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    • 6. 发明专利
    • Metal coordination compound, polymer composition, and organic electroluminescent element using them
    • 金属协调化合物,聚合物组合物和有机电致发光元件
    • JP2005023071A
    • 2005-01-27
    • JP2004171228
    • 2004-06-09
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • NOMURA MICHIYUKIMORISHITA YOSHIITSUDA YOSHIHIRO
    • H01L51/50C07C49/92C07F15/00C08K5/56C08L101/00C09K11/06H05B33/14
    • PROBLEM TO BE SOLVED: To provide a metal coordination compound which emits light covering from green to red and has a long drive life, to provide a polymer composition, and to provide an organic electroluminescent element using them.
      SOLUTION: The metal coordination compound is represented by any one of formulae (1) to (6) [wherein M is Ir, Rh, Ru, Os, Pd, or Pt; n is 2 or 3; another bidentate ligand is further bonded to M when M is Ir, Rh, Ru, or Os and n is 2; ring A is a cyclic compound containing a nitrogen atom bonded to M; X
      1 to X
      7 are each independently a substituent selected from the group consisting of -H, -OH, -R
      1 , -OR
      2 , -SR
      3 , -OCOR
      4 , -COOR
      5 , -SiR
      6 R
      7 R
      8 , -NH
      2 , -NHR
      9 , and -NR
      10 R
      11 (wherein R
      1 to R
      11 are each an alkyl group, an aryl group, a heteroaryl group, or an aralkyl group), provided that ring A may have a substituent similar to a group defined in X
      1 to X
      7 ].
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种金属配位化合物,其发出从绿色到红色的光,并且具有长的驱动寿命,以提供聚合物组合物,并提供使用它们的有机电致发光元件。 解决方案:金属配位化合物由式(1)至(6)中的任一个表示[其中M为Ir,Rh,Ru,Os,Pd或Pt; n为2或3; 当M是Ir,Rh,Ru或Os,n是2时,另一个二齿配体进一步键合到M上; 环A是含有与M键合的氮原子的环状化合物; X 1 至X 7 各自独立地为选自-H,-OH,-R SP 1,-OR, SP> 2 ,-SR 3 ,-OCOR 4 ,-COOR 5 ,-SiR 6 R 11 (其中R 1 至R SP 11各自为烷基,芳基,杂芳基或芳烷基 基团),条件是环A可以具有类似于X 1 至X 7 中定义的基团的取代基。 版权所有(C)2005,JPO&NCIPI
    • 9. 发明专利
    • Metal coordination compound, polymer composition, and organic electroluminescent element using them
    • 金属协调化合物,聚合物组合物和有机电致发光元件
    • JP2005023072A
    • 2005-01-27
    • JP2004171704
    • 2004-06-09
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • NOMURA MICHIYUKIMORISHITA YOSHIITSUDA YOSHIHIRO
    • H01L51/50C07C49/92C07D213/50C07D249/18C07D263/32C07D277/66C07D409/04C07F15/00C09K11/06H05B33/14
    • PROBLEM TO BE SOLVED: To provide a metal coordination compound having blue phosphorescence excellent in color purity and long-drive-life phosphorescence ranging from blue to red, to provide a polymer composition, and to provide an organic electroluminescent element using them.
      SOLUTION: The metal coordination compound is represented by any one of formulae (1) to (6) [wherein M is Ir, Rh, Ru, Os, Pd, or Pt; n is 2 or 3; another bidentate ligand is further bonded to M when M is Ir, Rh, Ru, or Os and n is 2; ring A is a cyclic compound containing a nitrogen atom bonded to M; X
      1 to X
      6 and R are each a substituent selected from the group consisting of -R
      1 , -OR
      2 , -SR
      3 , -OCOR
      4 , -COOR
      5 , -SiR
      6 R
      7 R
      8 , and -NR
      9 R
      10 (wherein R
      1 to R
      10 are each a hydrogen atom, a halogen atom, a cyano group, a nitro group, or an optionally halogen-substituted alkyl, aryl, heteroaryl, or aralkyl group)].
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供具有蓝色磷光的金属配位化合物,其颜色纯度和蓝色至红色的长驱动寿命磷光都是优异的,以提供聚合物组合物,并提供使用它们的有机电致发光元件。 解决方案:金属配位化合物由式(1)至(6)中的任一个表示[其中M为Ir,Rh,Ru,Os,Pd或Pt; n为2或3; 当M是Ir,Rh,Ru或Os,n是2时,另一个二齿配体进一步键合到M上; 环A是含有与M键合的氮原子的环状化合物; X 1 至X 6,R各自为选自-R SP 1,-OR 2, SP>,-SR 3 ,-OCOR 4 ,-COOR 5 ,-SiR 6 R (其中R 1 R 8 > 10 各自为氢原子,卤素原子,氰基,硝基或任选卤素取代的烷基,芳基,杂芳基或芳烷基)]。 版权所有(C)2005,JPO&NCIPI