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    • 9. 发明申请
    • METAL BASED CERAMIC FILLERS AS CATALYSTS FOR SELECTIVE ELECTROLESS METAL PLATING
    • 金属基陶瓷填料作为选择性化学镀金属的催化剂
    • WO2018063398A1
    • 2018-04-05
    • PCT/US2016/055019
    • 2016-09-30
    • INTEL CORPORATIONRAGHUNATHAN, VivekLI, Yonggang
    • RAGHUNATHAN, VivekLI, Yonggang
    • H01L21/768
    • Embodiments include methods for selective electroless plating of dielectric layers and devices formed by such processes. According to an embodiment, patterned surfaces are formed in a dielectric layer that includes metallic ceramic fillers. In some embodiments, the patterned surfaces form a line opening and a via opening that exposes a conductive pad. In an embodiment, the metallic ceramic fillers are activated to form activated surfaces over the patterned surfaces. A first metal is then deposited into the via opening with a first electroless solution that is a bottom-up deposition process. Thereafter, embodiments include forming a seed layer over exposed portions of the activated surfaces. In an embodiment, mid-gap states of the activated surfaces have an energy level approximately equal to a reduction potential of metal ions in a second electroless solution. Embodiments may then include depositing a second metal into the via opening with a third electroless solution.
    • 实施方式包括用于选择性无电镀电介质层和通过这些工艺形成的器件的方法。 根据一个实施例,图案化表面形成在包括金属陶瓷填料的介电层中。 在一些实施例中,图案化表面形成暴露导电垫的线开口和通孔开口。 在一个实施例中,金属陶瓷填料被激活以在图案化表面上形成活化表面。 然后用第一种无电解决方案将第一种金属沉积到通孔开口中,该第一种无电解决方案是自底向上沉积工艺。 此后,实施例包括在激活表面的暴露部分上形成种子层。 在一个实施例中,激活表面的中间隙状态具有与第二无电解决方案中的金属离子的还原电位近似相等的能级。 然后,实施例可以包括利用第三无电解决方案将第二金属沉积到通孔开口中。