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    • 1. 发明授权
    • Pyrrole ring-or condensed pyrrole ring-containing azomethine dye
    • 含吡咯环或缩合吡咯环的偶氮甲碱染料
    • US5344933A
    • 1994-09-06
    • US942835
    • 1992-09-10
    • Hisashi MikoshibaKatsuyoshi YamakawaKozo SatoKoushin Matsuoka
    • Hisashi MikoshibaKatsuyoshi YamakawaKozo SatoKoushin Matsuoka
    • B41M5/39C07D487/04C09B55/00D06P5/13G03C1/83C07D471/04B41M5/00B41M5/30G03C7/30
    • B41M5/39C09B55/009G03C1/83
    • An azomethine dye is disclosed, represented by the general formula (I), (II) or (III): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represents a hydrogen atom or nonmetallic atom group; X represents --OH or --NR.sup.5 R.sup.6 ; R.sup.5 and R.sup.6 each independently represents a hydrogen atom, alkyl group, aryl group or heterocyclic group; R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 each independently represents a hydrogen atom or nonmetallic atom group; and R.sup.1 and R.sup.2, and/or R.sup.2 and R.sup.5, and/or R.sup.5 and R.sup.6, and/or R.sup.6 and R.sup.3, and/or R.sup.3 and R.sup.4, and/or R.sup.7 and R.sup.8, and/or R.sup.9 and R.sup.10, and/or R.sup.11 and R.sup.12, and/or R.sup.12 and R.sup.13 may be connected to each other to form a cyclic structure. A heat transfer dye providing material is also disclosed, comprising a support having thereon a dye providing layer containing a heat migrating dye, the dye providing layer comprising at least one azomethine dye represented by the general formula (I), (II) or (III).
    • 公开了由通式(I),(II)或(III)表示的偶氮甲碱染料:其中R1,R2,R3和R4各自独立地表示: 独立地表示氢原子或非金属原子团; X表示-OH或-NR 5 R 6; R5和R6各自独立地表示氢原子,烷基,芳基或杂环基; R 7,R 8,R 9,R 10,R 11,R 12和R 13各自独立地表示氢原子或非金属原子团; 和R 1和R 2和/或R 2和R 5,和/或R 5和R 6,和/或R 6和R 3,和/或R 3和R 4,和/或R 7和R 8,和/或R 9和R 10,和/或 R11和R12,和/或R12和R13可以彼此连接以形成环状结构。 还公开了一种传热染料提供材料,其包括其上具有含有热迁移染料的染料提供层的载体,所述染料提供层包含至少一种由通式(I),(II)或(III)表示的偶氮甲碱染料 )。
    • 8. 发明授权
    • Dye forming couplers and silver halide color photosensitive material
containing the same
    • 染料形成成色剂和含有卤化银色光敏材料
    • US5401624A
    • 1995-03-28
    • US145630
    • 1993-11-04
    • Kozo SatoYoshio IshiiKatsuyoshi Yamakawa
    • Kozo SatoYoshio IshiiKatsuyoshi Yamakawa
    • C07D487/04G03C7/38
    • C07D487/04G03C7/3825G03C7/383
    • A silver halide color photosensitive material which forms a cyan dye that has superior heat resistance and that will not readily fade in a reducing atmosphere. The silver halide color photosensitive material contains in at least one layer on a support at least one coupler represented by formula (I): ##STR1## wherein R.sup.1 represents hydrogen atom or a substituent; R.sup.2 represents a substituent; X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of a color developing agent; Z.sup.1 represents a nonmetallic atom group necessary for forming a nitrogen-containing, six-membered, heterocyclic ring which has at least one dissociative group: Z.sup.1 cannot be --C(.dbd.O)--N(R)--C(.dbd.O)--NH--; and R represents a substituent.Also disclosed is a novel dye forming coupler which exhibits a high coupling activity and which gives a dye having a large molar extinction coefficient and superior stability, the coupler being represented by the following formula (XX) or (XXI). Also disclosed is a silver halide color photosensitive material which contains at least one of the dye forming couplers of formulae (XX) and (XXI) and which provides sharp dye images with high fastness properties. ##STR2## wherein EWG represents an electron withdrawing group having a Hammett's .sigma..sub.p value of not less than 0.3; R.sub.1 and R.sub.2 each represent a substituent; and X represents hydrogen atom or a group releasable on a coupling reaction with an oxidation product of an aromatic primary amine developing agent.
    • 一种卤化银色感光材料,其形成具有优异耐热性且不易在还原气氛中褪色的青色染料。 卤化银色感光材料在载体上至少一层中含有至少一个由式(I)表示的成色剂:汤姆或取代基; R2表示取代基; X表示氢原子或可与显色剂的氧化产物偶联反应脱离的基团; Z1表示形成具有至少一个解离基团的含氮六元杂环所必需的非金属原子团:Z1不能为-C(= O)-N(R)-C(= O)-NH - ; R表示取代基。 还公开了一种新型的染料形成成色剂,其显示出高的偶联活性,并且得到具有大的摩尔吸光系数和优异的稳定性的染料,所述成色剂由下式(XX)或(XXI)表示。 还公开了含有式(XX)和(XXI)的染料形成成色剂中的至少一种的卤化银色感光材料,并提供具有高坚牢度性质的清晰的染料图像。 (XXI)(XXI)其中EWG表示哈米特σp值不小于0.3的吸电子基团; R1和R2各自表示取代基; X表示氢原子或可与芳族伯胺显影剂的氧化产物偶联反应脱离的基团。