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1. 发明授权

US08157930B2 Martensitic stainless steel 有权
标题翻译：马氏体不锈钢
公开(公告)号：US08157930B2
公开(公告)日：2012-04-17
申请号：US10798855
申请日：2004-03-12
申请人： Hisashi Amaya , Kunio Kondo , Masakatsu Ueda , Keiichi Nakamura , Takahiro Kushida , Kazuyo Kushida, legal representative
发明人： Hisashi Amaya , Kunio Kondo , Masakatsu Ueda , Keiichi Nakamura , Takahiro Kushida
IPC分类号： C22C38/22 , C21D8/02
CPC分类号： C22C38/44 , C22C38/001 , C22C38/002 , C22C38/04 , C22C38/42
摘要： A martensitic stainless steel comprising C: 0.01-0.10%, Si: 0.05-1.0%, Mn: 0.05-1.5%, P: not more than 0.03%, S: not more than 0.01%, Cr: 9-15%, Ni: 0.1-4.5%, Al: not more than 0.05% and N: not more than 0.1% in mass %, and further comprising at least one of Cu: 0.05-5% and Mo: 0.05-5%, the residual being Fe and impurities, is provided, wherein the contents of Cu and Mo satisfy the following formula (a) or (b), 0.2%≦Mo+Cu/4≦5% (a) 0.55%≦Mo+Cu/4≦5% (b) and wherein the hardness is 30-45 in HRC and the carbide amount in grain boundaries of the prior austenite is not more than 0.5 volume %. The marensitic stainless steel has excellent properties regarding the sulfide stress cracking resistance, the resistance to corrosive wear and the localized corrosion.
摘要翻译：一种马氏体不锈钢，其包含C：0.01〜0.10％，Si：0.05〜1.0％，Mn：0.05〜1.5％，P：0.03％以下，S：0.01％以下，Cr：9〜15％，Ni ：0.1-4.5％，Al：0.05％以下，N：0.1质量％以下，进一步含有Cu：0.05〜5％和Mo：0.05〜5％中的至少一种，残留物为Fe 提供Cu和Mo的含量满足下式（a）或（b）：0.2％＆lt; NlE; Mo + Cu / 4＆nlE; 5％（a）0.55％＆nlE; Mo + Cu / 4＆ 5％（b），硬度在HRC中为30-45，前奥氏体的晶界中的碳化物量不大于0.5体积％。锰矿不锈钢具有耐硫化物应力开裂性，耐腐蚀性和局部腐蚀性等优异性能。

2. 发明申请

US20050034790A1 Martensitic stainless steel 有权
标题翻译：马氏体不锈钢
公开(公告)号：US20050034790A1
公开(公告)日：2005-02-17
申请号：US10798855
申请日：2004-03-12
申请人： Hisashi Amaya , Kunio Kondo , Masakatsu Ueda , Keiichi Nakamura , Takahiro Kushida , Kazuyo Kushida
发明人： Hisashi Amaya , Kunio Kondo , Masakatsu Ueda , Keiichi Nakamura , Takahiro Kushida , Kazuyo Kushida
IPC分类号： C22C38/00 , C22C38/04 , C22C38/42 , C22C38/44 , C22C38/54 , C22C38/22
CPC分类号： C22C38/44 , C22C38/001 , C22C38/002 , C22C38/04 , C22C38/42
摘要： A martensitic stainless steel comprising C: 0.01-0.10%, Si: 0.05-1.0%, Mn: 0.05-1.5%, P: not more than 0.03%, S: not more than 0.01%, Cr: 9-15%, Ni: 0.1-4.5%, Al: not more than 0.05% and N: not more than 0.1% in mass %, and further comprising at least one of Cu: 0.05-5% and Mo: 0.05-5%, the residual being Fe and impurities, is provided, wherein the contents of Cu and Mo satisfy the following formula (a) or (b), 0.2%≦Mo+Cu/4≦5% (a) 0.55%≦Mo+Cu/4≦5% (b) and wherein the hardness is 30-45 in HRC and the carbide amount in grain boundaries of the prior austenite is not more than 0.5 volume %. The marensitic stainless steel has excellent properties regarding the sulfide stress cracking resistance, the resistance to corrosive wear and the localized corrosion.
摘要翻译：一种马氏体不锈钢，其包含C：0.01〜0.10％，Si：0.05〜1.0％，Mn：0.05〜1.5％，P：0.03％以下，S：0.01％以下，Cr：9〜15％，Ni ：0.1-4.5％，Al：0.05％以下，N：0.1质量％以下，进一步含有Cu：0.05〜5％和Mo：0.05〜5％中的至少一种，残留物为Fe 和杂质，其中Cu和Mo的含量满足下式（a）或（b），0.2％<= Mo + Cu / 4 <= 5％（a）0.55％<= Mo + Cu / 4 <= 5％（b），其中HRC中的硬度为30-45，并且原奥氏体的晶界中的碳化物量不大于0.5体积％。锰矿不锈钢具有耐硫化物应力开裂性，耐腐蚀性和局部腐蚀性等优异性能。

