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1. 发明授权

US06582756B1 Method and apparatus for fabricating polymer-based electroluminescent displays 有权
标题翻译：用于制造基于聚合物的电致发光显示器的方法和装置
公开(公告)号：US06582756B1
公开(公告)日：2003-06-24
申请号：US09717655
申请日：2000-11-21
申请人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
发明人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
IPC分类号： B05D512
CPC分类号： H01L27/3283 , H01L51/0004 , H01L51/5221 , H01L51/5253 , H01L2251/5315 , Y10S428/917
摘要： A method for fabricating an electroluminescent display and the substrate and apparatus used therein. The display is preferably constructed on a pre-constructed substrate that includes a flexible base layer having a conducting surface on one side thereof. The base layer is impermeable to oxygen and water. The substrate includes a plurality of wells defined by a barrier layer, each well having an electrode layer connected electrically with the conducting surface. A removable protective layer covering the wells protects the electrode layer from attack by oxygen and water prior to being utilized to make the display. In one embodiment, each of the wells also contains an electron transfer layer in contact with the electrode layer.
摘要翻译：一种用于制造电致发光显示器的方法及其中使用的基板和装置。显示器优选地构造在包括在其一侧具有导电表面的柔性基底层的预构造的基底上。基层对氧和水是不透水的。衬底包括由阻挡层限定的多个阱，每个阱具有与导电表面电连接的电极层。覆盖井的可移除的保护层在用于制造显示器之前保护电极层免受氧气和水的侵害。在一个实施例中，每个阱还包含与电极层接触的电子转移层。

2. 发明授权

US06174613B1 Method and apparatus for fabricating polymer-based electroluminescent displays 有权
标题翻译：用于制造基于聚合物的电致发光显示器的方法和装置
公开(公告)号：US06174613B1
公开(公告)日：2001-01-16
申请号：US09363964
申请日：1999-07-29
申请人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
发明人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
IPC分类号： B32B900
CPC分类号： H01L27/3283 , H01L51/0004 , H01L51/5221 , H01L51/5253 , H01L2251/5315 , Y10S428/917
摘要： A method for fabricating an electroluminescent display and the substrate and apparatus used therein. The display is preferably constructed on a pre-constructed substrate that includes a flexible base layer having a conducting surface on one side thereof. The base layer is impermeable to oxygen and water. The substrate includes a plurality of wells defined by a barrier layer, each well having an electrode layer connected electrically with the conducting surface. A removable protective layer covering the wells protects the electrode layer from attack by oxygen and water prior to being utilized to make the display. In one embodiment, each of the wells also contains an electron transfer layer in contact with the electrode layer. The electron transfer layer includes a material that improves the efficiency of the injection of electrons from the electrode layer into the electroluminescent layer of the display. This display is fabricated by moving a first dispenser relative to the substrate so as to quantitatively deposit a first electroluminescent material on the substrate, different amounts of the first electroluminescent material being deposited at different locations on the substrate in response to signals defining an illumination pattern to be generated by the display. A conducting material is deposited on the first electroluminescent material. In color displays, a second electroluminescent material is also deposited, the second electroluminescent material emitting light at a different wavelength than the first electroluminescent material. A non-luminescent material, which is preferably an electrical insulator, can be deposited in wells at locations on the display that are not to emit light prior to depositing the conductive material.
摘要翻译：一种用于制造电致发光显示器的方法及其中使用的基板和装置。显示器优选地构造在包括在其一侧具有导电表面的柔性基底层的预构造的基底上。基层对氧和水是不透水的。衬底包括由阻挡层限定的多个阱，每个阱具有与导电表面电连接的电极层。覆盖井的可移除的保护层在用于制造显示器之前保护电极层免受氧气和水的侵害。在一个实施例中，每个阱还包含与电极层接触的电子转移层。电子转移层包括提高从电极层向显示器的电致发光层注入电子的效率的材料。通过相对于衬底移动第一分配器来制造该显示器，以便在衬底上定量沉积第一电致发光材料，响应于限定照明图案的信号，不同量的第一电致发光材料沉积在衬底上的不同位置由显示器生成。导电材料沉积在第一电致发光材料上。在彩色显示器中，还沉积第二电致发光材料，第二电致发光材料以与第一电致发光材料不同的波长发射光。优选为电绝缘体的非发光材料可以沉积在显示器上的在沉积导电材料之前不发光的位置的孔中。

