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1. 发明申请

US20100302476A1 LIQUID CRYSTAL LIGHT CONTROL DEVICE AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：液晶灯控制装置及其制造方法
公开(公告)号：US20100302476A1
公开(公告)日：2010-12-02
申请号：US12744659
申请日：2008-11-13
申请人： Masaatsu Kido , Mitsuhiro Kawazu , Yuichi Yano , Daisuke Shinike , Hitoshi Shinike
发明人： Masaatsu Kido , Mitsuhiro Kawazu , Yuichi Yano , Daisuke Shinike , Hitoshi Shinike
IPC分类号： G02F1/1335 , B32B37/02
CPC分类号： C09K19/544 , G02F1/1334 , Y10T156/10
摘要： In the production method of the present invention, an emulsion including a copolymer with a glass transition temperature (Tg) of −50 to 20° C. is obtained by the emulsion polymerization of a monomer group including a monomer A that is a (meth)acrylic acid alkyl ester (where the alkyl group is an open chain group with 1 to 20 carbon atoms or a cyclic group with 5 to 20 carbon atoms) as the main monomer and a monomer B having a carbon-carbon double bond and a nonionic hydrophilic group such as a polyoxyalkylene group, an amide group, and a hydroxyl group. Liquid crystals are dispersed in this emulsion, which is applied onto a conductive film-coated substrate. Another conductive film-coated substrate is laminated thereto, and thus a liquid crystal light control device is obtained. A monomer C having a carboxyl group and/or an amino group and a carbon-carbon double bond may be used in combination with a crosslinking agent so that a crosslinked structure is introduced into the copolymer. The present invention provides a liquid crystal light control device in which the transparency with a voltage applied and the shielding property with no voltage applied are compatible at high level.
摘要翻译：在本发明的制造方法中，通过包含单体A（甲基）丙烯酸酯单体的乳液聚合，得到玻璃化转变温度（Tg）为-50〜20℃的共聚物的乳液，丙烯酸烷基酯（其中烷基是具有1至20个碳原子的开链基团或具有5至20个碳原子的环状基团）作为主要单体和具有碳 - 碳双键的单体B和非离子亲水性例如聚氧化烯基，酰胺基和羟基。将液晶分散在该乳液中，将其施加到导电膜涂覆的基底上。将另一个导电膜涂覆的基板层压，从而获得液晶光控制装置。具有羧基和/或氨基的单体C和碳 - 碳双键可以与交联剂组合使用，使得交联结构被引入到共聚物中。本发明提供了一种液晶光控制装置，其中施加电压的透明度和没有施加电压的屏蔽性能在高水平上是兼容的。

2. 发明授权

US09188705B2 Cover glass for photoelectric conversion devices and method for producing the same 有权
标题翻译：光电转换装置用盖玻璃及其制造方法
公开(公告)号：US09188705B2
公开(公告)日：2015-11-17
申请号：US13513972
申请日：2010-11-05
申请人： Mizuho Koyo , Toru Yamamoto , Mitsuhiro Kawazu , Masaatsu Kido
发明人： Mizuho Koyo , Toru Yamamoto , Mitsuhiro Kawazu , Masaatsu Kido
IPC分类号： B32B5/16 , B05D1/02 , G02B1/113 , G02B1/115 , H01L31/0216
CPC分类号： G02B1/113 , G02B1/115 , H01L31/02168 , Y02E10/50 , Y10T428/24421
摘要： In order to eliminate non-uniformity in the appearance of a cover glass for photoelectric conversion devices, the reflectance curve of the cover glass is extremely flattened. Provided is a cover glass for photoelectric conversion devices that includes a glass sheet having an uneven surface such as a figured glass, and a reflection-reducing film formed on the uneven surface. The reflection-reducing film includes silica fine particles and a binder for the silica fine particles. The silica fine particles are arranged in a single layer on the top portion of the uneven surface of the glass sheet, while the silica fine particles are arranged in stacks to a thickness equivalent to at least three layers on the bottom portion of the uneven surface. The uneven surface of the glass sheet has an average spacing Sm of at least 0.4 mm but not more than 2.5 mm and an arithmetic average roughness Ra of 0.5 μm to 5 μm. The cover glass has a reflectance of at least 1.5% but not more than 3% over the entire wavelength range of 380 nm to 780 nm for incident light from the side on which the reflection-reducing film is formed.
摘要翻译：为了消除用于光电转换装置的玻璃罩外观的不均匀性，盖玻璃的反射率曲线非常扁平化。提供一种用于光电转换装置的玻璃罩，其包括具有不平坦表面的玻璃板，例如图案玻璃，以及形成在不平坦表面上的反射减少膜。减反射膜包括二氧化硅微粒和二氧化硅微粒的粘合剂。二氧化硅微粒在玻璃板的不平坦表面的顶部上排列成单层，而二氧化硅微粒以不均匀表面的底部相当于三层的厚度排列。玻璃板的不平坦表面的平均间隔Sm为至少0.4mm但不大于2.5mm，算术平均粗糙度Ra为0.5μm至5μm。对于从形成有减反射膜的一侧的入射光，玻璃罩在380nm〜780nm的整个波长范围内具有至少1.5％且不大于3％的反射率。

