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    • 1. 发明授权
    • Heat-developable color photographic material
    • 可热成像的彩色照相材料
    • US4473631A
    • 1984-09-25
    • US548818
    • 1983-11-04
    • Hiroyuki HiraiHideki NaitoHiroshi HaraKozo Sato
    • Hiroyuki HiraiHideki NaitoHiroshi HaraKozo Sato
    • G03C1/06G03C1/498G03C8/40G03C5/54G03C1/10G03C1/40
    • G03C8/4033G03C1/06G03C1/49845
    • A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing compound reductive and capable of releasing a hydrophilic dye and a compound represented by the following general formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent selected from an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, a substituted aryl group and a heterocyclic group, or A.sub.1 and A.sub.2 or A.sub.3 and A.sub.4 may combine with each other to form a ring.The heat-developable color photographic material can easily provide in a short time a clear and stable color image having a high color density and low fog by imagewise exposure and heat development procedure. A method of forming a color image using the heat-developable color photographic material is also disclosed.
    • 公开了一种可热显影的彩色照相材料。 该材料由至少具有感光卤化银,亲水性粘合剂,还原性染料的化合物和能够释放亲水染料的载体和由以下通式(A)表示的化合物组成: (A)其中A1,A2,A3和A4可以相同或不同,表示氢原子或选自烷基,取代的烷基,环烷基,芳烷基,芳基 基团,取代的芳基和杂环基,或者A1和A2或A3和A4可以相互结合形成环。 可热显影的彩色照相材料可以在短时间内通过图像曝光和热显影程序容易地提供具有高色密度和低雾度的清晰稳定的彩色图像。 还公开了使用可热显色彩色照相材料形成彩色图像的方法。
    • 4. 发明授权
    • Heat developable photographic materials
    • 热显影照相材料
    • US4705737A
    • 1987-11-10
    • US767405
    • 1985-08-20
    • Hiroyuki HiraiKozo SatoYoshiharu YabukiKen Kawata
    • Hiroyuki HiraiKozo SatoYoshiharu YabukiKen Kawata
    • G03C1/43G03C1/498G03C8/40G03C5/54G03C1/40
    • G03C8/4086C07C317/00C07C321/00G03C1/43G03C8/4033Y10S430/156
    • A heat developable photographic material comprising a support having thereon at least a photosensitive silver halide, a binder, and at least on of base precursors represented by following formula (I) or (II): ##STR1## wherein R represents an alkyl group, an alkylene group, an aryl group, an arylene group, a monovalent or divalent heterocyclic group, each of which may be unsubstituted or substituted; B represents a mono- or di-acidic, nitrogen-containing, sulfur-free base having a pKa of not lower than about 7 and containing 12 carbon atoms or less; x is an integer of 1 when R represents a monovalent group or an integer of 2 when R represents a divalent group, y is the same as x when B represents the mono-acidic base or an integer of 1 when B represents the di-acidic base; and z is an integer of 2 when R represents a monovalent group and B represents the di-acidic base or otherwise an integer of 1; R' represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group or a heterocyclic group, each of which may be substituted or unsubstituted; X represents a substituent; p represents an integer of 0 to 4; and m' represents the valence number of M whereby stability with the passge of time prior to heat development is improved.
    • 一种可显影照相材料,其包含至少一种光敏卤化银,粘合剂和至少一种由下式(I)或(II)表示的基础前体的载体:[R(SO 2 CH 2 COOH)x] z.By( I)其中R表示烷基,亚烷基,芳基,亚芳基,一价或二价杂环基,其各自可以是未取代的或取代的; B表示pKa不低于约7并且含有12个碳原子或更少的单 - 或二 - 酸,含氮,无硫的碱; 当R表示二价基团,当R表示一价基团或整数2时,x为1,当B表示单酸性碱时,y与x相同,当B表示二酸时,x表示1以上的整数 基础; 当R表示一价基团时,z表示2的整数,B表示二酸基,否则为1的整数。 R'表示可以被取代或未取代的烷基,环烷基,烯基,炔基,芳烷基,芳基或杂环基, X表示取代基; p表示0〜4的整数, 并且m'表示M的化合价数,从而提高了在显影之前经过时间的稳定性。
    • 7. 发明授权
    • Color filter and process for producing the color filter
    • 彩色滤光片和彩色滤光片的制造工艺
    • US5576127A
    • 1996-11-19
    • US426010
    • 1995-04-20
    • Hiroyuki HiraiKozo Sato
    • Hiroyuki HiraiKozo Sato
    • G03C7/20G02B5/20G03C7/12G03C7/30G03C7/34G03F7/00G03F9/00
    • G03C7/12G03C7/346G03F7/0007G03C2200/33G03C7/34
    • A process for producing a color filter is disclosed, which comprises the steps of (a) pattern-exposing a light-sensitive material comprising a light-transmitting substrate having thereon at least three silver halide emulsion layers, and (b) subjecting the exposed light-sensitive material to color development processing, bleaching and fixing processing, and washing processing, wherein the at least three silver halide emulsion layers (i) comprise a layer containing at least a cyan coupler, a layer containing at least a magenta coupler and a layer containing at least a yellow coupler and (ii) have different color sensitivity; and the cyan coupler is a compound represented by the following formula (I): ##STR1## A color filter produced by the above-described process is also disclosed.
