专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US5329017A Vinylsulfone nor-pyrethric compounds 失效
标题翻译：乙烯基砜除虫菊酯化合物
公开(公告)号：US5329017A
公开(公告)日：1994-07-12
申请号：US51177
申请日：1993-04-22
申请人： Didier Babin , Jean-Pierre Demoute , Jean Tessier
发明人： Didier Babin , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07C69/743 , C07D327/04
CPC分类号： C07C69/743
摘要： Novel all possible stereoisomers and mixtures thereof of vinylsulfone nor-pyrethric compounds of the formula ##STR1## wherein R.sub.a is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms unsubstituted or substituted with at least one functional group, n is 0, 1 or 2, R.sub.b is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms, all unsubstituted or unsubstituted with at least one functional group or R.sub.a and R.sub.b together with the C-S-C to which they are attached form ##STR2##
摘要翻译：其中R a选自1至18个碳原子的烷基，2至18个碳原子的烯基和炔基，3个环烷基的全部可能的立体异构体及其混合物，至18个碳原子，4至18个碳原子的环烷基烷基和未被取代或被至少一个官能团取代的6至14个碳原子的芳基，n为0,1或2，Rb选自1至 2至18个碳原子的烯基和炔基，3至18个碳原子的环烷基，4至18个碳原子的环烷基烷基和6至14个碳原子的芳基，全部未取代或未取代，至少有一个官能团或Ra 和Rb与它们所连接的CSC一起形成

2. 发明授权

US5135951A 3-(2-cyano-2-halo-ethenyl)-2,2-dimethyl-cyclopropanecarboxylates 失效
标题翻译： 3-（2-氰基-2-甲基-2-戊烯）-2,2-二甲基 - 环丙烷氧基甲酸酯
公开(公告)号：US5135951A
公开(公告)日：1992-08-04
申请号：US661383
申请日：1991-02-26
申请人： Didier Babin , Marc Benoit , Jean-Pierre Demoute , Jean Tessier
发明人： Didier Babin , Marc Benoit , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07F7/10 , A01N53/00 , A01N53/06 , A01N53/08 , A01N55/10 , C07C253/30 , C07C255/31 , C07C255/39 , C07C255/55 , C07C319/20 , C07C323/16 , C07F7/12
CPC分类号： A01N53/00 , C07C255/31
摘要： All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein the cyclopropane copula has (1R, cis) or (1R, trans) structure, the geometry of the double bond carried by the 3-carbon atom is (E) or (Z), X is halogen, Z is selected from the group consisting of hydrogen, methyl, --CN and --C.tbd.CH, n is an integer from 1 to 5, m represents the number 5-n, Y is selected from the group consisting of hydrogen, halogen, --CH.sub.2 --CN, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms unsubstituted or substituted with at least one halogen, --CN, --COOAlk, --COAlk, --(CH.sub.2).sub.m' OAlk, --(CH.sub.2).sub.m' --S--Alk, --(CH.sub.2).sub.m' --N(Alk).sub.2, --Si(Alk).sub.3, --OAr and (CH.sub.2).sub.m' --Ar, m' is 0, 1,2,3 or 4, Alk is optionally unsaturated alkyl of 1 to 8 carbon atom unsubstituted or substituted with at least one halogen and Ar is aryl of 6 to 14 carbon atoms and the Ys identical or different may be on any position of the phenyl having pesticidal properties.
摘要翻译：式（I）化合物的所有立体异构体形式及其混合物，其中环丙烷共聚物具有（1R，顺式）或（1R，反式）结构，由3-碳原子携带的双键的几何形状为（E ）或（Z）中，X为卤素，Z选自氢，甲基，-CN和-C 3BOND CH，n为1〜5的整数，m为5〜n的数，Y为由氢，卤素，-CH 2 -CN，-OH，未取代或被至少一个卤素，-CN，-COOAlk，-COAlk， - （CH 2）m'取代或被取代的碳原子数1〜 OAlk， - （CH 2）m'-S-Alk， - （CH 2）m'-N（Alk）2，-Si（Alk）3，-OAr和（CH 2）m'-Ar，m' ，2,3或4，Alk任选是未被取代或被至少一个卤素取代的1至8个碳原子的不饱和烷基，Ar是6至14个碳原子的芳基，并且Y相同或不同可以在苯基的任何位置具有杀虫性。

