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    • 1. 发明授权
    • Synthesis of urea
    • 尿素合成
    • US4365089A
    • 1982-12-21
    • US293926
    • 1981-08-18
    • Hiroshi OnoHidetsugu FujiiShigeru Inoue
    • Hiroshi OnoHidetsugu FujiiShigeru Inoue
    • C07C67/00C07C239/00C07C273/04C07C126/02
    • C07C273/04
    • The specification describes a process for synthesizing urea. The process comprises reacting ammonia and carbon dioxide in a molar ratio of 3:1-5:1 and at a pressure of 150-250 Kg/cm.sup.2 G, subjecting the resultant reaction mixture to a stripping step using gaseous carbon dioxide at a pressure substantially equal to the urea synthesis pressure and a temperature of 195.degree.-210.degree. C. to remove unreacted ammonia and unreacted carbon dioxide contained in the reaction mixture so that the content of unreacted ammonia is lowered to 10-15% by weight. This invention ensures a high conversion ratio from carbon dioxide to urea, considerably little formation of biuret during the stripping step, and reduced consumption of high pressure steam.
    • 该说明书描述了合成尿素的方法。 该方法包括使氨和二氧化碳以3:1-5:1的摩尔比和150-250Kg / cm2G的压力进行反应,将所得反应混合物进行汽提步骤,使用气态二氧化碳,压力基本相等 至尿素合成压力和195℃-210℃的温度以除去反应混合物中所含的未反应的氨和未反应的二氧化碳,使得未反应的氨的含量降低至10-15重量%。 本发明确保了从二氧化碳到尿素的高转化率,在汽提步骤期间几乎不少的缩二脲形成,并降低了高压蒸汽的消耗。
    • 2. 发明授权
    • Process for synthesizing urea
    • 尿素合成方法
    • US4504679A
    • 1985-03-12
    • US430557
    • 1982-09-30
    • Shigeru InoueHiroshi OnoAkito FukuiHidetsugu FujiiHaruyuki MorikawaSuguru Watanabe
    • Shigeru InoueHiroshi OnoAkito FukuiHidetsugu FujiiHaruyuki MorikawaSuguru Watanabe
    • C07C67/00C07C239/00C07C273/04C07C126/02
    • C07C273/04
    • Disclosed herein is a process of synthesizing urea including reacting ammonia and carbon dioxide at a urea synthesis pressure and temperature in a urea synthesis zone, separating excess ammonia and unreacted ammonium carbamate from the thus-obtained urea synthesis melt as a gaseous mixture containing ammonia and carbon dioxide, recirculating the gaseous mixture to the urea synthesis zone, and, on the other hand, obtaining urea from an aqueous urea solution which has been obtained by separating the excess ammonia and unreacted ammonium carbamate. The above process features ingeniously combined conditions of various process steps. It produces urea using less high-pressure steam and recovers less low-pressure steam. A stripping operation making use of carbon dioxide can be effectively incorporated in the above process. The above process permits to cut the construction cost of a urea synthesis plant.
    • 本文公开了一种合成尿素的方法,其包括在尿素合成区中的尿素合成压力和温度下使氨和二氧化碳反应,将由此得到的尿素合成熔体中的过量氨和未反应的氨基甲酸铵与含有氨和碳的气体混合物分离 二氧化物,将气体混合物再循环到尿素合成区,另一方面,从通过分离过量的氨和未反应的氨基甲酸铵获得的尿素水溶液获得尿素。 上述过程巧妙地结合了各种工艺步骤的组合条件。 它使用更少的高压蒸汽产生尿素,并回收较少的低压蒸汽。 在上述过程中可以有效地并入使用二氧化碳的剥离操作。 上述过程允许减少尿素合成设备的建造成本。
    • 3. 发明授权
    • Process for synthesizing urea
    • 尿素合成方法
    • US4354040A
    • 1982-10-12
    • US298302
    • 1981-09-01
    • Shigeru InoueHiroshi OnoHidetsugu Fujii
    • Shigeru InoueHiroshi OnoHidetsugu Fujii
    • C07C67/00C07C239/00C07C273/04C07C120/02
    • C07C273/04
    • In a synthesis of urea using ammonia in a highly excessive molar ratio, unreacted materials are decomposed and separated by subjecting the urea synthesis effluent to a stripping step using carbon dioxide at a pressure equal to the urea synthesis pressure. The thus-separated gaseous mixture of ammonia and carbon dioxide is condensed through an indirect heat exchange with an effluent stream discharged from the stripping step and lowered to a predetermined pressure level. Resulting condensation heat is used for the decomposition and separation of unreacted materials still remaining in said effluent stream. By choosing suitable operation conditions for each step of the present invention, it is possible to reduce the amount of high pressure steam to be required and to minimize the amount of low pressure steam to be recovered.
