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    • 4. 发明授权
    • Process for processing silver halide photographic material
    • 卤化银照相材料的处理方法
    • US4738918A
    • 1988-04-19
    • US907335
    • 1986-09-15
    • Shoji IshiguroHiroyuki MifuneShigeo HiranoNobuyuki Iwasaki
    • Shoji IshiguroHiroyuki MifuneShigeo HiranoNobuyuki Iwasaki
    • G03C7/30G03C1/10G03C5/29G03C5/305G03C7/392G03C5/24
    • G03C5/305G03C1/10G03C7/3924
    • A process for processing silver halide photographic material is disclosed, which comprises development-processing a silver halide photographic material in the presence of a compound represented by formula (I) or a salt thereof with an inorganic or organic acid: ##STR1## wherein Z represents an atomic group of carbon atoms, nitrogen atoms, or a combination thereof forming a 5-, 6-, or 7-membered unsaturated heterocyclic ring, said unsaturated heterocyclic ring being optionally fused with a monocyclic or bicyclic aryl group;R.sup.0 represents ##STR2## R.sup.1 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group;R.sup.2 and R.sup.3 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group, an alkoxy group, a substituted alkoxy group, an amino group, or a substituted amino group;R.sup.4 represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group; andR.sup.5 represents an acyl group, a sulfinyl group, a sulfonyl group, or a carbamoyl group, or represents a group selected from the groups represented by R.sup.1, R.sup.2, R.sup.3 and R.sup.4.
    • 公开了一种用于处理卤化银照相材料的方法,其包括在由式(I)表示的化合物或其盐与无机或有机酸存在下显影处理卤化银照相材料:(I) 其中Z表示碳原子的原子团,氮原子或其组合形成5-,6-或7-元不饱和杂环,所述不饱和杂环任选地与单环或双环芳基稠合; R 0表示R 1表示烷基,取代的烷基,芳基或取代的芳基; R2和R3各自表示氢原子,烷基,取代的烷基,芳基,取代的芳基,烷氧基,取代的烷氧基,氨基或取代的氨基; R4表示氢原子,烷基,取代的烷基,芳基或取代的芳基; 并且R 5表示酰基,亚磺酰基,磺酰基或氨基甲酰基,或表示选自由R 1,R 2,R 3和R 4表示的基团的基团。
    • 6. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4272614A
    • 1981-06-09
    • US105689
    • 1979-12-20
    • Hiroyuki MifuneShigeo Hirano
    • Hiroyuki MifuneShigeo Hirano
    • C07D233/88C07D277/12C07D277/18C07D277/54C07D277/82G03C1/043G03C1/06G03C1/09
    • G03C1/043C07D277/54C07D277/82G03C1/061G03C1/09Y10S430/15
    • A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; Ar represents a divalent aromatic group which may be substituted; Y represents a divalent linking group; n represents 0 or 1; R.sup.2 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; and Z represents a nonmetallic atomic group necessary to form a 5-membered or 6-membered heterocyclic ring together with the ##STR2## linkage.
    • 一种卤化银摄影感光材料,其具有至少一个卤化银照相乳剂层,其包含基本上表面的潜像型卤化银颗粒,并且在所述照相乳剂层或至少一种其它亲水胶体层中含有下列通式 式(I):其中R 1表示氢原子,可被取代的脂肪族基团或可被取代的芳香族基团的化合物(I) Ar表示可以被取代的二价芳基; Y表示二价连接基团; n表示0或1; R2表示氢原子,可以被取代的脂肪族基团或可以被取代的芳香族基团; Z表示与键形成5元或6元杂环所必需的非金属原子团。
    • 7. 发明授权
    • Photothermographic material and method for forming images
    • 光热成像材料和形成图像的方法
    • US06593069B2
    • 2003-07-15
    • US09809024
    • 2001-03-16
    • Toyohisa OyaKazunobu KatohShigeo Hirano
    • Toyohisa OyaKazunobu KatohShigeo Hirano
    • G03C134
    • G03C1/49845G03C1/49827G03C7/305Y10S430/166
    • A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing compound represented by the following formula (1) or (2), (d) a binder and (e) a coupler compound on the same side of a support: wherein, in the formula (1), V1 to V4 each independently represent hydrogen atom or a substituent, and V5 represents a substituted or unsubstituted alkyl group, aryl group or heterocyclic group: Q1—NHNH—V6  (2) wherein, in the formula (2), Q1 represents a 5- to 7-membered unsaturated ring bonding to NHNH—V6 at a carbon atom, and V6 represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group. The photothermographic material of the present invention shows good photographic properties including sensitivity, fog and so forth, and enables control of color tone of the photothermographic material in an arbitrary wavelength region even as a monosheet type photothermographic material.