3. 发明授权

US06713955B1 Organic light emitting device having a current self-limiting structure 有权
标题翻译：具有电流自限制结构的有机发光器件
公开(公告)号：US06713955B1
公开(公告)日：2004-03-30
申请号：US09197012
申请日：1998-11-20
申请人： Daniel B. Roitman , Ronald L. Moon , Homer Antoniadis , James R. Sheats
发明人： Daniel B. Roitman , Ronald L. Moon , Homer Antoniadis , James R. Sheats
IPC分类号： H05B3302
CPC分类号： H01L51/5203 , H01L51/50 , H01L2251/5392 , H01L2251/568
摘要： An organic light emitting device having a process compatible current self-limiting (CSL) structure applied in the vicinity of an electrode of the device prevents the occurrence of high current flow in the vicinity of a short within the device. Should a short occur, the CSL structure becomes resistive, or non-conducting in the vicinity of the short, thus preventing the occurrence of “runaway” current in the vicinity of the short. By limiting the current flow between conductors in the device, the non-emissive areas of the device can be minimized, thus improving the overall reliability of the device.
摘要翻译：具有应用于器件电极附近的工艺兼容电流自限制（CSL）结构的有机发光器件防止在器件内的短路附近发生高电流流动。如果发生短路，则CSL结构在短路附近变成电阻或不导通，从而防止在短路附近发生“失控”电流。通过限制器件中的导体之间的电流流动，器件的非发射区域可以最小化，从而提高器件的整体可靠性。

4. 发明授权

US06680570B2 Polymer organic light emitting device with improved color control 有权
标题翻译：聚合物有机发光装置，具有改进的颜色控制
公开(公告)号：US06680570B2
公开(公告)日：2004-01-20
申请号：US09814381
申请日：2001-03-21
申请人： Daniel B. Roitman , Homer Antoniadis
发明人： Daniel B. Roitman , Homer Antoniadis
IPC分类号： H01J162
CPC分类号： H01L51/5265 , H01L51/5012
摘要： An OLED for emitting light at a predetermined peak wavelength, &lgr;. The OLED includes an anode layer, a cathode layer and an electroluminescent layer constructed from an organic light emitting compound that generates light, including light having a wavelength equal to &lgr;, by the recombination of holes and electrons. The electroluminescent layer is electrically connected to the anode layer and the cathode layer and is located between the anode and cathode layers. The OLED includes a first reflector and a second reflector, displaced from one another. The anode layer or cathode layer can serve as one of the reflectors. A spacer layer constructed from a material that is transparent at &lgr; is included between the reflectors and has a thickness that is adjusted such that the optical path length between the first and second reflectors is equal to N &lgr;/2, where N is a positive integer.
摘要翻译：用于发射预定峰值波长λ的OLED。 OLED包括阳极层，阴极层和由有机发光化合物构成的电致发光层，其通过空穴和电子的复合产生包括波长等于λ的光的光。电致发光层电连接到阳极层和阴极层并位于阳极和阴极层之间。 OLED包括彼此移位的第一反射器和第二反射器。阳极层或阴极层可以用作反射器之一。由λ构成的材料构成的间隔层包含在反射体之间，其厚度被调整为使得第一和第二反射器之间的光程长度等于Nλ/ 2，其中N是正整数。

