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    • 6. 发明授权
    • Photoresist cross-linker and photoresist composition comprising the same
    • 光阻抗交联剂和包含其的光致抗蚀剂组合物
    • US06312868B1
    • 2001-11-06
    • US09501096
    • 2000-02-09
    • Keun Kyu KongJae Chang JungMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho Baik
    • Keun Kyu KongJae Chang JungMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho Baik
    • G03F7004
    • G03F7/0045G03F7/038
    • The present invention is directed to photoresist cross-linkers selected from the group consisting of a cross-linker monomer represented by following Chemical Formula 1, and homopolymers and copolymers thereof. Such cross-linkers are suitable for use in photolithography processes employing KrF(248nm), ArF(193nm), E-beam, ion-beam or EUV light sources. wherein X1 and X2 individually represent CH2, CH2CH2, O or S; p and s individually represent an integer from 0 to 5; q is 0 or 1; R′ and R″ independently represent hydrogen or methyl; R represents straight or branched C1-10 alkyl, straight or branched C1-10 ether, straight or branched C1-10 ester, straight or branched C1-10 ketone, straight or branched C1-10 carboxylic acid, straight or branched C1-10 acetal, straight or branched C1-10 alkyl including at least one hydroxyl group, straight or branched C1-10 ether including at least one hydroxyl group, straight or branched C1-10 ester including at least one hydroxyl group, straight or branched C1-10 ketone including at least one hydroxyl group, straight or branched C1-10 carboxylic acid including at least one hydroxyl group, and straight or branched C1-10 acetal including at least one hydroxyl group; R1 and R2 independently represent hydrogen, straight or branched C1-10 alkyl, straight or branched C1-10 ester, straight or branched C1-10 ketone, straight or branched C1-10 carboxylic acid, straight or branched C1-10 acetal, straight or branched C1-10 alkyl including at least one hydroxyl group, straight or branched C1-10 ester including at least one hydroxyl group, straight or branched C1-10 ketone including at least one hydroxyl group, straight or branched C1-10 carboxylic acid including at least one hydroxyl group, and straight or branched C1-10 acetal including at least one hydroxyl group.
    • 本发明涉及选自由以下化学式1表示的交联剂单体和其均聚物和共聚物的光致抗蚀剂交联剂。 这种交联剂适用于采用KrF(248nm),ArF(193nm),电子束,离子束或EUV光源的光刻工艺.X1和X2分别表示CH2,CH2CH2,O或S; p和s各自表示0至5的整数; q为0或1; R'和R“独立地表示氢或甲基; R代表直链或支链C 1-10烷基,直链或支链C1-10醚,直链或支链C1-10酯,直链或支链C 1-10酮,直链或支链C 1-10羧酸,直链或支链C 1-10缩醛 包括至少一个羟基的直链或支链C 1-10烷基,包括至少一个羟基的直链或支链C 1-10醚,包括至少一个羟基的直链或支链C 1-10酯,直链或支链C 1-10酮 包括至少一个羟基,包括至少一个羟基的直链或支链C 1-10羧酸,和包含至少一个羟基的直链或支链C 1-10缩醛; R 1和R 2独立地表示氢,直链或支链C 1-10烷基,直链或支链C 1-10酯,直链或支链C 1-10酮,直链或支链C 1-10羧酸,直链或支链C 1-10缩醛,直链或 包括至少一个羟基的支链C 1-10烷基,包括至少一个羟基的直链或支链C 1-10酯,包括至少一个羟基,直链或支链C 1-10羧酸的直链或支链C 1-10酮包括 至少一个羟基,以及包含至少一个羟基的直链或支链C 1-10缩醛。
    • 8. 发明授权
    • Photoresist cross-linker and photoresist composition comprising the same
    • 光阻抗交联剂和包含其的光致抗蚀剂组合物
    • US06482565B1
    • 2002-11-19
    • US09448964
    • 1999-11-24
    • Jae Chang JungKeun Kyu KongMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho Baik
    • Jae Chang JungKeun Kyu KongMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho Baik
    • G03F7004
    • C07D407/12C07D317/12C07D319/06
    • The present invention relates to a cross-linker for use in a photoresist which is suitable for a photolithography process using KrF (248 ru), ArF (193 nm), E-beam, ion beam or EUV light source. According to the present invention, preferred cross-linkers comprise a copolymer having repeating units derived from: (i) a compound represented by following Chemical Formula 1 and/or (ii) one or more compound(s) selected from the group consisting of acrylic acid, methacrylic acid and maleic anhydride. wherein, R1, R2 and R individually represent straight or branched C1-10 alkyl, straight or branched C1-10 ester, straight or branched C1-10 ketone, straight or branched C1-10 carboxylic acid, straight or branched C1-10 acetal, straight or branched C1-10 alkyl including at least one hydroxyl group, straight or branched C1-10 ester including at least one hydroxyl group, straight or branched C1-10 ketone including at least one hydroxyl group, straight or branched C1-10 carboxylic acid including at least one hydroxyl group, and straight or branched C1-10 acetal including at least one hydroxyl group; R3 represents hydrogen or methyl; m represents 0 or 1; and n represents a number of 1 to 5.
