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1. 发明授权

US06852420B2 Optical device, mold, and method of producing the same 失效
标题翻译：光学装置，模具及其制造方法
公开(公告)号：US06852420B2
公开(公告)日：2005-02-08
申请号：US10001201
申请日：2001-12-04
申请人： Hiroaki Yamamoto , Masahiro Hori , Koichiro Nakamura , Kenichi Nakama , Katsuhide Shimmo
发明人： Hiroaki Yamamoto , Masahiro Hori , Koichiro Nakamura , Kenichi Nakama , Katsuhide Shimmo
IPC分类号： G11B7/22 , C03B8/02 , C03B11/00 , C03C27/00 , C03C27/02 , G02B3/00 , G02B3/08 , G02B5/18 , B32B9/00 , B28B7/00 , B32B17/06
CPC分类号： G11B7/261 , C03C27/00 , C03C27/02 , G02B5/1852
摘要： According to the present invention, there is provided a mold constituted by an electrically conductive thin plate having a predetermined surface shape, and an electrically insulating reinforcement material, wherein the electrically conductive thin plate and the electrically insulating reinforcement material are bonded to each other by an anodic bonding method. Particularly, the electrically conductive thin plate is preferably formed out of silicon single crystalline and the electrically insulating reinforcement material is preferably oxide glass.
摘要翻译：根据本发明，提供一种由具有预定表面形状的导电薄板和电绝缘增强材料构成的模具，其中导电薄板和电绝缘增强材料通过一个阳极接合法。特别地，导电薄板优选由单晶硅形成，并且电绝缘增强材料优选为氧化物玻璃。

2. 发明授权

US06740366B2 Article having predetermined surface shape and method for preparing the same 失效
标题翻译：具有预定表面形状的制品及其制备方法
公开(公告)号：US06740366B2
公开(公告)日：2004-05-25
申请号：US10204324
申请日：2002-08-21
申请人： Masahiro Hori , Koichiro Nakamura , Mitsuhiro Kawadu , Hiroko Shikata , Hiroaki Yamamoto
发明人： Masahiro Hori , Koichiro Nakamura , Mitsuhiro Kawadu , Hiroko Shikata , Hiroaki Yamamoto
IPC分类号： C08J704
CPC分类号： B29C39/148 , B29C39/10 , C08F283/12 , C08F299/08 , C08G77/20 , C08L51/085 , C09D183/04 , Y10T428/24479 , Y10T428/31612 , Y10T428/31663
摘要： An article having a predetermined surface configuration, such as an optical element having fine irregularities in the surface which has high heat resistance, small heat shrinkage at the time of molding a film and high dimensional stability, and a production process therefor. The article having a predetermined surface configuration is produced by setting a composition comprising a compound which contains a dimethylsiloxane skeleton having at least three recurring units and at least one polymerizable organic group in the molecule between and in contact with the surface of a substrate and the molding surface of a mold in the form of a film, applying at least one of heat and ultraviolet radiation to the composition, removing the mold, and heating as required to form a film having a surface configuration which is the inversion of the surface configuration of the mold on the surface of the substrate.
摘要翻译：具有预定表面构造的物品，例如具有高耐热性的表面上具有细微凹凸的光学元件，成型薄膜时的热收缩小和尺寸稳定性高的物品及其制造方法。具有预定表面构型的制品是通过将包含含有二甲基硅氧烷骨架的化合物的组合物制成的，所述组合物在分子内具有至少三个重复单元和至少一个可聚合的有机基团，并与基底的表面接触，以薄膜形式的模具的表面，将至少一种热和紫外线辐射施加到组合物上，去除模具，并根据需要进行加热以形成具有表面形状的膜，该表面构型是表面构型的倒转模塑在基材的表面上。

