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1. 发明授权

US5455150A Color photographic negative elements with enhanced printer compatibility 失效
标题翻译：彩色照相底片，增强打印机兼容性
公开(公告)号：US5455150A
公开(公告)日：1995-10-03
申请号：US75068
申请日：1993-06-10
申请人： Jared B. Mooberry , Paul B. Merkel , Stephen P. Singer
发明人： Jared B. Mooberry , Paul B. Merkel , Stephen P. Singer
IPC分类号： G03C7/00 , G03C1/83 , G03C7/18 , G03C7/392 , G03C1/46
CPC分类号： G03C7/18 , G03C1/83
摘要： A silver halide photographic negative has a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a coupler which reacts with oxidized color developer to form a magenta dye. The coupler in the green sensitive layer produces a magenta dye which has relatively low density in the 560-590 nm range as compared with magenta dyes produced by pyrazolotriazole type couplers or 1-phenyl-3-acylamino-5-pyrazolone couplers. The element additionally has an inert dye present, preferably positioned below the green sensitive layer containing the foregoing coupler. The inert dye has a peak absorption between 560-590 nm so that the negative has a ratio of density at 580 nm to density at 550 nm, both as measured at neutral midscale exposure, which is greater than exhibited by the element absent the inert dye.
摘要翻译：卤化银照相底片具有含有与氧化显色剂反应形成青色染料的成色剂的红色敏感层，含有与氧化显色剂反应形成黄色染料的成色剂的蓝色敏感层和含有与氧化的彩色显影剂反应形成品红色染料的成色剂。绿色敏感层中的成色剂产生品红色染料，与由吡唑并三唑型成色剂或1-苯基-3-酰基氨基-5-吡唑啉酮成色剂产生的品红色染料相比，在560-590nm范围内具有相对较低的密度。元素另外具有存在的惰性染料，优选位于含有前述成色剂的绿色敏感层下方。惰性染料在560-590nm之间具有峰值吸收，使得阴性在580nm处的密度与550nm处的密度之比（无论是在惰性染料中没有表现出的中性中值曝光）。

2. 发明授权

US5447831A Photographic element employing hue correction couplers 失效
标题翻译：采用色相校正耦合器的照相元件
公开(公告)号：US5447831A
公开(公告)日：1995-09-05
申请号：US139238
申请日：1993-10-19
申请人： Stephen P. Singer , Jared B. Mooberry
发明人： Stephen P. Singer , Jared B. Mooberry
IPC分类号： G03C7/00 , G03C7/20 , G03C7/26 , G03C7/30 , G03C7/32 , G03C7/333 , G03C7/36 , G03C7/38 , G03C7/384 , G03C1/46
CPC分类号： G03C7/3225 , G03C7/3041 , G03C7/36 , G03C7/3825 , G03C7/384
摘要： The invention provides a silver halide color negative photographic element comprising a red sensitive silver halide emulsion layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive silver halide emulsion layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive silver halide emulsion layer containing a coupler which upon reaction with oxidized color developer forms a magenta image dye, the element additionally comprising a hue correction coupler associated with a green sensitive layer which coupler reacts with oxidized developer to form a magenta dye having a peak absorption between 565-600 nm so that the element has a D580/D550 ratio which is greater than that exhibited by the element absent the hue correction coupler. The invention also provides a process for forming an image in the element described.
摘要翻译：本发明提供一种卤化银彩色负型照相材料，其包含红色感光卤化银乳剂层，其含有与氧化显色剂反应形成青色染料的成色剂，含有与氧化显色剂反应的成色剂的蓝色感光卤化银乳剂层形成黄色染料和含有成色剂的绿色感光卤化银乳剂层，其与氧化的彩色显影剂反应形成品红色图像染料，该元件还包含与绿色敏感层相关联的色调校正耦合剂，该成色剂与氧化的显影剂反应形成峰值吸收在565-600nm之间的品红色染料，使得该元件的D580 / D550比率大于不存在色调校正耦合器的元件所显示的值。本发明还提供了一种在所描述的元件中形成图像的方法。

