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    • 2. 发明授权
    • Method for forming images
    • 图像形成方法
    • US5278025A
    • 1994-01-11
    • US931508
    • 1992-08-21
    • Hisashi OkamuraKazunobu KatohTetsuro Kojima
    • Hisashi OkamuraKazunobu KatohTetsuro Kojima
    • G03C1/06G03C1/34G03C1/43G03C5/305G03C5/26G03C5/30
    • G03C1/061G03C1/34G03C1/43G03C5/305Y10S430/158
    • A method for forming an image comprising the steps of: (a) imagewise exposing silver halide photographic materials; where said photographic material contains (1) a compound represented by formula (I) ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, or an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; and A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 or A.sub.2 represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, and (2) a redox compound that can release a development inhibitor when oxidized; and (b) subjecting said imagewise exposed silver halide photographic materials to development-processing where a bath used in said development-processing contains a nucleation development accelerator.
    • 一种用于形成图像的方法,包括以下步骤:(a)成像曝光卤化银照相材料; 其中所述照相材料包含(1)由式(I)表示的化合物(*化学结构*)(I)其中R 1表示脂族基团或芳族基团; R2表示氢原子,烷基或芳基,烷氧基,芳氧基,氨基,氨基甲酰基或氧羰基; G1表示羰基,磺酰基,磺氧基,(*化学结构*)或亚氨基亚甲基; 和A1和A2均表示氢原子,或A1或A2中的一个表示氢原子,另一个表示取代或未取代的烷基磺酰基,取代或未取代的芳基磺酰基或取代或未取代的酰基,(2) 氧化还原化合物,当氧化时可释放显影抑制剂; 和(b)对所述成像曝光的卤化银照相材料进行显影处理,其中所述显影处理中使用的浴含有成核显影促进剂。
    • 3. 发明授权
    • Photographic material and method for forming an image
    • 摄影材料和形成图像的方法
    • US5328801A
    • 1994-07-12
    • US846926
    • 1992-03-06
    • Shoji YasudaKazunobu KatohHisashi Okamura
    • Shoji YasudaKazunobu KatohHisashi Okamura
    • G03C1/06G03C1/43G03C5/29G03C7/305
    • G03C1/061G03C7/30511Y10S430/158
    • A method for forming an image is disclosed, which comprises processing with a developer having a pH value of 9 to 12 and comprising 0.2 mol/liter or more of a sulfite an imagewise exposed silver halide photographic material comprising a compound represented by formula (I): ##STR1## wherein Het represents a group represented by formula (II) and the remaining terms are as defined in the specification: ##STR2## wherein the terms are as defined in the specification. In a preferred embodiment, the compound represented by formula (I) is a compound represented by formula (III): ##STR3## wherein the terms are as defined in the specification. The light-sensitive material may comprise a hydrazine derivative in addition to the compound represented by formula (I) or (III).
    • 公开了一种用于形成图像的方法,其包括用pH值为9至12的显影剂加工并包含0.2mol /升或更多的亚硫酸盐,其包含由式(I)表示的化合物的成像曝光的卤化银照相材料, :ED-(时间)t-(Link)s-Het(I)其中Het表示由式(II)表示的基团,其余的术语如本说明书中所定义:其中术语为 在规范中定义。 在优选的实施方案中,由式(I)表示的化合物是由式(III)表示的化合物:其中术语如说明书中所定义。 除了式(I)或(III)表示的化合物之外,感光材料可以包含肼衍生物。
    • 5. 发明授权
    • Silver halide photographic materials
    • 卤化银照相材料
    • US5252438A
    • 1993-10-12
    • US763688
    • 1991-09-23
    • Kazumi NiiHisashi OkamuraKazunobu Katoh
    • Kazumi NiiHisashi OkamuraKazunobu Katoh
    • G03C7/305G03C1/06G03C1/43G03C1/42
    • G03C1/061Y10S430/158
    • Disclosed is a silver halide photographic material containing a compound of a general formula (1) or (2):ED-(Time).sub.t -Y-L-Z (1)wherein ED represents a group that releases the moiety (Time).sub.t -Y-L-Z by reaction with an oxidation product of a developing agent; Time represents a divalent linking group; t represents 0 or 1; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety ED-(Time).sub.t ; L represents a divalent group which is capable of being cleaved by reaction with components in a developer; and Z represents a monovalent functional group that expresses a development inhibiting effect; ##STR1## wherein Time, t, L and Z have the same meanings as above; Y represents a divalent group comprising a hetero atom through which Y bonds to the moiety ##STR2## R.sub.1 represents an aliphatic group or an aromatic group; G.sub.1 represents is ##STR3## G.sub.2 represents a mere bond, --O--, --S-- or ##STR4## R.sub.2 has the same meaning as R.sub.1 or represents a hydrogen atom; when the compound has plural R.sub.2 's, they may be same as or different from each other; and one of A.sub.1 and A.sub.2 represents a hydrogen atom, and the other represents a hydrogen atom, or an acyl group, an alkylsulfonyl group or an arylsulfonyl group. The material may reproduce excellently a line original to form an ultra-hard image having a high background density. It also has a broad exposure latitude in halftone dot image-taking work and can form an ultra-hard halftone dot image with a high image quality. The material is useful in formation of ultra-hard negative images by photomechanical process.
    • 9. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5017456A
    • 1991-05-21
    • US470658
    • 1990-01-26
    • Hisashi OkamuraKazunobu Katoh
    • Hisashi OkamuraKazunobu Katoh
    • G03C1/06G03C1/485
    • G03C1/061
    • A silver halide photographic material which comprises a support having thereon at least one hydrophilic colloid layer, wherein at least one hydrophilic colloid layer is a silver halide photographic emulsion layer, and at least one hydrophilic colloid layer contains a compound represented by the following general formula (I): ##STR1## wherein A.sub.1 and A.sub.2 both represent a hydrogen atom, or one of A.sub.1 and A.sub.2 is a hydrogen atom and the other is a sulfonyl group or an acyl group; R.sub.1 represent an aliphatic group or an aromatic group; Y.sub.1 represents a divalent linking group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, a group of ##STR2## wherein R.sub.2 is an alkoxy group or an aryloxy group, a group of ##STR3## or an iminomethylene group; and Z.sub.1 represents a residue of a nitrogen-containing heterocyclic ring.
    • 一种卤化银照相材料,其包括其上具有至少一个亲水胶体层的载体,其中至少一个亲水胶体层是卤化银照相乳剂层,并且至少一个亲水胶体层含有由以下通式表示的化合物 I):其中A 1和A 2均表示氢原子,或者A 1和A 2中的一个为氢原子,另一个为磺酰基或酰基。 R1表示脂族基团或芳香族基团; Y1表示二价连接基团; G1表示羰基,磺酰基,亚磺酰基,亚砜基,其中R2是烷氧基或芳氧基,一个“IMAGE”或“亚氨基亚甲基”的基团; Z1表示含氮杂环的残基。