3. 发明授权

US06849350B2 Article having a predetermined surface shape and method for preparation thereof 失效
标题翻译：具有预定表面形状的制品及其制备方法
公开(公告)号：US06849350B2
公开(公告)日：2005-02-01
申请号：US10258809
申请日：2002-02-22
申请人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Masahiro Hori , Hiroaki Yamamoto , Koichiro Nakamura
发明人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Masahiro Hori , Hiroaki Yamamoto , Koichiro Nakamura
IPC分类号： C03C17/25 , C08G79/00 , C08L85/00 , C09D183/04 , C09D183/14 , C09D185/00 , G02B1/10 , G02B3/00 , B32B9/00
CPC分类号： G02B1/10 , C03C17/25 , C03C2217/23 , C03C2218/113 , C08G79/00 , C08L85/00 , C09D183/04 , C09D183/14 , C09D185/00 , G02B3/0031
摘要： An article having a predetermined surface configuration comprising a substrate and a gelled film having a high refractive index, excellent heat resistance, high film hardness and excellent transferability formed on the surface of the substrate.A process for producing an article having a gelled film with a transferred surface on the surface of a substrate by arranging a sol-gel material with close contact between the substrate and a mold in the form of a film and heating it. The sol-gel material contains a metal compound represented by M1Xm, a hydrolyzate thereof or a hydrolysis/polycondensation product thereof, and a metal compound represented by R1M2Yn, a hydrolyzate thereof or a hydrolysis/polycondensation product thereof, wherein at least one of M1 and M2 is a metal atom selected from Ti, Zr, Al, Ge, Sn or Sb and the metal atom accounts for at least 10 atom % of the total of M1 and M2.
摘要翻译：一种具有预定表面构型的制品，其包括基材和形成在基材表面上的具有高折射率，优异的耐热性，高的膜硬度和优异的转印性的凝胶膜。1.一种具有胶凝膜的制品的制造方法，通过在基板和模具之间紧密接触的溶胶 - 凝胶材料，以薄膜形式加热，将其转印到基板的表面上。溶胶凝胶材料含有由M 1 Xm表示的金属化合物，其水解产物或其水解/缩聚产物和由R 1 M 2 Yn表示的金属化合物，其水解产物或水解 /缩聚产物，其中M 1和M 2中的至少一个是选自Ti，Zr，Al，Ge，Sn或Sb的金属原子，并且金属原子占总量的至少10原子％的M 1和M 2。

4. 发明授权

US06721485B1 Echelon diffraction grating and optical waveguide element 失效
$Echelon diffraction grating and optical waveguide element$
标题翻译：梯形衍射光栅和光波导元件
公开(公告)号：US06721485B1
公开(公告)日：2004-04-13
申请号：US09806416
申请日：2001-03-30
申请人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
发明人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
IPC分类号： G02B600
CPC分类号： G02B6/138 , G02B1/04 , G02B5/1814 , G02B5/1852 , C08L83/04
摘要： An echelon diffraction grating which has excellent heat resistance and can be produced at a low cost and an optical waveguide which has high heat resistance, small absorption of a communication wavelength of a near infrared range, and satisfies reliability and a low loss at an optical communication range. The echelon diffraction grating comprises a substrate, and an organopolysiloxane film having a maximum thickness of 1 &mgr;m to 1 mm formed on the surface of the substrate and has a plurality of steps having a predetermined width of 1 to 500 &mgr;m and a predetermined height of 5 to 500 &mgr;m formed on the organopolysiloxane film, and the organopolysiloxane film contains dimethylsiloxane and phenyl(or substituted phenyl)siloxane as essential ingredients.
摘要翻译：具有优异的耐热性并且可以低成本地生产的梯形衍射光栅和具有高耐热性，较小吸收近红外范围的通信波长的光波导，并且在光通信中满足可靠性和低损耗的光波导梯形衍射光栅包括基板和形成在基板表面上的最大厚度为1μm至1mm的有机聚硅氧烷膜，并且具有预定宽度为1至500μm的多个台阶和预定高度在有机聚硅氧烷膜上形成5〜500μm，有机聚硅氧烷膜含有二甲基硅氧烷和苯基（或取代的苯基）硅氧烷作为必要成分。

