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1. 发明授权

US5330871A Toner for developing electrostatic image 失效
标题翻译：用于显影静电图像的调色剂
公开(公告)号：US5330871A
公开(公告)日：1994-07-19
申请号：US797915
申请日：1991-11-26
申请人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno
发明人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno
IPC分类号： G03G9/08 , G03G9/087 , G03G13/20 , G03G15/20 , G03G9/00
CPC分类号： G03G9/0821 , G03G9/08797
摘要： A toner for developing an electrostatic image is constituted by a binder resin and a colorant. The binder resin is characterized by containing at least 20 wt. % of an extraction residue after 6 hours of extraction and below 20 wt. % of an extraction residue after 72 hours of extraction respectively by Soxhlet extraction with tetrahydrofuran. The toner shows a dynamic modulus and a loss modulus, respectively at 200.degree. C. and 0.1 Hz, which are substantially unchanging with time. The properties provide the toner with a harmonization of anti-offset characteristic and fixability as well as stable viscoelasticity under heating.
摘要翻译：用于显影静电图像的调色剂由粘合剂树脂和着色剂构成。粘合剂树脂的特征在于含有至少20wt。提取6小时后的提取残留物的％和低于20wt。通过索氏提取用四氢呋喃分别提取72小时后的提取残留物的％。调色剂分别在200℃和0.1Hz下分别显示出动态模量和损耗模量，其随时间基本上不变。这些特性为调色剂提供了抗补偿特性和定影性的一致性，以及在加热下的稳定的粘弹性。

2. 发明授权

US5500318A Toner for developing electrostatic image and fixing method 失效
标题翻译：用于显影静电图像和定影方法的调色剂
公开(公告)号：US5500318A
公开(公告)日：1996-03-19
申请号：US266478
申请日：1994-06-27
申请人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno
发明人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno
IPC分类号： G03G9/08 , G03G9/087 , G03G13/20 , G03G15/20
CPC分类号： G03G9/0821 , G03G9/08797
摘要： A toner for developing an electrostatic image is constituted by a binder resin and a colorant The binder resin is characterized by containing at least 20 wt. % of an extraction residue after 6 hours of extraction and below 20 wt. % of an extraction residue after 72 hours of extraction respectively by Soxhlet extraction with tetrahydrofuran. The toner shows a dynamic modulus and a loss modulus, respectively at 200.degree. C. and 0.1 Hz, which are substantially unchanging with time. The properties provide the toner with a harmonization of anti-offset characteristic and fixability as well as stable viscoelasticity under heating.
摘要翻译：用于显影静电图像的调色剂由粘合剂树脂和着色剂构成。粘合剂树脂的特征在于含有至少20重量％提取6小时后的提取残留物的％和低于20wt。通过索氏提取用四氢呋喃分别提取72小时后的提取残留物的％。调色剂分别在200℃和0.1Hz下分别显示出动态模量和损耗模量，其随时间基本上不变。这些特性为调色剂提供了抗补偿特性和定影性的一致性以及在加热下的稳定的粘弹性。

3. 发明授权

US5268248A Toner for developing electrostatic image and process for production thereof 失效
标题翻译：用于显影静电图像的调色剂及其生产方法
公开(公告)号：US5268248A
公开(公告)日：1993-12-07
申请号：US798643
申请日：1991-11-26
申请人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno , Kazuyoshi Hagiwara
发明人： Hirohide Tanikawa , Masaki Uchiyama , Yoshinobu Joh , Yasutaka Akashi , Masaaki Taya , Makoto Unno , Kazuyoshi Hagiwara
IPC分类号： G03G9/087 , G03G9/09 , G03G9/097
CPC分类号： G03G9/08708 , G03G9/08706 , G03G9/08793 , G03G9/08795
摘要： A toner for developing an electrostatic image is provided as a pulverized mixture including a binder resin and a colorant. The binder resin is characterized by a molecular weight distribution on a GPC chromatogram of its tetrahydrofuran (THF)-soluble resin content including below 15% of a resin component in a molecular weight region of at most 5000 and at least 5 wt. % of a resin component in a molecular weight region of at least 5.times.10.sup.6 and showing a main peak in a molecular weight region of 5000 to 5.times.10.sup.6. The THF-soluble resin component in the molecular weight region of at least 5.times.10.sup.6 is extremely enriched during a melt-kneading step during the toner production, so as to effectively prevent toner flowout from a member for cleaning a fixing roller.

