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1. 发明授权

US4281182A Novel lactones of cis 2,2-dimethyl-cyclopropane-1-carboxylic acid and their use 失效
标题翻译：顺式2,2-二甲基 - 环丙烷-1-羧酸的新型内酯及其用途
公开(公告)号：US4281182A
公开(公告)日：1981-07-28
申请号：US27654
申请日：1979-04-06
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
IPC分类号： C07C61/40 , C07C51/00 , C07C51/09 , C07C61/35 , C07C62/02 , C07C67/00 , C07D307/93
CPC分类号： C07D307/93 , C07C62/02
摘要： Novel lactones of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 when identical are selected from the group consisting of chlorine and bromine and when at least two are different, are selected from the group consisting of fluorine, chlorine and bromine and a novel process for their preparation and a process for the preparation of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR2## The acids of formula IV are useful to prepare esters of elevated insecticidal activity.

2. 发明授权

US4513147A Process for preparing cis-3-(2,2-dihalovinyl)-2,2-dimethylcyclopropanecarboxylic acid 失效
标题翻译：顺式-3-（2,2-二卤代乙烯基）-2,2-二甲基环丙烷羧酸的制备方法
公开(公告)号：US4513147A
公开(公告)日：1985-04-23
申请号：US248719
申请日：1981-03-30
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
IPC分类号： C07C61/40 , C07C51/00 , C07C51/09 , C07C61/35 , C07C62/02 , C07C67/00 , C07D307/93 , C07C69/743
CPC分类号： C07D307/93 , C07C62/02
摘要： Novel lactones of 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 when identical are selected from the group consisting of chlorine and bromine and when at least two are different, are selected from the group consisting of fluorine, chlorine and bromine and a novel process for their preparation and a process for the preparation of cis 2,2-dimethylcyclopropane-1-carboxylic acids of the formula ##STR2##
摘要翻译：选择式I的2,2-二甲基 - 环丙烷-1-羧酸的新型内酯，其中X1，X2和X3当相同时选自氯和溴，并且当至少两个不同时，选择由氟，氯和溴组成的组以及它们制备的新方法和制备式（IV）的顺式2,2-二甲基环丙烷-1-羧酸的方法

3. 发明授权

US4166063A Lactones of 2,2-dimethyl-cyclopropane-1-carboxylic acids 失效
标题翻译： 2,2-二甲基 - 环丙烷-1-羧酸
公开(公告)号：US4166063A
公开(公告)日：1979-08-28
申请号：US914399
申请日：1978-06-12
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
IPC分类号： C07C61/40 , C07C51/00 , C07C51/09 , C07C61/35 , C07C62/02 , C07C67/00 , C07D307/93
CPC分类号： C07D307/93 , C07C62/02
摘要： Novel lactones of 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 when identical are selected from the group consisting of chlorine and bromine and when at least two are different, are selected from the group consisting of fluorine, chlorine and bromine and a novel process for their preparation and a process for the preparation of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR2##
摘要翻译：式XI的顺式2,2-二甲基 - 环丙烷-1-羧酸的新型内酯，其中X1，X2和X3当相同时选自氯和溴，当至少两个不同时，它们是选自氟，氯和溴的组合及其制备方法和制备式IV的顺式2,2-二甲基 - 环丙烷-1-羧酸的方法式IV的酸可用于制备提高杀虫活性的酯。

4. 发明授权

US4554361A Process for the preparation of a bicyclic lactone through a sulfonated derivative 失效
标题翻译：通过磺化衍生物制备双环内酯的方法
公开(公告)号：US4554361A
公开(公告)日：1985-11-19
申请号：US517794
申请日：1983-07-27
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07B61/00 , C07D307/33 , C07D307/60 , C07D307/93 , C07D307/77
CPC分类号： C07D307/33 , C07D307/60 , C07D307/93
摘要： A novel process for the preparation of sulfonic acid esters containing a lactonic ring comprising compounds in the trans form in the 4- and 5-positions having (4SR,5RS), (4S,5R) or (4R,5S) configuration of the formula ##STR1## wherein Z is selected from the group consisting of alkyl of 1 to 4 carbon atoms and cycloalkyl and monocyclic aryl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and nitro and R is organic residue of an optionally chiral alcohol of the formula ROH and a process using the compounds of formula I to prepare compounds of (1RS, 4RS, 5SR), (1S, 4S, 5R) or (1R, 4R, 5S) configuration of the formula ##STR2## wherein X is selected from the group consisting of hydrogen and R useful for the preparation of insecticidally active esters.
摘要翻译：一种制备含有内酯环的磺酸酯的新方法，其包含在4-和5-位的反式形式的具有式（4SR，5RS），（4S，5R）或（4R，5S）构型的式其中Z选自1至4个碳原子的烷基，环烷基和任选被至少一个由1至4个碳原子的烷基取代的单环芳基，1至4的烷氧基，碳原子，卤素和硝基，R是式ROH的任选手性醇的有机残基，以及使用式I化合物制备（1RS，4RS，5SR），（1S，4S，5R）或（ 1R，4R，5S）构型，其中X选自用于制备杀虫活性酯的氢和R。

