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1. 发明申请

US20020022692A1 Polycarbonate resin composition and shaped article 审中-公开
标题翻译：聚碳酸酯树脂组合物和成型制品
公开(公告)号：US20020022692A1
公开(公告)日：2002-02-21
申请号：US09891293
申请日：2001-06-27
申请人： Idemitsu Petrochemical Co., Ltd.
发明人： Masaya Okamoto , Masahiro Kitayama , Akio Nodera
IPC分类号： C08L051/00
CPC分类号： C08K5/5419 , C08L27/12 , C08L51/04 , C08L69/00 , C08L83/04 , C08L2666/02
摘要： The polycarbonate resin composition of the present invention comprises (A) 100 parts by mass of an end-modified polycarbonate resin terminated with a (C10-C35 alkyl)phenoxy group or a polycarbonate resin mixture comprising the end-modified polycarbonate resin and another polycarbonate resin; (B) 0.1 to 10 parts by mass of a functionalized silicone compound; and (C) 0.2 to 10 parts by mass of a core-shell type rubber-like graft elastomer. Another polycarbonate resin composition of the present invention comprises a resin mixture comprising 100 parts by mass of a resin mixture comprising (Anull) 1 to 99% by mass of an end-modified polycarbonate resin terminated with a (C10-C35 alkyl)phenoxy group or a polycarbonate mixture comprising the end-modified polycarbonate resin and another polycarbonate resin and (Bnull) 99 to 1% by mass of a styrene resin; and (Cnull) 0.01 to 5 parts by mass of a polyfluoroolefin resin. By the combined use of the polycarbonate having a specific terminal structure with the functionalized silicone compound and the core-shell type rubber-like graft elastomer, or with the styrene resin and the polyfluoroolefin resin, the moldability/extrudability, i.e., melt fluidity, of the polycarbonate composition is improved while retaining the good impact resistance inherent to polycarbonate resin, thereby enabling the production of thin-wall shaped articles. The polycarbonate resin composition of the present invention is also improved in the flame retardancy without using a halogen- or phosphorus-containing flame retardant, and is therefore excellent in the heat resistance and the recyclability.
摘要翻译：本发明的聚碳酸酯树脂组合物包含（A）100质量份用（C 10 -C 35烷基）苯氧基封端的末端改性聚碳酸酯树脂或包含末端改性聚碳酸酯树脂和另一聚碳酸酯树脂的聚碳酸酯树脂混合物 ; （B）0.1〜10质量份官能化硅氧烷化合物; 和（C）0.2〜10质量份的核 - 壳型橡胶状接枝弹性体。本发明的另一种聚碳酸酯树脂组合物包括一种树脂混合物，其包含100质量份的由（A'）1至99质量％的由（C 10 -C 35烷基）苯氧基封端的末端改性聚碳酸酯树脂或包含端改性聚碳酸酯树脂和另一聚碳酸酯树脂的聚碳酸酯混合物和（B'）99〜1质量％的苯乙烯树脂; 和（C'）0.01〜5质量份的聚氟烯烃树脂。通过将具有特定末端结构的聚碳酸酯与官能化硅酮化合物和核 - 壳型橡胶状接枝弹性体，或与苯乙烯树脂和聚氟烯烃树脂的组合使用，成型性/挤出性即熔体流动性改善了聚碳酸酯组合物，同时保持了聚碳酸酯树脂固有的良好的抗冲击性，从而能够生产薄壁形制品。本发明的聚碳酸酯树脂组合物在不使用含卤素或含磷阻燃剂的情况下也具有阻燃性的提高，耐热性和可回收性优异。

