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    • 1. 发明授权
    • Silver halide photographic light-sensitive element
    • 卤化银照相感光元件
    • US4334010A
    • 1982-06-08
    • US284164
    • 1981-07-17
    • Hiroyuki MifuneShoji IshiguroTadao ShishidoYoshiharu FuseyaTeruaki Tsujikawa
    • Hiroyuki MifuneShoji IshiguroTadao ShishidoYoshiharu FuseyaTeruaki Tsujikawa
    • C07C13/20C07D333/22C07D335/02G03C1/34
    • G03C1/34C07D333/22
    • A silver halide photographic light-sensitive element is described comprising a support having thereon at least one silver halide emulsion layer, wherein at least one compound represented by formula (I) is incorporated in the silver halide emulsion layer or in another hydrophilic colloid layer: ##STR1## wherein X represents a hydroxy group or a group represented by ##STR2## wherein R.sup.2 and R.sup.3 (which may be the same or different) each reprsents hydrogen, an alkyl group, or an aryl group; R.sup.1 represents a sulfur-containing saturated heterocyclic group or a group represented by -A-S-B, wherein A represents an alkylene group and B represents hydrogen, an alkyl group, or an aryl group; and Z represents an atomic group forming a 5-membered or 6-membered unsubstituted or substituted carbocyclic ring.In the silver halide photographic light-sensitive element, the so-called "latent image fading" phenomenon is prevented without accompanying degradation of other photograhic properties.
    • 描述了一种卤化银照相感光元件,其包括其上具有至少一个卤化银乳剂层的载体,其中至少一种由式(I)表示的化合物引入卤化银乳剂层或另一亲水胶体层中: 图像(I)其中X表示羟基或由其表示的基团,其中R2和R3(可以相同或不同)各自代表氢,烷基或芳基; R1表示含硫的饱和杂环基或由-A-S-B表示的基团,其中A表示亚烷基,B表示氢,烷基或芳基; Z表示形成5元或6元未取代或取代的碳环的原子团。 在卤化银摄影感光元件中,防止所谓的“潜像褪色”现象,而不伴随着其它光致变色性能的降低。
    • 3. 发明授权
    • Method for processing color photographic light-sensitive material
    • 彩色照相感光材料的处理方法
    • US4524129A
    • 1985-06-18
    • US651150
    • 1984-09-17
    • Shinzo KishimotoShigeru OhnoTeruaki Tsujikawa
    • Shinzo KishimotoShigeru OhnoTeruaki Tsujikawa
    • G03C7/38G03C7/42G03C7/00
    • G03C7/421
    • A method for processing a color photographic light-sensitive material by subjecting an exposed silver halide color photographic light-sensitive material to color development processing then to bleaching processing and fixing processing or to bleach-fixing processing, which process comprises using a ferric ion complex salt or a persulfate as a bleaching agent in the bleaching processing or bleach-fixing processing and incorporating a compound represented by the general formula (I) described below or a salt thereof in a bath of the bleaching processing or bleach-fixing processing or in a pre-bath thereof. ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom or a lower alkyl group; X represents a --NH.sup.3 R.sup.4 group, a --COOM group, a --SO.sub.3 M group or a hydroxy group; R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom or a substituted or unsubstituted alkyl group or R.sup.3 and R.sup.4 are bonded to each other to form a ring; M represents a cation; and n represents an integer of 1 to 5.The method of the present invention does not produce poisonous materials which are harmful to the environment and provides an excellent high speed bleaching process without harming other photographic properties.
    • 通过使曝光的卤化银彩色照相感光材料进行着色处理,然后进行漂白处理和定影处理或漂白定影处理来处理彩色照相感光材料的方法,该方法包括使用三价铁离子复合盐 或在漂白处理或漂白定影处理中作为漂白剂使用过硫酸盐,并将由下述通式(I)表示的化合物或其盐在漂白处理或漂白固定处理的浴中或预先 其中。 (I)其中R 1和R 2可以相同或不同,各自表示氢原子或低级烷基; X表示-NH 3 R 4基,-COOM基,-SO 3 M基或羟基; R 3和R 4可以相同或不同,各自表示氢原子或取代或未取代的烷基,或者R 3和R 4彼此键合形成环; M表示阳离子; n表示1〜5的整数。本发明的方法不产生对环境有害的有害物质,并且不会损害其它照相性能而提供优异的高速漂白工艺。