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1. 发明授权

US09061959B2 Method for manufacturing optically active menthol 有权
标题翻译：光学活性薄荷醇的制造方法
公开(公告)号：US09061959B2
公开(公告)日：2015-06-23
申请号：US13990872
申请日：2011-12-01
申请人： Hironori Maeda , Hisanori Itoh , Shinya Yamada , Yoji Hori
发明人： Hironori Maeda , Hisanori Itoh , Shinya Yamada , Yoji Hori
IPC分类号： C07C29/132 , C07B53/00 , C07C29/17 , C07C29/56 , B01J31/18 , B01J31/26 , B01J21/18 , B01J23/44
CPC分类号： C07C29/132 , B01J21/18 , B01J23/44 , C07B53/00 , C07B2200/07 , C07C29/17 , C07C29/56 , C07C2601/14 , C07C35/12 , C07C35/17
摘要： An object of the present invention is to provide a method for manufacturing an optically active menthol having fewer steps, which generates less environmentally polluting waste because a catalytic reaction is involved in all of the steps, and is capable of saving a production cost. The present invention relates to a method for manufacturing an optically active menthol, including the following steps: A-1) asymmetrically hydrogenating at least one of geranial and neral to thereby obtain an optically active citronellal, B-1) conducting a ring-closure reaction of the optically active citronellal in the presence of an acid catalyst to thereby obtain an optically active isopulegol, and C-1) hydrogenating the optically active isopulegol to thereby obtain an optically active menthol.
摘要翻译：本发明的目的是提供一种制造具有较少步骤的光学活性薄荷醇的方法，其由于在所有步骤中都涉及催化反应而产生较少环境污染的废物，并且能够节省生产成本。本发明涉及一种光学活性薄荷醇的制造方法，其包括以下步骤：A-1）不对称地氢化至少一种香叶酸和盐酸，从而获得光学活性香茅醛B-1，进行闭环反应的光学活性香茅醛在酸催化剂的存在下反应，从而得到光学活性的异胡列酮，和C-1）氢化光学活性异胡脑酮，从而得到光学活性的薄荷醇。

2. 发明授权

US09000192B2 Catalyst for asymmetric hydrogenation and method for manufacturing optically active carbonyl compound using the same 有权
标题翻译：用于不对称氢化的催化剂和使用其制备光学活性羰基化合物的方法
公开(公告)号：US09000192B2
公开(公告)日：2015-04-07
申请号：US13881181
申请日：2011-11-29
申请人： Shinya Yamada , Hironori Maeda , Yoji Hori
发明人： Shinya Yamada , Hironori Maeda , Yoji Hori
IPC分类号： B01J31/26 , C07B35/02 , B01J23/38 , B01J23/40 , B01J23/44 , B01J23/46 , C07B53/00 , C07C45/62 , C07D207/12 , C07D317/08 , C07D333/22 , B01J31/02 , B01J31/04
CPC分类号： B01J31/26 , B01J23/38 , B01J23/40 , B01J23/44 , B01J23/46 , B01J31/0209 , B01J31/0237 , B01J31/0245 , B01J31/04 , B01J2231/643 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C45/62 , C07D207/12 , C07D317/08 , C07D333/22 , C07C47/21
摘要： The present invention provides a catalyst used for manufacturing an optically active carbonyl compound by selective asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which is insoluble in a reaction mixture, and a method for manufacturing the corresponding optically active carbonyl compound. Particularly, the invention provides a catalyst for obtaining an optically active citronellal useful as a flavor or fragrance, by selective asymmetric hydrogenation of citral, geranial or neral. The invention relates to a catalyst for asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which comprises: a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which the at least one metal is supported on a support; an optically active cyclic nitrogen-containing compound; and an acid, and also relates to a method for manufacturing an optically active carbonyl compound using the same.
摘要翻译：本发明提供了通过选择性不对称氢化不溶于反应混合物的α，β-不饱和羰基化合物制备光学活性羰基化合物的催化剂，以及制备相应的光学活性羰基化合物的方法。特别地，本发明提供了一种用于获得可用作香料或香料的光学活性香茅醛的催化剂，通过柠檬醛，香叶醛或柠檬酸的选择性不对称氢化。本发明涉及一种α，β-不饱和羰基化合物的不对称氢化催化剂，它包括：选自属于元素周期表第8族至第10族的金属中的至少一种金属的粉末或金属负载其中所述至少一种金属被支撑在支撑体上的物质; 光学活性环状含氮化合物; 和酸，并且还涉及使用其制备具有光学活性的羰基化合物的方法。