3. 发明授权

US07648587B2 Steel product for use as line pipe having high HIC resistance and line pipe produced using such steel product 有权
标题翻译：钢产品用作具有高HIC电阻的管线管和使用这种钢产品生产的管线管
公开(公告)号：US07648587B2
公开(公告)日：2010-01-19
申请号：US10588122
申请日：2004-06-17
申请人： Takahiro Kushida , Kazuyo Kushida, legal representative , Tomohiko Omura , Mitsuhiro Numata
发明人： Takahiro Kushida , Tomohiko Omura , Mitsuhiro Numata
IPC分类号： C22C38/00
CPC分类号： C22C38/02 , C22C38/04
摘要： A steel product for a line pipe according to the invention has a composition containing, in mass %, C : 0.03% to 0.15%, Si: 0.05% to 1.0%, Mn: 0.5% to 1.8%, P: 0.015% or less, S: 0.004% or less, O: 0.01% or less, N: 0.007% or less, sol. Al: 0.01% to 0.1%, Ti: 0.024% or less, Ca: 0.0003% to 0.02%, and the balance consisting of Fe and impurities. The size of TiN in the steel product for a line pipe is at most 30 μm. The steel product has high HIC resistance and its crack area ratio can be reduced to 3% or less.
摘要翻译：根据本发明的管线用钢产品具有质量％C：0.03〜0.15％，Si：0.05〜1.0％，Mn：0.5〜1.8％，P：0.015％以下的组合物，S：0.004％以下，O：0.01％以下，N：0.007％以下，溶胶。 Al：0.01〜0.1％，Ti：0.024％以下，Ca：0.0003〜0.02％，余量由Fe和杂质构成。用于管道管道的钢制品中的TiN的尺寸至多为30μm。该钢产品具有高HIC电阻，裂纹面积比可以降低到3％以下。

