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1. 发明公开

CN1032656A 二苯胺的制备方法失效
公开(公告)号：CN1032656A
公开(公告)日：1989-05-03
申请号：CN87107052
申请日：1987-10-21
申请人：尤尼罗亚尔化学公司
发明人：鲁塞尔·E·马茨
IPC分类号： C07C87/54 , C07C85/24
摘要：在约380-475℃间使苯胺与氧化铝催化剂接触以制备二苯胺。该催化剂的总孔体积中至少约有30％是直径约为120-200埃的所有孔的孔体积，该催化剂中硫的含量SO4形式计低于0.02％(重)。

2. 发明公开

CN85102099A 改良氧化催化剂失效
公开(公告)号：CN85102099A
公开(公告)日：1987-01-10
申请号：CN85102099
申请日：1985-04-01
申请人：孟山都公司
发明人：夏因K·乔
IPC分类号： B01J27/20 , B01J37/12 , C01B31/08 , C07C85/24
摘要：本发明涉及一种改良氧化催化剂的方法。该方法通过除去活性炭表面的酸性氧化物，来增加用于氧化反应中该活性炭的催化活性。

3. 发明专利

JPS5037657B1 失效
公开(公告)号：JPS5037657B1
公开(公告)日：1975-12-04
申请号：JP3022270
申请日：1970-04-10
IPC分类号： C07D213/26 , C07B31/00 , C07B37/00 , C07B37/04 , C07C17/26 , C07C22/04 , C07C29/00 , C07C31/34 , C07C45/69 , C07C47/24 , C07C49/16 , C07C49/223 , C07C65/32 , C07C67/00 , C07C205/12 , C07C255/32 , C07C255/53 , C07D207/26 , C07D213/24 , C07D295/04 , C07D303/08 , C07D303/16 , C07C85/24 , C07C76/02 , C07C79/12 , C07C79/46 , C07C87/28 , C07C121/60 , C07C121/66 , C07C149/40

4. 发明专利

JPS5239610A PROCESS FOR CONVERSING HALOGENATED QUARTERNARY AMMONIUM TO QUARTERNARY AMMONIUM SALTS OF ACIDS OTHER THAN HALOGENATED HYDROGEN 失效
公开(公告)号：JPS5239610A
公开(公告)日：1977-03-28
申请号：JP11436776
申请日：1976-09-22
申请人： ICI LTD
发明人： JIYOOJI HENRII RANGU
IPC分类号： C07D213/20 , C07C67/00 , C07C209/00 , C07C211/63 , C07C211/64 , C07D213/22 , C07D471/14 , C07C87/30 , C07C85/24 , C07C87/68 , C07D487/14

5. 发明专利

JPS5146108B2 失效
公开(公告)号：JPS5146108B2
公开(公告)日：1976-12-07
申请号：JP6489871
申请日：1971-08-25
IPC分类号： C07B61/00 , B01J23/00 , B01J23/74 , C07C67/00 , C07C209/00 , C07C209/72 , C07C211/36 , H04N5/95 , C07C87/32 , C07C85/24

6. 发明专利

JPS6016954A PRODUCTION OF ALICYCLIC ENAMINE CONTAINING SUBSTITUENT GROUP 失效
公开(公告)号：JPS6016954A
公开(公告)日：1985-01-28
申请号：JP12168683
申请日：1983-07-06
申请人： NIPPON ZEON CO
发明人： KOMATSUZAKI SHIGERU , OOSAWA AKINOBU , GOTOU KUNIAKI
IPC分类号： C07C49/647 , C07C45/00 , C07C45/42 , C07C67/00 , C07C209/00 , C07C209/68 , C07C211/25 , C07C211/40 , C07D295/02 , C07C87/451 , C07C85/24
摘要： PURPOSE:To produce the titled compound in high yield, by reacting an alicyclic enamine with an aldehyde in the presence of an inert solvent, wherein the condensed liquid of the volatile component is separated into the organic layer and the water layer, the organic layer is dehydrated to a water content below a specific level, and the dehydrated product is recycled to the reaction system. CONSTITUTION:The alicyclic enamine of formula II containing substituent group is produced by condensing the alicyclic enamine of formula I (R1 is water- soluble secondary amine residue; n is 2-9) with the aldehyde of formula R2- CHO (R2 is hydrocarbon residue) in the presence of an inert solvent (e.g. benzene) while refluxing and condensing the solvent. In the above process, the condensed liquid of the volatile components is separated into the organic layer and the water layer, and the organic layer is dehydrated to a water-content of