3. 发明授权

US08674144B2 Catalyst for asymmetric hydrogenation and method for manufacturing optically active carbonyl compound using the same 有权
标题翻译：用于不对称氢化的催化剂和使用其制备光学活性羰基化合物的方法
公开(公告)号：US08674144B2
公开(公告)日：2014-03-18
申请号：US13304925
申请日：2011-11-28
申请人： Shinya Yamada , Hironori Maeda , Yoji Hori
发明人： Shinya Yamada , Hironori Maeda , Yoji Hori
IPC分类号： C07C45/62 , B01J31/28
CPC分类号： B01J31/04 , B01J21/12 , B01J23/40 , B01J23/44 , B01J23/74 , B01J23/755 , B01J27/053 , B01J29/068 , B01J29/072 , B01J31/062 , B01J31/1616 , B01J31/2217 , B01J31/26 , B01J2231/645 , B01J2531/0275 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07B2200/07 , C07C45/62 , Y02P20/588 , C07C47/21
摘要： The present invention provides a catalyst used for manufacturing an optically active carbonyl compound by selective asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, which is insoluble in a reaction mixture, and a method for manufacturing the corresponding optically active carbonyl compound. Particularly, the invention provides a catalyst for obtaining an optically active citronellal useful as a flavor or fragrance, by selective asymmetric hydrogenation of citral, geranial or neral. The invention relates to a catalyst for asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, which comprises: a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which the at least one metal is supported on a support; an optically active peptide compound; and an acid, and also relates to a method for manufacturing an optically active carbonyl compound using the same.
摘要翻译：本发明提供了通过选择性不对称氢化不溶于反应混合物的α，β-不饱和羰基化合物和用于制备相应的光学活性羰基化合物的方法制备光学活性羰基化合物的催化剂。特别地，本发明提供了一种用于获得可用作香料或香料的光学活性香茅醛的催化剂，通过柠檬醛，香叶醛或柠檬酸的选择性不对称氢化。本发明涉及α，β-不饱和羰基化合物的不对称氢化催化剂，其包括：选自属于元素周期表第8族至第10族的金属的至少一种金属的粉末或金属负载物质其中所述至少一种金属支撑在支撑件上; 光学活性肽化合物; 和酸，并且还涉及使用其制备具有光学活性的羰基化合物的方法。

4. 发明申请

US20130217895A1 CATALYST FOR ASYMMETRIC HYDROGENATION AND METHOD FOR MANUFACTURING OPTICALLY ACTIVE CARBONYL COMPOUND USING THE SAME 有权
标题翻译：不对称氢化的催化剂及使用该反应的制造光活性碳化合物的方法
公开(公告)号：US20130217895A1
公开(公告)日：2013-08-22
申请号：US13881181
申请日：2011-11-29
申请人： Shinya Yamada , Hironori Maeda , Yoji Hori
发明人： Shinya Yamada , Hironori Maeda , Yoji Hori
IPC分类号： B01J31/26 , C07B35/02
CPC分类号： B01J31/26 , B01J23/38 , B01J23/40 , B01J23/44 , B01J23/46 , B01J31/0209 , B01J31/0237 , B01J31/0245 , B01J31/04 , B01J2231/643 , C07B35/02 , C07B53/00 , C07B2200/07 , C07C45/62 , C07D207/12 , C07D317/08 , C07D333/22 , C07C47/21
摘要： The present invention provides a catalyst used for manufacturing an optically active carbonyl compound by selective asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which is insoluble in a reaction mixture, and a method for manufacturing the corresponding optically active carbonyl compound. Particularly, the invention provides a catalyst for obtaining an optically active citronellal useful as a flavor or fragrance, by selective asymmetric hydrogenation of citral, geranial or neral. The invention relates to a catalyst for asymmetric hydrogenation of an α, β-unsaturated carbonyl compound, which comprises: a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which the at least one metal is supported on a support; an optically active cyclic nitrogen-containing compound; and an acid, and also relates to a method for manufacturing an optically active carbonyl compound using the same.
摘要翻译：本发明提供了通过选择性不对称氢化不溶于反应混合物的α，β-不饱和羰基化合物和用于制备相应的光学活性羰基化合物的方法制备光学活性羰基化合物的催化剂。特别地，本发明提供了一种用于获得可用作香料或香料的光学活性香茅醛的催化剂，通过柠檬醛，香叶醛或柠檬酸的选择性不对称氢化。本发明涉及α，β-不饱和羰基化合物的不对称氢化催化剂，其包括：选自属于元素周期表第8族至第10族的金属中的至少一种金属的粉末或金属负载物质其中所述至少一种金属支撑在支撑件上; 光学活性环状含氮化合物; 和酸，并且还涉及使用其制备具有光学活性的羰基化合物的方法。

