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1. 发明申请

US20070216289A1 Organic Electroluminescence Display Device 审中-公开
标题翻译：有机电致发光显示装置
公开(公告)号：US20070216289A1
公开(公告)日：2007-09-20
申请号：US11587095
申请日：2005-04-07
申请人： Hitoshi Kuma , Hiroshi Tokailin , Keiko Yamamichi , Kenichi Fukuoka , Kimihiro Yuasa , Chishio Hosokawa
发明人： Hitoshi Kuma , Hiroshi Tokailin , Keiko Yamamichi , Kenichi Fukuoka , Kimihiro Yuasa , Chishio Hosokawa
IPC分类号： H01J1/63
CPC分类号： H01L51/5265 , H01L27/322 , H01L51/0017 , H01L51/0056 , H01L51/0059 , H01L51/006 , H01L51/007
摘要： An organic electroluminescent display comprising a first organic electroluminescent device (10) wherein an optical distance between first (12) and second (14) reflecting members is set to select light of a first color, a second organic electroluminescent device (20) wherein an optical distance between first (12) and second (14) reflecting members is set to select light of a second color, and a third organic electroluminescent device (30) wherein an optical distance between first (12) and second (14) reflecting members is set to select light of a third color, the first reflecting member (12) having an average reflectance of 65% or more for light having a wavelength of 400 nm to 700 nm.
摘要翻译：一种有机电致发光显示器，包括第一有机电致发光器件（10），其中第一（12）和第二（14）反射部件之间的光学距离被设置为选择第一颜色的光，第二有机电致发光器件（20）将第一（12）和第二（14）反射构件之间的距离设置为选择第二颜色的光;以及第三有机电致发光器件（30），其中设置第一（12）和第二（14）反射构件之间的光学距离为了选择第三颜色的光，对于波长为400nm至700nm的光，第一反射部件（12）的平均反射率为65％以上。

2. 发明授权

US06509109B1 Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：US06509109B1
公开(公告)日：2003-01-21
申请号：US09281953
申请日：1999-03-31
申请人： Hiroaki Nakamura , Chishio Hosokawa , Kenichi Fukuoka , Hiroshi Tokailin
发明人： Hiroaki Nakamura , Chishio Hosokawa , Kenichi Fukuoka , Hiroshi Tokailin
IPC分类号： H05B3300
CPC分类号： H01L51/5092 , H01L51/002 , H01L51/0052 , H01L51/0058 , H01L51/0059 , H01L51/006 , H01L51/007 , H01L51/0081 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： An organic EL device is improved to produce an increased luminance and have a prolonged lifetime. In an organic EL device comprising a cathode layer 16, an electron injection region 14, a light emission region 12 and an anode layer 10 as laminated in that order, the electron injection region 14 contains an aromatic compound composed of carbon and hydrogen or an aromatic compound composed of carbon, hydrogen and oxygen, along with a reducing dopant, and the electron affinity of the electron injection region is controlled to fall between 1.8 and 3.6 eV; or the electron injection region 14 contains an electron-transporting compound and a reducing dopant having a work function of at most 2.9 eV, and the electron affinity of the electron injection region is controlled to fall between 1.8 and 3.6 eV.
摘要翻译：有机EL器件被改进以产生增加的亮度并且具有延长的寿命。在包括依次层叠的阴极层16，电子注入区域14，发光区域12和阳极层10的有机EL器件中，电子注入区域14含有由碳和氢或芳族化合物构成的芳族化合物由碳，氢和氧组成的化合物以及还原性掺杂剂，电子注入区的电子亲和力控制在1.8和3.6eV之间; 或电子注入区域14含有电子传输性化合物和功函数为2.9eV以下的还原性掺杂剂，电子注入区域的电子亲和力控制在1.8〜3.6eV之间。

3. 发明授权

US6093864A Aromatic dimethylidyne compounds 失效
标题翻译：芳香族二甲基化合物
公开(公告)号：US6093864A
公开(公告)日：2000-07-25
申请号：US87134
申请日：1993-07-02
申请人： Hiroshi Tokailin , Hisahiro Higashi , Chishio Hosokawa
发明人： Hiroshi Tokailin , Hisahiro Higashi , Chishio Hosokawa
IPC分类号： C07C13/28 , C07C15/52 , C07C15/58 , C07C15/60 , C07C43/215 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14 , C07C43/20
CPC分类号： H05B33/14 , C07C13/28 , C07C15/52 , C07C15/58 , C07C15/60 , C07C43/215 , C09K11/06 , H01L51/005 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0067 , C07C2101/14 , H01L2251/308 , H01L51/0053 , H01L51/007 , H01L51/5012 , Y10S428/917
摘要： An aromatic dimethylidyne compound of the formula: ##STR1## wherein X and Y are the same or different and are each an alkyl having 1 to 4 carbons, a phenyl, a cyclohexyl, a naphthyl, or a pyridyl and Ar' is ##STR2## A process for preparing an aromatic dimethylidyne compound which comprises condensing a phosphorus compound and a ketone compound.
摘要翻译：具有下式的芳族二甲基化合物：其中X和Y相同或不同，并且各自为具有1至4个碳的烷基，苯基，环己基，萘基或吡啶基，Ar'是用于制备芳族化合物的方法包括使磷化合物和酮化合物缩合的二甲基化合物。

