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    • 2. 发明授权
    • Dielectric ceramic compound
    • 介电陶瓷化合物
    • US5525562A
    • 1996-06-11
    • US363901
    • 1994-12-27
    • Hiroshi KagataJunichi KatoKeiji Nishimoto
    • Hiroshi KagataJunichi KatoKeiji Nishimoto
    • C04B35/465C04B35/495C04B35/497H01B3/12H01P7/10C04B35/46
    • C04B35/497C04B35/465C04B35/495H01B3/12H01P7/10
    • This invention provides a dielectric ceramic compound for microwave use which has a high dielectric constant and a high Q value, and which also has a small temperature coefficient of a resonant frequency. The dielectric ceramic compound comprising a compound represented by Formula 1 at least includes calcium oxide, magnesium oxide, zinc oxide, niobium oxide, tantalum oxide, and titanium oxide, (Formula 1)Ca[{(Mg.sub.1-x Zn.sub.x).sub.1/3 (Nb.sub.1-z Ta.sub.z).sub.2/3 }.sub.1-y Ti.sub.y ]O.sub.3wherein x and y are present within an area formed by the following apexes A, B, C, and D, excluding an area on straight line AB,A: (x, y)=(0.0, 0.0)B: (x, y)=(0.0, 0.5)C: (x, y)=(1.0, 0.55)D: (x, y)=(1.0, 0.0)and z is present in the range of 0.0.ltoreq.z.ltoreq.1.0, excluding z=1.0 when y=0.0.
    • 本发明提供一种具有高介电常数和高Q值的微波用介电陶瓷化合物,并且其谐振频率的温度系数也较小。 包含式1化合物的介电陶瓷化合物至少包括氧化钙,氧化镁,氧化锌,氧化铌,氧化钽和氧化钛,(式1)Ca [{((Mg1-xZnx))1/3(Nb1 -zTaz)2/3} 1-yTiy] O3其中x和y存在于由以下顶点A,B,C和D形成的区域中,除了直线AB上的区域,A:(x,y) =(0.0,0.0)B:(x,y)=(0.0,0.5)C:(x,y)=(1.0,0.55)D:(x,y)=(1.0,0.0) 0.0≤z≤0.0的范围,当y = 0.0时不包括z = 1.0。
    • 4. 发明授权
    • Method for manufacturing a dielectric ceramic composition dielectric
ceramic and multilayer high frequency device
    • 电介质陶瓷组合物介电陶瓷和多层高频器件的制造方法
    • US5629252A
    • 1997-05-13
    • US662700
    • 1996-06-13
    • Keiji NishimotoHiroshi KagataJunichi KatoTatsuya Inoue
    • Keiji NishimotoHiroshi KagataJunichi KatoTatsuya Inoue
    • C04B35/465C04B35/495H01G4/12C04B35/46
    • H01G4/1218C04B35/465C04B35/495H01G4/1254
    • A dielectric ceramic composition that can be sintered at a low temperature of around 1000.degree. C. and also can have a high dielectric constant, a high Q value and small temperature coefficient at a resonant frequency includes a glass component that promotes sintering. The dielectric ceramics include: the main component comprising calcium oxide, magnesium oxide, niobium oxide and titanium oxide and expressed by the Formula: Ca{(Mg.sub. 1/3 Nb.sub. 2/3).sub.1-x Ti.sub.x }O.sub.3 (wherein X is more than 0 not more than 0.50) within the range of not less than 40 parts by weight nor more than 98 parts by weight; the accessory component comprising at least one selected from SiO.sub.2 and B.sub.2 O.sub.3 within the range of not less than 2 parts by weight nor more than 60 parts by weight; and at least one oxide selected from the group consisting of MgO, NiO, CuO, MNO.sub.2 and WO.sub.3 within the range of not less than 0.1 parts by weight nor more than 10 parts by weight. Consequently, the dielectric ceramic composition of the present invention can be sintered at low temperature. The dielectric ceramic composition also has a stability in composition and high Q value, which can used for the dielectric ceramic and multilayer high frequency device.
