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1. 发明授权

US08546299B2 Color-developing composition and recording material containing the same 有权
标题翻译：显色组合物和含有它们的记录材料
公开(公告)号：US08546299B2
公开(公告)日：2013-10-01
申请号：US12997791
申请日：2009-06-18
申请人： Hiroshi Fujii , Tadashi Kawakami , Satoshi Kodama , Kazumi Jyujyo
发明人： Hiroshi Fujii , Tadashi Kawakami , Satoshi Kodama , Kazumi Jyujyo
IPC分类号： B41M5/333 , C09D11/00
CPC分类号： B41M5/3336 , B41M5/155 , B41M5/327 , B41M5/3275 , B41M5/3333 , B41M5/3335
摘要： Provided is a recording material with a superior heat resistance and having a low content of a dihydroxydiphenylsulfone derivative, and a color-developing composition for producing the recording material. With the use of this color-developing composition, a recording material with a superior heat resistance at the background part can be provided and the content of a dihydroxydiphenylsulfone derivative, such as 4,4′-dihydroxydiphenylsulfone, in the color-developing composition can be reduced to 2% by mass or less, or further to 1% by mass or less.
摘要翻译：提供具有优异的耐热性和低含量的二羟基二苯基砜衍生物的记录材料和用于制备记录材料的显色组合物。通过使用该显色组合物，可以提供在背景部分具有优异的耐热性的记录材料，并且显色组合物中的二羟基二苯基砜衍生物如4,4'-二羟基二苯基砜的含量可以是降低到2质量％以下，进一步降低到1质量％以下。

2. 发明申请

US20110104619A1 COLOR-DEVELOPING COMPOSITION AND RECORDING MATERIAL CONTAINING THE SAME 有权
标题翻译：彩色显影组合物和记录材料
公开(公告)号：US20110104619A1
公开(公告)日：2011-05-05
申请号：US12997791
申请日：2009-06-18
申请人： Hiroshi Fujii , Tadashi Kawakami , Satoshi Kodama , Kazumi Jyujyo
发明人： Hiroshi Fujii , Tadashi Kawakami , Satoshi Kodama , Kazumi Jyujyo
IPC分类号： G03G9/00
CPC分类号： B41M5/3336 , B41M5/155 , B41M5/327 , B41M5/3275 , B41M5/3333 , B41M5/3335
摘要： Provided is a recording material with a superior heat resistance and having a low content of a dihydroxydiphenylsulfone derivative, and a color-developing composition for producing the recording material. With the use of this color-developing composition, a recording material with a superior heat resistance at the background part can be provided and the content of a dihydroxydiphenylsulfone derivative, such as 4,4′-dihydroxydiphenylsulfone, in the color-developing composition can be reduced to 2% by mass or less, or further to 1% by mass or less.
摘要翻译：提供具有优异的耐热性和低含量的二羟基二苯基砜衍生物的记录材料和用于制备记录材料的显色组合物。通过使用该显色组合物，可以提供在背景部分具有优异的耐热性的记录材料，并且显色组合物中的二羟基二苯基砜衍生物如4,4'-二羟基二苯基砜的含量可以是降低到2质量％以下，进一步降低到1质量％以下。

3. 发明授权

US08529688B2 Phenolic compound and recording material 有权
标题翻译：酚类化合物和记录材料
公开(公告)号：US08529688B2
公开(公告)日：2013-09-10
申请号：US13138301
申请日：2010-02-01
申请人： Satoshi Kodama , Shinichi Satoh , Toshio Aihara , Tadashi Kawakami , Kazumi Jyujyo
发明人： Satoshi Kodama , Shinichi Satoh , Toshio Aihara , Tadashi Kawakami , Kazumi Jyujyo
IPC分类号： C09D7/12 , C07C235/38
CPC分类号： B41M5/3335 , B41M2205/28 , C07C233/29
摘要： Provided is a recording material with a superior storage property for the background and image, particularly with a remarkable superiority in any of light resistance of the background, and light, moisture and heat resistance of the image. The recording material contains a phenolic compound represented by formula (I) [wherein R1-R3 each independently represent a hydrogen atom or C1-C4 alkyl group; R5 represents a hydrogen atom, C1-C4 alkyl group or C1-C4 alkoxy group, with the proviso that when R5 is a hydrogen atom, R4 is a C1-C4 alkyl group, when R5 is a C1-C4 alkyl group, R4 is a hydrogen atom, and when R5 is a C1-C4 alkoxy group, R4 is a C1-C4 alkoxy group].
摘要翻译：提供了一种具有优异的背景和图像存储性能的记录材料，特别是在背景的任何耐光性以及图像的光，湿度和耐热性方面均显着优越。记录材料含有由式（I）表示的酚类化合物[其中R 1 -R 3各自独立地表示氢原子或C 1 -C 4烷基; R5表示氢原子，C1-C4烷基或C1-C4烷氧基，条件是当R5是氢原子时，R4是C1-C4烷基，当R5是C1-C4烷基时，R4是氢原子，当R5为C1-C4烷氧基时，R4为C1-C4烷氧基]。

