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    • 3. 发明授权
    • Negative active material for lithium rechargeable batteries and method of fabricating same
    • 锂可充电电池用负极活性物质及其制造方法
    • US07285358B2
    • 2007-10-23
    • US10160204
    • 2002-05-30
    • Jung-Joon ParkHo-Jin KweonJang-Ho YoonJun-Won Suh
    • Jung-Joon ParkHo-Jin KweonJang-Ho YoonJun-Won Suh
    • H01M4/58B05D5/12
    • H01M4/583H01M4/366H01M4/525H01M4/62
    • The present invention relates to a negative active material for a lithium rechargeable battery and a method of preparing the same, and the negative active material prepared by coating a carbon source with a coating liquid, and drying the carbon source, and the negative active material comprises a core having a carbon source with surface-treatment layer formed on the surface of the core, the surface-treatment layer having at least one compound of coating element selected from the group cosnsisting of amorphous, semi crystalline, or crystalline hydroxides, oxyhydroxides, oxycarbonates, and hydroxidecarbonates.The present invention provides a negative active material coated with a surface-treatment layer of a coating-element-included hydroxide, a coating-element-included oxyhydroxide, a coating-element-included oxycarbonate, or a coating-element-included hydroxycarbonate, and thereby a battery having the negative active material has less change in thickness after expansion of the active material, that is, from 12.2% to 5.3%, and furthermore, cycle-life characteristics are improved (7% or more improvement at the 200th cycle) and voltage characteristics are improved (0.04 V or more improvement at the 200th cycle).
    • 本发明涉及一种用于锂可再充电电池的负极活性材料及其制备方法,通过用涂布液涂覆碳源并干燥碳源制备的负极活性材料和负极活性材料包括 具有形成在芯表面上的具有表面处理层的碳源的芯体,所述表面处理层具有至少一种选自由无定形,半结晶或结晶氢氧化物,羟基氧化物,碳酸氧化物组成的组的涂层元素化合物 ,和水合罗非糖类。 本发明提供涂覆有包含涂覆元素的氢氧化物的表面处理层的负极活性材料,包含涂覆元素的羟基氧化合物,包含涂覆元素的含氧碳酸酯或包含涂覆元素的羟基碳酸酯,以及 从而具有负极活性物质的电池在活性物质膨胀后的厚度变化较小,即12.2%〜5.3%,此外,循环寿命特性提高(第200次循环的7%以上的改善) 并提高电压特性(在第200次循环时为0.04V以上的改善)。