    • 本发明涉及用于光致抗蚀剂的交联剂,其适用于使用KrF(248uR),ArF(193nm),电子束,离子束或EUV光源的光刻工艺。 根据本发明,优选的交联剂包含具有衍生自以下的重复单元的共聚物:(i)由以下化学式1表示的化合物和/或(ii)一种或多种选自丙烯酸的化合物 酸,甲基丙烯酸和马来酸酐。其中R1,R2和R各自表示直链或支链C1-10烷基,直链或支链C1-10酯,直链或支链C1-10酮,直链或支链C1-10羧酸, 包括至少一个羟基的直链或支链C 1-10烷基,包括至少一个羟基的直链或支链C 1-10烷基,包括至少一个羟基的直链或支链C 1-10酮, 包含至少一个羟基的直链或支链C 1-10羧酸,和包含至少一个羟基的直链或支链C 1-10缩醛; R3表示氢或甲基; m表示0或1; n表示1〜5的数。
    • 9. 发明授权
    • Photoresist cross-linker and photoresist composition comprising the same
    • 光阻抗交联剂和包含其的光致抗蚀剂组合物
    • US06368773B1
    • 2002-04-09
    • US09448916
    • 1999-11-24
    • Jae Chang JungKeun Kyu KongMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho BaikJin Soo Kim
    • Jae Chang JungKeun Kyu KongMyoung Soo KimHyoung Gi KimHyeong Soo KimKi Ho BaikJin Soo Kim
    • G03F7027
    • C08F216/38C07C43/303C08F220/06G03F7/0382
    • The present invention relates to a cross-linker for photoresist compositions which is suitable for a photolithography process using KrF (248 mn), ArF (193 mn), E-beam, ion beam or EUV light sources. Preferred cross-linkers, according to the present invention, comprise a copolymer of (i) a compound represented by following Chemical Formula 1 and/or (ii) one or more compound(s) selected from the group consisting of acrylic acid, methacrylic acid and maleic anhydride. wherein, R1 and R2 individually represent straight or branched C1-10 alkyl, straight or branched C1-10 ester, straight or branched C1-10 ketone, straight or branched C1-10 carboxylic acid, straight or branched C1-10 acetal, straight or branched C1-10 alkyl including at least one hydroxyl group, straight or branched C1-10 ester including at least one hydroxyl group, straight or branched C1-10 ketone including at least one hydroxyl group, straight or branched C1-10 carboxylic acid including at least one hydroxyl group, and straight or branched C1-10 acetal including at least one hydroxyl group; and R3 represents hydrogen or methyl.
    • 本发明涉及适用于使用KrF(248nm),ArF(193nm),电子束,离子束或EUV光源的光刻工艺的光致抗蚀剂组合物的交联剂。 根据本发明,优选的交联剂包含(i)由以下化学式1表示的化合物和/或(ii)一种或多种选自丙烯酸,甲基丙烯酸 其中R1和R2分别表示直链或支链C1-10烷基,直链或支链C1-10酯,直链或支链C1-10酮,直链或支链C1-10羧酸,直链或支链C1-10 包括至少一个羟基的直链或支链C 1-10烷基,包括至少一个羟基的直链或支链C 1-10酯,包括至少一个羟基的直链或支链C 1-10酮直链或支链C 1-10 包含至少一个羟基的羧酸,和包含至少一个羟基的直链或支链C 1-10缩醛; 并且R 3表示氢或甲基。