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    • 8. 发明授权
    • Methods for forming and integrated circuit structures containing enhanced-surface-area conductive layers
    • 包含增强表面积导电层的形成方法和集成电路结构
    • US07253102B2
    • 2007-08-07
    • US10860341
    • 2004-06-02
    • Cem BasceriMark VisokayThomas M. GraettingerSteven D. Cummings
    • Cem BasceriMark VisokayThomas M. GraettingerSteven D. Cummings
    • H01L21/4763H01L21/44
    • H01L28/82H01L28/55
    • An enhanced-surface-area conductive layer compatible with high-dielectric constant materials is created by forming a film or layer having at least two phases, at least one of which is electrically conductive. The film may be formed in any convenient manner, such as by chemical vapor deposition techniques, which may be followed by an anneal to better define and/or crystallize the at least two phases. The film may be formed over an underlying conductive layer. At least one of the at least two phases is selectively removed from the film, such as by an etch process that preferentially etches at least one of the at least two phases so as to leave at least a portion of the electrically conductive phase. Ruthenium and ruthenium oxide, both conductive, may be used for the two or more phases. Iridium and its oxide, rhodium and its oxide, and platinum and platinum-rhodium may also be used. A wet etchant comprising ceric ammonium nitrate and acetic acid may be used. In the case of this etchant and a ruthenium/ruthenium oxide film, the etchant preferentially removes the ruthenium phase, leaving a pitted or “islanded” surface of ruthenium oxide physically and electrically connected by the underlying conductive layer. The remaining pitted or islanded layer, together with the underlying conductive layer, if any, constitutes an enhanced-surface-area conductive layer. The enhanced-surface-area conductive layer may be used to form a plate of a storage capacitor in an integrated circuit, such as in a memory cell of a DRAM or the like.
    • 与高介电常数材料兼容的增强表面积导电层是通过形成具有至少两个相的膜或层,其中至少一个导电层是导电的。 膜可以以任何方便的方式形成,例如通过化学气相沉积技术,其后可以进行退火以更好地限定和/或结晶至少两个相。 膜可以形成在下面的导电层上。 所述至少两个相中的至少一个相被选择性地从膜上移除,例如通过蚀刻工艺,其优先蚀刻至少两个相中的至少一个,以便留下导电相的至少一部分。 导电的钌和氧化钌可以用于两个或多个相。 也可以使用铱及其氧化物,铑及其氧化物,以及铂和铂 - 铑。 可以使用包含硝酸铈铵和乙酸的湿蚀刻剂。 在这种蚀刻剂和钌/氧化钌膜的情况下,蚀刻剂优先除去钌相,留下通过下面的导电层物理和电连接的氧化钌的凹陷或“孤立”的表面。 剩余的凹陷或孤岛层与下面的导电层(如果有的话)一起构成增强的表面积导电层。 增强表面积导电层可用于在诸如DRAM等的存储单元中的集成电路中形成存储电容器的板。
    • 10. 发明授权
    • Methods for forming and integrated circuit structures containing enhanced-surface-area conductive layers
    • 包含增强表面积导电层的形成方法和集成电路结构
    • US06764943B2
    • 2004-07-20
    • US10196535
    • 2002-07-15
    • Cem BasceriMark VisokayThomas M. GraettingerSteven D. Cummings
    • Cem BasceriMark VisokayThomas M. GraettingerSteven D. Cummings
    • H01L214763
    • H01L28/82H01L28/55
    • An enhanced-surface-area conductive layer compatible with high-dielectric constant materials is created by forming a film or layer having at least two phases, at least one of which is electrically conductive. The film may be formed in any convenient manner, such as by chemical vapor deposition techniques, which may be followed by an anneal to better define and/or crystallize the at least two phases. The film may be formed over an underlying conductive layer. At least one of the at least two phases is selectively removed from the film, such as by an etch process that preferentially etches at least one of the at least two phases so as to leave at least a portion of the electrically conductive phase. Ruthenium and ruthenium oxide, both conductive, may be used for the two or more phases. Iridium and its oxide, rhodium and its oxide, and platinum and platinum-rhodium may also be used. A wet etchant comprising ceric ammonium nitrate and acetic acid may be used. In the case of this etchant and a ruthenium/ruthenium oxide film, the etchant preferentially removes the ruthenium phase, leaving a pitted or “islanded” surface of ruthenium oxide physically and electrically connected by the underlying conductive layer. The remaining pitted or islanded layer, together with the underlying conductive layer, if any, constitutes an enhanced-surface-area conductive layer. The enhanced-surface-area conductive layer may be used to form a plate of a storage capacitor in an integrated circuit, such as in a memory cell of a DRAM or the like.
    • 与高介电常数材料兼容的增强表面积导电层是通过形成具有至少两个相的膜或层,其中至少一个导电层是导电的。 膜可以以任何方便的方式形成,例如通过化学气相沉积技术,其后可以进行退火以更好地限定和/或结晶至少两个相。 膜可以形成在下面的导电层上。 所述至少两个相中的至少一个相被选择性地从膜上移除,例如通过蚀刻工艺,其优先蚀刻至少两个相中的至少一个,以便留下导电相的至少一部分。 导电的钌和氧化钌可以用于两个或多个相。 也可以使用铱及其氧化物,铑及其氧化物,以及铂和铂 - 铑。 可以使用包含硝酸铈铵和乙酸的湿蚀刻剂。 在这种蚀刻剂和钌/氧化钌膜的情况下,蚀刻剂优先除去钌相,留下通过下面的导电层物理和电连接的氧化钌的凹陷或“孤立”的表面。 剩余的凹陷或孤岛层与下面的导电层(如果有的话)一起构成增强的表面积导电层。 增强表面积导电层可用于在诸如DRAM等的存储单元中的集成电路中形成存储电容器的板。