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1. 发明授权

US4418228A Process for ring bromination of nitrobenzene 失效
标题翻译：硝基苯环溴化法
公开(公告)号：US4418228A
公开(公告)日：1983-11-29
申请号：US370733
申请日：1982-04-22
申请人： James J. Harrison , John P. Pellegrini , Charles M. Selwitz
发明人： James J. Harrison , John P. Pellegrini , Charles M. Selwitz
IPC分类号： C07C205/12 , C07C79/12
CPC分类号： C07C205/12 , C07C201/12
摘要： A process for ring bromination of nitrobenzene which comprises contacting the nitrobenzene with an alkali metal bromate and aqueous sulfuric acid.
摘要翻译：硝基苯的环溴化方法，其包括使硝基苯与碱金属溴酸盐和硫酸水溶液接触。

2. 发明授权

US4356325A Process for preparation of acetylene terminated sulfones, oligomers and precursors therefor 失效
标题翻译：乙炔封端的砜，低聚物和前体的制备方法
公开(公告)号：US4356325A
公开(公告)日：1982-10-26
申请号：US211318
申请日：1980-11-28
申请人： James J. Harrison , Edward T. Sabourin , Charles M. Selwitz
发明人： James J. Harrison , Edward T. Sabourin , Charles M. Selwitz
IPC分类号： C07C315/00 , C07C317/22 , C07C147/10 , C07C147/06 , C07C147/12
CPC分类号： C07C315/00
摘要： Acetylene terminated sulfones and oligomers thereof are prepared by reacting a sulfonyldiphenol with a material selected from the group consisting of a meta-dibromobenzene, a para-dibromobenzene and mixtures thereof in the presence of a potassium base to form a bis-bromophenoxydiphenyl sulfone, which is reacted with a substituted terminal acetylene compound containing at least three carbon atoms and an hydroxy group on the carbon atom adjacent to the acetylene group to form an hydroxy-acetylene terminated phenoxydiphenyl sulfone, which is then subjected to base catalyzed cleavage to form the desired acetylene terminated sulfones and oligomers. An hydroxy-arylacetylene terminated sulfone is prepared by reacting a sulfonyldiphenyl with a material selected from the group consisting of meta-dibromobenzene para-dibromobenzene and mixtures thereof in the presence of a sodium base. The resulting hydroxyphenylbromophenoxyphenyl sulfone can be: (1) reacted with a substituted terminal acetylene compound to form an hydroxy-arylacetylene terminated sulfone which in turn can be reacted with a dinitrofluorobenzene to form a dinitro-acetylene terminated sulfone which in turn can be reacted with sodium dithionite and sodium hydroxide to form a diaminoacetylene terminated sulfone; (2) reacted with a dibromobenzene to form a bis-bromophenoxydiphenyl sulfone; or (3) reacted with a bis-bromophenoxydiphenyl sulfone to form an oligomeric bromophenoxydiphenyl sulfone, which can be used to form an oligomeric actylene terminated sulfone. Metal contaminants, such as palladium and copper, used in the preparation of the acetylene terminated sulfones are removed by admixing the metal contaminated sulfone with a hydrogen halide and then contacting the admixture with an amino compound to complex the metal contaminant.
摘要翻译：乙炔封端的砜及其低聚物是通过在钾碱存在下使磺酰基二苯酚与选自间二溴苯，对二溴苯及其混合物的材料反应形成双溴苯氧基二苯砜来制备的，与在乙炔相邻的碳原子上含有至少三个碳原子和羟基的取代的末端乙炔化合物反应形成羟基 - 乙炔封端的苯氧基二苯基砜，然后进行碱催化裂解以形成所需的乙炔终止砜和低聚物。羟基 - 芳基乙炔封端的砜通过在钠碱存在下使磺酰基二苯与选自间二溴苯对二溴苯及其混合物的材料反应来制备。所得的羟基苯基溴苯氧基苯砜可以是：（1）与取代的末端乙炔化合物反应形成羟基 - 芳基乙炔封端的砜，其又可以与二硝基氟苯反应形成二硝基乙炔封端的砜，其又可以与钠反应连二亚硫酸盐和氢氧化钠以形成二氨基乙炔封端的砜; （2）与二溴苯反应形成双溴苯氧基二苯砜; 或（3）与双溴苯氧基二苯砜反应形成低聚溴苯氧基二苯砜，其可用于形成低聚丙烯封端的砜。通过将金属污染的砜与卤化氢混合，然后将该混合物与氨基化合物接触以使金属污染物复合，来除去用于制备乙炔封端的砜的金属污染物，例如钯和铜。