4. 发明授权

US5130603A Organic electroluminescence device 失效
标题翻译：有机电致发光器件
公开(公告)号：US5130603A
公开(公告)日：1992-07-14
申请号：US490337
申请日：1990-03-08
申请人： Hiroshi Tokailin , Hisahiro Higashi , Chishio Hosokawa
发明人： Hiroshi Tokailin , Hisahiro Higashi , Chishio Hosokawa
IPC分类号： C07C13/28 , C07C15/52 , C07C15/58 , C07C15/60 , C07C43/215 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： H05B33/14 , C07C13/28 , C07C15/52 , C07C15/58 , C07C15/60 , C07C43/215 , C09K11/06 , H01L51/005 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0067 , C07C2101/14 , H01L2251/308 , H01L51/0053 , H01L51/007 , H01L51/5012 , Y10S428/917
摘要： An electroluminescence device comprising, as a light emitting material, a compound of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl, cyclohexyl, alkoxy, cyano or aryl, R.sup.3 and R.sup.4 are a heterocyclic or aryl and Ar is an arylene. Aromatic dimethylidyne compounds of the formula: ##STR2## wherein X and Y are each an alkyl, phenyl, cyclohexyl, naphthyl or pyridyl and Ar' is ##STR3## Electroluminescence devices (EL devices) using the above compounds as a light emitting material provide EL light emission of high luminance in a region of bluish purple to green.

5. 发明授权

US5126214A Electroluminescent element 失效
标题翻译：电致发光元件
公开(公告)号：US5126214A
公开(公告)日：1992-06-30
申请号：US488702
申请日：1990-03-05
申请人： Hiroshi Tokailin , Chishio Hosokawa , Tadashi Kusomoto
发明人： Hiroshi Tokailin , Chishio Hosokawa , Tadashi Kusomoto
IPC分类号： C09K11/06 , G09F9/33 , H01L27/32 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14
CPC分类号： H05B33/14 , C09K11/06 , G09F9/33 , H01L51/005 , H01L51/0052 , H01L51/5036 , H01L2251/308 , H01L27/322 , H01L51/0035 , H01L51/0036 , H01L51/0053 , H01L51/0059 , H01L51/0067 , H01L51/0071 , H01L51/0072 , H01L51/0073 , Y10S428/917 , Y10T428/24975
摘要： An electroluminescent element comprising an electroluminescent (EL) material part which emits a near ultraviolet ray of light and a fluorescent material part which absorbs the ultraviolet light emitted from the electroluminescent material and emits a fluorescence in a visible light range from blue to red. The electroluminescent element provides for emission of lights with a wide range of wavelength and three elementary colors of blue, green and red can be expressed by appropriate combinations of the organic EL material and the fluorescent material. Consequently, the electroluminescent element provides for a full color display.

6. 发明授权

US06280861B1 Organic EL device 有权
标题翻译：有机EL器件
公开(公告)号：US06280861B1
公开(公告)日：2001-08-28
申请号：US09194424
申请日：1999-01-21
申请人： Chishio Hosokawa , Masahide Matsuura , Hiroshi Tokailin
发明人： Chishio Hosokawa , Masahide Matsuura , Hiroshi Tokailin
IPC分类号： H05B3314
CPC分类号： H05B33/28 , H01L51/5206 , H01L51/5209 , H01L51/5215 , Y10S428/917 , Y10T428/24479 , Y10T428/24537 , Y10T428/24917 , Y10T428/31
摘要： An amorphous electrically conductive oxide such as In—Zn—O-containing amorphous oxide or amorphous ITO is used alone, or a laminate having a two- or three-layer structure constituted of the amorphous electrically conductive oxide and at least a thin metal layer is used, to form a transparent electrode whose side surface has a tapered form and whose top layer is formed of a layer of the above amorphous electrically conductive oxide, an organic single-layer portion or an organic multi-layer portion containing at least an organic light-emitting material is formed on the above transparent electrode, and further, an opposing electrode is formed on the above organic single-layer portion or the above organic multi-layer portion, whereby an organic EL device is obtained. A flattening layer is optionally provided so as to abut on the side surface of the transparent electrode for moderating a height-level difference between the above transparent electrode and the surface of the above substrate. Further, the above organic EL device is used to form an organic EL display panel.
摘要翻译：单独使用无定形导电氧化物，例如含In-Zn-O的无定形氧化物或非晶ITO，或由非晶导电氧化物和至少一薄层金属层构成的二层或三层结构的层压体用于形成其侧表面具有锥形并且其顶层由上述非晶导电氧化物层形成的透明电极，有机单层部分或至少含有有机光的有机多层部分在上述透明电极上形成发光材料，并且在上述有机单层部分或上述有机多层部分上形成相对电极，从而获得有机EL器件。可选地设置平坦化层以邻接透明电极的侧表面，以缓和上述透明电极与上述基板的表面之间的高度差。此外，使用上述有机EL器件来形成有机EL显示面板。