3. 发明授权

US4840884A Photographic element and process comprising a dye releasing group 失效
标题翻译：摄影元件和包含染料释放基团的方法
公开(公告)号：US4840884A
公开(公告)日：1989-06-20
申请号：US109371
申请日：1987-10-19
申请人： Jared B. Mooberry , Stephen P. Singer
发明人： Jared B. Mooberry , Stephen P. Singer
IPC分类号： G03C7/32 , G03C7/305
CPC分类号： G03C7/30547 , Y10S430/159
摘要： A new photographic coupler comprises a coupling-off group bonded to the coupler at the coupling position represented by the formula:--L--NR.sup.1 --DYEwherein L is a linking group; NR.sup.1 is a substituted nitrogen atom bonded to DYE that together with NR.sup.1 is a releasable dye comprising an electrically neutral chromophore. Such a coupler enables dye hue stabilization without mordanting the dye formed. Such a new coupler is useful in a photographic silver halide element and process to provide increased dye density, higher contrast dye images, and lower pH sensitivity upon processing.

4. 发明授权

US5246820A Carbamic acid solubilized smearing couplers 失效
标题翻译：碳酸溶解性农药偶联剂
公开(公告)号：US5246820A
公开(公告)日：1993-09-21
申请号：US845290
申请日：1992-03-03
申请人： Jared B. Mooberry , James J. Seifert , Stephen P. Singer
发明人： Jared B. Mooberry , James J. Seifert , Stephen P. Singer
IPC分类号： G03C7/32
CPC分类号： G03C7/32 , Y10S430/159
摘要： A photographic element having improved granularity contains a dye-forming coupler containing a carbamic acid precursor capable of being converted into a carbamic acid group during processing, and wherein after processing the carbamic acid group decomposes, leaving the dye substantially non-diffusable.

5. 发明授权

US5364745A Azoaniline masking couplers for photographic materials 失效
标题翻译：用于摄影材料的偶氮苯掩蔽成色剂
公开(公告)号：US5364745A
公开(公告)日：1994-11-15
申请号：US778828
申请日：1991-12-19
申请人： Jared B. Mooberry , Stephen P. Singer , James J. Seifert , Robert J. Ross , Daniel L. Kapp
发明人： Jared B. Mooberry , Stephen P. Singer , James J. Seifert , Robert J. Ross , Daniel L. Kapp
IPC分类号： G03C7/305 , G03C7/333 , G03C5/54 , G03C7/18 , G03C7/32 , G03C7/34
CPC分类号： G03C7/3335 , G03C7/30547 , Y10S430/159
摘要： A photographic element including a support bearing a silver halide photographic emulsion, at least one color-forming coupler and a masking coupler, wherein said masking coupler is represented by the formula A:COUP--LINK--DYE (A)wherein COUP is a coupler moiety;LINK is any group releasable or cleavable from COUP by coupling with an oxidized developing agent during photographic processing; and DYE is an azoaniline dye and preferably an azoaniline dye blocked at the nitrogen-inclusive auxochromic site.
摘要翻译： PCT No.PCT / US91 / 09640 Sec。 371 1991年12月19日第 102（e）1991年12月19日PCT PCT 1991年12月19日PCT公布。出版物WO92 / 日本时间1992年7月9日。一种照相元件，包括带有卤化银照相乳剂的支持物，至少一种成色剂和遮蔽偶联剂，其中所述掩蔽成色剂由式A表示：COUP-LINK-DYE ）其中COUP是成色剂部分; LINK是通过在照相处理过程中与氧化的显影剂耦合而从COUP可释放或可切割的组; 并且DYE是偶氮苯胺染料，优选在包含氮的辅助色素位点处阻断的偶氮苯胺染料。