5. 发明授权

US07006291B2 Optical device and method for fabricating the same 失效
标题翻译：光学装置及其制造方法
公开(公告)号：US07006291B2
公开(公告)日：2006-02-28
申请号：US10630925
申请日：2003-07-31
申请人： Masahiro Hori , Teruyuki Sasaki , Hiroaki Yamamoto , Kentaro Fukuda , Kenichi Yamada , Toshiaki Anzaki , Kenjiro Hamanaka , Koichiro Nakamura , Masaatsu Kido
发明人： Masahiro Hori , Teruyuki Sasaki , Hiroaki Yamamoto , Kentaro Fukuda , Kenichi Yamada , Toshiaki Anzaki , Kenjiro Hamanaka , Koichiro Nakamura , Masaatsu Kido
IPC分类号： G02B1/10
CPC分类号： G02B1/14 , G02B1/041 , G02B1/105 , G02B1/113 , G02B3/0006 , G02B3/0031 , G02B3/0056 , C08L63/00
摘要： The optical device having a predetermined surface profile of the invention is fabricated by forming a multi-layered dielectric film on the surface of a solid composition layer having a glass transition temperature of not lower than 100° C. The solid composition layer is formed by molding and curing a polymerizable organic group-having fluid composition. The curing may be effected through photopolymerization or thermal polymerization of the polymerizable organic group in the composition, and a predetermined surface profile is transferred onto the composition layer from the mold used. The cured composition is released from the mold, and this is coated with a multi-layered dielectric film.
摘要翻译：通过在玻璃化转变温度不低于100℃的固体组合物层的表面上形成多层电介质膜来制造具有本发明的预定表面轮廓的光学装置。固体组合物层通过模制并固化具有可聚合的含有机基团的流体组合物。可以通过组合物中的可聚合有机基团的光聚合或热聚合来实现固化，并且将预定的表面轮廓从所使用的模具转移到组合物层上。固化的组合物从模具中释放，并用多层电介质膜涂覆。

6. 发明授权

US06849209B2 Article having predetermined surface shape and method for production thereof 失效
标题翻译：具有预定表面形状的制品及其制造方法
公开(公告)号：US06849209B2
公开(公告)日：2005-02-01
申请号：US09959451
申请日：2001-02-21
申请人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Masahiro Hori , Koichiro Nakamura , Hiroaki Yamamoto
发明人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Masahiro Hori , Koichiro Nakamura , Hiroaki Yamamoto
IPC分类号： G02B1/04 , B05D1/18 , B29C33/42 , B29C37/00 , B29C39/10 , B29C43/18 , B29C59/02 , C03C17/30 , C08G77/22 , C08J5/00 , C09D183/04 , G02B3/00 , B29D7/00 , B32B3/30
CPC分类号： B29C43/021 , B05D1/185 , B29C33/42 , B29C33/424 , B29C37/0028 , B29C39/10 , B29C43/18 , B29C59/022 , B29C59/026 , B29C2059/023 , B29K2083/00 , B29K2105/0061 , B29L2011/0016 , C03C1/008 , C03C17/007 , C03C2204/08 , C03C2217/213 , C03C2218/113 , C03C2218/32 , C08J5/00 , Y10T428/24479 , Y10T428/26 , Y10T428/31663
摘要： An article with a predetermined surface pattern that is coated with a film which makes possible the complete transfer of the pattern of a patterning die and thick-film patterning having a depth to the order of several tens of micrometers, prevents the occurrence of cracks, has high film hardness, and has a surface pattern which is the inverse of the surface pattern of the patterning die. This article is produced by joining a patterning die closely to a substrate with a sol-gel material containing the silane compound represented by the formula: R1SiX3 (wherein R1 is an alkyl group or hydrogen and X is an alkoxyl group or a halogen atom) and the silane compound represented by the formula: R2SiY3 (wherein R2 is an aryl group or a substituted aryl group and Y is an alkoxyl group or a halogen atom) disposed therebetween in the form of a film and heating them to coat the surface of the substrate with a gel film having a surface pattern which is the inverse of the surface pattern of the patterning die.
摘要翻译：具有涂覆有膜的预定表面图案的制品使得能够完全转印图案形成芯片的图案和具有几十微米级的深度的厚膜图案化可以防止裂纹的发生，具有高膜硬度，并且具有与图案化模具的表面图案相反的表面图案。该制品通过使含有由下式表示的硅烷化合物的溶胶 - 凝胶材料与基材紧密接合而制成：Si 1 Si 3（其中R 1为烷基或氢，X为烷氧基基团或卤原子）和由下式表示的硅烷化合物：其中R 2 SiY 3（其中R 2是芳基或取代的芳基，Y是烷氧基或卤素原子）形成薄膜并加热它们以使具有与图案化模具的表面图案相反的表面图案的凝胶膜涂覆在基材表面上。