3. 发明授权

US5089511A Insecticides and nematicides 失效
标题翻译：杀虫剂和杀虫剂
公开(公告)号：US5089511A
公开(公告)日：1992-02-18
申请号：US467040
申请日：1990-01-18
申请人： Werner Bonin , Jean-Pierre Demoute , Jean Tessier
发明人： Werner Bonin , Jean-Pierre Demoute , Jean Tessier
IPC分类号： C07D209/48 , A01N53/00 , A01N53/02 , A23K1/16 , B01J27/122 , C07B37/04 , C07B61/00 , C07C67/343 , C07C69/743 , C07C235/06 , C07C253/30 , C07C255/37 , C07C255/39 , C07C327/44 , C07D213/64 , C07D213/647 , C07D213/68 , C07D233/72 , C07D307/45 , C07D309/38 , C07F7/18
CPC分类号： C07D213/647 , A01N53/00 , A23K20/00
摘要： A process for the preparation of trifluoromethylvinyl compounds in all their possible steroisomeric forms and mixtures thereof comprising reacting a salt of trifluoroacetic acid with a halovinyl compound in the presence of a cuprous salt to obtain the same stero-specific compound and all possible stero-isomeric forms and mixtures thereof of 1R, trans compounds of the formula ##STR1## wherein R is an alcohol residue used in pyrethrinoid series, or an alcohol residue capable of blocking the acid function, and Z is aryl or haloaryl and the double bond has Z geometry having pesticide activity.

4. 发明授权

US4554361A Process for the preparation of a bicyclic lactone through a sulfonated derivative 失效
标题翻译：通过磺化衍生物制备双环内酯的方法
公开(公告)号：US4554361A
公开(公告)日：1985-11-19
申请号：US517794
申请日：1983-07-27
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07B61/00 , C07D307/33 , C07D307/60 , C07D307/93 , C07D307/77
CPC分类号： C07D307/33 , C07D307/60 , C07D307/93
摘要： A novel process for the preparation of sulfonic acid esters containing a lactonic ring comprising compounds in the trans form in the 4- and 5-positions having (4SR,5RS), (4S,5R) or (4R,5S) configuration of the formula ##STR1## wherein Z is selected from the group consisting of alkyl of 1 to 4 carbon atoms and cycloalkyl and monocyclic aryl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and nitro and R is organic residue of an optionally chiral alcohol of the formula ROH and a process using the compounds of formula I to prepare compounds of (1RS, 4RS, 5SR), (1S, 4S, 5R) or (1R, 4R, 5S) configuration of the formula ##STR2## wherein X is selected from the group consisting of hydrogen and R useful for the preparation of insecticidally active esters.
摘要翻译：一种制备含有内酯环的磺酸酯的新方法，其包含在4-和5-位的反式形式的具有式（4SR，5RS），（4S，5R）或（4R，5S）构型的式其中Z选自1至4个碳原子的烷基，环烷基和任选被至少一个由1至4个碳原子的烷基取代的单环芳基，1至4的烷氧基，碳原子，卤素和硝基，R是式ROH的任选手性醇的有机残基，以及使用式I化合物制备（1RS，4RS，5SR），（1S，4S，5R）或（ 1R，4R，5S）构型，其中X选自用于制备杀虫活性酯的氢和R。

5. 发明授权

US4421928A 4-Methyl-3-formyl-pentanoic acid esters 失效
标题翻译： 4-甲基-3-甲酰基 - 戊酸酯
公开(公告)号：US4421928A
公开(公告)日：1983-12-20
申请号：US352259
申请日：1982-02-25
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/67 , C07C51/00 , C07C62/16 , C07C67/00 , C07C67/313 , C07C67/347 , C07C69/708 , C07D307/33 , C07C69/716
CPC分类号： C07D307/33 , C07C62/16
摘要： Novel 4-methyl-3-formyl-pentanoic acid derivative of the formula ##STR1## wherein Hal is a halogen, R.sub.1 is alkyl of 1 to 12 carbon atoms and A and B are .dbd.0 or A is halogen and B is --OR.sub.2 and R.sub.2 is alkyl of 1 to 12 carbon atoms, their preparation and their use as intermediates.
摘要翻译：具有式Ia的新型4-甲基-3-甲酰基 - 戊酸衍生物，其中Hal是卤素，R1是1-12个碳原子的烷基，A和B是= 0或A是卤素，B是-OR2 并且R 2是1至12个碳原子的烷基，它们的制备及其作为中间体的用途。

6. 发明授权

US4281182A Novel lactones of cis 2,2-dimethyl-cyclopropane-1-carboxylic acid and their use 失效
标题翻译：顺式2,2-二甲基 - 环丙烷-1-羧酸的新型内酯及其用途
公开(公告)号：US4281182A
公开(公告)日：1981-07-28
申请号：US27654
申请日：1979-04-06
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
IPC分类号： C07C61/40 , C07C51/00 , C07C51/09 , C07C61/35 , C07C62/02 , C07C67/00 , C07D307/93
CPC分类号： C07D307/93 , C07C62/02
摘要： Novel lactones of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 when identical are selected from the group consisting of chlorine and bromine and when at least two are different, are selected from the group consisting of fluorine, chlorine and bromine and a novel process for their preparation and a process for the preparation of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR2## The acids of formula IV are useful to prepare esters of elevated insecticidal activity.