3. 发明授权

US4139561A Novel substituted amino-aromatic acetylenes and their method of preparation 失效
标题翻译：新型取代氨基 - 芳族乙炔及其制备方法
公开(公告)号：US4139561A
公开(公告)日：1979-02-13
申请号：US881198
申请日：1978-02-27
申请人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
发明人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
IPC分类号： C07B43/04 , B01J23/00 , B01J23/46 , C07B31/00 , C07B61/00 , C07C67/00 , C07C211/45 , C07C213/00 , C07C213/02 , C07C215/68 , C07C215/70 , C07C85/11 , C07C85/24 , C07C91/40
CPC分类号： C07C209/36
摘要： Substituted acetylenes wherein the amino and acetylene groups are directly connected to aromatic ring carbon atoms and wherein the substituted acetylene has at least 3 carbon atoms and a hydroxyl group on the carbon atom adjacent to the acetylene group are claimed as new compositions of matter. The new compositions are prepared by the selective reduction of the corresponding nitroaromatic by contacting the nitroaromatic and free molecular hydrogen with a catalyst consisting essentially of ruthenium. A new process is also described for the preparation of an aminophenylacetylene.
摘要翻译：取代的乙炔，其中氨基和乙炔基团直接连接到芳族环碳原子上，其中取代的乙炔具有至少3个碳原子，并且与乙炔基相邻的碳原子上的羟基被要求为物质的新组合物。通过使硝基芳族和游离分子氢与基本上由钌组成的催化剂接触，通过选择性还原相应的硝基芳族化合物来制备新组合物。还描述了用于制备氨基苯乙炔的新方法。

4. 发明授权

US4065470A Process for producing maleic anhydride from mixture of five and six carbon hydrocarbons 失效
标题翻译：从5和6碳碳氢化合物的混合物生产马来酸酐的方法
公开(公告)号：US4065470A
公开(公告)日：1977-12-27
申请号：US714047
申请日：1976-08-13
申请人： John D. Bacha , Joseph S. Matthews , Charles M. Selwitz
发明人： John D. Bacha , Joseph S. Matthews , Charles M. Selwitz
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , C07C51/31 , C07D307/60
CPC分类号： C07C51/252 , B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , C07C51/313
摘要： A process for producing maleic anhydride from a hydrocarbon mixture containing C.sub.5 monoolefinic hydrocarbons, C.sub.5 diolefinic hydrocarbons, (cyclic and acylic) C.sub.5 paraffins, C.sub.6 paraffins and benzene which involves separating the C.sub.5 cyclic diolefinic hydrocarbons from the mixture and then reacting the resulting mixture with molecular oxygen in vapor phase in the presence of an oxidation catalyst at elevated temperatures.
摘要翻译：一种从含有C5单烯烃，C5二烯烃，（环状和酰基）C 5链烷烃，C 6链烷烃和苯的烃混合物生产马来酸酐的方法，其包括从混合物中分离出C5环状二烯烃，然后使所得混合物与分子在氧化催化剂存在下，在升高的温度下，气相中的氧气。

5. 发明授权

US4003800A Styrene purification process 失效
标题翻译：苯乙烯净化工艺
公开(公告)号：US4003800A
公开(公告)日：1977-01-18
申请号：US646403
申请日：1976-01-02
申请人： John D. Bacha , Charles M. Selwitz
发明人： John D. Bacha , Charles M. Selwitz
IPC分类号： C07C7/20 , C07C7/04
CPC分类号： C07C7/20
摘要： The present invention relates to the use of quinone alkides as polymerization inhibitors in a styrene purification process. The inhibitors are prepared by oxidizing hindered phenols to the corresponding quinone alkide.
摘要翻译：本发明涉及在苯乙烯纯化过程中醌醌作为聚合抑制剂的用途。抑制剂通过将受阻酚氧化成相应的醌类碱来制备。

6. 发明授权

US4361440A M-Alkynylanilides and use as herbicides 失效
标题翻译： M-炔基酰苯胺，用作除草剂
公开(公告)号：US4361440A
公开(公告)日：1982-11-30
申请号：US297641
申请日：1981-08-31
申请人： Edward T. Sabourin , Charles M. Selwitz
发明人： Edward T. Sabourin , Charles M. Selwitz
IPC分类号： A01N37/22 , A01N47/12 , A01N47/30 , A01N53/00 , C07C275/32 , A01N37/18 , C07C103/19 , C07C103/34
CPC分类号： A01N37/22 , A01N47/12 , A01N47/30 , A01N53/00 , C07C275/32
摘要： Compounds of the general structural formula, ##STR1## in which R.sup.1 is C.sub.1 to C.sub.4 lower alkyl, cycloalkyl or alkylamino and R.sup.2 is H or lower N-alkylcarbamyl are made from corresponding m-aminophenylacetylenic compounds by conventional methods and are useful as selective herbicides.
摘要翻译：通式为其中R1为C1-C4低级烷基，环烷基或烷基氨基，R2为H或低级N-烷基氨基甲酰基的通式结构式化合物由相应的间氨基苯基乙炔化合物通过常规方法制备，可用作选择性除草剂。