7. 发明授权

US06555236B1 Articles having an uneven surface and production process therefor 有权
标题翻译：具有不均匀表面的制品及其制造方法
公开(公告)号：US06555236B1
公开(公告)日：2003-04-29
申请号：US09786484
申请日：2001-03-06
申请人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
发明人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
IPC分类号： B32B904
CPC分类号： G02B3/0006 , G02B5/1852 , Y10T428/31507 , Y10T428/31612 , Y10T428/31663
摘要： A process for producing an article having a fine uneven surface, coated with a film which has high heat resistance, does not crack and does not peel off from a substrate. The process for producing the article comprises disposing a film-forming solution between a substrate and a mold in the form of a film so as to make the solution closely contact with the substrate and the mold, said solution being prepared by carrying out the hydrolysis and dehydration polycondensation reaction of a stock solution containing a specific silane compound (A) having an unhydrolyzable organic group and a hydrolyzable group, a specific silane compound (B) having a hydrolyzable group and a catalyst, and heating to form an article having an uneven film having a surface shape which is the inversion of the surface shape of the mold on the surface of the substrate. The film-forming solution contains the above silane compounds (A) and (B) in the form of unhydrolysates in amounts of 0.5 to 40 wt % and 0.5 to 60 wt % based on the amount of the above silane compound (A) and the amount of the above silane compound (B) contained in the stock solution, respectively. A condensate formed by the dehydration condensation reaction of the film-forming solution has a molecular weight of 300 to 1,900.
摘要翻译：制造具有微细凹凸表面的制品的方法，其涂覆有耐热性高的膜，不会破裂并且不会从基材上剥离。制造该制品的方法包括以薄膜形式在基材和模具之间设置成膜溶液，以使溶液与基材和模具紧密接触，所述溶液通过进行水解和含有具有不可水解的有机基团的特定硅烷化合物（A）和可水解基团的储备溶液的脱水缩聚反应，具有可水解基团的特定硅烷化合物（B）和催化剂，并加热形成具有不均匀膜的物品具有表面形状，该表面形状是基板表面上模具的表面形状的倒转。成膜溶液含有上述硅烷化合物（A）的量为0.5〜40重量％，0.5〜60重量％的非水解产物的上述硅烷化合物（A）和（B）上述硅烷化合物（B）的含量分别为原料溶液。由成膜溶液的脱水缩合反应形成的冷凝物的分子量为300〜1,900。