4. 发明授权

US5383983A Martensitic stainless steel suitable for use in oil wells 失效
标题翻译：马氏体不锈钢适用于油井
公开(公告)号：US5383983A
公开(公告)日：1995-01-24
申请号：US45596
申请日：1993-04-09
申请人： Kunio Kondo , Takahiro Kushida , Masakatsu Ueda
发明人： Kunio Kondo , Takahiro Kushida , Masakatsu Ueda
IPC分类号： C22C38/00 , C22C38/44 , C22C38/50
CPC分类号： C22C38/44
摘要： A martensitic stainless steel for use in oil wells has improved stability in strength and good resistance to sulfide stress corrosion cracking The steel has a chemical composition consisting essentially, on a weight basis, of: Si: not greater than 1.0%, Mn: not greater than 1.0%, Cr: 10.0-14.0%, Mo: 0.5-7.0%, Ni: 4.0-8.0%, Al: 0.001-0.1%, either Ti in an amount satisfying the following inequality (1) or Zr in an amount satisfying the following inequality (2), optionally one or both of Mg: 0.001-0.05% and Ce: 0.001-0.05%, and a balance of Fe and incidental impurities in which the contents of C, P, S, N, and V as impurities are limited to 0.05% or less, 0.04% or less, 0.005% or less, 0.05% or less, and 0.2% or less, respectively, the composition further satisfying the following inequalities (3) and (4):4(%C).ltoreq.%Ti.ltoreq.{-0.01/(%C+0.015))}+0.75 (1)10(%C).ltoreq.%Zr.ltoreq.2 0% (2)30(%Cr)+36(%Mo)+14(%Si)-28(%Ni).ltoreq.455 (3)21(%Cr)+25(%Mo)+17(%Si)+35(%Ni).ltoreq.731 (4).
摘要翻译：用于油井的马氏体不锈钢具有提高的强度稳定性和良好的耐硫化应力腐蚀开裂性。钢的化学组成基本上以重量计：Si：不大于1.0％，Mn：不大 1.0％，Cr：10.0〜14.0％，Mo：0.5〜7.0％，Ni：4.0〜8.0％，Al：0.001-0.1％，满足以下不等式（1）的Ti或满足以下不等式（2），Mg：0.001-0.05％和Ce：0.001-0.05％中的任意一种或两种，以及C，P，S，N和V的含量的Fe和杂质的余量为杂质分别限制在0.05％以下，0.04％以下，0.005％以下，0.05％以下，0.2％以下，进一步满足以下不等式（3）和（4）：4（％ C）

5. 发明申请

US20050274436A1 Martensitic stainless steel 有权
标题翻译：马氏体不锈钢
公开(公告)号：US20050274436A1
公开(公告)日：2005-12-15
申请号：US10411186
申请日：2003-04-11
申请人： Kunio Kondo , Takahiro Kushida , Yuichi Komizo , Masaaki Igarashi
发明人： Kunio Kondo , Takahiro Kushida , Yuichi Komizo , Masaaki Igarashi
IPC分类号： C21D8/00 , C21D8/02 , C22C38/00 , C22C38/18 , C22C38/42 , C22C38/44 , C22C38/46 , C22C38/54
CPC分类号： C22C38/44 , C21D8/005 , C21D8/0263 , C21D2211/008 , C22C38/42 , C22C38/46
摘要： A martensitic stainless steel having a C content of 0.01 to 0.1 mass %, a Cr content of 9 to 15 mass % and a N content of not more than 0.1 mass %, wherein the maximum length of the carbides in the steel is 10 to 200 nm in the direction of the minor axis, or wherein the ratio of the average Cr concentration [Cr] to the average Fe concentration [Fe] in carbides in the steel ([Cr]/[Fe]) is not more than 0.4, or wherein the content of M23C6 type carbides is not more than 1 volume %, the content of M3C type carbides is 0.01 to 1.5 volume % and the content of MN type or M2N type nitrides is not more than 0.3 volume % is provided. This stainless steel has a high toughness in spite of both a relatively more C content and a high strength, thereby providing a, wide applicability to pipe material for oil wells containing carbon dioxide and a small amount of hydrogen sulfide, in particular for oil wells having a much greater depth.
摘要翻译： C含量为0.01〜0.1质量％，Cr含量为9〜15质量％，N含量为0.1质量％以下的马氏体系不锈钢，其中，碳的最大长度为10〜200 或其中钢中的碳化物中的平均Cr浓度[Cr]与平均Fe浓度[Fe]的比例（[Cr] / [Fe]））不大于0.4，或者其中M 23 C 6 C型碳化物的含量不超过1体积％，M 3 C型碳化物的含量为0.01〜 1.5体积％，并且MN型或M 2 N型氮化物的含量不大于0.3体积％。该不锈钢虽然具有较高的C含量和较高的强度，但具有较高的韧性，从而为含有二氧化碳和少量硫化氢的油井的管道材料提供了广泛的应用，特别是对于具有更深的深度

