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    • 1. 发明授权
    • Surfactant oil recovery systems and recovery of oil therewith
    • 表面活性剂油回收系统和油的回收
    • US4561501A
    • 1985-12-31
    • US508709
    • 1983-06-28
    • James E. ShawJerry E. Pardue
    • James E. ShawJerry E. Pardue
    • C09K8/584E21B43/22
    • C09K8/584Y10S507/936
    • In accordance with the present invention, oil is recovered from a subsurface earth formation by injecting into the subsurface formation an aqueous surfactant system containing a polyvalent metal carboxylate, as a surfactant, a cosurfactant and an electrolyte in concentrations and proportions to form multiphase system with the reservoir oil, thereafter, injecting into the earth formation a drive fluid to drive the multiphase system through the reservoir and displace a significant amount of the reservoir oil and withdrawing the thus displaced oil from the subsurface earth formation. A novel aqueous surfactant system, adapted to thus recover oil from a subsurface formation, comprises a polyvalent metal carboxylate, such as calcium isosteareate, as a surfactant, and an alcohol having at least five carbon atoms, as a cosurfactant, and an electrolyte, such as sodium chloride, in proportions which form a multiphase system with the reservoir oil.
    • 根据本发明,通过向地下地层注入含有多价金属羧酸盐的表面活性剂体系,作为表面活性剂,助表面活性剂和电解质的浓度和比例,从地下地层中回收油,以形成多相体系 储层油,此后将注入到地层中的驱动流体驱动多相系统通过储存器,并移出大量的储层油,并将如此排出的油从地下地层排出。 一种适于从地下地层回收油的新型含水表面活性剂体系包括多价金属羧酸盐,例如作为表面活性剂的异辛酸钙,以及具有至少五个碳原子的醇作为辅助表面活性剂,以及电解质,例如 作为氯化钠,以与储层油形成多相体系的比例。
    • 3. 发明授权
    • Phosphinate inhibitor for scale squeeze applications
    • 用于鳞片挤压应用的磷酸盐抑制剂
    • US5018577A
    • 1991-05-28
    • US561854
    • 1990-08-02
    • Jerry E. PardueJames F. Kneller
    • Jerry E. PardueJames F. Kneller
    • C02F5/14C07F9/30C09K8/528
    • C09K8/528C02F5/14C07F9/301Y10S507/927
    • A squeeze treatment for preventing scale utilizes as the scale inhibitor a predominantly phosphinate containing composition comprising:______________________________________ Mole Percent - Ingredients Less Than ______________________________________ A. Monosodium phosphinicobis - 22 (succinic acid) B. Monosodium phosphinico- 26 succinic acid C. Sodium phosphonosuccinic acid 12 D. Sodium phosphate 5 E. Sodium phosphite 6 F. Sodium hypophosphite, and 6 G. A phosphinicosuccinic acid oligomer having the probable structural formula: ##STR1## ______________________________________ wherein G exceeds 25 mole percent, M is H, Na, K, NH.sub.4, amine salts and mixtures thereof and m and n are either 0 or a small whole number with the proviso that either m or n is a small whole number and the sum of m plus n is greater than 2.
    • 用于防止垢的挤压处理用作阻垢剂,主要是含磷酸盐的组合物,其包含: - 摩尔百分数 - 小于-A的成分。 次膦酸二钠22 - (琥珀酸)-B。 次膦酸二钠26-琥珀酸-C。 次膦酸琥珀酸钠12-D。 磷酸钠5 -E。 亚磷酸钠6 -F。 次磷酸钠和6 -G。 具有可能结构式的次膦酸琥珀酸低聚物:其中G超过25摩尔%,M为H,Na,K,NH 4,胺盐及其混合物,m和n为0或小整数 数字,条件是m或n是小整数,m + n的和大于2。