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    • 4. 发明授权
    • Azopyrazolone masking couplers
    • 唑吡酮掩蔽剂
    • US5492799A
    • 1996-02-20
    • US263642
    • 1994-06-22
    • Daniel L. KappRobert J. RossStephen P. SingerBernard A. Clark
    • Daniel L. KappRobert J. RossStephen P. SingerBernard A. Clark
    • G03C7/00C09B29/50G03C7/333G03C7/384G03C7/18
    • C09B29/366G03C7/3335
    • The invention provides a photographic element comprising a support bearing a light-sensitive photographic silver halide layer having associated therewith a masking coupler comprising:(1) a parent group containing a -1-phenyl-3-anilinopyrazolin-5-one having electron-withdrawing substituents on the phenyl and anilino rings of a type and number sufficient to provide a combined Hammett sigma(para) value for such substituents of at least 1.4;(2) a coupling-off group at the 4 position of the pyrazolone of the parent group comprising an arylazo dye containing on the aryl ring the following:(A) a substituent para to the azo functionality selected from the group consisting of hydroxyl, and alkoxy, carbonamido, and sulfonamido, each unsubstituted or substituted with nonaromatic groups, and(B) "n" additional substituents selected from the group consisting of alkyl, alkoxy, carbonamido, and sulfonamido, unsubstituted or substituted with nonaromatic groups, where "n" is 0 to 4;provided that substituent (A) and a substituent (B) may form a ringwherein one of the substituents (A) or (B) contains an alkyl group of at least 8 carbon atoms, unsubstituted or substituted with nonaromatic substituents, and said substituent contains at least 70% of the saturated carbon atoms in all of the substituents (A) and (B) provided that where the substituent (A) forms a ring with a substituent (B), the entire ring will be counted as said one of the substituents which contains an alkyl group of at least 8 carbon atoms for purposes of satisfying the 70% requirement.
    • 本发明提供了一种照相元件,其包括带有感光照相卤化银层的载体,其具有与之相关的掩蔽成色剂,其包含:(1)含有具有吸电子的1-苯基-3-苯胺基吡唑啉-5-酮的母体基团 苯基和苯胺基环上的取代基的类型和数目足以提供至少1.4的这种取代基的组合哈米特σ(对)值; (2)在母体基团的吡唑啉酮的4位上的偶联基团,其包含在芳基环上含有芳基偶氮染料,如下:(A)选自羟基和 烷氧基,碳酰胺基和亚磺酰氨基,各自未取代或被非芳族基团取代,和(B)选自烷基,烷氧基,碳酰氨基和亚磺酰氨基的“n”个附加取代基,未取代或被非芳族基团取代,其中“n” 为0〜4; 条件是取代基(A)和取代基(B)可以形成环,其中取代基(A)或(B)之一含有至少8个碳原子的烷基,未取代或被非芳族取代基取代,所述取代基包含 所有取代基(A)和(B)中的饱和碳原子的至少70%条件是当取代基(A)与取代基(B)形成环时,整个环将按照 含有至少8个碳原子的烷基的取代基用于满足70%的要求。