5. 发明授权

US08217204B2 Catalyst for asymmetric hydrogenation 有权
标题翻译：非对称氢化催化剂
公开(公告)号：US08217204B2
公开(公告)日：2012-07-10
申请号：US12792016
申请日：2010-06-02
申请人： Hironori Maeda , Yoji Hori
发明人： Hironori Maeda , Yoji Hori
IPC分类号： C07C45/62 , C07C29/17 , B01J31/02
CPC分类号： C07D207/06 , B01J31/181 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07B2200/07 , C07C45/62 , C07D207/08 , C07D207/16 , C07D233/32 , C07D241/44 , C07D405/04 , C07C47/21
摘要： This invention aims at providing a catalyst for producing an optically active aldehyde or an optically active ketone, which is an optically active carbonyl compound, by carrying out selective asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, particularly a catalyst which is insoluble in a reaction mixture for obtaining optically active citronellal which is useful as a flavor or fragrance, by carrying out selective asymmetric hydrogenation of citral, geranial or neral; and a method for producing a corresponding optically active carbonyl compound. The invention relates to a catalyst for asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, which comprises a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table is supported on a support, an optically active cyclic nitrogen-containing compound and an acid.
摘要翻译：本发明的目的在于提供一种用于制备光学活性醛或光学活性酮的催化剂，它是光学活性的羰基化合物，通过进行α，β-不饱和羰基化合物的选择性不对称氢化，特别是不溶于在用于获得可用作香料或香料的光学活性香茅醛的反应混合物中，通过进行柠檬醛，香叶醛或香精的选择性不对称氢化; 以及制备相应的光学活性羰基化合物的方法。本发明涉及一种α，β-不饱和羰基化合物的不对称氢化催化剂，它包括选自属于元素周期表第8至第10族金属的至少一种金属的粉末或金属负载物质其中选自属于元素周期表第8族至第10族的金属中的至少一种金属负载在载体，光学活性环状含氮化合物和酸上。

6. 发明授权

US08550711B2 Treatment table system 有权
标题翻译：治疗台系统
公开(公告)号：US08550711B2
公开(公告)日：2013-10-08
申请号：US12997727
申请日：2008-06-18
申请人： Hironori Maeda , Hiroshi Otani
发明人： Hironori Maeda , Hiroshi Otani
IPC分类号： A61B6/04
CPC分类号： A61N5/1049 , A61B6/0457 , A61N2005/1061 , A61N2005/1087
摘要： Lesion positioner systems and, which perform positioning of a lesion A by moving a top board for allowing a subject to be placed thereon, set an isocenter of a diagnostic 3D imaging unit as a virtual isocenter at the time when a treatment table is in a 3D imaging diagnosis position, and positions the lesion A to the virtual isocenter, based on a three-dimensional diagnostic image in consideration of particle beam therapy. A treatment table moving mechanism moves the treatment table to the treatment position relative to the particle beam therapy system while maintaining states of the top board and the lesion positioner systems and at the time of positioning, thereby positioning the lesion A to the isocenter of the particle beam therapy system.
摘要翻译：病变定位器系统，并且通过移动顶板以允许被摄体放置在其上来执行病变A的定位，将诊断3D成像单元的等角点设置为处理台处于3D时的虚拟等角点成像诊断位置，并且基于考虑到粒子束治疗的三维诊断图像将病变A定位到虚拟等角点。治疗台移动机构将治疗台相对于粒子束治疗系统移动到治疗位置，同时保持顶板和病变定位器系统的状态，并且在定位时，将病变A定位到颗粒的等角点射束治疗系统。