    • 可以在约1000℃的低温下烧结并且在共振频率下也可以具有高介电常数,高Q值和小的温度系数的介电陶瓷组合物包括促进烧结的玻璃成分。 电介质陶瓷包括:主要成分包括氧化钙,氧化镁,氧化铌和氧化钛,并由下式表示:Ca {(Mg + E,fra 1/3 + EE Nb + E,fra 2/3 + EE) 1-xTix} O 3(其中X大于0不大于0.50)在不小于40重量份的范围内,不大于98重量份; 所述辅助成分包含选自SiO 2和B 2 O 3中的至少一种,其含量在不小于2重量份,不大于60重量份的范围内; 以及选自MgO,NiO,CuO,MNO 2和WO 3中的至少一种氧化物,其含量在0.1重量份以上,10重量份以下。 因此,本发明的电介质陶瓷组合物可以在低温下烧结。 电介质陶瓷组合物的组成稳定性和Q值高,可用于介电陶瓷和多层高频器件。
    • 7. 发明授权
    • Dielectric ceramic and dielectric device
    • 介质陶瓷和电介质器件
    • US06762142B2
    • 2004-07-13
    • US10251585
    • 2002-09-19
    • Kojiro OkuyamaJunichi KatoHiroshi KagataKenji Iijima
    • Kojiro OkuyamaJunichi KatoHiroshi KagataKenji Iijima
    • C04B35465
    • C04B35/49C04B35/6262C04B2235/3206C04B2235/3249C04B2235/3251C04B2235/3262C04B2235/3275C04B2235/3284C04B2235/604C04B2235/786C04B2235/94C04B2235/96H01P7/10
    • A dielectric ceramic is made of a sintered body of a complex oxide including at least one element selected from the group consisting of Zr, Ti and Mn, at least one element selected from the group consisting of Mg, Zn and Co, and at least one element selected from the group consisting of Nb and Ta, wherein, the complex oxide is represented by a formula xZrO2-yTiO2-zA(1+w)/3B(2−w)/3O2 where ‘A’ in the formula denotes at least one element selected from the group (A) consisting of Mg, Zn and Co, ‘B’ denotes at one element selected from the group (B) consisting of Nb and Ta; x, y, z and w denote values in the respective ranges of 0.20≦x≦0.55, 0.40≦y≦0.55, 0.05≦z≦0.25, and 0≦w≦0.30, and x, y and z have a relationship represented as x+y+z=1; MnO is present in a range of 0.1 mol % to 1.0 mol % to the complex oxide; and an average grain size of the dielectric ceramic is from 10 &mgr;m to 70 &mgr;m, thereby providing a dielectric ceramic that has a high dielectric constant (&egr;r) and an unloaded (Qu) value even in a comparatively low frequency region as a microwave region i.e., in a range of 0.4 GHz to 2.4 GHz and that realizes a desired temperature coefficient (&tgr;f) of a resonant frequency with a high mechanical strength, and thus a dielectric device using the dielectric ceramic is provided.
    • 电介质陶瓷由包含选自Zr,Ti和Mn中的至少一种元素的复合氧化物的烧结体,选自Mg,Zn和Co中的至少一种元素和至少一种 元素选自Nb和Ta,其中复合氧化物由式xZrO2-yTiO2-zA(1 + w)/ 3B(2-w)/ 3O2表示,其中式中的“A”至少表示 选自由Mg,Zn和Co组成的组(A)中的一种元素,'B'表示选自Nb和Ta组成的组(B)中的一种元素; x,y,z和w分别表示0.20 <= x <= 0.55,0.40 <= y <= 0.55,0.05 <= z <= 0.25,0 <= w <0.30的各个范围内的值,x, y和z具有表示为x + y + z = 1的关系; MnO以0.1mol%至1.0mol%的范围存在于复合氧化物中; 并且电介质陶瓷的平均晶粒尺寸为10μm至70μm,从而提供即使在作为微波区域的较低频率区域中也具有高介电常数(ε)和无载(Qu)值的电介质陶瓷,即 ,在0.4GHz至2.4GHz的范围内,并且实现具有高机械强度的谐振频率的期望温度系数(tauf),因此提供了使用电介质陶瓷的电介质器件。