    • 在使用高度过量摩尔比的氨的尿素合成中,通过在等于尿素合成压力的压力下,使用二氧化碳将尿素合成流出物进行汽提步骤,使未反应的物质分解和分离。 这样分离的氨和二氧化碳的气体混合物通过与从汽提步骤排出的流出物流的间接热交换而冷凝,并降低到预定的压力水平。 所得的冷凝热用于分解和分离仍残留在所述流出物流中的未反应物质。 通过为本发明的每个步骤选择合适的操作条件,可以减少所需的高压蒸汽的量并使要回收的低压蒸汽的量最小化。
    • 6. 发明授权
    • Synthesis of urea
    • 尿素合成
    • US4301299A
    • 1981-11-17
    • US203595
    • 1980-11-03
    • Shigeru InoueHiroshi Ono
    • Shigeru InoueHiroshi Ono
    • C07C67/00C07C239/00C07C273/04C07C126/02C07C126/08
    • C07C273/04
    • A process for synthesizing urea in which a urea synthesis effluent obtained by reacting carbon dioxide and ammonia at urea synthesis pressures and temperatures is subjected to stripping treatment with carbon dioxide under pressures substantially equal to urea synthesis pressures to separate the unreacted carbon dioxide and ammonia contained in the urea synthesis effluent as a gaseous mixture, and a sufficient amount of said gaseous mixture to maintain the urea synthesis temperatures at a predetermined level is recycled to the urea synthesis in the gaseous state, the balance being subjected to condensation to be recycled in the liquid state to the urea synthesis.
    • 一种合成尿素的方法,其中通过使二氧化碳和氨在尿素合成压力和温度下反应而获得的尿素合成流出物在基本上等于尿素合成压力的压力下用二氧化碳进行汽提处理,以将未反应的二氧化碳和氨 作为气态混合物的尿素合成流出物和足够量的所述气态混合物以将尿素合成温度保持在预定水平,在气态下再循环到尿素合成中,余量经过冷凝再循环到液体中 状态到尿素合成。
    • 7. 发明授权
    • Process for separating and recovering unreacted materials in urea
synthesis
    • 在尿素合成中分离和回收未反应物质的方法
    • US4081469A
    • 1978-03-28
    • US718562
    • 1976-08-30
    • Hiroshi OnoShigeru Inoue
    • Hiroshi OnoShigeru Inoue
    • C07C67/00C07C239/00C07C273/04C07C126/02
    • C07C273/04Y02P20/142
    • Carbon dioxide is reacted with a stoichiometric excess of ammonia at urea synthesis temperatures and pressures in a urea synthesis zone with the mol ratio of ammonia to carbon dioxide being in the range of from 5:1 to 12:1. The urea synthesis effluent from the urea synthesis zone is pressurized to a pressure higher than the urea synthesis pressure, and heated to a temperature higher than the urea synthesis temperature in a separation zone, wherein unreacted ammonium carbamate and excess ammonia contained in said urea synthesis effluent are separated from urea synthesis effluent in the form of a gaseous mixture of ammonia and carbon dioxide. The thus separated gaseous mixture of ammonia and carbon dioxide is recycled to said urea synthesis zone by means of the pressure difference.
    • 在尿素合成区的尿素合成温度和压力下,二氧化碳与化学计量过量的氨反应,氨与二氧化碳的摩尔比在5:1至12:1的范围内。 来自尿素合成区的尿素合成流出物被加压至高于尿素合成压力的压力,并加热到高于分离区中的尿素合成温度的温度,其中所述尿素合成流出物中含有未反应的氨基甲酸铵和过量氨 以氨和二氧化碳的气体混合物的形式与尿素合成流出物分离。 这样分离的氨和二氧化碳的气体混合物通过压力差再循环到所述尿素合成区。