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1. 发明授权

US4387237A Process for making vicinal epoxides 失效
标题翻译：制造邻位环氧化物的方法
公开(公告)号：US4387237A
公开(公告)日：1983-06-07
申请号：US367720
申请日：1982-04-12
申请人： James M. Renga , Gerald C. Kolb
发明人： James M. Renga , Gerald C. Kolb
IPC分类号： C07D301/02
CPC分类号： C07D301/02
摘要： Vicinal epoxides are prepared by decomposition of .beta.-haloalkyl carbonates or bis(.beta.-haloalkyl) carbonates in the presence of a complex of an alkali metal halide and a monomeric or polymeric chelating agent comprising an element of group V of the Periodic Table at a temperature from about 25.degree. C. to about 250.degree. C.
摘要翻译：通过在碱金属卤化物和包含元素周期表第V族元素的单体或聚合物螯合剂的络合物存在下，在温度下分解β-卤代烷基碳酸酯或双（β-卤代烷基）碳酸酯来制备端环氧化物约25℃至约250℃

2. 发明授权

US4705872A Cyclic acetal-alcohols 失效
标题翻译：环状缩醛醇
公开(公告)号：US4705872A
公开(公告)日：1987-11-10
申请号：US431902
申请日：1982-09-30
申请人： Gerald C. Kolb , Thomas W. Regulski
发明人： Gerald C. Kolb , Thomas W. Regulski
IPC分类号： C07D317/20
CPC分类号： C07D317/20
摘要： Novel cyclic diacetal-alcohols having cycloaliphatic bridging groups.
摘要翻译：具有脂环族桥连基团的新型环状二缩醛。

3. 发明授权

US4376861A Method for preparing 2-alkenyl-2-oxazolines 失效
标题翻译： 2-链烯基-2-恶唑啉的制备方法
公开(公告)号：US4376861A
公开(公告)日：1983-03-15
申请号：US327299
申请日：1981-12-03
申请人： James W. Lalk , Gerald C. Kolb , Donald A. Tomalia , Peter W. Owen
发明人： James W. Lalk , Gerald C. Kolb , Donald A. Tomalia , Peter W. Owen
IPC分类号： C07D263/12 , C07D263/14
CPC分类号： C07D263/14 , C07D263/12
摘要： The process comprises the steps of:(A) reacting by contacting an anhydrous or substantially anhydrous 2-alkyl-2-oxazoline with formaldehyde in a molar ratio of at least about 1.5 moles of 2-alkyl-2-oxazoline per mole of formaldehyde, thereby forming 2-(.alpha.-hydroxymethylalkyl)-2-oxazoline,(B) recovering the 2-(.alpha.-hydroxymethylalkyl)-2-oxazoline from the reaction product of step (A), and(C) reacting by contacting the 2-(.alpha.-hydroxymethylalkyl)-2-oxazoline and step B with an alkali or alkaline earth metal hydroxide, thereby forming 2-alkenyl-2-oxazoline.As an example, step A was conducted by reacting 2-ethyl-2-oxazoline (4 moles) having less than 1,000 ppm of water with paraformaldehyde (1 mole) at a reaction temperature of 100.degree. C. for approximately 5.5 hours. The excess oxazoline reactant was removed along with water as "overheads" by fractional distillation of the reaction product, leaving the 2-(.alpha.-hydroxymethylethyl)-2-oxazoline in approximately 96 percent yield. Step C was then conducted by continuously adding the 2-(.alpha.-hydroxymethylethyl)-2-oxazoline to a stirred solution of sodium hydroxide in the mono-methyl ether of triethylene glycol at a temperature of from 100.degree.-105.degree. C. Under these conditions, the 2-isopropenyl-2-oxazoline and water were volatilized and recovered from the overheads. The product yield was approximately 98 percent of theory.
摘要翻译：该方法包括以下步骤：（A）使无水或基本上无水的2-烷基-2-恶唑啉与甲醛的摩尔比为至少约1.5摩尔的2-烷基-2-恶唑啉/摩尔甲醛，从而形成2-（α-羟甲基烷基）-2-恶唑啉，（B）从步骤（A）的反应产物中回收2-（α-羟甲基烷基）-2-恶唑啉，和（C）（α-羟甲基烷基）-2-恶唑啉和步骤B与碱金属或碱土金属氢氧化物反应，从而形成2-链烯基-2-恶唑啉。作为实例，通过在100℃的反应温度下使具有小于1000ppm水的2-乙基-2-恶唑啉（4摩尔）与多聚甲醛（1摩尔）反应约5.5小时来进行步骤A. 通过反应产物的分馏，将过量的恶唑啉反应物与水一起作为“塔顶馏出物”除去，留下2-（α-羟基甲基乙基）-2-恶唑啉约96％产率。然后通过将2-（α-羟基甲基乙基）-2-恶唑啉连续加入到三乙二醇的单甲基醚的搅拌的氢氧化钠溶液中，在100〜105℃的温度下进行步骤C.在这些条件下，将2-异丙烯基-2-恶唑啉和水挥发并从塔顶馏出物中回收。产品产量约为理论的98％。