4. 发明申请

US20110308429A1 Phenolic compound and recording material 有权
标题翻译：酚类化合物和记录材料
公开(公告)号：US20110308429A1
公开(公告)日：2011-12-22
申请号：US13138301
申请日：2010-02-01
申请人： Satoshi Kodama , Shinichi Satoh , Toshio Aihara , Tadashi Kawakami , Kazumi Jyujyo
发明人： Satoshi Kodama , Shinichi Satoh , Toshio Aihara , Tadashi Kawakami , Kazumi Jyujyo
IPC分类号： C09D7/12 , C07C235/38
CPC分类号： B41M5/3335 , B41M2205/28 , C07C233/29
摘要： Provided is a recording material with a superior storage property for the background and image, particularly with a remarkable superiority in any of light resistance of the background, and light, moisture and heat resistance of the image. The recording material contains a phenolic compound represented by formula (I) [wherein R1-R3 each independently represent a hydrogen atom or C1-C4 alkyl group; R5 represents a hydrogen atom, C1-C4 alkyl group or C1-C4 alkoxy group, with the proviso that when R5 is a hydrogen atom, R4 is a C1-C4 alkyl group, when R5 is a C1-C4 alkyl group, R4 is a hydrogen atom, and when R5 is a C1-C4 alkoxy group, R4 is a C1-C4 alkoxy group].
摘要翻译：提供了一种具有优异的背景和图像存储性能的记录材料，特别是在背景的任何耐光性以及图像的光，湿度和耐热性方面均显着优越。记录材料含有由式（I）表示的酚类化合物[其中R 1 -R 3各自独立地表示氢原子或C 1 -C 4烷基; R5表示氢原子，C1-C4烷基或C1-C4烷氧基，条件是当R5是氢原子时，R4是C1-C4烷基，当R5是C1-C4烷基时，R4是氢原子，当R5为C1-C4烷氧基时，R4为C1-C4烷氧基]。

5. 发明申请

US20110287931A1 Rewritable recording material 审中-公开
标题翻译：可重写记录材料
公开(公告)号：US20110287931A1
公开(公告)日：2011-11-24
申请号：US13138302
申请日：2010-02-01
申请人： Satoshi Kodama , Hiroshi Fujii , Tadashi Kawakami
发明人： Satoshi Kodama , Hiroshi Fujii , Tadashi Kawakami
IPC分类号： B41M5/323 , C07C235/38 , C07C233/29 , C09K9/02 , G02B5/23
CPC分类号： B41M5/3335 , B41M5/305 , B41M2205/28 , C07C233/29 , C07C235/38 , C09B67/0077
摘要： A rewritable recording material can be provided which contains at least one kind of phenolic compounds represented by formula (I) and which is capable of stably repeating coloring and discoloring for a long period of time as well as exerting superior storage properties such as heat resistance and moisture and heat resistance of the colored image and light resistance of the background. Also provided are a composition for forming a rewritable color-forming layer which is capable of forming a color-forming layer of the recording material, and a composition of a color-developing agent for a rewritable recording material.
摘要翻译：可以提供包含至少一种式（I）表示的酚类化合物的可重写记录材料，其能够长时间稳定地重复着色和变色，并且具有优异的储存性能如耐热性和彩色图像的湿度和耐热性以及背景的耐光性。还提供了一种用于形成能够形成记录材料的着色层的可重写成色层的组合物和可重写记录材料的显色剂的组合物。

6. 发明授权

US08420568B2 Color-developing compositions and recording material containing same 有权
标题翻译：显色组合物和含有它们的记录材料
公开(公告)号：US08420568B2
公开(公告)日：2013-04-16
申请号：US12990178
申请日：2009-05-01
申请人： Satoshi Kodama , Toshiyuki Fukami , Hiroshi Fujii , Tadashi Kawakami , Toshio Aihara
发明人： Satoshi Kodama , Toshiyuki Fukami , Hiroshi Fujii , Tadashi Kawakami , Toshio Aihara
IPC分类号： B41M5/333
CPC分类号： B41M5/3336 , B41M2205/04 , C07C317/22
摘要： Provided is a color-developing composition for recording materials having a superior heat resistance. The color-developing composition is a reaction composition containing a mixture of compounds represented by formula (III) obtained by reacting a dihydroxydiphenylsulfone derivative represented by formula (I) with a dihalide represented by formula (II) X—Y—X (II), wherein, in a composition where the content of a compound with n=1 in said reaction composition is from 5 to 80% by mass of the total solid content of the composition, at least 10% by mass of the compound with n=1 is a crystalline material.
摘要翻译：提供了一种具有优异耐热性的用于记录材料的显色组合物。显色性组合物是含有式（III）表示的化合物与通式（I）表示的二羟基二苯基砜衍生物与式（II）表示的二卤化物X-Y-X（II）反应得到的化合物的混合物的反应组合物，其中，在所述反应组合物中n = 1的化合物的含量为所述组合物的总固体成分的5〜80质量％的组成中，n = 1的化合物的至少10质量％一种结晶材料。