4. 发明授权

US5504272A Magnetic toner having defined particle distribution 失效
标题翻译：具有确定颗粒分布的磁性调色剂
公开(公告)号：US5504272A
公开(公告)日：1996-04-02
申请号：US246754
申请日：1994-05-20
申请人： Masaki Uchiyama , Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Makoto Unno
发明人： Masaki Uchiyama , Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Makoto Unno
IPC分类号： G03G9/08 , G03G9/087 , G03G13/09 , G03G15/09 , G03G15/08
CPC分类号： G03G13/09 , G03G15/0907 , G03G9/0819 , G03G9/08795
摘要： An image forming method in which a toner-carrying member for carrying a specific magnetic toner is placed adjacent a latent image-bearing member for carrying an electrostatic latent image so as to form a developing region of a predetermined gap size. The magnetic toner on the toner-carrying member forms a toner layer of a regulated thickness smaller than the above-mentioned gap. An asymmetric bias is applied to the magnetic toner so as to cause the magnetic toner from the toner-carrying member to be conveyed to the latent image-bearing member thereby to develop the electrostatic latent image.
摘要翻译：一种图像形成方法，其中用于承载特定磁性调色剂的调色剂承载构件邻近用于承载静电潜像的潜像承载构件放置以形成预定间隙尺寸的显影区域。调色剂承载构件上的磁性调色剂形成的调色剂层的厚度小于上述间隙。对磁性调色剂施加不对称偏压，使得来自调色剂承载构件的磁性调色剂被输送到潜像承载部件，从而显影静电潜像。

5. 发明授权

US5338894A Image forming method with improved development 失效
标题翻译：具有改进发展的图像形成方法
公开(公告)号：US5338894A
公开(公告)日：1994-08-16
申请号：US763253
申请日：1991-09-20
申请人： Masaki Uchiyama , Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Makoto Unno
发明人： Masaki Uchiyama , Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Makoto Unno
IPC分类号： G03G9/08 , G03G9/087 , G03G13/09 , G03G15/09 , G03G15/08
CPC分类号： G03G13/09 , G03G15/0907 , G03G9/0819 , G03G9/08795
摘要： An image forming method in which a toner-carrying member for carrying a specific magnetic toner is placed adjacent a latent image-bearing member for carrying an electrostatic latent image so as to form a developing region of a predetermined gap size. The magnetic toner on the toner-carrying member forms a toner layer of a regulated thickness smaller than the above-mentioned gap. An asymmetric bias is applied to the magnetic toner so as to cause the magnetic toner from the toner-carrying member to be conveyed to the latent image-bearing member thereby to develop the electrostatic latent image.
摘要翻译：一种图像形成方法，其中用于承载特定磁性调色剂的调色剂承载构件邻近用于承载静电潜像的潜像承载构件放置以形成预定间隙尺寸的显影区域。调色剂承载构件上的磁性调色剂形成的调色剂层的厚度小于上述间隙。对磁性调色剂施加不对称偏压，使得来自调色剂承载构件的磁性调色剂被输送到潜像承载部件，从而显影静电潜像。

6. 发明授权

US5296326A Magnetic toner 失效
标题翻译：磁性调色剂
公开(公告)号：US5296326A
公开(公告)日：1994-03-22
申请号：US994473
申请日：1992-12-21
申请人： Masaaki Taya , Hirohide Tanikawa , Yasutaka Akashi , Makoto Unno , Masaki Uchiyama , Kiichiro Sakashita
发明人： Masaaki Taya , Hirohide Tanikawa , Yasutaka Akashi , Makoto Unno , Masaki Uchiyama , Kiichiro Sakashita
IPC分类号： G03G9/083
CPC分类号： G03G9/0833
摘要： A magnetic toner for electrophotography having stable triboelectric chargeability under various environmental conditions may be provided by using magnetic iron oxide particles having a moderately high surface Feo content, specified by the following conditions: (a) a dissolved Fe (II) content in dissolved total iron of 14-33.3 wt. % at a dissolved total iron percentage of 5.+-.1 wt. %, (b) a dissolved Fe (II) content in dissolved total iron of 17-33.3 wt. % at a dissolved total iron percentage of 10.+-.1 wt. %, and (c) a dissolved Fe (II) content in dissolved total iron of 18-33.3 wt. % at a dissolved total iron percentage of 15.+-.1 wt.
摘要翻译：可以通过使用具有适度高的表面Feo含量的磁性氧化铁颗粒来提供在各种环境条件下具有稳定的摩擦带电性的电子照相用磁性调色剂，其特征在于以下条件：（a）溶解的总铁中溶解的Fe（II）含量为14-33.3重量％％的溶解总铁百分比为5 + -1wt。％，（b）溶解的总铁中溶解的Fe（II）含量为17-33.3wt。％的溶解总铁百分比为10 + 1wt。％，和（c）溶解的总铁中溶解的Fe（II）含量为18-33.3wt。％的溶解总铁百分比为15 + 1重量％。

