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    • 1. 发明专利
    • Organic electroluminescent element
    • 有机电致发光元件
    • JP2006024432A
    • 2006-01-26
    • JP2004200967
    • 2004-07-07
    • Japan Science & Technology AgencyRennie JohnKomatsu Seiren Co LtdTakeshi MasudaTadaoki Mitaniレニー ジョン忠興 三谷小松精練株式会社剛 枡田独立行政法人科学技術振興機構
    • JOHN RENNIEMITANI TADAOKIMASUDA TAKESHIUOZUMI KONOSUKE
    • H05B33/28H01L51/50
    • PROBLEM TO BE SOLVED: To provide an organic electroluminescent element having a large surface area and capable of uniformly emitting light by eliminating influence of roughness of the surface of a transparent electrode.
      SOLUTION: On the organic electroluminescent element, an organic compound thin film at least including an organic light-emitting layer is formed on an anode, and a cathode is formed on the organic compound thin film. The anode is a complex electrode having a low-resistance organic film formed on a surface of an inorganic transparent conductive film. A sheet resistance of the inorganic transparent conductive film is 50 Ω/square to 150 Ω/square. The low-resistance organic film has a thickness of 200 nm or thicker, a resistance of 300 Ω/cm or less at the thickness of 200 nm, and an ionization potential at the highest occupied molecular orbital level of 4.9 eV to 5.4 eV. For example, the low-resistance organic film can be formed by doping F4-TCNQ in 2-TNATA.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有大表面积并能够通过消除透明电极表面粗糙度的影响而均匀发光的有机电致发光元件。 解决方案:在有机电致发光元件上,在阳极上形成至少包含有机发光层的有机化合物薄膜,在有机化合物薄膜上形成阴极。 阳极是在无机透明导电膜的表面上形成有低电阻有机膜的复合电极。 无机透明导电膜的薄层电阻为50Ω/□〜150Ω/□。 低电阻有机膜的厚度为200nm以上,厚度为200nm时的电阻为300Ω/ cm以下,最高占位分子轨道电位的电离电位为4.9eV〜5.4eV。 例如,可以通过在2-TNATA中掺杂F4-TCNQ来形成低电阻有机膜。 版权所有(C)2006,JPO&NCIPI
    • 3. 发明专利
    • Organic electroluminescence element
    • 有机电致发光元件
    • JP2006024711A
    • 2006-01-26
    • JP2004200976
    • 2004-07-07
    • Japan Science & Technology AgencyRennie JohnKomatsu Seiren Co LtdTakeshi MasudaTadaoki Mitaniレニー ジョン忠興 三谷小松精練株式会社剛 枡田独立行政法人科学技術振興機構
    • JOHN RENNIEMITANI TADAOKIUOZUMI KONOSUKEMASUDA TAKESHI
    • H01L51/50
    • PROBLEM TO BE SOLVED: To realize high transportation efficiency for a positive hole and an electron, and excellent light emitting characteristics with a simplified structure. SOLUTION: An organic electroluminescence element comprises at least an organic thin film 3 formed between an positive electrode 2 and an anode electrode 4, wherein the organic thin film 3 comprises a single host material layer and a plurality of different kinds of dopants which are doped to the single host material layer with a distribution in the film thickness direction. One of the dopants is a dopant 12 which is provided with light emitting characteristics, and the others are a dopant 11 provided with positive hole implanting characteristics and/or positive hole transport characteristics, and a dopant 13 provided with electron implanting characteristics and/or electron transport characteristics. The manufacturing method has a step of sequentially forming in the film thickness direction of the host material layer a positive hole dopant region where the dopant 11 is implanted which is provided with the positive the positive hole implanting characteristics and/or positive hole transport characteristics, a light emitting region where the dopant 12 is doped which is provided with the light emitting characteristics, and an electron dopant region where the dopant 13 provided with the electron implanting characteristics and/or electron transport characteristics is doped. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了实现空穴和电子的高运输效率,并且以简单的结构具有优异的发光特性。 解决方案:有机电致发光元件至少包括形成在正电极2和阳极电极4之间的有机薄膜3,其中有机薄膜3包括单个主体材料层和多种不同种类的掺杂剂,其中 被掺杂到单个主体材料层,并且在膜厚度方向上具有分布。 掺杂剂中的一种是具有发光特性的掺杂剂12,其它的是具有空穴注入特性和/或空穴传输特性的掺杂剂11,以及具有电子注入特性和/或电子的掺杂剂 运输特点。 该制造方法具有在主体材料层的膜厚度方向依次形成掺杂了掺杂剂11的空穴掺杂剂区域的步骤,该空穴掺杂剂区域具有正的空穴注入特性和/或空穴传输特性为正,a 掺杂了掺杂剂12的发光区域,其具有发光特性,以及掺杂有电子注入特性和/或电子传输特性的掺杂剂13的电子掺杂剂区域。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Manufacturing method of organic electroluminescent element
    • 有机电致发光元件的制造方法
    • JP2005353502A
    • 2005-12-22
    • JP2004174861
    • 2004-06-11
    • Japan Science & Technology AgencyKomatsu Seiren Co LtdTadaoki Mitani忠興 三谷小松精練株式会社独立行政法人科学技術振興機構
    • UOZUMI KONOSUKEJOHN RENNIEMITANI TADAOKIMASUDA TAKESHI
    • H05B33/10H01L51/50H05B33/14H05B33/28
    • PROBLEM TO BE SOLVED: To enhance in-plane uniformity of affinity between an electrode acting as a grounding and an organic substance layer formed on it, and to prevent local and abnormal film deposition or uneven film deposition on the boundary of these.