7. 发明授权

US5121029A Electroluminescence device having an organic electroluminescent element 失效
标题翻译：具有有机电致发光元件的电致发光器件
公开(公告)号：US5121029A
公开(公告)日：1992-06-09
申请号：US461407
申请日：1990-01-05
申请人： Chishio Hosokawa , Tadashi Kusumoto , Hiroshi Tokailin , Hisahiro Higashi
发明人： Chishio Hosokawa , Tadashi Kusumoto , Hiroshi Tokailin , Hisahiro Higashi
IPC分类号： C09K11/06 , H05B33/14
CPC分类号： H05B33/14 , C09K11/06 , Y10S428/917
摘要： An electroluminescence device (EL device) and method of manufacture thereof in which an emitting material is made of an organic compound represented by general formula (I), (I') or (II): ##STR1## The EL device displays a high brightness by applying only low voltage.
摘要翻译：发光材料由通式（I），（I'）或（II）表示的有机化合物制成的电致发光器件（EL器件）及其制造方法：XCHCHYCHCHZ（I））XCHCHZ（II）EL器件通过仅施加低电压来显示高亮度。

8. 发明授权

US06284393B1 Organic electroluminescent device 失效
标题翻译：有机电致发光器件
公开(公告)号：US06284393B1
公开(公告)日：2001-09-04
申请号：US08980345
申请日：1997-11-28
申请人： Chishio Hosokawa , Masahide Matsuura , Hiroshi Tokailin
发明人： Chishio Hosokawa , Masahide Matsuura , Hiroshi Tokailin
IPC分类号： H05B3326
CPC分类号： H05B33/28 , H01L51/5092 , H01L51/5234 , H01L2251/5315 , Y10S428/917
摘要： Transparent, organic EL devices comprising an positive electrode, a negative electrode and an organic layer including an organic light-emitting layer as sandwiched between the two electrodes, in which the negative electrode is comprised of an electron injection electrode layer and an amorphous transparent conductive film, and the electron injection electrode layer is adjacent to the organic layer, or in which the negative electrode is comprised of an electron injection electrode layer, a transparent conductive film and a thin metal film having a specific resistance of not larger than 1×10−5 &OHgr;·cm, as laminated in that order with the electron injection electrode layer being adjacent to the organic layer, and a thin transparent film is formed outside the negative electrode. Preferably, the transparent conductive film is an amorphous one. The devices have a negative electrode with low resistance and high transparency, and have high luminous efficiency and good durability (wet heat resistance). The light emission can be taken out through the side of the negative electrode of the devices. The devices are usable for high-resolution display.
摘要翻译：透明的有机EL器件包括正电极，负电极和包含夹在两电极之间的有机发光层的有机层，其中负电极由电子注入电极层和非晶透明导电膜，并且电子注入电极层与有机层相邻，或者其中负极由电子注入电极层，透明导电膜和电阻率不大于1×10 -5Ω的金属薄膜组成 cm，电子注入电极层与有机层相邻地依次层叠，在负极外侧形成薄的透明膜。优选地，透明导电膜是非晶形导电膜。这些器件具有低电阻和高透明度的负极，并且具有高发光效率和良好的耐久性（耐湿热性）。可以通过器件的负极侧取出发光。这些设备可用于高分辨率显示。