6. 发明授权

US06267828B1 Low alloy steel for oil country tubular goods and method of making 有权
标题翻译：石油国家管状低合金钢及其制造方法
公开(公告)号：US06267828B1
公开(公告)日：2001-07-31
申请号：US09456917
申请日：1999-12-07
申请人： Takahiro Kushida , Kaori Miyata , Kunio Kondo , Tomohiko Omura
发明人： Takahiro Kushida , Kaori Miyata , Kunio Kondo , Tomohiko Omura
IPC分类号： C22C3822
CPC分类号： C21D6/02 , C21D1/18 , C22C38/22 , C22C38/24
摘要： A low alloy steel for oil country tubular well which has a yield stress of 110 ksi or above, and excellent sulfide stress cracking resistance. The low alloy steel comprises, by weight, 0.2 to 0.35% carbon, 0.2 to 0.7% chromium, 0.1 to 0.5% molybdenum, 0.1 to 0.3% vanadium, 0 to 0.5% silicon, 0 to 1% manganese, 0 to 0.1% aluminum, 0 to 0.1% niobium, 0 to 0.05% titanium, 0 to 0.005% boron, 0 to 0.1% zirconium, 0 to 1% tungsten, 0 to 0.01% calcium, 0.025% or less phosphorus, 0.01% or less sulfur, 0.01% or less nitrogen, and 0.01% or less oxygen. The low alloy steel further comprises a total amount of precipitated carbides between about 2 to 5% by weight, and a ratio of the MC type carbide to the total amount of the precipitated carbides is between about 8 to 40% by weight.
摘要翻译：用于油井管的低合金钢，其屈服应力为110ksi以上，并且具有优异的耐硫化物应力开裂性。低合金钢的重量为0.2〜0.35％的碳，0.2〜0.7％的铬，0.1〜0.5％的钼，0.1〜0.3％的钒，0〜0.5％的硅，0〜1％的锰，0〜0.1％的铝，0〜0.1％的铌，0〜0.05％的钛，0〜0.005％的硼，0〜0.1％的锆，0〜1％的钨，0〜0.01％的钙，0.025％以下的磷，0.01％以下的硫，0.01 ％以下的氮，0.01％以下的氧。低合金钢还含有约2〜5重量％的沉淀碳化物的总量，MC型碳化物与沉淀碳化物总量的比例为约8〜40重量％。

7. 发明授权

US06379821B2 Martensitic stainless steel welded pipe 有权
标题翻译：马氏体不锈钢焊管
公开(公告)号：US06379821B2
公开(公告)日：2002-04-30
申请号：US09822233
申请日：2001-04-02
申请人： Takahiro Kushida , Tomohiko Omura , Kunio Kondo , Kazuhiro Ogawa , Masahiko Hamada
发明人： Takahiro Kushida , Tomohiko Omura , Kunio Kondo , Kazuhiro Ogawa , Masahiko Hamada
IPC分类号： B32B1518
CPC分类号： B23K9/23 , B23K9/0253 , B23K35/308 , B23K35/3086 , B23K2101/06 , C22C38/002 , C22C38/004 , C22C38/42 , C22C38/44 , C22C38/46 , C22C38/50 , Y10S148/909 , Y10T428/12958 , Y10T428/12979 , Y10T428/12986
摘要： This invention relates to a large-diameter, thick-wall martensitic stainless steel welded pipe. For this welded pipe, the size of the raised weld bead portion on the inside surface is restricted to be small based on a conditional formula derived by considering the bead width and height and the yield strength of the base metal and of the weld metal. As a result, the base metal portion and pipe inside surface seam portion of this welded pipe are superior in corrosion resistance, in particular stress corrosion cracking resistance (SCC resistance). The sulfide stress corrosion resistance (sour gas resistance) and carbon dioxide corrosion resistance can be further improved by selecting the chemical compositions. This welded pipe is very well suited for use as a pipe for a pipeline for conveying a crude oil and a natural gas with no dehydration treatment, which is highly corrosive to metals.
摘要翻译：本发明涉及一种大直径，厚壁的马氏体不锈钢焊管。对于该焊接管，基于通过考虑焊道宽度和高度以及基体金属和焊接金属的屈服强度导出的条件公式将内表面上的凸起焊道部分的尺寸限制为小。结果，该焊接管的贱金属部分和管内表面接缝部分具有优异的耐腐蚀性，特别是耐应力腐蚀开裂性（SCC电阻）。通过选择化学成分可以进一步提高耐硫化物应力腐蚀性（耐酸性气体阻力）和二氧化碳耐腐蚀性。该焊接管非常适用于输送原油和无脱水处理的天然气管道的管道，该管道对金属具有高度的腐蚀性。