6. 发明授权

US5019492A Photographic element and process comprising a blocked photographically useful compound 失效
标题翻译：摄影元件和包含封闭的照相用化合物的方法
公开(公告)号：US5019492A
公开(公告)日：1991-05-28
申请号：US343981
申请日：1989-04-26
申请人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
发明人： John M. Buchanan , Ewell R. Cook , Jared B. Mooberry , Gary S. Proehl , Stephen P. Singer , William N. Washburn
IPC分类号： G03C1/06 , G03C1/43 , G03C7/305 , G03C7/392
CPC分类号： G03C7/30511 , Y10S430/156 , Y10S430/157 , Y10S430/158 , Y10S430/159 , Y10S430/16 , Y10S430/161
摘要： A novel blocked photographically useful compound comprises a new blocking group that (a) comprises two electrophilic groups, the least electrophilic of which is bonded directly or through a timing group to the photographically useful group (PUG) of the compound, (b) is capable of reacting with a dinucleophile reagent, and (c) has the two electrophilic groups separated from each other by a bond or unsubstituted or substituted atom that enables nucleophilic displacement to occur with release of PUG when the compound is reacted with a dinucleophile reagent. Such a blocked photographically useful compound is useful in a photographic material and process to provide increased stability and enable more rapid release of the photographically useful group upon reaction with a dinucleophile reagent.

7. 发明授权

US5298368A Photographic coupler compositions and methods for reducing continued coupling 失效
标题翻译：摄影耦合器组合物和减少连续耦合的方法
公开(公告)号：US5298368A
公开(公告)日：1994-03-29
申请号：US689436
申请日：1991-04-23
申请人： Paul B. Merkel , Edward Schofield , Stephen P. Singer
发明人： Paul B. Merkel , Edward Schofield , Stephen P. Singer
IPC分类号： G03C7/384 , G03C7/30 , G03C7/388 , G03C7/392 , G03C1/34 , G03C7/42
CPC分类号： G03C7/3003 , G03C7/3012 , G03C7/3885
摘要： Photographic coupler compositions comprise (a) a pyrazolone magenta dye-forming coupler compound, and (b) a sulfoxide compound in an amount sufficient to reduce continued coupling of the coupler compound during the bleach step of a color photographic process. The sulfoxide compound is of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of straight and branched chain alkyl groups, alkenyl groups and alkylene groups; straight and branched chain alkyl groups, alkenyl groups and alkylene groups containing at least one substituent selected from the group consisting of alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms; a phenyl group; and a phenyl group containing at least one substituent selected from the group consisting of alkyl, alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms. Additionally, R.sub.1 and R.sub.2 combined contain at least 12 carbon atoms. Preferably, the coupler composition is substantially free of phenol compounds when R.sub.1 and R.sub.2 are other than unsubstituted alkyl, alkenyl or alkylene groups.
摘要翻译：摄影成色剂组合物包含（a）形成吡唑啉酮品红色染料的成色剂化合物，和（b）足够量的亚砜化合物，其量可以在彩色照相法漂白步骤期间减少偶合剂化合物的持续偶联。亚砜化合物具有式（*化学结构*），其中R 1和R 2分别选自直链和支链烷基，烯基和亚烷基; 直链和支链烷基，烯基和含有至少一个选自烷氧基，芳氧基，芳基，烷氧基羰基，芳氧基羰基，酰氧基，碳酰氨基和氨基甲酰基和卤素原子的取代基的亚烷基; 苯基; 和含有至少一个选自烷基，烷氧基，芳氧基，芳基，烷氧基羰基，芳氧基羰基，酰氧基，碳酰氨基和氨基甲酰基和卤素原子的取代基的苯基。另外，R 1和R 2组合含有至少12个碳原子。当R 1和R 2不是未取代的烷基，烯基或亚烷基时，优选地，所述成色剂组合物基本上不含酚化合物。