7. 发明授权

US4223172A Process for the preparation of bromoarylacetylene and aryldiacetylene precursors 失效
标题翻译：制备溴代芳基乙炔和芳基二乙炔前体的方法
公开(公告)号：US4223172A
公开(公告)日：1980-09-16
申请号：US967244
申请日：1978-12-07
申请人： Edward T. Sabourin , Charles M. Selwitz
发明人： Edward T. Sabourin , Charles M. Selwitz
IPC分类号： C07C29/32 , C07C29/62 , C07C29/00 , C07C33/04 , C07C33/10
CPC分类号： C07C29/32 , C07C29/62
摘要： Bromoarylacetylenes such as m-bromophenylacetylene and certain precursors to such bromoarylacetylene are prepared by reacting an aryldibromide with a substituted terminal acetylene compound containing at least three carbon atoms and a hydroxy group on the carbon atom adjacent to the acetylene group in the presence of a dialkyl or trialkyl amine solvent and a catalyst system consisting of a palladium complex containing two halogen moieties and two tri-substituted phosphine moieties. Additional triphenylphosphine can be added. A cuprous iodide promoter is also employed in the reaction sequence. The bromoarylacetylenes can be reacted with a substituted terminal acetylene compound as defined using the same catalyst system as defined to produce the corresponding aryldihydroxy substituted acetylenes. Certain bromophenylhydroxy substituted acetylenes are claimed as new compositions.
摘要翻译：溴芳基乙炔如间溴苯乙炔和这种溴代芳基乙炔的某些前体通过在二烷基或二烷基乙炔的存在下使芳基二溴化物与在乙炔基附近的碳原子上含有至少三个碳原子和羟基的取代的末端乙炔化合物反应来制备，三烷基胺溶剂和由含有两个卤素部分和两个三取代膦部分的钯络合物组成的催化剂体系。可添加额外的三苯基膦。在反应顺序中也使用碘化亚铜助催化剂。溴代芳基乙炔可以与使用与所定义相同的催化剂体系所定义的取代的末端乙炔化合物反应，生成相应的芳基二羟基取代的乙炔。作为新组合物要求某些溴苯基羟基取代的乙炔。

8. 发明授权

US4219679A Selective hydrogenation of nitro groups on nitroaromatic acetylenes using an unsupported cobalt polysulfide catalyst 失效
标题翻译：使用无载体的多硫化钴催化剂选择性氢化硝基芳烃乙炔上的硝基
公开(公告)号：US4219679A
公开(公告)日：1980-08-26
申请号：US958162
申请日：1978-11-06
申请人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
发明人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
IPC分类号： B01J27/043 , C07C79/22 , C07C85/11 , C07C85/24
CPC分类号： B01J27/043
摘要： Aromatic nitroacetylene compounds wherein both the nitro and acetylene groups are directly connected to aromatic ring carbon atoms are hydrogenated at high conversion levels to selectively reduce the nitro function using an unsupported cobalt polysulfide catalyst. Of particular interest is the preparation of aminophenylacetylenes from nitrophenylacetylene.
摘要翻译：将硝基和乙炔基团直接与芳环碳原子连接的芳族硝基乙炔化合物以高转化率被氢化，以选择性地降低硝基功能，使用无载体的多硫化钴催化剂。特别感兴趣的是从硝基苯乙炔制备氨基苯乙炔。

9. 发明授权

US4216341A Selective hydrogenation of certain nitroaromatic hydroxy substituted acetylenes over a heterogeneous RuS.sub.2 catalyst 失效
标题翻译：某些硝基芳族羟基取代的乙炔在异质RuS2催化剂上的选择性加氢
公开(公告)号：US4216341A
公开(公告)日：1980-08-05
申请号：US958161
申请日：1978-11-06
申请人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
发明人： Anatoli Onopchenko , Edward T. Sabourin , Charles M. Selwitz
IPC分类号： B01J27/045 , C07C79/22 , C07C85/11 , C07C85/24
CPC分类号： B01J27/045
摘要： Nitroaromatic hydroxy substituted acetylene compounds wherein both the nitro and acetylene groups are directly connected to aromatic ring carbon atoms are hydrogenated in an inert solvent to selectively reduce the nitro function over a ruthenium disulfide catalyst. Of particular interest is the preparation of aminophenylacetylene from nitrophenyl hydroxy substituted acetylene.
摘要翻译：其中硝基和乙炔基直接与芳香环碳原子连接的硝基芳族羟基取代的乙炔化合物在惰性溶剂中氢化以选择性地降低二硫化钌催化剂上的硝基官能团。特别感兴趣的是由硝基苯基羟基取代的乙炔制备氨基苯乙炔。

10. 发明授权

US4175210A Etherification process 失效
标题翻译：醚化过程
公开(公告)号：US4175210A
公开(公告)日：1979-11-20
申请号：US916969
申请日：1978-06-19
申请人： Charles M. Selwitz , John G. McNulty
发明人： Charles M. Selwitz , John G. McNulty
IPC分类号： C07C41/06
CPC分类号： C07C41/06
摘要： A process for converting an olefin, or a mixture of olefins, to an ether, or a mixture of ethers, which comprises reacting said olefin, or said mixture of olefins, with an alcohol in contact with silicatungstic acid.
摘要翻译：将烯烃或烯烃混合物转化为醚或醚的混合物的方法，该方法包括使所述烯烃或所述烯烃混合物与与二氧化钨酸接触的醇反应。

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