5. 发明授权

US5719467A Organic electroluminescent device 失效
标题翻译：有机电致发光器件
公开(公告)号：US5719467A
公开(公告)日：1998-02-17
申请号：US508020
申请日：1995-07-27
申请人： Homer Antoniadis , Daniel B. Roitman , Jeffrey N. Miller
发明人： Homer Antoniadis , Daniel B. Roitman , Jeffrey N. Miller
IPC分类号： H05B33/20 , H01L51/50 , H01L51/52 , H05B33/12 , H05B33/14 , H05B33/26
CPC分类号： H01L51/5088 , H05B33/14 , H05B33/26 , H01L51/5206
摘要： An organic electroluminescent device with a conducting polymer layer beneath the hole transport layer. A conducting polymer layer of doped polyaniline (PANI) is spin-cast onto an indium-tin oxide (ITO) anode coating on a glass substrate. Then a hole transport layer, for example TPD or another aromatic tertiary amine, is vapor-deposited onto the conducting polymer layer, followed by an electron transport layer and a cathode. Polyester may be blended into the PANI before spin-casting and then removed by a selective solvent after the spincasting, leaving a microporous layer of PANI on the anode. The conducting polymer layer may instead be made of a .pi.-conjugated oxidized polymer or of TPD dispersed in a polymer binder that is doped with an electron-withdrawing compound. An additional layer of copper-phthalocyanine, or of TPD in a polymer binder, may be disposed between the conducting polymer layer and the hole transport layer. The conducting polymer layer may serve as the anode, in which case the ITO is omitted.
摘要翻译：一种在空穴传输层下方具有导电聚合物层的有机电致发光器件。将掺杂聚苯胺（PANI）的导电聚合物层自旋铸在玻璃基板上的氧化铟锡（ITO）阳极涂层上。然后将空穴传输层，例如TPD或另一种芳族叔胺，汽相沉积到导电聚合物层上，随后是电子传输层和阴极。在旋转浇铸之前，聚酯可以混合到PANI中，然后在旋转浇铸之后通过选择性溶剂除去，在阳极上留下微孔层的PANI。导电聚合物层可以替代地由分散在掺杂有吸电子化合物的聚合物粘合剂中的π-共轭氧化聚合物或TPD制成。可以在导电聚合物层和空穴传输层之间设置另外的铜 - 酞菁层或聚合物粘合剂中的TPD。导电聚合物层可以用作阳极，在这种情况下，省略了ITO。

6. 发明授权

US5948552A Heat-resistant organic electroluminescent device 失效
标题翻译：耐热有机电致发光器件
公开(公告)号：US5948552A
公开(公告)日：1999-09-07
申请号：US704476
申请日：1996-08-27
申请人： Homer Antoniadis , Daniel B. Roitman , William R. Shiang , Edmund P. Woo , Weishi Wu
发明人： Homer Antoniadis , Daniel B. Roitman , William R. Shiang , Edmund P. Woo , Weishi Wu
IPC分类号： H05B33/10 , C09K11/06 , G09F9/30 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14 , H05B33/00 , B05D5/12
CPC分类号： H05B33/14 , H01L51/0035 , H01L51/0059 , H01L51/5012 , H01L2251/308 , H01L51/0081 , Y10S428/917 , Y10T428/31678
摘要： An organic electroluminescent device that comprises a substrate, a first conductive layer on the substrate, an electron-transporting and light-emitting layer, a second conductive layer adjacent the electron-transporting and light-emitting layer and remote from the first conductive layer, and a hole-conducting layer sandwiched between the first conductive layer and the electron-transporting and light-emitting layer. The hole-conducting layer comprises a poly(arylamine) including at least one compound of formula (I): ##STR1## In this: R is independently in each occurrence a C.sub.1-24 hydrocarbyl, hydrocarboxyl, hydrothiocarboxy, hydroarylcarboxy, or hydrothioarylcarboxy; Ar.sub.1 and Ar.sub.2 are independently in each occurrence a C.sub.6-18 aryl moiety optionally substituted with one or more C.sub.1-24 hydrocarbyl, hydrocarboxyl, hydrothiocarboxy, hydroarycarboxy, or hydrothioarylcarboxy; A is independently in each occurrence hydrogen or a halogen; x is independently in each occurrence a positive number between 0 and 1; n is a whole number from 0 to 4; and m is a number from about 5 to about 1000.
摘要翻译：一种有机电致发光器件，包括衬底，衬底上的第一导电层，电子传输和发光层，与电子传输和发光层相邻并远离第一导电层的第二导电层，以及夹在第一导电层和电子传输和发光层之间的空穴传导层。空穴传导层包括包含至少一种式（I）化合物的聚（芳基胺）：其中：R在每次出现时独立地为C 1-4烃基，氢化羧基，氢硫代羧基，氢化芳基羧基或氢硫代芳基羧基; Ar 1和Ar 2在每次出现时独立地为任选被一个或多个C 1-4烃基，氢羧基，氢硫代羧基，羟基羧基或氢硫代芳基羧基取代的C 6-18芳基部分; 在每次出现氢时，A独立地为氢或卤素; x在每次出现时独立地为0和1之间的正数; n是从0到4的整数; m为约5至约1000的数。

