公开(公告)日：1997-01-07
申请号：US340952
申请日：1994-11-17
申请人： Jean-Luc Birbaum , J urgen Kaschig , Dieter Reinehr , Manfred Rembold , Andr e Schmitter , Helmut Luther , Bernd Herzog , Dietmar H uglin
发明人： Jean-Luc Birbaum , J urgen Kaschig , Dieter Reinehr , Manfred Rembold , Andr e Schmitter , Helmut Luther , Bernd Herzog , Dietmar H uglin
IPC分类号： C07D251/02 , A61K8/00 , A61K8/42 , A61K8/49 , A61K8/85 , A61Q17/04 , C07D251/12 , C07D251/24 , C08K5/3492 , C08L67/00 , C09K3/00 , D06P1/642 , D06P3/52 , C07D251/00
CPC分类号： C08K5/3492 , A61K8/4966 , A61Q17/04 , C07D251/24 , D06P1/6426
摘要： o-Hydroxyphenyl-s-triazines are described which contain at least two alkoxyphenyl substituents. They have the formula (1).The compounds according to the invention are suitable as stabilizers for textile fiber materials, in particular polyester fiber materials, and for organic polymers. Furthermore, they are suitable for use as sunscreens in cosmetic preparations.
摘要翻译：描述了含有至少两个烷氧基苯基取代基的邻羟基苯基-s-三嗪。他们有公式（1）。根据本发明的化合物适用于纺织纤维材料，特别是聚酯纤维材料和有机聚合物的稳定剂。此外，它们适合用作化妆品制剂中的防晒剂。

2. 发明授权

US5760111A o-Hydroxyphenyl-s-triazines 失效
标题翻译：邻羟基苯基-s-三嗪
公开(公告)号：US5760111A
公开(公告)日：1998-06-02
申请号：US715056
申请日：1996-09-17
申请人： Jean-Luc Birbaum , Jurgen Kaschig , Dieter Reinehr , Manfred Rembold , Andre Schmitter , Helmut Luther , Bernd Herzog , Dietmar Huglin
发明人： Jean-Luc Birbaum , Jurgen Kaschig , Dieter Reinehr , Manfred Rembold , Andre Schmitter , Helmut Luther , Bernd Herzog , Dietmar Huglin
IPC分类号： C07D251/02 , A61K8/00 , A61K8/42 , A61K8/49 , A61K8/85 , A61Q17/04 , C07D251/12 , C07D251/24 , C08K5/3492 , C08L67/00 , C09K3/00 , D06P1/642 , D06P3/52 , C08K5/3495
CPC分类号： C08K5/3492 , A61K8/4966 , A61Q17/04 , C07D251/24 , D06P1/6426
摘要： o-Hydroxyphenyl-s-triazines are described which contain at least two alkoxyphenyl substituents. They have the formula (1). The compounds according to the invention are suitable as stabilizers for textile fiber materials, in particular polyester fiber materials, and for organic polymers. Furthermore, they are suitable for use as sunscreens in cosmetic preparations.
摘要翻译：描述了含有至少两个烷氧基苯基取代基的邻羟基苯基-s-三嗪。他们有公式（1）。根据本发明的化合物适用于纺织纤维材料，特别是聚酯纤维材料和有机聚合物的稳定剂。此外，它们适合用作化妆品制剂中的防晒剂。

3. 发明授权

US06384284B1 Biphenyl compounds substituted by camphor or hydantoin derivatives as sunscreen compositions 有权
标题翻译：由樟脑或乙内酰脲衍生物取代的联苯化合物作为防晒组合物
公开(公告)号：US06384284B1
公开(公告)日：2002-05-07
申请号：US09806358
申请日：2001-03-29
申请人： Rudolf Zink , Dieter Reinehr , Helmut Luther , Bernd Herzog
发明人： Rudolf Zink , Dieter Reinehr , Helmut Luther , Bernd Herzog
IPC分类号： C07C4900
CPC分类号： C07C309/24 , A61K8/35 , A61K8/466 , A61K8/4946 , A61Q17/04 , C07C45/74 , C07C49/683
摘要： A description is given of diphenyl compounds of formula wherein R is a camphor or hydantoin derivative; and R1 is hydrogen; or C1-C5alkyl. These compounds are suitable as light stabilizers in cosmetic, pharmaceutical and veterinary formulations.
摘要翻译：给出了二烷基化合物的描述，R是樟脑或乙内酰脲衍生物; 并且R 1是氢; 或C1-C5烷基。这些化合物在化妆品，药物和兽药制剂中适合作为光稳定剂。