8. 发明授权

US07361236B2 Martensitic stainless steel 有权
标题翻译：马氏体不锈钢
公开(公告)号：US07361236B2
公开(公告)日：2008-04-22
申请号：US10411186
申请日：2003-04-11
申请人： Kunio Kondo , Takahiro Kushida , Yuichi Komizo , Masaaki Igarashi
发明人： Kunio Kondo , Takahiro Kushida , Yuichi Komizo , Masaaki Igarashi
IPC分类号： C22C38/44 , C22C38/46 , C22C38/48 , C22C38/50
CPC分类号： C22C38/44 , C21D8/005 , C21D8/0263 , C21D2211/008 , C22C38/42 , C22C38/46
摘要： A martensitic stainless steel having a C content of 0.01 to 0.1 mass %, a Cr content of 9 to 15 mass % and a N content of not more than 0.1 mass %, wherein the maximum length of the carbides in the steel is 10 to 200 nm in the direction of the minor axis, or wherein the ratio of the average Cr concentration [Cr] to the average Fe concentration [Fe] in carbides in the steel ([Cr]/[Fe]) is not more than 0.4, or wherein the content of M23C6 type carbides is not more than 1 volume %, the content of M3C type carbides is 0.01 to 1.5 volume % and the content of MN type or M2N type nitrides is not more than 0.3 volume % is provided. This stainless steel has a high toughness in spite of both a relatively more C content and a high strength, thereby providing a, wide applicability to pipe material for oil wells containing carbon dioxide and a small amount of hydrogen sulfide, in particular for oil wells having a much greater depth.
摘要翻译： C含量为0.01〜0.1质量％，Cr含量为9〜15质量％，N含量为0.1质量％以下的马氏体系不锈钢，其中，碳的最大长度为10〜200 或其中钢中的碳化物中的平均Cr浓度[Cr]与平均Fe浓度[Fe]的比例（[Cr] / [Fe]））不大于0.4，或者其中M 23 C 6 C型碳化物的含量不超过1体积％，M 3 C型碳化物的含量为0.01〜 1.5体积％，并且MN型或M 2 N型氮化物的含量不大于0.3体积％。该不锈钢虽然具有较高的C含量和较高的强度，但具有较高的韧性，从而为含有二氧化碳和少量硫化氢的油井的管道材料提供了广泛的应用，特别是对于具有更深的深度

