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    • 5. 发明授权
    • Process for producing 5-vinyl-2-norbornene
    • 5-乙烯基-2-降冰片烯的制备方法
    • US5565069A
    • 1996-10-15
    • US452279
    • 1995-05-26
    • Nobuo OiKazuo KimuraKenichi Nariyama
    • Nobuo OiKazuo KimuraKenichi Nariyama
    • C07C4/22C07C13/43B01D3/34C07C2/50
    • C07C13/43C07C4/22C07C2101/10C07C2102/42Y02P20/582
    • A process for producing 5-vinyl-2-norbornene which comprises the steps of subjecting a liquid raw material in which tetrahydroindene/dicyclopentadiene ratio (by weight) falls within the range of from 5/100 to 80/100 to a thermal decomposition in liquid phase in the presence of an aromatic hydrocarbon solvent having a boiling point of from 250.degree. C. to 300.degree. C. at a reaction temperature of not lower than 200.degree. C. and lower than 240.degree. C. for a reaction time of from 10 minutes to 120 minutes to obtain a liquid reaction mixture (A-1) composed of 50% to 70% by weight of cyclopentadiene, distilling the liquid reaction mixture (A-1) to obtain fraction (B-1) composed of 90% to 100% by weight of cyclopentadiene and fraction (B-2) composed of 60% to 90% by weight of the total of dicyclopentadiene and tetrahydroindene, further distilling the fraction (B-2) to obtain fraction (B-3) composed of 15% to 40% by weight of dicyclopentadiene and fraction (B-4) composed of 60% to 100% by weight of tetrahydroindene, recycling the fraction (B-3) into the liquid raw material, removing the fraction (B-4) out of the system, and subjecting the fraction (B-1) to a Diels Alder reaction with butadiene to obtain a liquid reaction mixture (C-1) composed of 20% to 40% by weight of 5-vinyl-2-norbornene.
    • 一种制备5-乙烯基-2-降冰片烯的方法,其包括以下步骤:使四氢茚/二环戊二烯比(重量比)的液体原料在5/100至80/100范围内与液体中的热分解 在不低于200℃且低于240℃的反应温度下,在沸点为250℃至300℃的芳族烃溶剂存在下,反应时间为10 分钟至120分钟,得到由50重量%至70重量%的环戊二烯组成的液体反应混合物(A-1),蒸馏出液体反应混合物(A-1),得到组分(B-1)为90%〜 100重量%的环戊二烯和由二环戊二烯和四氢茚的总量的60重量%至90重量%组成的级分(B-2),进一步蒸馏馏分(B-2),得到组分(B-3)15 %至40重量%的二环戊二烯和由60重量%至100重量%组成的组分(B-4) 四氢茚,将级分(B-3)再循环到液体原料中,从体系中除去级分(B-4),并将级分(B-1)与丁二烯进行Diels Alder反应,得​​到液体反应 由20重量%至40重量%的5-乙烯基-2-降冰片烯组成的混合物(C-1)。
    • 7. 发明授权
    • Process for producing olefin copolymer
    • 制备烯烃共聚物的方法
    • US07230059B2
    • 2007-06-12
    • US10540512
    • 2003-12-18
    • Nobuo OiHitoshi Tsukui
    • Nobuo OiHitoshi Tsukui
    • C08F236/20C08F236/22
    • C08F210/18C08F2500/17
    • A process for producing an olefin-based copolymer, which comprises copolymerizing at least one olefin selected from the group consisting of ethylene and straight chain α-olefins, and a vinyl compound (I) and a polyene (II) described below:Vinyl compound (I); a vinyl compound represented by the general formula CH2═CH—R, wherein the substituent R is a saturated hydrocarbon group and steric parameters Es and B1 of the substituent R are respectively −1.64 or less and 1.53 or more; andPolyene (II); a compound having two or more of ethylene bonds and at least one combination of two ethylene bonds in which those are bonded to each other through at least three carbon atoms.
    • 一种烯烃类共聚物的制造方法,其包括将选自乙烯和直链α-烯烃的至少一种烯烃和下述乙烯基化合物(I)和多烯(II)共聚合:乙烯基化合物( 一世); 由通式CH 2 -CH-R表示的乙烯基化合物,其中取代基R是饱和烃基,取代基R的空间参数Es和B1分别为-1.64以下且1.53或 更多; 和聚烯(II); 具有两个或更多个乙烯键的化合物和两个乙烯键的至少一个组合,其中它们通过至少三个碳原子彼此键合。