4. 发明授权

US6111103A Diresorcinyl-alkoxy- and -aryloxy-s-triazines 失效
标题翻译：二氧化物 - 烷氧基 - 和 - 芳氧基-s-三嗪
公开(公告)号：US6111103A
公开(公告)日：2000-08-29
申请号：US287029
申请日：1999-04-06
申请人： Thomas Ehlis , Elek Borsos , Helmut Luther , Bernd Herzog
发明人： Thomas Ehlis , Elek Borsos , Helmut Luther , Bernd Herzog
IPC分类号： A61K8/00 , A61K8/49 , A61Q17/04 , C07D251/22 , C07D251/26 , C07D405/12 , C08K5/3492 , C09K3/00 , C09K15/30
CPC分类号： C07D405/12 , A61K8/4966 , A61Q17/04 , C07D251/22
摘要： The invention relates to diresorcinyl-alkoxy- and -aryloxy-triazines of the formula ##STR1## in which R.sub.1 is C.sub.2 -C.sub.30 alkyl; C.sub.2 -C.sub.30 alkenyl; unsubstituted or C.sub.1 -C.sub.5 alkyl-mono- or polysubstituted C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.5 alkoxy-C.sub.1 -C.sub.12 alkyl; amino-C.sub.1 -C.sub.12 alkyl; C.sub.1 -C.sub.5 monoalkylamino-C.sub.1 -C.sub.12 alkyl; C.sub.1 -C.sub.5 dialkylamino-C.sub.1 -C.sub.12 alkyl; a radical of the formula ##STR2## R.sub.2, R.sub.3 and R.sub.4, independently of one another, are hydrogen, hydroxyl, C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.30 alkenyl,R.sub.5 is hydrogen; or C.sub.1 -C.sub.5 alkyl;m.sub.1 is 0 or 1; andn.sub.1 is 1 to 5.The novel compounds are suitable as cosmetic UV-A absorbers.
摘要翻译：本发明涉及下式的二缩水甘油基 - 烷氧基 - 和 - 芳氧基 - 三嗪，其中R 1是C 2 -C 30烷基; C2-C30烯基; 未取代的或C 1 -C 5烷基 - 单取代或多取代的C 5 -C 12环烷基，C 1 -C 5烷氧基-C 1 -C 12烷基; 氨基-C 1 -C 12烷基; C 1 -C 5单烷基氨基-C 1 -C 12烷基; C 1 -C 5二烷基氨基-C 1 -C 12烷基; 式R2，R3和R4彼此独立的基团是氢，羟基，C 1 -C 30烷基，C 1 -C 30烯基，R 5是氢; 或C 1 -C 5烷基; m1为0或1; n1为1〜5。新化合物适合作为化妆品UV-A吸收剂。

5. 发明授权

US5688995A o-Hydroxyphenyl-s-triazines 失效
标题翻译：邻羟基苯基-s-三嗪
公开(公告)号：US5688995A
公开(公告)日：1997-11-18
申请号：US649940
申请日：1996-05-15
申请人： Helmut Luther , Dietmar Huglin , Bernd Herzog
发明人： Helmut Luther , Dietmar Huglin , Bernd Herzog
IPC分类号： A61K8/00 , A61K8/42 , A61K8/49 , A61Q17/04 , C07D251/24 , C08K5/3477 , C08K5/3492 , C09K3/00 , C07C229/00
CPC分类号： A61K8/4966 , A61Q17/04 , C07D251/24
摘要： A description is given of o-hydroxyphenyl-s-triazines containing at least two alkoxyphenyl-substituents. They have the formula (1). The compounds according to the invention are particularly suitable as sunscreen agents in cosmetic preparations.
摘要翻译：给出了含有至少两个烷氧基苯基取代基的邻羟基苯基-s-三嗪的描述。他们有公式（1）。根据本发明的化合物特别适合作为化妆品制剂中的防晒剂。