      SOLUTION: This manufacturing method of an organic electroluminescent element is to form at least an organic compound thin film containing a light emitting region on a first electrode, and to form a second electrode on the organic compound thin film. Before forming the organic compound thin film, surface treatment is applied to the surface of the first electrode by an organic solvent, and the organic compound thin film, a hole injection layer for example, is deposited by vacuum thin film forming technology with an organic solvent molecule remaining on the surface of the electrode. The organic solvent is, for example, at least one kind selected from cyclohexanone, p-xylene, o-xylene, m-xylene, tetrahydrofuran, toluene, ethylbenzene, cyclohexane, ethylene glycol monomethyl ether, and ethylene glycol monobutyl ether.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提高作为接地的电极和形成在其上的有机物质层之间的亲和性的面内均匀性,并且防止在其上的边界上局部和异常的膜沉积或不均匀的膜沉积。 解决方案:这种有机电致发光元件的制造方法是至少在第一电极上形成含有发光区域的有机化合物薄膜,并在有机化合物薄膜上形成第二电极。 在形成有机化合物薄膜之前,通过有机溶剂对第一电极的表面进行表面处理,并且通过真空薄膜形成技术用有机溶剂沉积有机化合物薄膜(例如空穴注入层) 残留在电极表面上的分子。 有机溶剂例如为选自环己酮,对二甲苯,邻二甲苯,间二甲苯,四氢呋喃,甲苯,乙苯,环己烷,乙二醇单甲醚,乙二醇单丁醚中的至少一种。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Pressure excessive response preventing device
    • 压力过高的预防措施
    • JP2000074257A
    • 2000-03-14
    • JP25752998
    • 1998-08-26
    • Hidenobu HoriIshikawa Seisakusho LtdTadaoki MitaniNikkiso Co Ltd三谷 忠興秀信 堀日機装株式会社株式会社石川製作所
    • MITANI TADAOKIHORI HIDENOBUNIKI TOSHIICHIHABU YOSHIHIKOCHIBA TOSHIAKI
    • F16K21/00F16K47/14F16L55/04H01L21/027
    • PROBLEM TO BE SOLVED: To provide a device without a transient response obtaining sufficient performance and eliminating a reverse flow relating to chemicals of acid, alkali, etc., by constituting the transient response of pressure in the chemicals due to opening/closing of a valve so as to be prevented by elastic deformation of a hollow fiber in a housing. SOLUTION: Many hollow fibers 6 having a fine hole in an outer peripheral surface and having a prescribed length and a fine internal diameter are stored in a housing 8 by fixing left/right end parts thereof. The housing 8, formed in cylindrical shape, is constituted by a lower part communicating with a hollow pipe 2b, left side surface communicating with a hollow pipe 2c, and an upper part communicating with a discharge pipe 10. Since a developing solution is delivered onto a wafer from a nozzle with chemicals passing in the hollow fiber from the fine hole of the hollow fiber outer peripheral surface in the housing, a transient response in the chemicals due to opening/closing of a valve is absorbed by elastic deformation of the hollow fiber, generation of bubbles in the vicinity of the valve is prevented, and a shock generated in the pipe can be relaxed.
    • 要解决的问题:通过构成由于阀的打开/关闭而导致的化学品中的压力的​​瞬态响应,提供一种没有瞬态响应的装置,获得足够的性能并消除与酸,碱等化学物质相反的逆流 以防止壳体中的中空纤维的弹性变形。 解决方案:在外周表面具有细孔并且具有规定长度和细内径的许多中空纤维6通过固定其左/右端部而被保存在壳体8中。 形成为圆筒状的壳体8由与中空管2b连通的下部,与中空管2c连通的左侧面和与排出管10连通的上部构成。由于显影液被输送到 来自喷嘴的晶片,其中化学品从壳体中空纤维外周表面的细孔穿过中空纤维,由于阀的打开/关闭而导致的化学品中的瞬态响应被中空纤维的弹性变形吸收 能够防止在阀附近产生气泡,能够缓和管内的冲击。