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    • 1. 发明授权
    • Acrylic film-laminated molded article and acrylic film
    • 丙烯酸薄膜层压成型品和丙烯酸薄膜
    • US5804287A
    • 1998-09-08
    • US737598
    • 1996-11-25
    • Hiroki HatakeyamaKazuhiko NakagawaTomonori Terasawa
    • Hiroki HatakeyamaKazuhiko NakagawaTomonori Terasawa
    • C08J5/18C08L33/06
    • C08J5/18C08J2333/12Y10T428/24851Y10T428/24868Y10T428/24884Y10T428/254Y10T428/26Y10T428/31507Y10T428/31917Y10T428/31924Y10T428/31928
    • An acrylic film with a thickness of 300 .mu.m or less for acrylic-laminated injection molded articles, which comprises 0-10 parts by weight of a thermoplastic polymer (I) consisting mainly of methyl methacrylate and having a reduced viscosity exceeding 0.2 L/g; 5.5-25 parts by weight of a rubber-containing polymer (II) which is a polymer wherein a monomer consisting mainly of a methacrylic acid ester is linked with an elastic copolymer consisting mainly of an alkyl acrylate, and which has a particle size of 0.2 .mu.m-0.4 .mu.m; and 65-94.5 parts by weight of a thermoplastic polymer (III) consisting mainly of a methacrylic acid ester and having a reduced viscosity of no greater than 0.1 L/g, wherein the total of the components (I), (II) and (III) is 100 parts by weight, and the proportion of the elastic copolymer in the rubber-containing polymer (II) is 5-18 wt % of the total of components (I), (II) and (III); as well as molded articles laminated with the acrylic film.
    • PCT No.PCT / JP96 / 00836 Sec。 371日期:1996年11月25日 102(e)日期1996年11月25日PCT 1996年3月28日PCT公布。 出版物WO96 / 30435 日期:1996年3月10日丙烯酸层压注射成型品的厚度为300μm以下的丙烯酸类膜,其包含0〜10重量份的主要由甲基丙烯酸甲酯组成并且具有降低粘度的热塑性聚合物(I) 超过0.2 L / g; 5.5-25重量份作为聚合物的含橡胶聚合物(II),其中主要由甲基丙烯酸酯组成的单体与主要由丙烯酸烷基酯组成的弹性共聚物连接,并且其粒径为0.2 亩 - 0.4亩; 和65-94.5重量份的主要由甲基丙烯酸酯组成并且具有不大于0.1L / g的比浓粘度的热塑性聚合物(III),其中组分(I),(II)和( III)为100重量份,含橡胶的聚合物(II)中的弹性共聚物的比例为组分(I),(II)和(III)的总量的5-18重量%。 以及与丙烯酸膜层压的模制品。
    • 6. 发明申请
    • OPTICAL COPOLYMER AND MOLDED PRODUCT COMPRISING THE SAME
    • 光学共聚物和包含该共聚物的成型产品
    • US20090036624A1
    • 2009-02-05
    • US11574415
    • 2005-08-30
    • Yukinori OkimotoHiroki Hatakeyama
    • Yukinori OkimotoHiroki Hatakeyama
    • C08F220/24
    • C08F220/14C08F220/24C08F224/00
    • This invention provides an optical copolymer which is excellent in balance among high transmittance, high heat resistance, low birefringent property, and mechanical strength, and an optical molded article comprising the optical copolymer. The optical copolymer comprises 50 to 80% by mass of methyl methacrylate units, 10 to 20% by mass of units derived from a specific lactone compound, and 10 to 30% by mass of trifluoroethyl methacrylate units. The mass ratio of the trifluoroethyl methacrylate units is in the range of 0.5 to 2.0 when the mass of the units derived from the specific lactone compound is presumed to be 1, and the glass transition temperature is 120° C. or above. The optical copolymer is suitable for objective lenses, prisms, condenser lenses, diffraction gratings, collimator lenses and sensor lenses.
    • 本发明提供了高透光率,高耐热性,低双折射性和低机械强度之间平衡优异的光学共聚物,以及包含该光学共聚物的光学成型制品。 光学共聚物含有50〜80质量%的甲基丙烯酸甲酯单元,10〜20质量%的来自特定的内酯化合物的单元,10〜30质量%的甲基丙烯酸三氟乙酯单元。 当将来自特定内酯化合物的单元的质量推定为1,玻璃化转变温度为120℃以上时,甲基丙烯酸三氟乙酯单元的质量比在0.5〜2.0的范围内。 光学共聚物适用于物镜,棱镜,聚光透镜,衍射光栅,准直透镜和传感器透镜。
    • 8. 发明授权
    • Antistatic resin shaped article and process for preparation thereof
    • 抗静电树脂成型制品及其制备方法
    • US5093205A
    • 1992-03-03
    • US447825
    • 1989-12-08
    • Naoki YamamotoHiroki Hatakeyama
    • Naoki YamamotoHiroki Hatakeyama
    • B29C39/12B05D1/28B29C39/16C08F220/34C08J7/04C09K3/16
    • C08J7/047B05D1/286C08F220/34C09K3/16B05D2252/02C08J2433/00C08J2451/00Y10S428/922Y10T428/31928Y10T428/31935
    • A synthetic resin shaped article having good antistatic properties, composed of a substrate, at least part of which is covered with a synthetic resin surface layer integrated with the substrate. This shaped article is prepared by polymerizing 100 wt. parts of a mixture comprising (A) more than 20 wt. % of a monomer of the formula (I): ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2, R.sub.3 and R.sub.4 are H or C.sub.1-9 alkyl, m is from 1 to 10, and X.sup.- is an anion, (B) less than 79.99 wt. % of a monomer having one unsaturated double bond and (C) 0.01-10 wt. % of a monomer having at least two unsaturated double bonds; subsequently adding (D) up to 190 wt. parts of a monomer having one unsaturated double bond and (E) up to 10 wt. parts of a monomer having at least two unsaturated double bonds to the formed polymer and polymerizing them to form a copolymer(a); forming a film of the copolymer(a) on the surface of a casting mold; supplying a starting material for a synthetic resin substrate into the casting mold; and polymerizing the starting material to transfer the film to the substrate surface from the molding surface.
    • 一种具有良好抗静电性能的合成树脂成型制品,由基材组成,其至少一部分被与基材一体化的合成树脂表面层覆盖。 该成型制品通过聚合100重量% 部分混合物包含(A)大于20wt。 %的式(I)单体:其中R 1为H或CH 3,R 2,R 3和R 4为H或C 1-19烷基,m为1至10,X为阴离子(B )小于79.99重量% %具有一个不饱和双键的单体和(C)0.01-10重量% %具有至少两个不饱和双键的单体; 随后加入(D)至多190重量% 部分具有一个不饱和双键的单体和(E)至多10wt。 部分具有至少两个不饱和双键的单体与所形成的聚合物并使其聚合以形成共聚物(a); 在铸模的表面上形成共聚物(a)的膜; 将合成树脂基材的原料供给到铸模中; 并且使原料聚合以从成型表面将膜转移到基材表面。