5. 发明授权

US4421928A 4-Methyl-3-formyl-pentanoic acid esters 失效
标题翻译： 4-甲基-3-甲酰基 - 戊酸酯
公开(公告)号：US4421928A
公开(公告)日：1983-12-20
申请号：US352259
申请日：1982-02-25
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/67 , C07C51/00 , C07C62/16 , C07C67/00 , C07C67/313 , C07C67/347 , C07C69/708 , C07D307/33 , C07C69/716
CPC分类号： C07D307/33 , C07C62/16
摘要： Novel 4-methyl-3-formyl-pentanoic acid derivative of the formula ##STR1## wherein Hal is a halogen, R.sub.1 is alkyl of 1 to 12 carbon atoms and A and B are .dbd.0 or A is halogen and B is --OR.sub.2 and R.sub.2 is alkyl of 1 to 12 carbon atoms, their preparation and their use as intermediates.
摘要翻译：具有式Ia的新型4-甲基-3-甲酰基 - 戊酸衍生物，其中Hal是卤素，R1是1-12个碳原子的烷基，A和B是= 0或A是卤素，B是-OR2 并且R 2是1至12个碳原子的烷基，它们的制备及其作为中间体的用途。

6. 发明授权

US4224227A Novel cyclopropane carboxylic acid esters 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4224227A
公开(公告)日：1980-09-23
申请号：US18166
申请日：1979-03-07
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/74 , A01N33/00 , A01N53/00 , A01N53/02 , A01N53/04 , A01N53/08 , A01P3/00 , A23K1/16 , A61K31/215 , A61K31/34 , A61K31/40 , A61K35/14 , A61P31/04 , C07C20060101 , C07C51/00 , C07C51/363 , C07C53/50 , C07C61/04 , C07C61/15 , C07C67/00 , C07C69/743 , C07C253/00 , C07C255/39 , C07D209/48 , C07D209/49 , C07D307/42 , C07D307/45 , C07D307/54 , C07D317/54 , G01G13/295 , A01N9/28
CPC分类号： C07D209/49 , A01N53/00 , C07C255/00 , C07C61/15 , C07D307/42 , Y10S514/949
摘要： Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.
摘要翻译：新的式（I）的环丙烷羧酸酯，其中X 1选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3选自的氯，溴和碘，R选自和任选被至少一个由1至4个碳原子的烷基取代的苄基， 2至6个碳原子的烯氧基，2至6个碳原子的链烯氧基，4至8个碳原子的链二烯基，亚甲二氧基，苄基和卤素，R1选自氢和甲基，R2选自单环芳基和-CH 2 -C 3 CH 3，R 3是具有至少一个双键的2至6个碳原子的脂族基，R 4选自氢，-CN和-C 3位CH，R 5选自由氯和甲基组成 n为0,1或2，R6，R7，R8和R9分别选自氢，氯和甲基，S / I表示该环可为具有杀虫性质的芳香族二氢或四氢，以及一个他们准备的过程。

7. 发明授权

US4463014A Cyclopropane carboxylates 失效
标题翻译：环丙烷羧酸盐
公开(公告)号：US4463014A
公开(公告)日：1984-07-31
申请号：US365462
申请日：1982-04-05
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： A01N37/08 , A01N37/10 , A01N37/34 , A01N53/00 , A01N53/08 , A23K1/00 , A23K1/16 , A61K31/215 , C07C67/00 , C07C69/74 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/38 , C07C255/39 , C07C255/53 , C07D307/93 , C07D333/04 , C07D333/32
CPC分类号： C07C255/00 , A01N53/00 , C07D307/93 , C07D333/32
摘要： Esters in their stereoisomeric form or mixtures thereof of the formula ##STR1## wherein R.sub.1 and R are different and individually selected from the group consisting of hydrogen, fluorine and bromine, R.sub.2 is selected from the group consisting of --CN and --C.tbd.CH and R.sub.3 is a hydrocarbyl group having pesticidal properties and their preparations.
摘要翻译：它们的立体异构体形式的酯或其混合物，其中R 1和R 2不同且分别选自氢，氟和溴，R 2选自-CN和-C 3 CH 3， R3是具有杀虫特性的烃基及其制备方法。