    • 一种光热成像材料,其至少包含(a)感光卤化银,(b)可还原的银盐,(c)由下式(1)或(2)表示的还原化合物,(d)粘合剂和(e) 其中在式(1)中,V1至V4各自独立地表示氢原子或取代基,V5表示取代或未取代的烷基,芳基或杂环基:其中, 在式(2)中,Q1表示在碳原子上与NHNH-V6键合的5至7元不饱和环,V 6表示氨基甲酰基,酰基,烷氧基羰基,芳氧基羰基,磺酰基 或氨磺酰基。本发明的光热敏成像材料显示出良好的照相性质,包括灵敏度,雾度等,并且即使作为单片型光热敏成像材料也能够控制光热成像材料在任意波长区域中的色调。
    • 8. 发明授权
    • Heat-developable recording material
    • 热显影记录材料
    • US06358677B1
    • 2002-03-19
    • US09528450
    • 2000-03-17
    • Masahiko TaniguchiKatsuyuki WatanabeShigeo HiranoMinoru Sakai
    • Masahiko TaniguchiKatsuyuki WatanabeShigeo HiranoMinoru Sakai
    • G03C1498
    • G03C1/49845
    • A heat-developable recording material having, at least on one side and the same side of the support, (a) reducible silver salt, (b) a reducing agent other than a compound represented by the general formula (1) below, (c) a binder, and (d) at least one compound represented by the general formula (1) below; content of the compound represented by the general formula (1) being 0.01 to 100 mol % with respect to the reducing agent: [where in the general formula (1), R1, R2, R3, X1 and X2 independently represent a hydrogen atom; halogen atom; or substituent which is bound to the benzene ring via a carbon atom, oxygen atom, nitrogen atom, sulfur atom or phosphorus atom. At least either X1 or X2 represents a group represented as —NR4R5, where R4 and R5 independently represent a group selected from a hydrogen atom, alkyl group and the like.]
    • (a)可还原银盐,(b)除了下述通式(1)表示的化合物以外的还原剂,(c)的可热显影记录材料,至少在一个侧面和同一侧上,(c) )粘合剂,和(d)至少一种由下述通式(1)表示的化合物; 通式(1)表示的化合物的含量相对于还原剂为0.01〜100摩尔%[其中,在通式(1)中,R 1,R 2,R 3,X 1和X 2独立地表示氢原子; 卤素原子; 或通过碳原子,氧原子,氮原子,硫原子或磷原子与苯环结合的取代基。 X 1或X 2中至少有一个表示为-NR 4 R 5的基团,其中R 4和R 5独立地表示选自氢原子,烷基等的基团。
    • 9. 发明授权
    • Photothermographic or thermographic image-forming material
    • 光热成像或热成像成像材料
    • US6165707A
    • 2000-12-26
    • US333271
    • 1999-06-15
    • Shigeo HiranoSatoru TodaMasahiko TaniguchiHiroyuki Suzuki
    • Shigeo HiranoSatoru TodaMasahiko TaniguchiHiroyuki Suzuki
    • G03C1/498G03C1/34
    • G03C1/49845
    • An image-forming material comprising a support and a constituent layer(s) comprising at least (a) a thermographic image-forming layer containing a reducible silver salt, a reducing agent of the reducible silver salt and a binder or (b) a photothermographic image-forming layer containing a light-sensitive silver halide as a photocatalyst, reducible silver salt, a reducing agent of the reducible silver salt and a binder, wherein the image-forming material comprises a compound represented by formula (I-1) or (II-1) in at least one constituent layer: ##STR1## wherein R represents a secondary alkyl group or a cycloalkyl group; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion; ##STR2## wherein R.sup.1 represents a secondary alkyl group, a cycloalkyl group, an aryl group, or a primary alkyl group substituted with a substituent bonded via a hetero atom; and M.sup.1 and M.sup.2 each represents a hydrogen atom, a metal ion or an ammonium ion.
    • 一种成像材料,其包括载体和构成层,其至少包含(a)含有可还原银盐的热成像图像形成层,可还原银盐的还原剂和粘合剂或(b)光热敏成像 含有感光卤化银作为光催化剂的成像层,可还原银盐,可还原银盐的还原剂和粘合剂,其中成像材料包含由式(I-1)或( II-1)至少一个构成层:其中R表示仲烷基或环烷基; M1和M2各自表示氢原子,金属离子或铵离子; 其中R1表示被通过杂原子键合的取代基取代的仲烷基,环烷基,芳基或伯烷基; M1和M2各自表示氢原子,金属离子或铵离子。