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    • 1. 发明申请
    • SOLID ACID CATALYST CONTAINING PLATINUM GROUP METAL COMPONENT AND METHOD FOR PREPARATION THEREOF
    • 含有铂族金属成分的固体酸催化剂及其制备方法
    • WO02070129A9
    • 2003-01-03
    • PCT/JP0201873
    • 2002-02-28
    • JAPAN ENERGY CORPFURUTA SATOSHIOGAWA MINORU
    • FURUTA SATOSHIOGAWA MINORU
    • B01J23/42B01J27/053B01J29/068B01J35/10B01J37/02
    • B01J29/068B01J23/42B01J27/053B01J35/006B01J35/10B01J35/1019B01J35/1038B01J35/1061
    • A solid acid catalyst which contains a porous catalyst pellet exhibiting solid acid properties and a platinum group metal component carried on the catalyst pellet and can be used in an acid-catalyzed reaction, wherein it has a platinum group metal component distribution therein such that a value obtained by dividing a standard deviation of concentrations of the platinum group metal component by an average concentration is 0.4 or less; a method for preparing the solid acid catalyst which comprises providing a solution to be carried containing a platinum group metal as a cation and impregnating a crystalline porous catalyst pellet exhibiting solid acid properties with the solution to be carried; and a method for isomerizing a hydrocarbon which comprises contacting a hydrocarbon stock containing 70 wt % or more of saturated hydrocarbon components having 4 to 10 carbon atoms with the solid acid catalyst. The above solid acid catalyst having an above specified distribution of a platinum group metal component exhibits an enhanced catalyst activity.
    • 一种固体酸催化剂,其含有表现出固体酸性质的多孔催化剂颗粒和载于催化剂颗粒上的铂族金属组分,可用于酸催化反应,其中铂族金属组分分布在其中,使得值 通过将铂族金属成分的浓度的标准偏差除以平均浓度而得到的值为0.4以下; 一种制备固体酸催化剂的方法,其包括提供含有铂族金属作为阳离子的载体溶液,并用待携带的溶液浸渍显示固体酸性质的结晶多孔催化剂颗粒; 和烃的异构化方法,其包括使含有70重量%以上的具有4〜10个碳原子的饱和烃成分的烃原料与固体酸催化剂接触。 具有上述特定分布的铂族金属组分的上述固体酸催化剂表现出提高的催化剂活性。
    • 3. 发明公开
    • SOLID ACID CATALYST CONTAINING PLATINUM GROUP METAL COMPONENT AND METHOD FOR PREPARATION THEREOF
    • 随着对生产铂族金属组分和方法固体酸催化剂
    • EP1374993A4
    • 2006-05-17
    • EP02702717
    • 2002-02-28
    • JAPAN ENERGY CORP
    • FURUTA SATOSHIOGAWA MINORU
    • B01J23/42B01J27/053B01J29/068B01J35/10B01J37/02
    • B01J29/068B01J23/42B01J27/053B01J35/006B01J35/10B01J35/1019B01J35/1038B01J35/1061
    • A solid acid catalyst which contains a porous catalyst pellet exhibiting solid acid properties and a platinum group metal component carried on the catalyst pellet and can be used in an acid-catalyzed reaction, wherein it has a platinum group metal component distribution therein such that a value obtained by dividing a standard deviation of concentrations of the platinum group metal component by an average concentration is 0.4 or less; a method for preparing the solid acid catalyst which comprises providing a solution to be carried containing a platinum group metal as a cation and impregnating a crystalline porous catalyst pellet exhibiting solid acid properties with the solution to be carried; and a method for isomerizing a hydrocarbon which comprises contacting a hydrocarbon stock containing 70 wt % or more of saturated hydrocarbon components having 4 to 10 carbon atoms with the solid acid catalyst. The above solid acid catalyst having an above specified distribution of a platinum group metal component exhibits an enhanced catalyst activity.
    • 本发明提供用于与催化剂活性的铂族金属组分的催化剂in'a的浓度分布可被增加,并且用于支撑铂族金属与此浓度分布可以实现的方法。 本发明是一种固体酸催化剂确实包含多孔催化剂丸粒显示固体酸特性,和铂族金属组分由合成催化剂粒料支撑,并且没有被用于酸催化的反应,其中将所述标准偏差的一个商 在通过催化剂的平均浓度的铂族金属组分的浓度分布的浓度为0.4或更小。 用于制备这种催化剂的方法,包括:制备一个支撑溶液包含铂族金属作为阳离子的步骤,和浸渍结晶的步骤,多孔丸的催化剂表现出与此支持溶液中的固体酸的特性。 本发明因此提供了用于异构化的烃,worin固体酸催化剂被带入与烃包括具有4至10个碳原子的饱和烃成分的至少70%(重量)接触的方法。