7. 发明申请

US20110045973A1 COLOR-DEVELOPING COMPOSITIONS AND RECORDING MATERIAL CONTAINING SAME 有权
标题翻译：彩色发光组合物和记录材料
公开(公告)号：US20110045973A1
公开(公告)日：2011-02-24
申请号：US12990178
申请日：2009-05-01
申请人： Satashi Kodama , Toshiyuki Fukami , Hiroshi Fujii , Tadashi Kawakami , Toshio Aihara
发明人： Satashi Kodama , Toshiyuki Fukami , Hiroshi Fujii , Tadashi Kawakami , Toshio Aihara
IPC分类号： B41M5/26 , C07C315/00 , C07C317/14
CPC分类号： B41M5/3336 , B41M2205/04 , C07C317/22
摘要： Provided is a color-developing composition for recording materials having a superior heat resistance. The color-developing composition is a reaction composition containing a mixture of compounds represented by formula (III) obtained by reacting a dihydroxydiphenylsulfone derivative represented by formula (I) with a dihalide represented by formula (II) X-Y-X (II), wherein, in a composition where the content of a compound with n=1 in said reaction composition is from 5 to 80% by mass of the total solid content of the composition, at least 10% by mass of the compound with n=1 is a crystalline material.
摘要翻译：提供了一种具有优异耐热性的用于记录材料的显色组合物。显色性组合物是含有式（III）表示的化合物与式（I）表示的二羟基二苯基砜衍生物与式（II）所示的二卤化物XYX（II）反应而成的化合物的混合物的反应组合物，其中，组合物，其中所述反应组合物中n = 1的化合物的含量为组合物总固体含量的5-80质量％，n = 1的化合物的至少10质量％是结晶材料。

8. 发明授权

US07390771B2 Recording material and recording sheet 失效
标题翻译：记录材料和记录纸
公开(公告)号：US07390771B2
公开(公告)日：2008-06-24
申请号：US10999630
申请日：2004-11-30
申请人： Tadashi Kawakami , Shinichi Sato , Hiroshi Fujii
发明人： Tadashi Kawakami , Shinichi Sato , Hiroshi Fujii
IPC分类号： B41M5/20 , C07C303/00
CPC分类号： B41M5/3336 , B41M5/155 , B41M5/3333 , B41M5/3375 , B41M2205/04
摘要： The present invention provides a composition and a recording material made from the composition having an excellent dynamic sensitivity in recording as well as an excellent image stability and, particularly, having excellent resistance for heat and humidity, heat, light, plasticizer and water. The composition and the recording material include the following compounds (1), (2), and (3): wherein R1, R2, R6, R7, R11, and R12 each represents hydrogen or an alkyl group; a1 to a3 each represents an integer of 1-6; n1 to n3 each represents 0, 1 or 2; m1, m4 and m7 each represents 0, 1, 2 or 3; R3, R4, R8, R9, R13 and R14 each represents an alkyl group; m2, m3, m5, m6, m8 and m9 each represents 0, 1 or 2; and Y1 to Y3 each represents CO or NRCO (R represents hydrogen, etc.).
摘要翻译：本发明提供一种由该组合物制成的组合物和记录材料，其具有良好的记录动态灵敏度和良好的图像稳定性，特别是具有优异的耐热，耐湿，耐光，增塑剂和水的耐性。组合物和记录材料包括以下化合物（1），（2）和（3）：其中R 1，R 2，R 6， R 11，R 11，R 12和R 12各自表示氢或烷基; 每个^{1 1 各自表示1-6的整数; n <1> 1〜n 3各自表示0,1或2; m 1，m 4和m 7各自表示0,1,2或3; R 3，R 4，R 8，R 9，R 13和R 9， R 14各自表示烷基; m 2，m 3，m 5，m 6，m 8，和8，每个表示0,1或2; 和Y 1〜Y 3各自表示CO或NRCO（R表示氢等）。}

