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    • 1. 发明申请
    • Makeup cosmetic and skin cosmetic
    • 化妆化妆品和皮肤化妆品
    • US20040228827A1
    • 2004-11-18
    • US10841518
    • 2004-05-10
    • Masato YoshiokaAiko TakidaniTakashi Adachi
    • A61K007/06A61K007/11C08G063/48
    • A61Q1/08A61K8/64A61Q1/10
    • A makeup cosmetic and a skin cosmetic, which is produced by the following process and has viscosity in a specific range, wherein said process comprises: polycondensing one or more kind selected from silylated peptides represented by the general formula (I) with one or more kind selected from silane compounds represented by the general formula (II) in an aqueous solution to form a polycondensed polymer, and then adding by addition reaction a silane compound represented by the general formula (III) in an aqueous solution to said polycondensed polymer; wherein said silylated peptide represented by the following general formula (I) is 1 , in which R1 represents a hydroxy group etc., R2 represents a residual group of a side chain obtained by removing the terminal end amino group of a basic amino acid having an amino group at the end of a side chain, R3 represents a side chain of an amino acid other than R2, A is a connecting moiety, and x is from 0 to 50, y is from 1 to 100 and xnully is from 1 to 100; wherein said silane compound represented by the following general formula (II) is R4mSi(OH)pY(4nullpnullm) nullnull(II) , in which m represents an integer from 0 to 2, p represents an integer from 2 to 4, mnullp is not more than 4, R4 represents an organic group; and wherein silane compound represented by the following general formula (III) is R53Si(OH) nullnull(III) wherein three R5s represent organic groups.
    • 一种化妆品和皮肤化妆品,其通过以下方法制备并具有特定范围的粘度,其中所述方法包括:将选自通式(I)表示的甲硅烷基化肽中的一种或多种与一种或多种类型缩聚 在水溶液中选自由通式(II)表示的硅烷化合物,以形成缩聚聚合物,然后通过加成反应将由通式(III)表示的硅烷化合物在水溶液中加入到所述缩聚聚合物中; 其中由以下通式(I)表示的所述甲硅烷基化肽是其中R 1表示羟基等,R 2表示通过除去末端氨基取代的侧链的残基, 在侧链末端具有氨基的碱性氨基酸,R 3表示除R 2以外的氨基酸的侧链,A为连接部分,x为0〜50,y为 1〜100,x + y为1〜100; 其中所述由以下通式(II)表示的硅烷化合物是R 4 mSi(OH)pY(4-pm)(II),其中m表示0至2的整数,p表示2至 4,m + p不大于4,R 4表示有机基团; 并且其中由以下通式(III)表示的硅烷化合物是R 5 3 Si(OH)(III),其中三个R 5表示有机基团。
    • 3. 发明申请
    • Polymers derived from polysaccharides comprising one or more oxime or amine functions, and uses thereof
    • 衍生自包含一种或多种肟或胺官能团的多糖的聚合物及其用途
    • US20040197288A1
    • 2004-10-07
    • US10481931
    • 2004-05-21
    • Etienne FleuryAlain Domard
    • A61K007/06A61K007/11C08G063/48C08G063/91
    • A61L2/16C08B37/00C08B37/006C08B37/0087C08B37/0096
    • The invention concerns a polymer derived from a polysaccharide copolymer consisting of a main chain comprising several similar or different anhydrohexose units, and branches comprising at least a neutral or anionic anhydropentose and/or anhydrohexose unit; said polymer derivative comprising one or several units bearing an oxime function at least on position C2. Furthermore, the polymer is obtainable by carrying out the following steps: a) contacting a polysaccharide with an aqueous solution comprising at least an oxidising agent for oxidising at least the hydroxyl radical borne by the carbon C2 of one or several units, into a ketone function; b) contacting the resulting polymer with hydroxylamine or a derivative to transform the ketone function into an oxime function. The invention also concerns a polymer obtainable by carrying out a step c) which consists in contacting the polymer having at least an oxime function at least on position C2 of said unit, with an agent reducing the oxime function. The resulting polymer bears an amine function at least on position C2. The invention further concerns the uses of said polymers.