7. 发明申请

US20110098479A1 CONDENSATION REACTION BY METAL CATALYST 审中-公开
标题翻译：金属催化剂冷凝反应
公开(公告)号：US20110098479A1
公开(公告)日：2011-04-28
申请号：US12980502
申请日：2010-12-29
申请人： KAZUSHI MASHIMA , Takashi Ohshima , Takanori Iwasaki , Hironori Maeda , Kenya Ishida
发明人： KAZUSHI MASHIMA , Takashi Ohshima , Takanori Iwasaki , Hironori Maeda , Kenya Ishida
IPC分类号： C07F7/10 , C07D263/12 , C07D263/10 , C07D263/14 , C07D263/52
CPC分类号： C07D263/12 , B01J31/2226 , B01J2531/26 , C07C53/18 , C07C231/02 , C07C253/30 , C07D263/10 , C07D263/14 , C07D263/52 , C07D413/06 , C07F3/003 , C07F7/1892 , C07F9/5022 , C07K1/088 , C07K1/10
摘要： The invention relates to a method for producing an azoline compound represented by the general formula (3): wherein R1 represents an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, an optionally substituted alkoxycarbonyl group, a halogen atom, a substituted amino group, a substituted carbamoyl group or an optionally substituted heterocyclic group; R3, R4, R5 and R6 may be the same or different and each represents a hydrogen atom, an optionally substituted hydrocarbon group, an optionally substituted alkoxy group, an optionally substituted alkoxycarbonyl group, a halogen atom, a substituted amino group, a substituted carbamoyl group or an optionally substituted heterocyclic group; two arbitrary groups selected from R3, R4, R5 and R6 may bond to each other to form a ring; and Z1 represents an oxygen atom, a sulfur atom or a selenium atom;comprising reacting a carboxylic acid or a carboxylic acid derivative represented by the general formula (1): R1CO2R2 (1) wherein R1 is as defined above; R2 represents a hydrogen atom, an optionally substituted alkyl group or an optionally substituted aryl group; and R1 and R2 may bond to each other to form a ring;with an aminochalcogenide represented by the general formula (2): wherein R3, R4, R5, R6 and Z1 are as defined above; in the presence of a compound containing a group 12 metal element in the periodic table.
摘要翻译：本发明涉及一种制备由通式（3）表示的唑啉化合物的方法：其中R1表示任选取代的烃基，任选取代的烷氧基，任选取代的烷氧基羰基，卤素原子，取代的氨基，取代的氨基甲酰基或任选取代的杂环基; R3，R4，R5和R6可以相同或不同，各自表示氢原子，任选取代的烃基，任选取代的烷氧基，任选取代的烷氧基羰基，卤素原子，取代的氨基，取代的氨基甲酰基基团或任选取代的杂环基团; 选自R3，R4，R5和R6中的两个任意基团可以彼此键合形成环; Z1表示氧原子，硫原子或硒原子; 包括使由通式（1）表示的羧酸或羧酸衍生物：R1CO2R2（1）其中R1如上定义; R2表示氢原子，任选取代的烷基或任选取代的芳基; 并且R 1和R 2可以彼此键合形成环; 与通式（2）表示的氨基硫族化物：其中R3，R4，R5，R6和Z1如上定义; 在含有元素周期表中第12族金属元素的化合物存在下进行。