8. 发明授权

US5200309A Color photographic materials including magenta coupler, carbonamide compound and aniline or amine compound, and methods 失效
标题翻译：彩色摄影材料，包括MAGENTA COUPLER，碳酰胺化合物和苯胺或胺化合物，以及方法
公开(公告)号：US5200309A
公开(公告)日：1993-04-06
申请号：US751469
申请日：1991-08-29
申请人： Paul B. Merkel , Stephen P. Singer
发明人： Paul B. Merkel , Stephen P. Singer
IPC分类号： G03C7/384 , G03C7/30 , G03C7/388 , G03C7/392
CPC分类号： G03C7/3885 , G03C7/3012
摘要： Color photographic materials comprise a support bearing a silver halide emulsion and a coupler composition. The coupler composition comprises a two-equivalent pyrazolone magenta dye-forming coupler, a ballasted carbonamide compound, and a ballasted aniline or amine compound. The carbonamide compound and the aniline or amine compound reduce continued coupling of the pyrazolone magenta dye-forming coupler during the bleach step in a color photographic process without altering the advantageous color image properties provided by the two-equivalent pyrazolone magenta dye-forming coupler

9. 发明授权

US5376519A Photographic material containing a coupler composition comprising magenta coupler, phenolic solvent, and at least one aniline or amine 失效
标题翻译：含有包含品红成色剂，酚类溶剂和至少一种苯胺或胺的成色剂组合物的照相材料
公开(公告)号：US5376519A
公开(公告)日：1994-12-27
申请号：US872940
申请日：1992-04-23
申请人： Paul B. Merkel , Stephen P. Singer
发明人： Paul B. Merkel , Stephen P. Singer
IPC分类号： G03C7/30 , G03C7/305 , G03C7/388 , G03C7/392 , G03C1/08 , G03C7/26 , G03C7/32
CPC分类号： G03C7/3012 , G03C7/30529 , G03C7/3885 , G03C7/39236 , G03C7/39244 , Y10S430/158
摘要： A color photographic material and process provide a two-equivalent 3-anilino pyrazolone magenta dye-forming coupler, a phenolic coupler solvent and at least one amine compound.
摘要翻译：彩色照相材料和方法提供了2-当量的3-苯胺基吡唑啉酮品红色染料形成成色剂，酚类成色剂溶剂和至少一种胺化合物。

10. 发明授权

US5350667A Photographic elements containing magenta couplers and process for using same 失效
标题翻译：含有品红色成色剂的摄影元件及其使用方法
公开(公告)号：US5350667A
公开(公告)日：1994-09-27
申请号：US79538
申请日：1993-06-17
申请人： Stephen P. Singer , Paul B. Merkel , Bernard Arthur J. Clark , Paul Louis R. Stanley
发明人： Stephen P. Singer , Paul B. Merkel , Bernard Arthur J. Clark , Paul Louis R. Stanley
IPC分类号： G03C7/305 , G03C7/384
CPC分类号： G03C7/30529 , G03C7/384
摘要： A photographic element contains a light-sensitive silver halide layer having associated therewith a coupler which is a pyrazolone compound with a coupling-off substituent at the -4-position, said compound having the formula: ##STR1## wherein each R.sup.1 is independently a substituted or unsubstituted alkylsulfonyl or arylsulfonyl group; each R.sup.2 and R.sup.3 is independently a substituent; R.sup.4, R.sup.5, and R.sup.6 are independently hydrogen or substituted or unsubstituted alkyl groups; m and n are independently 0 or 1 but both are not 0; x1 and x2 are independently 0 to 5; and y is 0 to 3; provided that each of R.sup.3, R.sup.4, R.sup.5, and R.sup.6 is selected such that the calculated log P of the thiophenol corresponding to the substituent at the 4-position of the pyrazolone is at least 4. The photographic element provides an improved combination of low continued coupling together with a magenta hue exhibiting a long wavelength of maximum absorption.
摘要翻译：照相元件含有与其相关联的成色剂的感光卤化银层，其为在-4位具有偶联取代基的吡唑啉酮化合物，所述化合物具有下式：其中每个R 1独立地是取代的或未取代的烷基磺酰基或芳基磺酰基; 每个R 2和R 3独立地是取代基; R4，R5和R6独立地是氢或取代或未取代的烷基; m和n独立地为0或1，但都不为0; x1和x2分别为0〜5; y为0〜3; 条件是选择R3，R4，R5和R6中的每一个，使得对应于吡唑啉酮的4-位上的取代基的苯硫酚的计算log P为至少4.照相元件提供了低持续的改进的组合与显示长波长最大吸收的品红色相连。

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