7. 发明专利

JPS59222451A PRODUCTION OF MONOCHLORO-MINONITROANILINE 失效
公开(公告)号：JPS59222451A
公开(公告)日：1984-12-14
申请号：JP9573883
申请日：1983-06-01
申请人： NIPPON KAYAKU KK
发明人： ISHIKURA TSUKASA , FUKUSHIMA TATSUHARU
IPC分类号： C07C209/76 , C07C67/00 , C07C209/00 , C07C209/10 , C07C211/52 , C07C87/60 , C07C85/24
摘要： PURPOSE:To obtain the titled compound useful as an intermediate for dyes and pigments, etc. in high yield, by reacting a monochloroaniline with a nitrating agent in sulfuric acid while keeping the ratio between water and sulfuric acid in a reaction solution, by adding fuming sulfuric acid or sulfur trioxide to the reaction solution. CONSTITUTION:A monochloroaniline is nitrated in sulfuric acid while keeping the weight ratio between water and sulfuric acid in the reaction medium at 0- 0.04 by adding fuming sulfuric acid or sulfur trioxide to the reaction solution to give the aimed monochloro-mononitroaniline. The ratio (H2O/H2SO4) between H2O and H2SO4 is slowly increased due to the water formed in the progress of the reaction in the usual nitration method, and side reactions occur at a stage when the value exceeds 0.04 to cause the reduction of yield and quality. The aimed monochloro-mononitroaniline containing little isomers and coloring is obtained without causing oxidation and condensation reactions, etc. involving amino groups by keeping the ratio (H2O/H2SO4) within the above-mentioned range.

8. 发明专利

JPS59216852A Preparation of alicylic diamines 失效
标题翻译：合成二胺的制备
公开(公告)号：JPS59216852A
公开(公告)日：1984-12-06
申请号：JP8924283
申请日：1983-05-23
申请人： Nippon Kayaku Co Ltd
发明人： ISHII SHIGERU , KAWAHARA KENICHI
IPC分类号： C07B61/00 , B01J23/00 , B01J23/46 , B01J27/00 , B01J27/18 , B01J27/24 , B01J31/00 , B01J31/02 , B01J31/28 , C07C67/00 , C07C209/00 , C07C209/72 , C07C211/36 , C07C85/24 , C07C87/38 , C07C87/40
CPC分类号： Y02P20/52
摘要： PURPOSE: To obtain the titled compound useful as a raw material for a curing agent of polyamide resin and epoxy resin with preventing side reactions, by subjecting an aromatic diamine to nucleus hydrogenation under specific conditions by the use of a rhodium catalyst in an aqueous medium under hydrogen pressure.
CONSTITUTION: An aromatic diamine is subjected to nucleus hydogenation in an aqueous medium in the presence of a rhodium catalyst, and trisodium phosphate or tripotassium phosphate, and one or more of ammonia, fatty secondary amine, and fatty tertiary amine at atmospheric pressure W300kg/cm
2 at 50W250°C preferably at 7W100kg/cm
2 at 65W180°C, to give an alicyclic diamine. The amount of the rhodium catalyst is 0.01W10wt%, based on the aromatic diamine, the amount of water is 0.5W10 times as the catalyst by weight, the amount of trisodium phosphate is 0.1W10wt%, and the amount of ammonia, fatty secondary amine or fatty tertiary amine is 1W20wt%.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：为了获得可用作聚酰胺树脂和环氧树脂的固化剂的预防副反应的原料的标题化合物，通过在特定条件下使用铑催化剂在水性介质中进行核氢化，氢气压力。构成：在铑催化剂，磷酸三钠或磷酸三钾，以及一种或多种氨，脂肪仲胺和脂肪叔胺的存在下，在大气压-300kg / cm 2的条件下，将芳族二胺在含水介质中进行核氢化，在50-250℃，优选7-100kg / cm 2，65-180℃下，得到脂环族二胺。铑催化剂的量为0.01-10重量％，基于芳族二胺，水的量为催化剂重量的0.5-10倍，磷酸三钠的量为0.1-10重量％，氨的用量，脂肪族仲胺或脂肪叔胺为1-20重量％。

9. 发明专利

JPS5720937B2 JPS5720937B2 - 失效
公开(公告)号：JPS5720937B2
公开(公告)日：1982-05-04
申请号：JP8691273
申请日：1973-08-03
IPC分类号： C08G12/00 , C07C20060101 , C07C67/00 , C07C209/00 , C07C209/18 , C07C209/78 , C07C211/50 , C08G20060101 , C08G12/08 , C07C87/50 , C07C85/24

10. 发明专利

JPS5641628B2 失效
公开(公告)号：JPS5641628B2
公开(公告)日：1981-09-29
申请号：JP6104673
申请日：1973-06-01
IPC分类号： C08G12/00 , C07C67/00 , C07C209/00 , C07C209/78 , C07C211/43 , C07C211/50 , C08G20060101 , C08G12/08 , C08G73/02 , C07C87/50 , C07C85/24

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