9. 发明授权

US5938865A Process for producing high-strength seamless steel pipe having excellent sulfide stress cracking resistance 失效
标题翻译：具有优异的耐硫化物应力开裂性的高强度无缝钢管的制造方法
公开(公告)号：US5938865A
公开(公告)日：1999-08-17
申请号：US952222
申请日：1998-02-05
申请人： Kunio Kondo , Takahiro Kushida , Hajime Osako , Hideki Takabe
发明人： Kunio Kondo , Takahiro Kushida , Hajime Osako , Hideki Takabe
IPC分类号： B21B19/04 , B21B23/00 , C21D8/10
CPC分类号： B21B23/00 , C21D8/10 , B21B19/04
摘要： A process for producing a seamless steel pipe wherein pipe manufacturing steps and the heat treatment steps are carried out in one production line. The properties of the pipe are comparative or superior to those of the pipe manufactured in the conventional reheating, quenching and tempering process. The process is characterized by using the billet of a low alloy steel containing C: 0.15-0.50%, Cr: 0.1-1.5%, Mo: 0.1-1.5%, Al: 0.005-0.50%, Ti: 0.005-0.50% and Nb: 0.003-0.50%, and comprising the following steps (1) to (5).(1) hot rolling with 40% or more of cross sectional reduction ratio,(2) finishing the hot rolling in a temperature range of 800-1100.degree. C.,(3) putting the manufactured steel pipe promptly in a complementary heating apparatus after the finish rolling, and complementarily heating at the temperature and time satisfying the following formula (a).(4) quenching the steel pipe immediately after taking out of the complementary heating apparatus, and(5) tempering the pipe at a temperature not higher than the Ac.sub.1 transformation point as the last heat treatment.23500.ltoreq.(T+273).times.(21+log t).ltoreq.26000 (a)where, T (.degree.C.) is a temperature of not lower than 850.degree. C., and t is time (hr). Further, an intermediate heat treatment consisting of quenching or combination of quenching and tempering may be applied between the steps (4) and (5).
摘要翻译： PCT No.PCT / JP96 / 01274 Sec。 371日期：1998年2月5日 102（e）日期1998年2月5日PCT提交1996年5月15日PCT公布。公开号WO96 / 36742 日期：1996年11月21日一种生产无缝钢管的方法，其中在一条生产线中进行管制造步骤和热处理步骤。管道的性能与传统的再加热，淬火和回火工艺中制造的管材的性能相比甚至更好。该方法的特征在于使用含有C：0.15-0.50％，Cr：0.1-1.5％，Mo：0.1-1.5％，Al：0.005-0.50％，Ti：0.005-0.50％的低合金钢和Nb ：0.003-0.50％，并且包括以下步骤（1）至（5）。（1）以40％以上的横截面减速比进行热轧，（2）在800-1100℃的温度范围内完成热轧，（3）将制造的钢管迅速置于互补的加热装置中精轧，并在满足下述式（a）的温度和时间下互补加热。（4）在取出补充加热装置后立即淬火钢管，（5）在不高于Ac1相变点的温度下对管进行回火作为最后的热处理.23500

10. 发明申请

US20070217942A1 Steel Product for Use as Line Pipe Having High Hic Resistance and Line Pipe Produced Using Such Steel Product 有权
标题翻译：钢制产品用作具有高耐热性的管线和使用这种钢产品生产的管线
公开(公告)号：US20070217942A1
公开(公告)日：2007-09-20
申请号：US10588122
申请日：2004-06-17
申请人： Takahiro Kushida , Kazuyo Kushida , Tomohiko Omura , Mitsuhiro Numata
发明人： Takahiro Kushida , Kazuyo Kushida , Tomohiko Omura , Mitsuhiro Numata
IPC分类号： C22C38/00
CPC分类号： C22C38/02 , C22C38/04
摘要： A steel product for a line pipe according to the invention has a composition containing, in mass %, C : 0.03% to 0.15%, Si: 0.05% to 1.0%, Mn: 0.5% to 1.8%, P: 0.015% or less, S: 0.004% or less, O: 0.01% or less, N: 0.007% or less, sol. Al: 0.01% to 0.1%, Ti: 0.024% or less, Ca: 0.0003% to 0.02%, and the balance consisting of Fe and impurities. The size of TiN in the steel product for a line pipe is at most 30 μm. The steel product has high HIC resistance and its crack area ratio can be reduced to 3% or less.
摘要翻译：根据本发明的管线用钢产品具有质量％C：0.03〜0.15％，Si：0.05〜1.0％，Mn：0.5〜1.8％，P：0.015％以下的组合物，S：0.004％以下，O：0.01％以下，N：0.007％以下，溶胶。 Al：0.01〜0.1％，Ti：0.024％以下，Ca：0.0003〜0.02％，余量由Fe和杂质组成。用于管道管道的钢制品中的TiN的尺寸至多为30μm。该钢产品具有高HIC电阻，裂纹面积比可以降低到3％以下。

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