7. 发明授权

US4224227A Novel cyclopropane carboxylic acid esters 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4224227A
公开(公告)日：1980-09-23
申请号：US18166
申请日：1979-03-07
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/74 , A01N33/00 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/08 , A01P3/00 , A23K1/16 , A61K31/215 , A61K31/34 , A61K31/40 , A61K35/14 , A61P31/04 , C07C20060101 , C07C51/00 , C07C51/363 , C07C53/50 , C07C61/04 , C07C61/15 , C07C67/00 , C07C69/743 , C07C253/00 , C07C255/39 , C07D209/48 , C07D209/49 , C07D307/42 , C07D307/45 , C07D307/54 , C07D317/54 , G01G13/295 , A01N9/28
CPC分类号： C07D209/49 , A01N53/00 , C07C255/00 , C07C61/15 , C07D307/42 , Y10S514/949
摘要： Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.
摘要翻译：新的式（I）的环丙烷羧酸酯，其中X 1选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3选自的氯，溴和碘，R选自和任选被至少一个由1至4个碳原子的烷基取代的苄基， 2至6个碳原子的烯氧基，2至6个碳原子的链烯氧基，4至8个碳原子的链二烯基，亚甲二氧基，苄基和卤素，R1选自氢和甲基，R2选自单环芳基和-CH 2 -C 3 CH 3，R 3是具有至少一个双键的2至6个碳原子的脂族基，R 4选自氢，-CN和-C 3位CH，R 5选自由氯和甲基组成 n为0,1或2，R6，R7，R8和R9分别选自氢，氯和甲基，S / I表示该环可为具有杀虫性质的芳香族二氢或四氢，以及一个他们准备的过程。

8. 发明授权

US5164409A Pyrroles possessing insecticidal activity 失效
标题翻译： PYRROLES POSSESSING INSECTICIDAL活动
公开(公告)号：US5164409A
公开(公告)日：1992-11-17
申请号：US661399
申请日：1991-02-26
申请人： Marc Benoit , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
发明人： Marc Benoit , Jacques Demassey , Jean-Pierre Demoute , Jean Tessier
IPC分类号： A01N53/00 , A01N53/04 , C07D207/32 , C07D207/333
CPC分类号： C07D207/333 , A01N53/00
摘要： All possible stereoisomers and mixtures of a compound of the formula ##STR1## wherein X and Y are different and are selected from the group consisting of hydrogen, halogen, --CN, alkyl and haloalkyl of 1 to 8 carbon atoms and phenyl optionally substituted by at least one member of the group consisting of halogen and alkyl and alkoxy of 1 to 8 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, methyl, --CN and ethynyl, ##STR2## A and B are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms and the --CF.sub.3 is in the 2-, 4- or 5-position of the pyrrole ring having pesticidal activity.
摘要翻译：式（I）化合物的所有可能的立体异构体和混合物，其中X和Y不同，并且选自氢，卤素，-CN，具有1至8个碳原子的烷基和卤代烷基，以及任选的苯基被至少一个由卤素和1至8个碳原子的烷基和烷氧基组成的组取代，R 1选自氢，甲基，-CN和乙炔基，A和B分别选自由氢，卤素，碳原子数1〜8的烷基和碳原子数为6〜14的芳基构成的基团，在具有杀虫活性的吡咯环的2-，4-或5-位。

9. 发明授权

US5026862A Process for the preparation of 1.R, cis cyclopropane di-carboxylic acid derivatives 失效
标题翻译：制备1.R，顺式环丙烷二羧酸衍生物的方法
公开(公告)号：US5026862A
公开(公告)日：1991-06-25
申请号：US416718
申请日：1989-10-03
申请人： Jean Tessier , Jean-Pierre Demoute
发明人： Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/743 , A01N53/10 , C07C67/00 , C07C67/343 , C07C67/44 , C07C69/608 , C07C69/747 , C07C253/30 , C07C255/39 , C07C325/00 , C07C327/12 , C07C327/22 , C07F9/6571
CPC分类号： C07F9/657181
摘要： A novel process for the preparation of compounds in all their possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, an easily cleavable derivative of the alcohol R-OH and a residue of an alcohol used in the pyrethrinoid series and when Y is --COOR' or --COSR', W is hydrogen and W is halogen when Y is --COOR' and R' is selected from the group consisting of hydrogen, optionally unsaturated alkyl of 1 to 18 carbon atoms and optionally substituted with at least one functional group, aryl optionally substituted with at least one functional group and heterocycle optionally substituted with at least one functional group and when W is hydrogen, the double bond has Z configuration and when W is halogen, the double bond has the E configuration comprising reacting a compound of the formula ##STR2## wherein R has the above definition with a compound of the formula ##STR3## wherein W and Y have the above definitions and A is alkylene of 1 to 18 carbon atoms attached to the two oxygen atoms fixed on the phosphorus atom to obtain a compound of formula I with the double bond having the Z configuration when W is hydrogen and having the E configuration when W is halogen, the cyclopropane and the carboxyl of Y being in both cases in the cis position with respect to the double bond and novel intermediates.
摘要翻译：一种用于制备其所有可能的式I化合物的化合物的新方法，其中R选自氢，1至18个碳原子的烷基，醇的易裂解衍生物R-OH 和在拟除虫菊酯类中使用的醇的残基，当Y是-COOR'或-COSR'时，W是氢，当Y是-COOR'时W是卤素，R'选自氢，任选不饱和的任选被至少一个官能团取代的芳基和任选被至少一个官能团取代的杂环，当W是氢时，该双键具有Z构型，并且当 W是卤素，双键具有E构型，其包括使式II的化合物其中R具有上述定义与式III的化合物反应，其中W和Y具有上述定义并且A是与固定在磷原子上的两个氧原子连接的1至18个碳原子的亚烷基，以便当W是氢时具有Z构型的双键并且当W是卤素时具有E构型的式I化合物在两种情况下，Y的环丙烷和羧基在双键的顺式位置和新的中间体。

