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1. 发明授权

US07378559B2 Continuous process and system of producing polyether polyols 失效
标题翻译：生产聚醚多元醇的连续工艺和体系
公开(公告)号：US07378559B2
公开(公告)日：2008-05-27
申请号：US10545661
申请日：2004-03-05
申请人： Jan W. Verwijs , John W. Weston , Walter J. S. Papadopulos , Richard J. Elwell , Carlos M. Villa
发明人： Jan W. Verwijs , John W. Weston , Walter J. S. Papadopulos , Richard J. Elwell , Carlos M. Villa
IPC分类号： C07C43/11 , C07C43/00
CPC分类号： B01J19/1837 , C08G65/2663 , C08G65/2696
摘要： A continuous process and system for producing polyether polyols that allows for continuously adding an unreacted oxide to a loop reactor while adding at least one thermally deactivating catalyst capable of thermally deactivating prior to decomposition of polyether polyol which can allow for greater concentrations of unreacted oxides and/or a rate of reaction in the loop reactor is at a rate at least two times faster than a rate of reaction in a loop reactor containing less than 14 weight percent unreacted oxide. In a preferred embodiment, the catalyst is a double metal cyanide catalyst and a plug flow reactor is formed in series with the loop reactor wherein neither reactor contains a vapor space.
摘要翻译：一种用于生产聚醚多元醇的连续方法和系统，其允许在环状反应器中连续加入未反应的氧化物，同时加入至少一种能够在聚醚多元醇分解之前热失活的热失活催化剂，其可以允许更大浓度的未反应的氧化物和/ 或者环管反应器中的反应速率比含有少于14重量％未反应氧化物的环管反应器中的反应速度快至少两倍。在优选的实施方案中，催化剂是双金属氰化物催化剂，并且活塞流反应器与环管反应器串联形成，其中两个反应器都不包含蒸气空间。

2. 发明申请

US20080221281A1 CONTINUOUS PROCESS AND SYSTEM OF PRODUCING POLYETHER POLYOLS 审中-公开
标题翻译：连续生产聚醚多元醇的方法和系统
公开(公告)号：US20080221281A1
公开(公告)日：2008-09-11
申请号：US12054782
申请日：2008-03-25
申请人： Jan W. Verwijs , Walter J. S. Papadopulos , John W. Weston , Richard J. Elwell , Carlos M. Villa
发明人： Jan W. Verwijs , Walter J. S. Papadopulos , John W. Weston , Richard J. Elwell , Carlos M. Villa
IPC分类号： C08F2/01
CPC分类号： B01J19/1837 , C08G65/2663 , C08G65/2696
摘要： A continuous process and system for producing polyether polyols that allows for continuously adding an unreacted oxide to a loop reactor while adding at least one thermally deactivating catalyst capable of thermally deactivating prior to decomposition of polyether polyol which can allow for greater concentrations of unreacted oxides and/or a rate of reaction in the loop reactor is at a rate at least two times faster than a rate of reaction in a loop reactor containing less than 14 weight percent unreacted oxide. In a preferred embodiment, the catalyst is a double metal cyanide catalyst and a plug flow reactor is formed in series with the loop reactor wherein neither reactor contains a vapor space.
摘要翻译：一种用于生产聚醚多元醇的连续方法和系统，其允许在环状反应器中连续加入未反应的氧化物，同时加入至少一种能够在聚醚多元醇分解之前热失活的热失活催化剂，其可以允许更大浓度的未反应的氧化物和/ 或者环管反应器中的反应速率比含有少于14重量％未反应氧化物的环管反应器中的反应速度快至少两倍。在优选的实施方案中，催化剂是双金属氰化物催化剂，并且活塞流反应器与环管反应器串联形成，其中两个反应器都不包含蒸气空间。

3. 发明授权

US06642423B2 Polymerization of ethylene oxide using metal cyanide catalysts 失效
公开(公告)号：US06642423B2
公开(公告)日：2003-11-04
申请号：US10131900
申请日：2002-04-24
申请人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock , John W. Weston , Richard J. Elwell
发明人： Katherine S. Clement , Louis L. Walker , Richard M. Wehmeyer , Robert H. Whitmarsh , David C. Molzahn , William P. Dianis , David E. Laycock , John W. Weston , Richard J. Elwell
IPC分类号： C07C4311
CPC分类号： C08G65/2609 , B01J27/26 , B01J37/0223 , C08G65/2603 , C08G65/2615 , C08G65/2618 , C08G65/2663 , C08G65/2693 , C08G65/2696
摘要： Ethoxylations of various initiator compounds are performed in the presence of metal cyanide catalysts. The catalysts surprisingly form a wide variety of polyether products that in most cases contain only small amounts of high molecular weight poly(ethylene oxide).