6. 发明授权

US06235271B1 UV-protection formulation 失效
标题翻译：紫外线防护配方
公开(公告)号：US06235271B1
公开(公告)日：2001-05-22
申请号：US09122554
申请日：1998-07-24
申请人： Helmut Luther , Albert Stehlin , Bernd Herzog
发明人： Helmut Luther , Albert Stehlin , Bernd Herzog
IPC分类号： A61K742
CPC分类号： A61K8/29 , A61K8/0241 , A61K8/0279 , A61K8/42 , A61K8/4946 , A61K8/496 , A61K8/4966 , A61K8/73 , A61K8/8147 , A61K8/8176 , A61K2800/412 , A61K2800/652 , A61K2800/654 , A61Q17/04 , Y10S514/937
摘要： The present invention provides, as a first aspect, a sun protection agent, which is especially suitable for use in pharmaceutical or cosmetic applications, comprising a) a micronized organic UV absorber; and one, or preferably both of; b) an oil-soluble, non-micronized UV absorber and/or an inorganic micropigment; and c) a polymeric hollow sphere additive and/or a polymer selected from xanthan and/or polyvinylpyrrolidone. The present invention also provides a sunscreen composition comprising A) 0.1 to 15%, preferably 0.5 to 10% by weight, based on the total composition of a sun screen agent according to the present invention; and B) a cosmetically acceptable carrier.
摘要翻译：作为第一方面，本发明提供了特别适用于药物或化妆品应用的防晒剂，其包括：a）微粉化有机UV吸收剂; 和b）油溶性非微粉化紫外线吸收剂和/或无机微胶囊中的一种，或优选两者; 和c）聚合物中空球体添加剂和/或选自黄原胶和/或聚乙烯吡咯烷酮的聚合物。本发明还提供防晒组合物，其包含A）基于总组合物的0.1至15重量％，优选0.5至10重量％根据本发明的防晒剂; 和B）美容上可接受的载体。

7. 发明授权

US5955060A Bis(resorcinyl)triazines useful as sunscreens in cosmetic preparations 失效
标题翻译：双（间苯二酚）三嗪可用作化妆品制剂中的防晒剂
公开(公告)号：US5955060A
公开(公告)日：1999-09-21
申请号：US752294
申请日：1996-11-19
申请人： Dietmar Huglin , Elek Borsos , Helmut Luther , Bernd Herzog , Frank Bachmann
发明人： Dietmar Huglin , Elek Borsos , Helmut Luther , Bernd Herzog , Frank Bachmann
IPC分类号： A61K8/00 , A61K8/49 , A61K8/58 , A61K8/86 , A61K8/89 , A61K31/53 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C07D251/22 , C07D251/24 , C07D403/04 , C07F7/08 , C08L83/04 , C09K3/00 , A61K7/42
CPC分类号： C07F7/0854 , A61K8/4966 , A61K8/585 , A61Q17/04 , C07D251/22 , C07D251/24 , C07D403/04
摘要： There are described bis(resorcinyl)triazines of the formula ##STR1## The compounds according to the invention are particularly suitable as sunscreens in cosmetic, pharmaceutical and veterinary medicinal preparations.
摘要翻译：描述了下式的双（间苯二酚）三嗪。根据本发明的化合物特别适用于化妆品，药用和兽用药物制剂中的防晒剂。

8. 发明授权

US6015575A Liposomogenic UV absorbers 失效
标题翻译：脂质体紫外线吸收剂
公开(公告)号：US6015575A
公开(公告)日：2000-01-18
申请号：US913531
申请日：1997-09-15
申请人： Helmut Luther , Dietmar Huglin , Bernd Herzog
发明人： Helmut Luther , Dietmar Huglin , Bernd Herzog
IPC分类号： A61K8/00 , A61K8/14 , A61K8/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q17/04 , C07C69/734 , C07C219/06 , C07C219/10 , C07C229/12 , C07C235/34 , C07D249/20 , C07D251/54 , C07D251/70 , C09K3/00
CPC分类号： C07D251/70 , A61K8/14 , A61K8/37 , A61K8/4966 , A61Q17/04 , B82Y30/00 , B82Y5/00 , C07C219/10 , C07C229/12 , C07C235/34 , C07C69/734 , C07D249/20 , A61K2800/57
摘要： There are described liposomogenic UV absorbers, comprising a hydrophilic head group (.dbd.Z), a spacer (.dbd.W), a UV chromophore (Q) having an absorption in the range from 285 to 400 nm and at least one hydrophobic tail group (.dbd.A) of the formula (1), in which A.sub.1 and A.sub.2, independently of one another, are a hydrophobic radical, Q is a UV chromophore, W is an organic radical, Z.sub.1 and Z.sub.2, independently of one another, are a hydrophilic radical, n.sub.1 and n.sub.2, independently of one another, are a number from 0 to 4, n.sub.1 =n.sub.2 =0 not being additionally included, p is 1 or 2, q is a number from 0 to 3, r.sub.1 is 1 or 2, r.sub.2 is 0 or 1, and s.sub.1 is a number from 1 to 3. The liposomogenic UV absorbers according to the invention are preferably used as sunscreen agents in cosmetic preparations. They are capable of self-organization into bimolecular layers, and can thereby penetrate into the stratum corneum to a high extent and behave there in an extremely wash-resistant manner. ##STR1##
摘要翻译： PCT No.PCT / EP96 / 00959 Sec。 371日期：1997年9月15日 102（e）1997年9月15日PCT PCT 1996年3月7日PCT公布。公开号WO96 / 29302 PCT。日本1996年9月26日描述了脂质体生成紫外线吸收剂，其包含亲水性头基（= Z），间隔物（= W），紫外发色团（Q），其吸收范围为285-400nm，至少一个其中A1和A2彼此独立地是疏水性基团，Q是UV发色团，W是有机基团，Z 1和Z 2彼此独立地是通式（1）的疏水性尾基（= A）是亲水基团，n1和n2彼此独立地为0至4的数，n1 = n2 = 0，不包括其中，p为1或2，q为0至3的数，r1为 1或2，r2为0或1，s1为1至3的数。根据本发明的脂质体生成的UV吸收剂优选用作化妆品制剂中的防晒剂。它们能够自组织成双分子层，并且因此可以高度渗透到角质层中，并以非常耐洗涤的方式在那里表现。

