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    • 1. 发明授权
      US4357335A Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides 失效
    • Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides
    • 二甲基环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途
    • US4357335A
    • 1982-11-02
    • US280547
    • 1981-07-06
    • Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
    • Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
    • A01N53/04 , A01N53/00 , A01N53/08 , A61K31/44 , C07D213/64 , C07D213/643 , C07D213/647 , C07D213/70 , C07D405/12 , C07D409/12 , C07D213/55
    • C07D213/643 , A01N53/00 , A61K31/44 , C07D213/647 , C07D213/70
    • Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein A is selected from the group consisting of ##STR2## R is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, Y is selected from the group consisting of oxygen and sulfur, Z is selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, alkylthio and alkylsulfonyl of 1 to 4 carbon atoms, cycloalkyl of 3 to 4 carbon atoms, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is an integer of 0, 1 or 2, Z.sub.1 and Z.sub.2 may both be methyl or Z.sub.1 is hydrogen and Z.sub.2 is ##STR3## R.sub.3 is selected from the group consisting of hydrogen and halogen, R.sub.1 and R.sub.2 are individually alkyl of 1 to 8 carbon atoms or taken together with the carbon they are attached to form cycloalkyl of 3 to 6 carbon atoms or ##STR4## X is selected from the group consisting of oxygen and sulfur, T is at least one member of the group consisting of halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms optionally substituted with at least one halogen and --CF.sub.3 and m is an integer from 0, 1 or 2 having insecticidal activity as well as nematocidal and acaricidal activity.
    • 所有可能的异构体形式的新型酯及其下式的混合物，其中A选自由下列组成的组：R 1选自氢，-CN和-C 3位CH，Y选自 Z为选自由1至4个碳原子的烷基和烷氧基组成的组，1至4个碳原子的烷硫基和烷基磺酰基，3至4个碳原子的环烷基，3,4-亚甲二氧基 ，氯，氟和溴，n是0,1或2的整数，Z1和Z2都可以是甲基或Z1是氢，Z2是选自氢和卤素，R1和R2 具有1至8个碳原子的单独烷基或与它们所连接的碳一起形成3至6个碳原子的环烷基，或者X选自氧和硫，T是至少一个 由卤素，1至8个碳原子的烷基，1至8个的烷氧基组成的组 任选被至少一个卤素和-CF 3取代的碳原子，m是具有杀虫活性以及杀线虫和杀螨活性的0,1或2的整数。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 5. 发明授权
      US4315868A Process for the preparation of .alpha.-cyanobenzyl esters 失效
    • Process for the preparation of .alpha.-cyanobenzyl esters
    • 制备α-氰基苄基酯的方法
    • US4315868A
    • 1982-02-16
    • US193798
    • 1980-10-03
    • Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Andre Teche
    • Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Andre Teche
    • C07C69/007 , A01N37/10 , A01N53/02 , A01N53/06 , A01N53/08 , C07C43/225 , C07C67/00 , C07C69/74 , C07C69/743 , C07C69/747 , C07C69/76 , C07C255/16 , C07C255/38 , C07C255/53 , C07C313/00 , C07C319/20 , C07C323/12 , C07D209/49 , C07D307/42 , C07C120/04 , C07C121/66 , C07C121/75
    • C07C255/00 , C07C43/225
    • Novel esters in the form of their stereoisomers and mixtures of stereoisomers of the formula ##STR1## wherein X is selected from the group consisting of fluorine, chlorine and bromine R.sub.1 is selected from the group consisting of ##STR2## Y.sub.1 and Y.sub.2 may both be methyl and when Y.sub.1 is hydrogen, Y.sub.2 is selected from the group consisting of ##STR3## and Y.sub.3 and Y.sub.4 are individually selected from the group consisting of fluorine, bromine and chlorine or the group consisting of hydrogen and methyl, Z is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms and alkoxy of 1 to 4 carbon atoms, and when Y.sub.2 is ##STR4## R.sub.2 is selected from the group consisting of ##STR5## A is selected from the group consisting of ##STR6## and when Y.sub.2 is -CHBr-CCl.sub.2 Br, R.sub.2 is m-phenoxy-phenyl and when R.sub.1 is R.sub.1 ' and Y.sub.2 is ##STR7## the said acid moiety may be in the cis or trans form or mixtures thereof or optically active isomeric form or racemic mixtures thereof and when R.sub.1 is R.sub.1 ", the said acid moiety is optically active isomeric form or racemic mixtures thereof and the compounds may be in one of two diastereoisomeric forms due to the existence of the asymetrical carbon atoms to which X is attached having insecticidal activity and their preparation.