8. 发明授权

US06415093B1 Optical device and adhesive composition used therefor 失效
标题翻译：用于其的光学装置和粘合剂组合物
公开(公告)号：US06415093B1
公开(公告)日：2002-07-02
申请号：US09670693
申请日：2000-09-28
申请人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
发明人： Koichiro Nakamura , Masahiro Hori , Hiroaki Yamamoto
IPC分类号： G02B600
CPC分类号： C09J183/04 , C03C27/10 , C09J183/14 , C09J185/00 , G02B6/32 , G02B6/3801 , G02B6/4212 , G02B6/4239
摘要： An optical device having at least two optically transparent optical parts which are bonded together with an optically transparent adhesive layer. The adhesive layer is formed from a matrix containing silicon, titanium, zirconium, aluminum or germianium, and oxygen atoms. At least part of the atoms is bonded to other atom(s) through a polyvalent hydrocarbon group and directly bonded a monovalent hydrocarbon group. The refractive index value of the adhesive layer approximates to the refractive index values of the at least two optically transparent optical parts. An adhesive composition for bonding optical parts and a method of bonding optical parts are also proposed.
摘要翻译：一种光学装置，其具有至少两个光学透明的光学部件，其与光学透明的粘合剂层结合在一起。粘合剂层由含有硅，钛，锆，铝或锗的基体和氧原子形成。至少部分原子通过多价烃基与其它原子键合并直接键合一价烃基。粘合剂层的折射率值近似于至少两个光学透明光学部件的折射率值。还提出了用于粘合光学部件的粘合剂组合物和粘合光学部件的方法。

9. 发明授权

US06723487B2 Method for producing article coated with patterned film and photosensitive composition 失效
标题翻译：用图案化薄膜和感光组合物涂覆制品的方法
公开(公告)号：US06723487B2
公开(公告)日：2004-04-20
申请号：US09936323
申请日：2001-09-12
申请人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Mitsuhiro Kawadu , Koichiro Nakamura , Hiroaki Yamamoto
发明人： Tsutomu Minami , Masahiro Tatsumisago , Kiyoharu Tadanaga , Atsunori Matsuda , Mitsuhiro Kawadu , Koichiro Nakamura , Hiroaki Yamamoto
IPC分类号： G03F7075
CPC分类号： G03F7/0042 , G03F7/0755 , G03F7/0757
摘要： There can be provided a method for producing a pattern film-coated article which has excellent film formability, can remove unexposed portions of a film completely in the development step after exposing the film to light. and has excellent pattern accuracy; and a photosensitive composition. The method for producing a pattern film-coated article comprises the steps of coating a photosensitive composition comprising an organometallic or organosilicon compound having photosensitivity and a hydrolyzable metal or silicon alkoxide on a substrate, irradiating the coated film on the substrate with light to polymerize the exposed portions of the coated film and then dissolving unexposed portions to remove them, wherein a pattern film-coated article is produced from an allyl group-containing metal or silicon alkoxide as the organometallic or organosilicon compound.
摘要翻译：可以提供一种制备具有优异成膜性的图案薄膜包衣制品的方法，可以在将薄膜曝光后在显影步骤中完全去除薄膜的未曝光部分。具有优异的图案精度; 和感光性组合物。制备图案薄膜包衣制品的方法包括以下步骤：在基材上涂布包含具有光敏性的有机金属或有机硅化合物的光敏组合物和可水解的金属或硅醇盐，在基材上照射基材上的涂膜，光使聚合涂膜的曝光部分，然后溶解未曝光部分以除去它们，其中由含烯丙基的金属或硅烷醇作为有机金属或有机硅化合物制备图案薄膜包衣制品。

10. 发明授权

US06590722B1 Optical element 失效
标题翻译：光学元件
公开(公告)号：US06590722B1
公开(公告)日：2003-07-08
申请号：US09709557
申请日：2000-11-13
申请人： Tadashi Koyama , Hiroaki Yamamoto , Koichiro Nakamura , Jun Yamaguchi
发明人： Tadashi Koyama , Hiroaki Yamamoto , Koichiro Nakamura , Jun Yamaguchi
IPC分类号： G02B702
CPC分类号： H01S3/0602 , G02B7/008 , H01S3/08072 , H01S3/14
摘要： An optical element comprises a solid material in an optical path of the optical element, wherein the solid material comprises a first material and a second material, and the first and second materials have first and second temperature coefficients of refractive index, respectively, wherein the first temperature coefficient of refractive index has a sign which is opposite that of the second temperature coefficient of refractive index.
摘要翻译：光学元件包括在光学元件的光路中的固体材料，其中固体材料包括第一材料和第二材料，并且第一和第二材料分别具有折射率的第一和第二温度系数，其中第一折射率的温度系数具有与第二温度系数折射率相反的符号。

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