9. 发明申请

US20050148468A1 Recording material and recording sheet 失效
标题翻译：记录材料和记录纸
公开(公告)号：US20050148468A1
公开(公告)日：2005-07-07
申请号：US10999630
申请日：2004-11-30
申请人： Tadashi Kawakami , Shinichi Sato , Hiroshi Fujii
发明人： Tadashi Kawakami , Shinichi Sato , Hiroshi Fujii
IPC分类号： B41M5/155 , B41M5/30 , B41M5/333 , B41M5/337 , B41M5/20 , B41M5/24
CPC分类号： B41M5/3336 , B41M5/155 , B41M5/3333 , B41M5/3375 , B41M2205/04
摘要： The present invention provides a composition and a recording material made from the composition having an excellent dynamic sensitivity in recording as well as an excellent image stability and, particularly, having excellent resistance for heat and humidity, heat, light, plasticizer and water. The composition and the recording material include the following compounds (1), (2), and (3): wherein R1, R2, R6, R7, R11, and R12 each represents hydrogen or an alkyl group; a1 to a3 each represents an integer of 1-6; n1 to n3 each represents 0, 1 or 2; m1, m4 and m7 each represents 0, 1, 2 or 3; R3, R4, R8, R9, R13 and R14 each represents an alkyl group; m2, m3, m5, m6, m8 and m9 each represents 0, 1 or 2; and Y1 to Y3 each represents CO or NRCO (R represents hydrogen, etc.).
摘要翻译：本发明提供一种由该组合物制成的组合物和记录材料，其具有良好的记录动态灵敏度和良好的图像稳定性，特别是具有优异的耐热，耐湿，耐光，增塑剂和水的耐性。组合物和记录材料包括以下化合物（1），（2）和（3）：其中R 1，R 2，R 6， R 11，R 11，R 12和R 12各自表示氢或烷基; 每个^{1 1 各自表示1-6的整数; n <1> 1〜n 3各自表示0,1或2; m 1，m 4和m 7各自表示0,1,2或3; R 3，R 4，R 8，R 9，R 13和R 9， R 14各自表示烷基; m 2，m 3，m 5，m 6，m 8，和8，每个表示0,1或2; 和Y 1〜Y 3各自表示CO或NRCO（R表示氢等）。}

10. 发明申请

US20050096222A1 Phenolic compound and recording material containing the same 失效
标题翻译：酚醛化合物和含有其的记录材料
公开(公告)号：US20050096222A1
公开(公告)日：2005-05-05
申请号：US10507781
申请日：2003-03-13
申请人： Tomoya Hidaka , Tadashi Kawakami
发明人： Tomoya Hidaka , Tadashi Kawakami
IPC分类号： G11B7/244 , B41M5/30 , B41M5/333 , C07C317/22 , C07C317/44 , C07C323/22 , C07C323/52 , C07C323/60 , C07C327/28 , C07C333/08 , C07C335/26 , C07C335/42 , G11B7/245 , G11B7/246 , B41M5/20
CPC分类号： B41M5/3336 , B41M5/155 , B41M5/3335 , C07C317/22 , C07C317/44 , C07C323/52 , C07C323/60 , C07C327/28 , C07C333/08 , G11B7/244 , G11B7/245
摘要： An object of the present invention is to provide a novel phenolic compound, and a recording material containing the same, which is excellent in storage stability. The object can be achieved by a phenolic compound represented by the formula (I): [wherein m represents an integer of 0 to 2; R1 and R2 each independently represents a C1-C6 alkyl group or a C1-C6 alkoxy group; p and q each independently represents an integer of 0 to 4; t and u each independently represents 0 or 1 and do not simultaneously represent 0; and X represents a group represented by any of the formulas (II) to (VII): (wherein R3, R4, R5, R6, R7, R8, R9, R10 and R11 each independently represents a hydrogen atom or a C1-C6 alkyl group; a represents an integer of 1 to 6; b represents an integer of 0 to 4; and c represents an integer of 0 to 6)] and a recording material containing the same.
摘要翻译：本发明的目的是提供一种新型酚类化合物及含有该酚类化合物的记录材料，其储存稳定性优异。该目的可以通过式（I）表示的酚类化合物来实现：[其中m表示0〜2的整数， R 1和R 2各自独立地表示C 1 -C 6烷基或C 1 -C 6烷氧基; p和q各自独立地表示0〜4的整数; t和u各自独立地表示0或1并且不同时表示0; 并且X表示由式（II）至（VII）中的任一个表示的基团：其中R 3，R 4，R 5， R 6，R 7，R 8，R 9，R 10，和R 11各自独立地表示氢原子或C 1 -C 6烷基; a表示1〜6的整数; b表示0〜4的整数，c表示0〜 6）]和含有该记录材料的记录材料。

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