7. 发明授权

US5219946A Binder resin and process for producing it 失效
标题翻译：粘合剂树脂及其生产工艺
公开(公告)号：US5219946A
公开(公告)日：1993-06-15
申请号：US611705
申请日：1990-11-08
申请人： Hirohide Tanikawa , Masaki Uchiyama , Tsutomu Kukimoto , Yasutaka Akashi , Masaaki Taya , Makoto Unno , Seiichi Takagi
发明人： Hirohide Tanikawa , Masaki Uchiyama , Tsutomu Kukimoto , Yasutaka Akashi , Masaaki Taya , Makoto Unno , Seiichi Takagi
IPC分类号： G03G9/087
CPC分类号： G03G9/08733 , G03G9/08726
摘要： A binder resin comprises a vinyl copolymer, a mixture of vinyl copolymers, or a mixture of a vinyl copolymer and a vinyl polymer. A resin component with a molecular weight of not more than 10,000 is contained in an amount of from 5 to 50% by weight based on the whole resin. The vinyl copolymer or the mixture of vinyl copolymers has an acid anhydride group and a carboxyl group.
摘要翻译：粘合剂树脂包括乙烯基共聚物，乙烯基共聚物的混合物或乙烯基共聚物和乙烯基聚合物的混合物。基于整个树脂，分子量不超过10,000的树脂组分的含量为5-50重量％。乙烯基共聚物或乙烯基共聚物的混合物具有酸酐基和羧基。

8. 发明授权

US5212524A Toner for developing electrostatic images, image forming method and image forming apparatus 失效
标题翻译：用于静电图像显影的调色剂，成像方法和图像形成装置
公开(公告)号：US5212524A
公开(公告)日：1993-05-18
申请号：US937114
申请日：1992-08-31
申请人： Hirohide Tanikawa , Yasutaka Akashi , Masaki Uchiyama , Makoto Unno , Masaaki Taya
发明人： Hirohide Tanikawa , Yasutaka Akashi , Masaki Uchiyama , Makoto Unno , Masaaki Taya
IPC分类号： G03G9/08 , G03G9/083 , G03G9/087
CPC分类号： G03G9/0819 , G03G9/0835 , G03G9/0838 , G03G9/08733
摘要： A toner for developing electrostatic images, comprises a binder resin and a colorant, wherein the binder resin comprises a vinyl copolymer having an acid anhydride group, and the binder resin has a total acid value (A) of 2-100 mgKOH/g and a total acid value (B) attributable to acid anhydride group of below 6 mgKOH/g so that [(B)/(A)].times.100 is 60% or less. Because the binder resin has a specified acid value partly attributable to acid anhydride group, the toner is provided with an adequate balance between chargeability and dischargeability, so that the toner shows a stable performance under various environmental conditions. The toner is particularly advantageously constituted as a magnetic toner of fine particle sizes suitably used under application of unsymmetrical alternating bias electric field.
摘要翻译：用于显影静电图像的调色剂包括粘合剂树脂和着色剂，其中粘合剂树脂包括具有酸酐基的乙烯基共聚物，并且粘合剂树脂的总酸值（A）为2-100mgKOH / g，和归因于酸酐基团的总酸值（B）低于6mgKOH / g，使得[（B）/（A）]×100为60％以下。由于粘合剂树脂具有部分归因于酸酐基团的特定酸值，因此调色剂在带电性和放电性之间具有足够的平衡，使得调色剂在各种环境条件下显示出稳定的性能。调色剂特别有利地构成为适用于不对称交流偏压电场的细粒度的磁性调色剂。