    • 本发明涉及由多糖共聚物衍生的聚合物,该多糖共聚物由包含若干相似或不同的脱氢己糖单元的主链和至少包含中性或阴离子脱水有机硅和/或脱氢己糖单元的分支组成; 所述聚合物衍生物包含至少在位置C2上具有肟官能团的一个或多个单元。 此外,通过进行以下步骤可获得聚合物:a)使多糖与至少包含氧化剂的水溶液接触,以至少将由一个或多个单元的碳C2承载的羟基自由氧化成酮官能团 ; b)使所得聚合物与羟胺或衍生物接触以将酮功能转化成肟功能。 本发明还涉及通过进行步骤c)可获得的聚合物,其包括使至少具有至少在所述单元的位置C2上的肟官能团的聚合物与降低肟功能的试剂接触。 所得聚合物至少在C2位置具有胺官能团。 本发明还涉及所述聚合物的用途。
    • 7. 发明申请
    • Multimodal polyamides, polyesters and polyester amides
    • 多峰聚酰胺,聚酯和聚酯酰胺
    • US20040152847A1
    • 2004-08-05
    • US10480232
    • 2003-12-10
    • Igor EmriBernd-Steffen von BernstorffVolker RauschenbergerHans Christoph Horn
    • C08G063/48C08G063/91C08L067/00
    • C08L77/02C08L67/02C08L77/00C08L77/06C08L77/12C08L2666/14
    • A thermoplastic polymer mixture comprising m polymers Pn, where m is a natural number greater than 1 and n is a natural number from 1 to m, where n is a natural number from 1 to m, where each of the polymers has one or more functional groups of the structure null(R1)xnullC(O)null(R2)ynullpresent as repeat units in the main chain of polymer Pn where x and y, independently of one another, are 0 or 1, and xnullynull1 R1 and R2, independently of one another, are oxygen or nitrogen bonded into the main polymer chain, where in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent the polymer mixture has at least two maxima of the relative frequency W, and after aging of the polymer mixture at the melting point of the polymer mixture determined to ISO 11357-1 and 11357-3 for 5 minutes, the polymer mixture has in the differential distribution curve W(M) determined to DIN 55672-2 in hexafluoroisopropanol as eluent at least 2 maxima of the relative frequency W, and the position of the maxima here after aging of the polymer mixture at the melting point of the polymer mixture is within three times the recurrent standard deviation sigma(r) of MP in percentage of the value measured to DIN 55672-2, based on the position of the maxima prior to aging of the polymer mixture at the melting point of the polymer mixture.
    • 一种包含m聚合物Pn的热塑性聚合物混合物,其中m是大于1的自然数,n是1至m的自然数,其中n是1至m的自然数,其中每个聚合物具有一个或多个官能 结构 - (R 1)xC(O) - (R 2)y-的基团作为聚合物Pn主链中的重复单元存在,其中x和y彼此独立地为0或1, 和x + y = 1 R 1和R 2彼此独立地是键合到主聚合物链中的氧或氮,其中根据DIN 55672-2在六氟异丙醇中测定的差分分布曲线W(M) 作为洗脱剂,聚合物混合物具有相对频率W的至少两个最大值,并且在根据ISO 11357-1和11357-3测定的聚合物混合物的熔点下老化聚合物混合物5分钟后,聚合物混合物具有 在六氟异丙醇中根据DIN 55672-2测定的差分分布曲线W(M)作为洗脱剂,相对频率至少为2个最大值 y W,并且聚合物混合物在聚合物混合物的熔点下老化之后的最大值的位置是按照DIN 55672-2测量的值的百分比,MP的反复标准偏差σ(r)的三倍, 基于在聚合物混合物的熔点下聚合物混合物老化之前的最大值的位置。