7. 发明授权

US06552488B1 Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：US06552488B1
公开(公告)日：2003-04-22
申请号：US09382025
申请日：1999-08-24
申请人： Daniel B. Roitman , John S. Hargreaves , Homer Antoniadis , Karen L. Seaward
发明人： Daniel B. Roitman , John S. Hargreaves , Homer Antoniadis , Karen L. Seaward
IPC分类号： H05B3306
CPC分类号： H01J37/32082 , H01L27/322 , H01L27/3244 , H01L51/5253 , H01L51/529 , H01L2251/5315
摘要： A color organic electroluminescent device includes color filters, light emitting layers and substrate integrated into a single assembly, with the light emitting layers lying between the substrate and the color filters. Unlike color electroluminescent devices where an image must be viewed through a transparent substrate, or where color filters are deposited upon another device and later combined with the assembly, the present disclosure calls for a transparent protective layer of silicon nitride or a similar material to be deposited over the light emitting layers to protect the light emitting layers from oxygen and moisture, and to serve as a platform for color filters. In order to achieve sufficient density in the protective layer and avoid defects, a cold plasma deposition or similar process is used for deposition of the protective layer. By viewing light through this protective layer instead of a substrate, nearly any substrate can be used.
摘要翻译：彩色有机电致发光器件包括滤色器，发光层和集成到单个组件中的衬底，其中发光层位于衬底和滤色器之间。不同于彩色电致发光器件，其中必须通过透明衬底观察图像，或者滤色器沉积在另一器件上并且随后与组件结合在一起，本公开要求具有氮化硅的透明保护层或要沉积的类似材料在发光层上，以保护发光层免受氧气和水分的影响，并且用作滤色器的平台。为了在保护层中获得足够的密度并避免缺陷，使用冷等离子体沉积或类似的工艺来沉积保护层。通过观察通过该保护层的光而不是基板，可以使用几乎任何基板。

8. 发明授权

US06191433B1 OLED display device and method for patterning cathodes of the device 有权
标题翻译： OLED显示装置和用于图案化装置的阴极的方法
公开(公告)号：US06191433B1
公开(公告)日：2001-02-20
申请号：US09528413
申请日：2000-03-17
申请人： Daniel B. Roitman , Homer Antoniadis
发明人： Daniel B. Roitman , Homer Antoniadis
IPC分类号： H01L3524
CPC分类号： H01L27/3281 , H01L51/5221 , H01L2251/5315
摘要： An OLED display device and a method of fabricating the device utilize a patterned layer of conductive pads formed over a substrate to fabricate a cathode layer without the need to subsequently pattern the cathode layer to create individually addressable cathodes. The design of the OLED display device is such that the cathode layer is positioned below the anode layer. The OLED display device may be configured to emit light through the substrate or through the top layer, i.e., the anode layer. In a first embodiment, the conductive pads have sharp edges that effectively pattern the cathode layer when it is formed over the pads. In a second embodiment, the conductive pads do not include sharp edges. In this embodiment, the cathode layer is made of a composite material, which includes cathode components and non-conducting components. The composite material allows the resulting cathode layer to have the desired characteristics to effectively inject electrons vertically into the EL region of the device, while limiting lateral conduction between the conductive pads.
摘要翻译： OLED显示装置和制造该器件的方法利用形成在衬底上的图形化的导电焊盘层以制造阴极层，而不需要随后对阴极层进行图案以产生可单独寻址的阴极。 OLED显示装置的设计使得阴极层位于阳极层下方。 OLED显示装置可以被配置为通过衬底或通过顶层即阳极层发光。在第一实施例中，导电焊盘具有尖锐边缘，当阴极层形成在焊盘上时，其有效地图案化阴极层。在第二实施例中，导电焊盘不包括锋利的边缘。在该实施例中，阴极层由包括阴极部件和非导电部件的复合材料制成。复合材料允许所得到的阴极层具有所需的特性，以有效地将电子垂直注入器件的EL区域，同时限制导电焊盘之间的横向传导。