4. 发明授权

US5155196A Polymer resulting from the cure of a preformed chromene-containing mixture 失效
标题翻译：由固化含有色烯的混合物得到的聚合物
公开(公告)号：US5155196A
公开(公告)日：1992-10-13
申请号：US532297
申请日：1990-06-01
申请人： Gerald C. Kolb , Daniel M. Scheck , Stoil Dirlikov , Muthiah Inbasekaran , James P. Godschalx
发明人： Gerald C. Kolb , Daniel M. Scheck , Stoil Dirlikov , Muthiah Inbasekaran , James P. Godschalx
IPC分类号： C07C41/16 , C07C43/215 , C07C43/225 , C07C45/71 , C07C49/84 , C07D311/58 , C08F24/00 , C08F224/00
CPC分类号： C07C317/00 , C07C41/16 , C07C43/215 , C07C43/225 , C07C45/71 , C07C49/84 , C07D311/58
摘要： This invention relates to a solvent process for the conversion of aromatic propargyl ethers into chromenes. The process can be catalyzed with copper or zinc salts. The preferred salt is cuprous chloride. The most preferred solvent is a dichlorobenzene. The invention also relates to chromene products formed using the process and to the polymerization of that chromene product and its polymerized product, the latter product having substantially improved flexural modulus and flexural strength properties. The polymerized product is also moisture insensitive.
摘要翻译：本发明涉及用于将芳族炔丙基醚转化为色烯的溶剂方法。该方法可以用铜或锌盐催化。优选的盐是氯化亚铜。最优选的溶剂是二氯苯。本发明还涉及使用该色烯产物及其聚合产物的方法和聚合形成的色烯产物，后者产品具有显着改善的弯曲模量和弯曲强度性质。聚合产物也是不敏感的。

5. 发明授权

US5204386A Acrylic-modified epoxy resin adhesive compositions with improved rheological control 失效
标题翻译：丙烯酸改性环氧树脂粘合剂组合物具有改进的流变学控制
公开(公告)号：US5204386A
公开(公告)日：1993-04-20
申请号：US896730
申请日：1992-06-09
申请人： Yasemin Ersun-Hallsby , Dwight K. Hoffman , Gerald C. Kolb , Gene D. Rose
发明人： Yasemin Ersun-Hallsby , Dwight K. Hoffman , Gerald C. Kolb , Gene D. Rose
IPC分类号： C08F283/10 , C09J163/00
CPC分类号： C09J163/00 , C08F283/10 , Y10S525/922
摘要： A thixoropic adhesive composition exhibiing good sag resistance is prepared comprising a mixture of a polymer-modified epoxy resin and a rheological control agent. The polymer-modified epoxy resin is preferably a dispersion of acrylic elastomer in an epoxy resin in which the acrylic elastomer particles have added hydroxyl functionality which interacts favorably with rheological control agents, such as fumed silica. Acrylic epoxy resin dispersions containing added hydroxyl functionality give improved rheological control.
摘要翻译：制备具有良好抗流挂性的触变胶粘剂组合物，其包含聚合物改性环氧树脂和流变控制剂的混合物。聚合物改性的环氧树脂优选是丙烯酸弹性体在环氧树脂中的分散体，其中丙烯酸弹性体颗粒已经加入与流变控制剂如热解法二氧化硅有利的羟基官能团。含有添加羟基官能团的丙烯酸环氧树脂分散体可改善流变学控制。

6. 发明授权

US4297452A Process for the manufacture of oxazoline and/or oxazine-modified adsorbent polymer resins 失效
标题翻译：恶唑啉和/或恶嗪改性吸附聚合物树脂的制造方法
公开(公告)号：US4297452A
公开(公告)日：1981-10-27
申请号：US109729
申请日：1980-01-04
申请人： Robert J. De Koch , Gerald C. Kolb , James W. Lalk
发明人： Robert J. De Koch , Gerald C. Kolb , James W. Lalk
IPC分类号： C08F8/30 , C08F8/20 , C08F8/24
CPC分类号： C08F8/30
摘要： A novel process is disclosed for increasing the amount of grafted polymer formed during the production of polyamide-modified macroporous polystyrene/divinylbenzene cross-linked beads. Greater selectivity for oxazolination and/or oxazination (grafting) of the chloromethylated polystyrene (CMPS) beads over homopolymer formation is achieved by forming an iodized cross-linked vinyl-addition polymer which is then contacted with an excess of oxazoline or oxazine until up to about 50 percent of said oxazoline or oxazine monomer is reacted. Subsequent hydrolysis of these polyamide-modified resins produces polyamine anion-exchange resins which exhibit greater than 2 times the weak base capacities of conventional anion-exchange resins.
摘要翻译：公开了用于增加在制备聚酰胺改性的大孔聚苯乙烯/二乙烯基苯交联的珠粒期间形成的接枝聚合物的量的新方法。通过形成碘化的交联乙烯基加成聚合物来实现氯甲基化聚苯乙烯（CMPS）珠对均聚物形成的更高选择性的恶唑化和/或恶唑化（接枝），然后与过量的恶唑啉或恶嗪接触直到高达约 50％的恶唑啉或恶嗪单体反应。随后的这些聚酰胺改性树脂的水解产生多胺阴离子交换树脂，其表现出大于常规阴离子交换树脂的弱碱容量的2倍。

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