    • 其立体异构体形式的新型酯和式IA的立体异构体的混合物，其中X选自氟，氯和溴。R1选自下组：Y1和Y2可以是 甲基，当Y1为氢时，Y2选自和Y3，Y4分别选自氟，溴和氯或由氢和甲基组成的组，Z选自 由氢，氟，氯，溴，1至4个碳原子的烷基和1至4个碳原子的烷氧基组成，当Y2是 R2时，选自 A是选自 + TR ，当Y2是-CHBr-CCl2Br时，R2是间苯氧基 - 苯基，当R1是R1'且Y2是< 所述酸部分可以是顺式或反式或其混合物或旋光异构体 ic形式或外消旋混合物，并且当R 1为R 1“时，所述酸部分为旋光异构体形式或其外消旋混合物，并且由于存在非对映异构体形式，化合物可以是非对映异构体形式之一，其中X 附着有杀虫活性及其制备。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 6. 发明授权
      US4277617A Process for the preparation of esters 失效
    • Process for the preparation of esters
    • 制备酯的方法
    • US4277617A
    • 1981-07-07
    • US951184
    • 1978-10-13
    • Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Andre Teche
    • Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Andre Teche
    • C07C69/007 , A01N37/10 , A01N53/02 , A01N53/06 , A01N53/08 , C07C43/225 , C07C67/00 , C07C69/74 , C07C69/743 , C07C69/747 , C07C69/76 , C07C255/16 , C07C255/38 , C07C255/53 , C07C313/00 , C07C319/20 , C07C323/12 , C07D209/49 , C07D307/42
    • C07C255/00 , C07C43/225
    • Novel esters in the form of their stereoisomers and mixtures of stereoisomers of the formula ##STR1## wherein X is selected from the group consisting of fluorine, chlorine and bromine R.sub.1 is selected from the group consisting of ##STR2## Y.sub.1 and Y.sub.2 may both be methyl and when Y.sub.1 is hydrogen, Y.sub.2 is selected from the group consisting of ##STR3## and Y.sub.3 and Y.sub.4 are individually selected from the group consisting of fluorine, bromine and chlorine or the group consisting of hydrogen and methyl, Z is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms and alkoxy of 1 to 4 carbon atoms, and when Y.sub.2 is ##STR4## R.sub.2 is selected from the group consisting of ##STR5## A is selected from the group consisting of ##STR6## and when Y.sub.2 is --CHBr--CCl.sub.2 Br, R.sub.2 is m-phenoxy-phenyl and when R.sub.1 is R.sub.1 ' and Y.sub.2 is ##STR7## the said acid moiety may be in the cis or trans form or mixtures thereof or optically active isomeric form or racemic mixtures thereof and when R.sub.1 is R.sub.1 ", the said acid moiety is optically active isomeric form or racemic mixtures thereof and the compounds may be in one of two diastereoisomeric forms due to the existence of the asymetrical carbon atoms to which X is attached having insecticidal activity and their preparation.