9. 发明授权

US5169738A Toner for developing electrostatic images, image forming method and image forming apparatus 失效
标题翻译：用于发展静电图像，图像形成方法和图像形成装置的调色剂
公开(公告)号：US5169738A
公开(公告)日：1992-12-08
申请号：US604207
申请日：1990-10-29
申请人： Hirohide Tanikawa , Yasutaka Akashi , Masaki Uchiyama , Makoto Unno , Masaaki Taya
发明人： Hirohide Tanikawa , Yasutaka Akashi , Masaki Uchiyama , Makoto Unno , Masaaki Taya
IPC分类号： G03G9/08 , G03G9/083 , G03G9/087
CPC分类号： G03G9/0819 , G03G9/0835 , G03G9/0838 , G03G9/08733
摘要： A toner for developing electrostatic images, comprises a binder resin and a colorant, wherein the binder resin comprises a vinyl copolymer having an acid anhydride group, and the binder resin has a total acid value (A) of 2-100 mgKOH/g and a total acid value (B) attributable to acid anhydride group of below 6 mgKOH/g so that [(B)/(A)].times.100 is 60% or less. Because the binder resin has a specified acid value partly attributable to acid anhydride group, the toner is provided with an adequate balance between chargeability and dischargeability, so that the toner shows a stable performance under various environmental conditions. The toner is particularly advantageously constituted as a magnetic toner of fine particle sizes suitably used under application of unsymmetrical alternating bias electric field.

10. 发明授权

US5202731A Image forming apparatus having an alternating bias electric field 失效
标题翻译：具有交替偏置电场的图像形成装置
公开(公告)号：US5202731A
公开(公告)日：1993-04-13
申请号：US935431
申请日：1992-08-26
申请人： Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Kuniko Kobayashi , Masaki Uchiyama
发明人： Hirohide Tanikawa , Yasutaka Akashi , Masaaki Taya , Kuniko Kobayashi , Masaki Uchiyama
IPC分类号： G03G9/08 , G03G13/09 , G03G15/09
CPC分类号： G03G9/0819 , G03G13/09 , G03G15/0907
摘要： An image forming apparatus is formed by providing a latent image-bearing member for holding an electrostatic image thereon and a toner-carrying member for carrying a prescribed magnetic toner comprising a binder resin and magnetic powder and having a particle size distribution including 12% by number or more of magnetic toner particles of 5 microns or smaller, 33% by number or less of magnetic toner particles of 8-12.7 microns and 2% by volume or less of magnetic toner particles of 16 microns or larger so as to provide a volume-average particle size of 4-10 microns. At the developing station, an alternating bias voltage comprising a DC voltage and an unsymmetrical AC voltage in superposition is applied between the toner-carrying member and the latent image-bearing member to provide an alternating bias electric field comprising a development-side voltage component and a reverse-development side voltage component. The development-side voltage component has a magnitude equal to or larger than that of the reverse development-side voltage component and a duration smaller than that of the reverse-development side voltage component, so that the magnetic toner on the toner-carrying member, particularly fine powdery fraction thereof effective for high-quality development, is effectively transferred to the latent image-bearing member to develop the electrostatic image thereon at the developing station.
摘要翻译：通过在其上提供用于保持静电图像的潜像承载部件和用于承载包含粘合剂树脂和磁粉的规定的磁性调色剂的调色剂承载部件形成图像形成装置，其粒度分布包括12数量级或更多的8微米或更小的磁性调色剂颗粒，8-12.7微米的磁性调色剂颗粒的数量少于33％，以及16微米或更大的磁性调色剂颗粒的2体积％以下的磁性调色剂颗粒，平均粒径为4-10微米。在显影站，在调色剂承载构件和潜像承载构件之间施加包括直流电压和不对称交流电压的交替偏置电压，以提供包括显影侧电压分量的交流偏置电场和反向显影侧电压分量。显影侧电压分量的幅度等于或大于反显影侧电压分量的幅度，并且持续时间小于反向显影侧电压分量的幅度，使得调色剂承载元件上的磁性调色剂，特别是对于高质量显影有效的细粉末级分有效地转移到潜像承载部件，以在显影站上显影静电图像。

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