9. 发明授权

US11103733B2 Water based concentrated product forms of oil-soluble organic UV absorbers 有权
公开(公告)号：US11103733B2
公开(公告)日：2021-08-31
申请号：US12664666
申请日：2008-06-30
申请人： Stefan Müller , Brigitte Lindemann , Bernd Herzog
发明人： Stefan Müller , Brigitte Lindemann , Bernd Herzog
IPC分类号： A61Q17/04 , A61K8/11 , A61K8/58 , A61K8/37 , A61K8/35 , A61K8/44 , A61K8/81 , A61K8/893 , A61K8/49
摘要： The instant invention refers to the use of a concentrated aqueous polymer dispersion with an average particle size of less than 1000 nm comprising (a) a polymer carrier prepared by heterophase radical polymerization of at least one ethylenically unsaturated monomer in the presence of (b) an oil-soluble organic UV absorber selected from the class of p-aminobenzoic acid derivatives; salicylic acid derivatives; benzophenone derivatives; diphenyl acrylate derivatives; benzofuran derivatives; polymeric UV absorbers, comprising one or more organosilicon radicals; cinnamic acid derivatives; camphor derivatives; s-triazine derivatives; trianilino-s-triazine derivatives; menthyl anthranilates; and benzotriazole derivatives; wherein the weight ratio of the oil-soluble organic UV absorber (b) to polymer carrier (a) is greater than 50 parts UV absorber per 100 parts of carrier; for the protection of human and animal hair and skin against the damaging effect of UV radiation. The concentrated aqueous polymer dispersions show unexpectedly high sunscreen effects and a positive skin feeling.

10. 发明授权

US07790769B2 Merocyanine derivatives 有权
标题翻译：梅花菁衍生物
公开(公告)号：US07790769B2
公开(公告)日：2010-09-07
申请号：US12086647
申请日：2006-12-11
申请人： Barbara Wagner , Astrid Walther , Bernd Herzog
发明人： Barbara Wagner , Astrid Walther , Bernd Herzog
IPC分类号： A61K31/136 , C07C211/26
CPC分类号： C07C317/44 , C07C255/31 , C07C2601/16
摘要： Disclosed are merocyanine derivatives of formula (1), wherein R1 and R2 independently from each other are branched C4-C22alkyl; or branched C4-C12 alkenyl; R3 and R4 independently from each other are cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; wherein at least one of R3 and R4 is cyano; R5 and R6 independently from each other are hydrogen; C1-C6alkyl; C5-C8cycloalkyl which may be substituted by one or more than one C1-C4alkyl; and R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation.
摘要翻译：公开了式（1）的部花青衍生物，其中R 1和R 2彼此独立地为支链C 4 -C 22烷基; 或支链C 4 -C 12烯基; R 3和R 4彼此独立地是氰基; COR7，COOR7; CONR7R8; SO2（C6-C12）芳基; C2-C12烷-1-烯基; C 3 -C 12环烯-1-烯基; C2-C12alk-1-inyl; C 2 -C 12杂烷基; C3-C5杂环烷基; C6-C10芳基; 或C 1 -C 9杂芳基; 其中R 3和R 4中的至少一个是氰基; R5和R6彼此独立地是氢; C1-C6烷基; 可被一个或多于一个C 1 -C 4烷基取代的C 5 -C 8环烷基; 并且R 7和R 8彼此独立地是氢; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; - （CH 2）t COOH; C7-C12芳烷基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C6-C10芳基; C1-C9杂芳基。这些化合物可用作紫外线吸收剂，用于保护人体毛发和皮肤免受紫外线辐射的破坏作用。

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