4. 发明授权

US06762274B2 Low emission polyurethane polymers made with autocatalytic polyols 有权
标题翻译：用自催化多元醇制成的低排放聚氨酯聚合物
公开(公告)号：US06762274B2
公开(公告)日：2004-07-13
申请号：US10203496
申请日：2002-08-10
申请人： Simon Waddington , Jean-Marie L. Sonney , Richard J. Elwell , Francois M. Casati , Antoine Storione
发明人： Simon Waddington , Jean-Marie L. Sonney , Richard J. Elwell , Francois M. Casati , Antoine Storione
IPC分类号： C08G1850
CPC分类号： C08G18/632 , C08G18/4072 , C08G18/482 , C08G18/5024 , C08G18/6674 , C08G2101/0008 , C08G2101/0025 , C08G2101/005 , C08G2101/0083
摘要： The present invention discloses a process for producing a polyurethane product with autocatalytic polyols. These auto-catalytic polyols are based on an initiator of the formula (I): HmA-(CH2)n—N(R)-(CH2)p-AHm where n and p are independently integers from 2 to 6, A at each occurrence is independently oxygen, nitrogen or hydrogen, with the proviso that only one of A can be hydrogen at one time, R is a C1 to C3 alkyl group, m is equal to 0 when A is hydrogen, is 1 when A B is oxygen and is 2 when A is nitrogen; or are polyols which contain an alkyl amine of within the polyol chain or a dialkylylamino group pendant to the polyol chain wherein the polyol chain is obtained by copolymerization of at least one monomer containing an alkyl aziridine or N,N-dialkyl glycidylamine with at least one alkylene oxide. These auto-catalytic polyols are reacted with a polyisocyanate in the presence of other additives and/or auxiliary agents known per se to produce polyurethane products.
摘要翻译：本发明公开了一种用自催化多元醇制备聚氨酯产品的方法。这些自催化多元醇基于式（I）的引发剂：HmA-（CH2）nN（R） - （CH2）p-AHm，其中n和p独立地为2至6的整数，每次出现A 独立地是氧，氮或氢，条件是A中只有一个可以同时为氢，R为C1至C3烷基，当A为氢时m等于0，当AB为氧时为1，当AB为氧时为2 当A是氮时; 或者是含有多元醇链中的烷基胺或多元醇链侧基的二烷基氨基的多元醇，其中所述多元醇链通过至少一种含烷基氮丙啶或N，N-二烷基缩水甘油胺与至少一种环氧烷。在本身已知的其它添加剂和/或辅助剂的存在下，这些自动催化多元醇与多异氰酸酯反应以生产聚氨酯产品。