10. 发明授权

US4801723A Intermediates for (1,5) 6,6-Dimethyl-4-Hydroxy-3-oxabicyclo (3,1,0) Hexan-2-one and its ethers 失效
标题翻译：（1,5）6,6-二甲基-4-羟基-3-氧杂双环（3,1,0）己酮-2-酮及其醚的中间体
公开(公告)号：US4801723A
公开(公告)日：1989-01-31
申请号：US36890
申请日：1987-04-10
申请人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
IPC分类号： C07D307/33 , C07D307/60 , C07D307/93 , C07D307/58
CPC分类号： C07D307/60 , C07D307/93
摘要： A process for the preparation of compounds of the (1RS, 4RS, 5SR), (1R, 4R, 5S) or (1S, 4S, 5R) configuration having the formula ##STR1## wherein Y is selected from the group consisting of hydrogen and the organic residue Z of an optionally chiral alcohol of the formula ZOH comprising reacting in the presence of an acid agent 5RS-hydroxy-2,5-dihydrofuran-2-one having the formula ##STR2## either (a) with an achiral alcohol of the formula ZOH to obtain the resulting ether and reacting the latter in an anhydrous medium with an isopropylidene sulfurane of the formula ##STR3## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of optionally substituted monocyclic aromatic groups, isopropyl, groups and tertiary alkyl groups, to obtain a compound of formula I of the (1RS, 4RS, 5SR) configuration and Y is Z and optionally hydrolyzing the latter in acid medium to obtain the compound of formula I wherein Y is hydrogen or (b) with an optically active chiral alcohol of the formula ZOH to obtain a mixture of stereoisomeric ether due to the asymetrical carbon in the 5-position which mixture is rich in one of the two diastereoisomers, separating the diastereoisomeric ethers by physical means and reacting the separated diastereoisomers with the compound of formula II in anhydrous medium to obtain the compound of formula I with (1R, 4R, 5S) or (1S, 4S, 5R) configuration wherein Y is Z and optionally hydrolyzing the latter in an acid media to obtain the compound of formula I wherein Y is hydrogen and novel intermediates. The compounds of formula I where Y is hydrogen are described in French Pat. No. 1,580,474 and are interemediates for diversely substituted cyclopropane carboxylic acids whose esters are may active insecticides.
摘要翻译：制备具有下式的（1RS，4RS，5SR），（1R，4R，5S）或（1S，4S，5R）构型的化合物的方法，其中Y选自氢和式ZOH的任选手性醇的有机残基Z包括在酸式试剂5RS-羟基-2,5-二氢呋喃-2-酮的存在下反应，式（II）与（a）与非手性醇，得到所得的醚，并使其在无水介质中与式III的异丙叉硫烷反应，其中R 1和R 2分别选自任选取代的单环芳基，异丙基，基团和叔烷基，得到（1RS，4RS，5SR）构型的式I化合物，Y为Z，并任选地在酸性介质中水解后者，得到其中Y为氢的式I化合物或（b）与一种光学活性的手性醇由于五位不对称碳在5位上得到立体异构体醚的混合物，该混合物富含两种非对映异构体之一，通过物理方法分离非对映异构体醚，并将分离的非对映异构体与式II化合物在无水（1R，4R，5S）或（1S，4S，5R）构型的式I化合物，其中Y是Z，并任选地在酸性介质中水解后者，得到其中Y是氢的式I化合物，新颖的中间体。其中Y是氢的式I化合物描述于French Pat。为1,580,474，并且是用于各种可取代的环丙烷羧酸的中间体，其酯可以是活性杀虫剂。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式