2. 发明申请

US20020115789A1 Thermoplastic resin compostions and thier injection moldings 失效
标题翻译：热塑性树脂组合物及其注射成型品
公开(公告)号：US20020115789A1
公开(公告)日：2002-08-22
申请号：US10060257
申请日：2002-02-01
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： Akio Nodera , Naoki Mitsuta
IPC分类号： C08G063/48
CPC分类号： C08L53/025 , C08K5/0066 , C08K5/1515 , C08K5/49 , C08K5/523 , C08L51/04 , C08L53/00 , C08L53/005 , C08L53/02 , C08L55/02 , C08L63/00 , C08L69/00 , C08L2666/14 , C08L2666/02 , C08L2666/24
摘要： The invention provides a thermoplastic resin composition characterized by both a polycarbonate resin and a styrenic resin, of which the moldings are not troubled by surface layer peeling and have good impact resistance. Even when a flame retardant is added thereto, the moldability of the composition is still good, and the moldings of the composition still have good impact resistance and aging resistance, and are recyclable. The invention also provides a non-halogen, flame-retardant polycarbonate resin composition having good flame retardancy, and its injection moldings having good impact strength and yellowing resistance even in high-temperature and high-humidity conditions and having good recyclability. The thermoplastic resin composition comprises 100 parts by weight of a resin mixture of (A) from 20 to 98% by weight of a polycarbonate resin and (B) from 2 to 80% by weight of a styrenic resin, from 0.1 to 20 parts by weight of (C) an epoxy-modified block copolymer and from 0.5 to 20 parts by weight of (D) a rubber-like elastomer component of a core/shell-type, grafted rubber-like elastomer. The flame-retardant polycarbonate resin composition comprises 100 parts by weight of a resin or resin mixture of (A) from 20 to 100% by weight of a polycarbonate resin and (B) from 0 to 80% by weight of a styrenic resin, from 1 to 30 parts by weight of (E) a flame retardant of an organic phosphorus compound, and from 0.1 to 10 parts by weight of (D) an epoxy group-containing compound.
摘要翻译：本发明提供一种热塑性树脂组合物，其特征在于聚碳酸酯树脂和苯乙烯树脂，其中模制品不受表面层剥离的困扰并具有良好的耐冲击性。即使添加阻燃剂，组合物的成型性仍然良好，组合物的成型品仍具有良好的耐冲击性和耐老化性，并且是可回收利用的。本发明还提供了具有良好阻燃性的非卤素阻燃聚碳酸酯树脂组合物，即使在高温高湿条件下也具有良好的冲击强度和耐黄变性，并且具有良好的可再循环性的注塑成型品。热塑性树脂组合物包含100重量份的（A）20至98重量％的聚碳酸酯树脂的树脂混合物和（B）2至80重量％的苯乙烯树脂，0.1至20重量份的（C）环氧改性嵌段共聚物的重量和0.5〜20重量份的（D）核/壳型接枝橡胶状弹性体的橡胶状弹性体成分。阻燃聚碳酸酯树脂组合物包含100重量份的（A）20至100重量％的聚碳酸酯树脂的树脂或树脂混合物和（B）0至80重量％的苯乙烯树脂，来自（E）有机磷化合物的阻燃剂1〜30重量份，（D）含环氧基化合物0.1〜10重量份。

3. 发明申请

US20030191245A1 Flame-retardant polycarbonate resin composition and formed article 失效
标题翻译：阻燃聚碳酸酯树脂组合物和成型制品
公开(公告)号：US20030191245A1
公开(公告)日：2003-10-09
申请号：US10389988
申请日：2003-03-18
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： Akio Nodera , Masahiro Kitayama
IPC分类号： C08F008/00
CPC分类号： C08L69/00 , C08G77/448 , C08L25/06 , C08L27/12 , C08L27/18 , C08L51/04 , C08L53/02 , C08L55/02 , C08L83/04 , C08L83/10 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04
摘要： Provided are a polycarbonate resin composition containing a non-halogen flame retardant enough to ensure good flame retardancy and capable of being formed into good moldings having good impact resistance and good thermal stability; and such moldings of the composition. One type of the resin composition comprises 100 parts by weight of a resin mixture of (A) from 60 to 99% by weight of a polycarbonate resin and (B) from 1 to 40 % by weight of a styrenic resin, and from 0.1 to 10 parts by weight of (C) a functional group-having silicone compound, and from 0.02 to 5 parts by weight of (D) a fluoro-olefin resin; another type thereof comprises 100 parts by weight of (A) a polycarbonate resin, from 0.1 to 10 parts by weight of (C) a functional group-having silicone compound, and from 0.2 to 10 parts by weight of (E) a core/shell-type, grafted rubbery elastomer; and still another type thereof comprises 100 parts by weight of a resin mixture of (A) from 1 to 99% by weight of a polycarbonate resin and (B) from 1 to 99% by weight of a styrenic resin, from 0.01 to 5 parts by weight of (D) a fluoro-olefin resin, from 1 to 100 parts by weight of (F) an inorganic filler, and from 1 to 500 parts by weight of (G) a polycarbonate-polyorganosiloxane copolymer and/or from 0.1 to 10 parts by weight of (C) a functional group-having silicone resin.
摘要翻译：提供一种聚碳酸酯树脂组合物，其含有足够的非卤素阻燃剂以确保良好的阻燃性并且能够形成具有良好的耐冲击性和良好的热稳定性的良好的模塑品; 和组合物的这种模制品。一种树脂组合物包含100重量份的（A）60至99重量％的聚碳酸酯树脂和（B）1至40重量％的苯乙烯树脂的树脂混合物，和0.1至 10重量份（C）具有官能团的硅氧烷化合物和0.02-5重量份的（D）氟代烯烃树脂; 另一种类型包括100重量份的（A）聚碳酸酯树脂，0.1至10重量份的（C）含官能团的硅氧烷化合物和0.2至10重量份的（E）核/ 壳型，接枝橡胶弹性体; 还有另一种类型包括100重量份的（A）1至99重量％的聚碳酸酯树脂的树脂混合物和（B）1至99重量％的苯乙烯树脂，0.01至5重量份（D）氟代烯烃树脂，1至100重量份的（F）无机填料和1至500重量份的（G）聚碳酸酯 - 聚有机硅氧烷共聚物和/或从0.1至 10重量份（C）具有官能团的硅氧烷树脂。