    • 其立体异构体形式的新型酯和式IA的立体异构体的混合物，其中X选自氟，氯和溴。R1选自下组：Y1和Y2可以是 甲基，当Y1为氢时，Y2选自和Y3，Y4分别选自氟，溴和氯或由氢和甲基组成的组，Z选自 由氢，氟，氯，溴，1至4个碳原子的烷基和1至4个碳原子的烷氧基组成，当Y2是 R2时，选自 + TR A选自 + TR ，当Y2为-CHBr-CCl2Br时，R2为间苯氧基 - 苯基，当R1为R1'且Y2为时， 所述酸部分可以是顺式或反式或其混合物或旋光异构形式 或其外消旋混合物，并且当R 1为R 1“时，所述酸部分为光学活性异构体形式或其外消旋混合物，并且由于X附着的非对称碳原子的存在，所述化合物可为两种非对映异构形式之一 具有杀虫活性及其制备方法。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 7. 发明授权
      US4569928A Anti-parasitic esters 失效
    • Anti-parasitic esters
    • 抗寄生酯
    • US4569928A
    • 1986-02-11
    • US546392
    • 1983-10-28
    • Jean Tessier , Andre Teche , Jean-Pierre Demoute
    • Jean Tessier , Andre Teche , Jean-Pierre Demoute
    • C07C325/00 , A01N53/00 , A01N53/02 , A01N53/10 , A23K1/16 , C07C67/00 , C07C69/74 , C07C327/22 , C07C327/24 , C07C327/26 , C07D233/72
    • A01N53/00 , A23K20/00
    • Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 18 carbon atoms and optionally unsaturated cycloalkyl or cycloalkylalkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', --NO.sub.2, ##STR2## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR3## R' is alkyl of 1 to 8 carbon atoms, R" and R'" are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substituent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, A is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having antiparasitic activity, especially insecticidal, acaricidal and nematocidal activity.
    • 具有式（I）的所有可能的异构体形式的新型酯及其混合物，其中R选自（a）1至18个碳原子的任选不饱和的烷基和3至8个碳原子的任选的不饱和环烷基或环烷基烷基 任选地被至少一个由卤素，-OH，-SH，-OR'，-SR'，-NO 2，SO 3，-SO 2 AlK 2，-SO 3 AlK 3取代的基团， 由-OH，1〜8个碳原子的烷氧基，1〜8个碳原子的烷基，卤素，-CF 3，-OCF 3，-SCF 3和R 8中的至少1个成员是1〜8个碳原子的烷基 原子，R“和R”“分别选自氢和1至8个碳原子的烷基，AlK1，AlK2和AlK3分别为1至18个碳原子的烷基（b）6至14的芳基 碳原子任选被至少一个选自-OH，1-8个碳原子的烷氧基，1个烷基的烷基取代的取代基 至8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选被至少一个由-OH，1-8个碳原子的烷氧基，1-8个碳原子的烷基取代的杂环 ，卤素，-CF 3，-OCF 3和-SCF 3，A选自任选不饱和的1至18个碳原子的烷基，任选的具有3至18个碳原子的不饱和环烷基，剩余的用于合成除虫菊酯的醇 酯，X是卤素，烯属双键可具有具有抗寄生虫活性的Z或E几何形状，特别是杀虫，杀螨和杀线虫活性。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 8. 发明授权
      US4513139A Substituted lactones of amino acids 失效
    • Substituted lactones of amino acids
    • 取代的氨基酸内酯
    • US4513139A
    • 1985-04-23
    • US393812
    • 1982-06-30
    • Jacques Martel , Jean Tessier , Andre Teche
    • Jacques Martel , Jean Tessier , Andre Teche
    • C07D307/33 , C07D207/16 , C07D307/93 , C07D405/04
    • C07D207/16
    • Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y--OH and B is the remainder of a heterocyclic amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.
    • 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余部分：III1衍生自式Y-OH的伯，仲或叔醇，B是杂环氨基酸的剩余部分3 至6个碳原子，它们的制备及其用于分解氨基酸的用途。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 9. 发明授权
      US4808749A Cyclopropane carboxylic esters and acids 失效
    • Cyclopropane carboxylic esters and acids
    • 环丙烷羧酸酯和酸
    • US4808749A
    • 1989-02-28
    • US932179
    • 1986-11-18
    • Jacques Martel , Jean Tessier , Andre Teche
    • Jacques Martel , Jean Tessier , Andre Teche
    • A01N53/00 , A01N53/02 , A23K1/16 , A61K31/22 , A61K31/225 , C07D213/64 , C07D213/647 , C07D233/74 , C07F9/40 , C07C121/46 , C07C53/134
    • C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A61K31/22 , A61K31/225 , C07D233/74 , C07F9/4006
    • Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkyl-alkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', --NO.sub.2, ##STR2## --CN, --SO.sub.3 H, --PO.sub.4 H.sub.2, ##STR3## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR4## R' is alkyl of 1 to 8 carbon atoms, R" and R"' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms, (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substitutent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, B is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal acaricidal and nematocidal activity.