8. 发明申请

US20100131224A1 TEST METHOD AND PROGRAM PRODUCT USED THEREFOR 失效
标题翻译：使用的测试方法和程序产品
公开(公告)号：US20100131224A1
公开(公告)日：2010-05-27
申请号：US12324096
申请日：2008-11-26
申请人： Hironori Maeda
发明人： Hironori Maeda
IPC分类号： G06F19/00
CPC分类号： G01R31/31907 , G01R31/3172
摘要： The testing method of the present invention for testing a plurality of devices under test connected to a test module includes (a) determining combinations of devices under test that can theoretically be measured simultaneously from among the combinations of the plurality of devices under test based on at least the connection relationship between the test module and the plurality of devices under test. The resting method further includes (b) testing the plurality of devices under test by sequentially selecting the combinations of devices under test to be actually measured simultaneously from the combinations determined in (a).
摘要翻译：用于测试连接到测试模块的多个待测器件的本发明的测试方法包括：（a）确定在理论上可以从被测试的多个器件的组合中基于at 至少测试模块与被测试的多个设备之间的连接关系。休息方法还包括（b）通过从（a）中确定的组合中顺序地选择要被实际测量的实际测量的被测器件的组合来测试被测试的多个器件。

9. 发明授权

US06725449B1 Semiconductor test program debugging apparatus 失效
标题翻译：半导体测试程序调试装置
公开(公告)号：US06725449B1
公开(公告)日：2004-04-20
申请号：US09639480
申请日：2000-08-15
申请人： Yoshinori Maeda , Hironori Maeda , Tadashi Oda
发明人： Yoshinori Maeda , Hironori Maeda , Tadashi Oda
IPC分类号： G06F944
CPC分类号： G01R31/31705 , G01R31/318307
摘要： A semiconductor test program debugging apparatus is disclosed to which data concerning a packet input to and output from the packet transfer memory device is supplied, and which extracts a part corresponding to the packet from data input to and output from the memory device with response to a test signal generated by a tester simulator and displays the details of the part.
摘要翻译：公开了一种半导体测试程序调试装置，其中提供了关于从分组传送存储装置输入和输出的分组的数据，并且从数据输入到从存储装置输出的部分响应于由测试仪模拟器产生的测试信号，并显示零件的细节。

10. 发明申请

US20120292801A1 IMPRINT APPARATUS, IMPRINT METHOD, AND DEVICE MANUFACTURING METHOD 有权
标题翻译：印刷装置，印刷方法和装置制造方法
公开(公告)号：US20120292801A1
公开(公告)日：2012-11-22
申请号：US13469829
申请日：2012-05-11
申请人： Hironori Maeda , Seiya Miura , Kazuhiko Mishima , Ken Minoda
发明人： Hironori Maeda , Seiya Miura , Kazuhiko Mishima , Ken Minoda
IPC分类号： B29C59/02
CPC分类号： G03F9/7042 , B82Y10/00 , B82Y40/00 , G03F7/0002 , G03F9/7088
摘要： An imprint apparatus, which is configured to transfer a pattern to an imprint material supplied on a substrate by using a mold having the pattern formed thereon, includes a light-receiving element, a detection system configured to illuminate a mark formed on the substrate and a mark formed on the mold, and guide light reflected from the mark formed on the substrate and the mark formed on the mold to the light-receiving element, and a relay optical system. The relay optical system is configured to form images of the light reflected from the mark formed on the substrate and the mark formed on the mold between the relay optical system and the detection system. The detection system is configured to guide the light image-formed by the relay optical system to the light-receiving element.
摘要翻译：一种压印装置，其被配置为通过使用其上形成有图案的模具将图案转印到提供在基板上的压印材料，包括光接收元件，被配置为照亮形成在基板上的标记的检测系统和形成在模具上的标记，以及将形成在基板上的标记和模具上形成的标记反射的光引导到光接收元件，以及中继光学系统。中继光学系统被配置为形成从形成在基板上的标记反射的光和在中继光学系统和检测系统之间形成在模具上的标记的图像。检测系统被配置为将由中继光学系统形成的光引导到光接收元件。

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