5. 发明授权

US06376625B1 Process for purifying polyethers 有权
标题翻译：聚醚的纯化方法
公开(公告)号：US06376625B1
公开(公告)日：2002-04-23
申请号：US09383171
申请日：1999-08-25
申请人： James P. Cosman , Paul D. Bettge , Richard J. Elwell , Raymond A. Plepys
发明人： James P. Cosman , Paul D. Bettge , Richard J. Elwell , Raymond A. Plepys
IPC分类号： C08F208
CPC分类号： C08G65/2648 , C08G65/30 , Y02P20/584
摘要： This invention involves several ways for improving a coalescing process for purifying a crude polyether. In one aspect, particulate zirconium dioxide is selected as a coalescing medium. In a second aspect, alkali metal catalyst is recovered and recycled to make additional polyether product. In a third aspect, a polyether stream obtained from the coalescing step is purified by stripping water in at least two phases, the first of which involves moderate conditions so that water but not allyl alcohol or higher molecular weight impurities are removed from the polyether, and the second of which involves more stringent stripping conditions. In a fourth aspect, crude polyether that is subjected to a holding period before undergoing a coalescing step is mixed with water to minimize the formation of impurities that are believed to compatibilize the aqueous and polyether phases. In a fifth aspect, the coalescing process is conducted under a non-oxidizing atmosphere.
摘要翻译：本发明涉及改进用于纯化粗聚醚的聚结过程的几种方法。在一个方面，选择颗粒二氧化锆作为聚结介质。在第二方面，碱金属催化剂被回收并再循环以制备额外的聚醚产物。在第三方面，从聚结步骤获得的聚醚流通过至少两相汽提水进行纯化，其中第一步涉及中等条件，从而从聚醚中除去水而不是烯丙醇或更高分子量的杂质，其中第二个涉及更严格的剥离条件。在第四方面，将经过聚结步骤之前的保持期的粗聚醚与水混合以最小化被认为使水相和聚醚相相容的杂质的形成。在第五方面，聚结过程在非氧化气氛下进行。

6. 发明授权

US5122548A Elastomeric polyisocyanate-based polymers from polyoxyalkylene polyols containing internal polyoxyethylene blocks 失效
标题翻译：含聚异氰酸酯聚合物的聚氧乙烯多元醇聚内酯聚内酰胺嵌段
公开(公告)号：US5122548A
公开(公告)日：1992-06-16
申请号：US497945
申请日：1990-03-23
申请人： Rene Broos , Johan A. Thoen , Richard J. Elwell
发明人： Rene Broos , Johan A. Thoen , Richard J. Elwell
IPC分类号： C08G18/48 , C08G65/26
CPC分类号： C08G65/2609 , C08G18/4841 , C08G2101/0008 , Y10S521/914
摘要： This invention relates to elastomeric polyisocyanate-based polymers, particularly polyurethane elastomeric polymers, prepared from polyol compositions comprising a polyoxyalkylene polyol having a hydroxyl equivalent weight of from about 800 to about 3000 and containing from 10 to 40 weight percent polymerized ethylene oxide wherein the ethylene oxide is distributed as a plurality of internal polyoxyethylene blocks having a molecular weight of from about 176 to about 600, and a polyoxyethylene cap use of such polyols. Polyols provides for polymers exhibiting desirable physical properties including good abrasion wear resistance.
摘要翻译：本发明涉及由多元醇组合物制备的基于弹性聚异氰酸酯的聚合物，特别是聚氨酯弹性体聚合物，所述多元醇组合物包含羟基当量为约800至约3000并且含有10至40重量％聚合的环氧乙烷的聚氧化烯多元醇，其中环氧乙烷分布为多个分子量为约176至约600的内部聚氧乙烯嵌段，以及这种多元醇的聚氧乙烯帽用途。多元醇提供了具有良好的耐磨性的物理性能的聚合物。

7. 发明授权

US5114989A Isocyanate-terminated prepolymer and polyurethane foam prepared therefrom 失效
标题翻译：异氰酸酯封端的预聚物和制备的聚氨酯泡沫
公开(公告)号：US5114989A
公开(公告)日：1992-05-19
申请号：US612722
申请日：1990-11-13
申请人： Richard J. Elwell , Robert A. Sewell , Werner A. Lidy , Johan A. Thoen
发明人： Richard J. Elwell , Robert A. Sewell , Werner A. Lidy , Johan A. Thoen
IPC分类号： C08G18/10 , C08G18/48 , C08G18/72 , C08G18/76 , C08G101/00 , C08J9/00 , C08J9/02
CPC分类号： C08G18/7664 , C08G18/10 , C08G18/4837 , C08G2101/0008 , C08G2101/0041 , C08G2101/0083
摘要： This invention relates to an isocyanate-terminated prepolymer prepared from a polyisocyanate comprising 4,4'-methylene diphenyldiisocyanate and polyoxyalkylene polyol wherein the polyol has an average functionality of from about 2 to about 4, a hydroxyl equivalent weight of from about 2200 to 3500 and containing oxyethylene residues in from about 40 to about 68 percent by weight; and the use thereof in the manufacturing of flexible polyurethane foam.

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