9. 发明授权

US06001413A Method for producing organic electroluminescent device 失效
标题翻译：生产有机电致发光器件的方法
公开(公告)号：US06001413A
公开(公告)日：1999-12-14
申请号：US36000
申请日：1998-03-06
申请人： Masahide Matsuura , Hiroshi Tokailin , Chishio Hosokawa
发明人： Masahide Matsuura , Hiroshi Tokailin , Chishio Hosokawa
IPC分类号： C23C14/56 , H01L51/50 , H01L51/56 , H05B33/10 , B05D5/06
CPC分类号： H05B33/10 , H01L51/56
摘要： Disclosed is a method for producing organic EL devices stably having intended capabilities. The method comprises cleaning an electrode-mounted substrate 17 followed by forming a plurality of film layers including organic layers and a counter electrode layer, on the electrode mounted on the substrate, successively one after another in vacuum, wherein the time just after the finish of cleaning the electrode-mounted substrate 17 and before the start of forming the first film layer on the electrode 12 is shorter than the time within which the value of the contact angle with water of the surface of the electrode 12 just after the finish of cleaning it increases by 30.degree. in vacuum. In producing organic EL devices having a plurality, n=1, 2, 3, . . . , of film layers on an electrode-mounted substrate, the time just after the finish of forming the n'th film layer and before the start of forming the next (n+1)'th film layer is shorter than the time within which the value of the contact angle with water of the surface of the n'th film layer just after having been formed increases by 30.degree. in vacuum. In the organic EL devices produced, the interfaces between the adjacent layers are protected from being contaminated with impurities.
摘要翻译：公开了一种稳定地具有预期能力的有机EL器件的制造方法。该方法包括清洁电极安装的基板17，随后在真空中依次连续地在安装在基板上的电极上形成包括有机层和对电极层的多个膜层，其中刚刚完成之后的时间清洁电极安装基板17，并且在电极12上开始形成第一膜层之前，比刚刚完成清洁之后电极12的表面与水的接触角的值的时间短在真空中增加30°。在制造具有多个n = 1,2,3的有机EL器件时。。。在电极安装基板上的薄膜层，形成第n薄膜层之后的时间和形成下一个（n + 1）薄膜层之前的时间短于其中刚刚形成第n层的表面与水接触角的值在真空中增加30°。在所生产的有机EL器件中，相邻层之间的界面被保护以免被杂质污染。

10. 发明授权

US5366811A Organic electroluminescence device 失效
标题翻译：有机电致发光器件
公开(公告)号：US5366811A
公开(公告)日：1994-11-22
申请号：US856028
申请日：1992-05-04
申请人： Hisahiro Higashi , Chishio Hosokawa , Hiroshi Tokailin
发明人： Hisahiro Higashi , Chishio Hosokawa , Hiroshi Tokailin
IPC分类号： C07C13/28 , C07C15/52 , C07C43/215 , C07C43/243 , C07C43/285 , C07C45/00 , C07C45/51 , C07C47/548 , C07C47/575 , C07C49/782 , C07C49/813 , C07C49/84 , C07D209/86 , C07D213/30 , C07D215/04 , C07D215/14 , C07D241/12 , C07D401/14 , C07D403/14 , C07D409/14 , C09K11/06 , H05B33/14 , B32B9/00
CPC分类号： C07D213/30 , C07C13/28 , C07C15/52 , C07C43/215 , C07C43/243 , C07C43/285 , C07C45/004 , C07C45/513 , C07C47/548 , C07C47/575 , C07C49/782 , C07C49/813 , C07C49/84 , C07D209/86 , C07D215/04 , C07D215/14 , C07D241/12 , C07D401/14 , C07D403/14 , C07D409/14 , C09K11/06 , H01L51/005 , H05B33/14 , C07C2101/14 , H01L51/5012 , Y10S428/917 , Y10T428/31678
摘要： An electroluminescence device (organic EL device) which comprises a pair of electrodes with an emitting layer therebetween. The emitting layer contains a dimerized styryl compound of the formula ##STR1## wherein D and D' are each an arylene group or a divalent aromatic heterocyclic group, E, E', F, F' G and G' are each a hydrogen, an aryl group, an alkyl group, an aralkyl group, an alkoxyl group or a monovalent aromatic heterocyclic group and Q is a divalent group which breaks the conjugation. The dimerized styryl compound has a desirable light emitting efficiency which serves to increase the molecular weight to improve the thin film property. The organic EL device of the present invention is useful in preparing display devices.
摘要翻译： PCT No.PCT / JP91 / 01228 Sec。 371日期：1992年5月4日 102（e）日期1992年5月4日PCT PCT 1991年9月17日PCT公布。出版物WO92 / 05131 日期：1992年4月2日。一种电致发光器件（有机EL器件），其包括在其间具有发光层的一对电极。发光层含有式“IMAGE”的二聚苯乙烯基化合物，其中D和D'各自为亚芳基或二价芳族杂环基，E，E'，F，F'G和G'各自为氢，芳基，烷基，芳烷基，烷氧基或一价芳香族杂环基，Q为断裂共轭的二价基。二聚苯乙烯基化合物具有期望的发光效率，其用于增加分子量以提高薄膜性能。本发明的有机EL器件在制备显示器件方面是有用的。

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