4. 发明申请

US20020193476A1 Polycarbonate resin composition 失效
公开(公告)号：US20020193476A1
公开(公告)日：2002-12-19
申请号：US10173005
申请日：2002-06-18
申请人： IDEMITSU PETROCHEMICAL CO., LTD.
发明人： Naoki Mitsuta , Akio Nodera
IPC分类号： C08L001/00 , C08K005/49
CPC分类号： C08K5/49 , C08K3/01 , C08K5/50 , C08L69/00
摘要： The invention relates to a polycarbonate resin composition having good durability even in high-moisture atmospheres, and to a flame-retardant polycarbonate resin composition in which the flame retardants adheres little to molds while the resin composition is molded. The polycarbonate resin composition comprises (A) a polycarbonate resin and (B) an inorganic filler, and contains (C) an arylphosphine and optionally (D) a flame retardant.

5. 发明申请

US20020026008A1 Polycarbonate resin composition and shaped article 审中-公开
标题翻译：聚碳酸酯树脂组合物和成型制品
公开(公告)号：US20020026008A1
公开(公告)日：2002-02-28
申请号：US09891521
申请日：2001-06-27
申请人： Idemitsu Petrochemical Co., Ltd.
发明人： Masaya Okamoto , Masahiro Kitayama , Akio Nodera
IPC分类号： C08L051/00 , C08G063/48
CPC分类号： C08L69/00 , C08L27/12 , C08L51/04 , C08L69/005 , C08L83/04 , C08L2666/02
摘要： The polycarbonate resin composition of the present invention comprises (A) a copolyester carbonate having an aliphatic segment or a polycarbonate resin mixture containing the copolyester carbonate; (B) a functionalized silicone compound; and (C) a core-shell type rubber-like graft elastomer. Another polycarbonate resin composition of the present invention comprises a resin mixture comprising (Anull) a copolyester carbonate having an aliphatic segment or a polycarbonate resin mixture containing the copolyester carbonate and (Bnull) a styrene resin; and (Cnull) a polyfluoroolefin resin. By the combined use of the copolyester carbonate having an aliphatic segment with the functionalized silicone compound and the core-shell type rubber-like graft elastomer, or with the styrene resin and the polyfluoroolefin resin, the moldability/extrudability, i.e., melt fluidity, of the polycarbonate composition is improved while retaining the good impact resistance inherent to polycarbonate resin, thereby enabling the production of thin-wall shaped articles. The polycarbonate resin composition of the present invention is also improved in the flame retardancy without using a halogen- or phosphorus-containing flame retardant, and is therefore excellent in the heat resistance and the recyclability.
摘要翻译：本发明的聚碳酸酯树脂组合物包含（A）具有脂肪族部分的共聚酯碳酸酯或含有共聚酯碳酸酯的聚碳酸酯树脂混合物; （B）官能化硅氧烷化合物; 和（C）核 - 壳型橡胶状接枝弹性体。本发明的另一种聚碳酸酯树脂组合物包含一种树脂混合物，其包含（A'）具有脂族部分的共聚酯碳酸酯或含有共聚酯碳酸酯和（B'）苯乙烯树脂的聚碳酸酯树脂混合物; 和（C'）聚氟烯烃树脂。通过将具有脂族部分的共聚酯碳酸酯与官能化硅氧烷化合物和核 - 壳型橡胶状接枝弹性体，或与苯乙烯树脂和聚氟烯烃树脂的组合使用，成型性/挤出性即熔体流动性改善了聚碳酸酯组合物，同时保持了聚碳酸酯树脂固有的良好的抗冲击性，从而能够生产薄壁形制品。本发明的聚碳酸酯树脂组合物在不使用含卤素或含磷阻燃剂的情况下也具有阻燃性的提高，耐热性和可回收性优异。

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