    • 式（Ⅰ）的所有可能异构体形式的新型酯，其中R选自（a）1-8个碳原子的任选不饱和烷基和任选不饱和的环烷基或3-8个碳原子的环烷基 - 烷基， 被至少一个由卤素，-OH，-SH，-OR'，-SR'，-NO 2，-CN，-SO 3 H，-PO 4 H 2，-SO 2 AlK 2，-SO 3 AlK 3 任选被-OH，1-8个碳原子的烷氧基，1-8个碳原子的烷基，卤素，-CF 3，-OCF 3，-SCF 3和R'中的至少一个成员取代的芳基是 1至8个碳原子的烷基，R“和R”'分别选自氢和1至8个碳原子的烷基，AlK1，AlK2和AlK3分别为1至18个碳原子的烷基（ b）6至14个碳原子的芳基，任选被至少一个选自-OH，1至8个碳原子的烷氧基，1〜 8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选被至少一个选自-OH，1-8个碳原子的烷氧基，1至8个碳原子的烷基取代的杂环， 卤素，-CF 3，-OCF 3和-SCF 3，B选自任选不饱和的1至18个碳原子的烷基，任选地具有3至18个碳原子的不饱和环烷基，剩余的用于合成除虫菊酯的醇 X是卤素，烯键式双键可具有具有寄生活性的Z或E几何形状，特别是杀虫杀螨和杀线虫活性。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 10. 发明授权
      US4732903A Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity 失效
    • Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity
    • 某些具有杀虫活性和杀虫活性的环丙基二羧酸酯
    • US4732903A
    • 1988-03-22
    • US756396
    • 1985-07-17
    • Jacques Martel , Jean Tessier , Andre Teche
    • Jacques Martel , Jean Tessier , Andre Teche
    • A01N53/00 , A23K1/16 , A61K31/22 , C07D209/48 , C07D213/64 , C07D213/647 , C07D233/72 , C07D307/20 , C07D307/45 , C07D309/12 , C07D213/55 , A01N43/40 , C07C69/743 , C07C121/75
    • C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A23K20/132 , A61K31/22 , C07D209/48 , C07D233/72 , C07D307/20 , C07D307/42 , C07D309/12
    • Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of wherein B is selected from the group consisting of --CH.sub.2 --, ##STR2## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3,--C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer from 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR3## wherein R.sub.13 is selected from the group consisting of hydrogen and ##STR4## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position, ##STR5## wherein R.sub.14 is selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR6## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3, 3,4-methylenedioxy, chlorine, bromine and fluorine B' is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.
    • 环丙烷羧酸衍生物与式（I）所示的3-不饱和侧链的新颖异构体及其混合物，其中A'选自由下列组成的组：其中B选自： -CH 2 - ， -O-和-S-，R 4选自氢，-CH 3，-C 3BOND N CONH 2，-CSNH 2和-C 3 CH 3，n是0的整数， （3）其中R 13选自氢和（4）其中R 13具有上述基团，其中R 13选自氢和 （14）其中R 14选自氢，甲基，乙炔基和-CN，R 15和R 16分别选自氢， ，溴和氟，并且其中R 14具有上述定义，p为0,1或2，每个R 17选自1至4个碳原子的烷基 1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基磺酰基，-CF 3，3,4-亚甲二氧基，氯，溴和氟B'选自： -O-和-S-，并且R选自被一个或多个任选不同的官能团取代的1至18个碳原子的烷基，任选被一个或多个任选不同的官能团取代的6至14个碳原子的芳基 组，具有Z或E几何形状的双键具有杀虫和杀线虫活性以及植物和动物杀螨活性及其制备。
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