    • 公开了一种制造滤色器的方法,其包括以下步骤:(a)对包含其上具有至少三个卤化银乳剂层的透光基底的感光材料进行图案曝光,和(b)对曝光的光 敏感材料进行显色处理,漂白和定影处理以及洗涤处理,其中所述至少三个卤化银乳剂层(i)包括至少包含青色成色剂的层,至少含有品红色成色剂的层和层 含有至少一种黄色成色剂和(ii)具有不同的颜色敏感性; 青色成色剂是由下式(I)表示的化合物:(I)也公开了通过上述方法制造的滤色器。
    • 9. 发明授权
    • Heat-developable light-sensitive material
    • US4657848A
    • 1987-04-14
    • US782811
    • 1985-10-02
    • Kozo SatoYoshiharu YabukiHiroyuki HiraiKen Kawata
    • Kozo SatoYoshiharu YabukiHiroyuki HiraiKen Kawata
    • G03C1/06G03C1/498G03C7/00G03C8/40G03C1/02
    • G03C1/49845G03C8/4086Y10S430/156
    • A heat-developable light-sensitive material is described, containing a compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkenylene group, a substituted or unsubstituted alkynylene group, a substituted or unsubstituted aralkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted divalent heterocyclic group; R.sub.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group; R.sub.3 represents an alkyl group, an alkoxyl group, a halogen atom, an acylamino group, a sulfonylamino group, an alkylamino group, a dialkylamino group, an alkylsulfonyl group, an arylsulfonyl group, a cyano group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group or an alkoxycarbonyl group; X represents a divalent group selected from ##STR2## (wherein R.sub.4 represents a hydrogen atom, a substituted or unsubstituted alkyl group), ##STR3## (wherein R.sub.5 represents a substituted or unsubstituted alkyl group), and ##STR4## M represents an alkali metal, an alkaline earth metal, a quaternary ammonium group, or an ammonium group represented by BH (wherein B represents an organic base); l is an integer of 0 to 3; and m and n are each an integer of 1 or 2, such that the electric charge of carboxylate anion is equivalent to that of M.This material is improved in activity and storage stability. That is, the material providing an image of high density and decreased fog, and which even when stored under high temperature/high humidity conditions, maintained good photographic performance.
    • 10. 发明授权
    • Heat-developable light-sensitive material
    • 可热成像的感光材料
    • US4650749A
    • 1987-03-17
    • US769274
    • 1985-08-26
    • Kozo SatoYoshiharu YabukiHiroyuki HiraiKen Kawata
    • Kozo SatoYoshiharu YabukiHiroyuki HiraiKen Kawata
    • G03C8/40B41M5/26C07C51/00C07C59/58C07C59/64C07C59/66C07C67/00C07C239/00C07C279/02C07C301/00C07C311/03C07D207/22C07D231/12C07D231/56C07D233/60C07D235/06C07D235/22C07D249/18C07D257/04C07D317/30C07D317/46C07D521/00G03C1/06G03C1/498G03C7/00G03C1/02
    • G03C1/49845Y10S430/156
    • A heat developable light-sensitive material containing a compound represented by formula (I) or (II) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, a carboxyl group or a salt thereof, a halogen atom, a cyano group, an alkylsulfonyl or arylsulfonyl group, a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl or aryloxycarbonyl group, a di- or mono-alkylphosphoryl or arylphosphoryl group, a di- or mono-alkylphosphinyl or arylphosphinyl group, an alkylsulfinyl or arylsulfinyl group, an acyl group, an amino group, an acylamino group, an acyloxy group or a group represented by X; X represents a decarboxylation accelerating group; or any two of R.sub.1, R.sub.2, and X may combine to form a ring; and the groups represented by R.sub.1, R.sub.2 and X may further be substituted with a substituent; B represents an organic base; and n represents 1 when B represents a monoacid base or 2 when B represents a diacid base, provided that when ##STR2## is a free dibasic acid, n is 1/2 of the above described numbers, respectively.The heat developable light-sensitive material containing a base precursor represented by formula (I) or (II) has excellent stability during preservation before use, and provides a color image having a high color density and low fog in a short time.
    • 含有式(I)或(II)表示的化合物的热显影性感光材料其中R 1和R 2各自表示氢原子,烷基,环烷基, 烯基,炔基,芳烷基,芳基,杂环基,羧基或其盐,卤素原子,氰基,烷基磺酰基或芳基磺酰基,氨磺酰基,氨基甲酰基, 烷氧基羰基或芳氧基羰基,二 - 或单烷基磷酰基或芳基磷酰基,二 - 或单烷基氧膦基或芳基氧膦基,烷基亚磺酰基或芳基亚磺酰基,酰基,氨基,酰氨基,酰氧基或 由X代表的组; X表示脱羧加成基团; 或者R1,R2和X中的任何两个可以结合形成环; 并且由R 1,R 2和X表示的基团可以进一步被取代基取代; B表示有机碱; 当B代表一酸基时,n表示1,B表示二酸基时,n表示1,条件是当为游离二元酸时,n分别为上述数字的1/2。 含有由式(I)或(II)表示的碱前体的可热显影的感光材料在使用前的保存期间具有优异的稳定性,并且在短时间内提供具有高着色密度和低雾度的彩色图像。