8. 发明授权

US4310542A Novel cyclopropane carboxylic acid esters 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4310542A
公开(公告)日：1982-01-12
申请号：US249195
申请日：1981-03-30
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： A01N53/00 , A23K1/16 , A61K31/215 , A61K31/275 , A61K31/34 , A61K31/40 , C07C51/60 , C07C61/04 , C07D209/48 , C07D307/45 , C07D307/93 , A01N37/34 , A01N43/16 , A01N43/36 , A01N65/00
CPC分类号： C07D209/49 , A01N53/00 , A23K20/105 , A61K31/275 , C07C51/60 , C07C61/04 , C07D209/48 , C07D307/42 , C07D307/93 , Y10S424/08
摘要： Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.
摘要翻译：新的式（I）的环丙烷羧酸酯，其中X 1选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3选自的氯，溴和碘，R选自 + TR＆lt; IMAGE＆gt;和任选被至少一个由1至4个碳原子的烷基取代的苄基 2至6个碳原子的烯基，2至6个碳原子的链烯氧基，4至8个碳原子的链二烯基，亚甲二氧基，苄基和卤素，R 1选自氢和甲基，R 2选自的单环芳基和-CH 2 -C 3 CH 3，R 3是具有至少一个双键的2至6个碳原子的脂族基，R 4选自氢，-CN和-C 3位CH，R 5选自该组由氯和甲基，n为0,1或2，R6，R7，R8和R9分别选自氢，氯和甲基，S / I表示该环可为具有杀虫性质的芳香族二氢或四氢，以及一个他们准备的过程。

9. 发明授权

US4303585A 3-Oxa-bicyclo (3,1,0)-hexan-2-one intermediates 失效
标题翻译： 3-氧杂双环（3,1,0） - 己烷-2-酮中间体
公开(公告)号：US4303585A
公开(公告)日：1981-12-01
申请号：US232118
申请日：1981-02-06
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N37/34 , A01N37/10 , A01N37/38 , A01N53/08 , A01P7/04 , C07B57/00 , C07C57/58 , C07C67/00 , C07C253/00 , C07C253/30 , C07C253/34 , C07C255/33 , C07C255/36 , C07C255/37 , C07C255/39 , C07C255/53 , C07D307/93
CPC分类号： C07D307/93 , A01N37/38 , C07C255/00 , C07C255/53 , C07C57/58
摘要： (S) .alpha.-cyano-3-phenoxy-benzyl alcohol having the formula ##STR1## and a novel process for its preparation and novel intermediates.
摘要翻译：（S）具有式“IMAGE”I的α-氰基-3-苯氧基 - 苄醇和其制备新颖的方法和新型中间体。

10. 发明授权

US4279835A Novel cyclopropane carboxylic acid esters 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4279835A
公开(公告)日：1981-07-21
申请号：US38728
申请日：1979-05-14
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： A01N53/00 , A23K1/16 , A61K31/215 , A61K31/275 , A61K31/34 , A61K31/40 , C07C51/60 , C07C61/04 , C07D209/48 , C07D307/45 , C07D307/93 , C07C69/74
CPC分类号： C07D209/49 , A01N53/00 , A23K20/105 , A61K31/275 , C07C51/60 , C07C61/04 , C07D209/48 , C07D307/42 , C07D307/93 , Y10S424/08
摘要： Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8, and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.
摘要翻译：新的式（I）的环丙烷羧酸酯，其中X 1选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3选自的氯，溴和碘，R选自和任选被至少一个由1至4个碳原子的烷基取代的苄基， 2至6个碳原子的烯氧基，2至6个碳原子的链烯氧基，4至8个碳原子的链二烯基，亚甲二氧基，苄基和卤素，R1选自氢和甲基，R2选自单环芳基和-CH 2 -C 3 CH 3，R 3是具有至少一个双键的2至6个碳原子的脂族基，R 4选自氢，-CN和-C 3位CH，R 5选自由氯和甲基组成 n为0,1或2，R 6，R 7，R 8和R 9分别选自氢，氯和甲基，S / I表示该环可为具有杀虫性质的芳香族二氢或四氢，及其准备过程。

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