9. 发明授权

US06366017B1 Organic light emitting diodes with distributed bragg reflector 有权
标题翻译：具有分布式布拉格反射器的有机发光二极管
公开(公告)号：US06366017B1
公开(公告)日：2002-04-02
申请号：US09353709
申请日：1999-07-14
申请人： Homer Antoniadis , Daniel B. Roitman
发明人： Homer Antoniadis , Daniel B. Roitman
IPC分类号： H01J6304
CPC分类号： H01L51/5203 , H01L51/0037 , H01L51/0038 , H01L51/0059 , H01L51/5265 , H01L2251/5315
摘要： The present invention provides OLEDs having superior brightness, which can be formed on opaque substrates such as silicon, and methods for producing such OLEDs. OLEDs according to the invention comprise a reflective electrode on the substrate, an organic active layer which provides electroluminescence, an injection layer, and a transparent organic electrode. Light from the active layer which is initially directed backward is reflected by the reflective layer to increase the apparent brightness of the diode in the forward direction.
摘要翻译：本发明提供具有优异亮度的OLED，其可以形成在诸如硅的不透明基板上，以及用于制造这种OLED的方法。根据本发明的OLED包括在基底上的反射电极，提供电致发光的有机活性层，注入层和透明有机电极。最初指向后方的有源层的光被反射层反射，以增加二极管在正向上的表观亮度。

10. 发明授权

US07923368B2 Junction formation on wafer substrates using group IV nanoparticles 有权
标题翻译：使用IV族纳米粒子在晶片衬底上形成结
公开(公告)号：US07923368B2
公开(公告)日：2011-04-12
申请号：US12109684
申请日：2008-04-25
申请人： Mason Terry , Homer Antoniadis , Dmitry Poplavskyy , Maxim Kelman
发明人： Mason Terry , Homer Antoniadis , Dmitry Poplavskyy , Maxim Kelman
IPC分类号： H01L21/44
CPC分类号： H01L21/2256 , H01L21/02532 , H01L21/02573 , H01L21/02601 , H01L21/02628 , H01L21/2257 , H01L31/1804 , Y02E10/547 , Y02P70/521
摘要： A method of forming a diffusion region is disclosed. The method includes depositing a nanoparticle ink on a surface of a wafer to form a non-densified thin film, the nanoparticle ink having set of nanoparticles, wherein at least some nanoparticles of the set of nanoparticles include dopant atoms therein. The method also includes heating the non-densified thin film to a first temperature and for a first time period to remove a solvent from the deposited nanoparticle ink; and heating the non-densified thin film to a second temperature and for a second time period to form a densified thin film, wherein at least some of the dopant atoms diffuse into the wafer to form the diffusion region.
摘要翻译：公开了形成扩散区域的方法。该方法包括在晶片的表面上沉积纳米颗粒油墨以形成非致密化薄膜，纳米颗粒油墨具有一组纳米颗粒，其中该组纳米颗粒中的至少一些纳米颗粒包括其中的掺杂剂原子。该方法还包括将非致密化薄膜加热至第一温度并且在第一时间段内从沉积的纳米颗粒油墨中除去溶剂; 以及将所述非致密化薄膜加热至第二温度并且持续第二时间以形成致密的薄膜，其中至少一些所述掺杂剂原子扩散到所述晶片中以形成所述扩散区域。

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