3. 发明授权

US08541106B2 Glass article provided with photocatalyst film 有权
标题翻译：玻璃制品配有光催化膜
公开(公告)号：US08541106B2
公开(公告)日：2013-09-24
申请号：US13390649
申请日：2010-08-17
申请人： Takeshi Yabuta , Fumiyoshi Kondo , Masaatsu Kido , Masahiro Hori , Mitsuhiro Kawazu , Kazutaka Kamitani
发明人： Takeshi Yabuta , Fumiyoshi Kondo , Masaatsu Kido , Masahiro Hori , Mitsuhiro Kawazu , Kazutaka Kamitani
IPC分类号： B32B17/06
CPC分类号： G02B1/11 , B01J21/063 , B01J35/002 , B01J35/004 , B01J35/006 , B01J37/0215 , C03C17/006 , C03C17/23 , C03C2217/42 , C03C2217/71 , C09D1/02 , C09D5/1618 , G02B27/0006 , Y10T428/259
摘要： Provided is a glass article that improves the film strength of a photocatalyst film while maintaining the photocatalytic function and the reflection suppressing function of the photocatalyst film. The photocatalyst film on the glass sheet is formed to contain, in mass %, 50 to 82% of silicon oxide particles, 8 to 40% of titanium oxide particles, and 7 to 20% of a binder component composed of silicon oxide. The average particle diameter of the silicon oxide particles is set to at least 5 times the average particle diameter of the titanium oxide particles. The photocatalyst film is formed to have a structure such that some of the silicon oxide particles in the film serve as protruding silicon oxide particles that are not in contact with the glass sheet and that have their top portions protruding from the surrounding titanium oxide particles and being exposed on the surface of the film, while some of the titanium oxide particles are interposed between the glass sheet and the protruding silicon oxide particles.
摘要翻译：提供一种玻璃制品，其在保持光催化剂功能和光催化剂膜的反射抑制功能的同时提高光催化剂膜的膜强度。形成玻璃板上的光催化剂膜，以质量％计含有50〜82％的氧化硅粒子，8〜40％的氧化钛粒子和7〜20％的由氧化硅构成的粘合剂成分。将氧化硅粒子的平均粒径设定为氧化钛粒子的平均粒径的5倍以上。光催化剂膜形成为具有这样的结构，使得该膜中的一些氧化硅颗粒用作与玻璃板不接触并且其顶部从周围的氧化钛颗粒突出的突出的氧化硅颗粒，并且是暴露在膜的表面上，而一些氧化钛颗粒介于玻璃板和突出的氧化硅颗粒之间。

4. 发明申请

US20120244318A1 COVER GLASS FOR PHOTOELECTRIC CONVERSION DEVICES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：用于光电转换装置的覆盖玻璃及其制造方法
公开(公告)号：US20120244318A1
公开(公告)日：2012-09-27
申请号：US13513972
申请日：2010-11-05
申请人： Mizuho Koyo , Toru Yamamoto , Mitsuhiro Kawazu , Masaatsu Kido
发明人： Mizuho Koyo , Toru Yamamoto , Mitsuhiro Kawazu , Masaatsu Kido
IPC分类号： B32B5/16 , B05D1/02
CPC分类号： G02B1/113 , G02B1/115 , H01L31/02168 , Y02E10/50 , Y10T428/24421
摘要： In order to eliminate non-uniformity in the appearance of a cover glass for photoelectric conversion devices, the reflectance curve of the cover glass is extremely flattened. Provided is a cover glass for photoelectric conversion devices that includes a glass sheet having an uneven surface such as a figured glass, and a reflection-reducing film formed on the uneven surface. The reflection-reducing film includes silica fine particles and a binder for the silica fine particles. The silica fine particles are arranged in a single layer on the top portion of the uneven surface of the glass sheet, while the silica fine particles are arranged in stacks to a thickness equivalent to at least three layers on the bottom portion of the uneven surface. The uneven surface of the glass sheet has an average spacing Sm of at least 0.4 mm but not more than 2.5 mm and an arithmetic average roughness Ra of 0.5 μm to 5 μm. The cover glass has a reflectance of at least 1.5% but not more than 3% over the entire wavelength range of 380 nm to 780 nm for incident light from the side on which the reflection-reducing film is formed.
摘要翻译：为了消除用于光电转换装置的玻璃罩外观的不均匀性，盖玻璃的反射率曲线非常扁平化。提供一种用于光电转换装置的玻璃罩，其包括具有不平坦表面的玻璃板，例如图案玻璃，以及形成在不平坦表面上的反射减少膜。减反射膜包括二氧化硅微粒和二氧化硅微粒的粘合剂。二氧化硅微粒在玻璃板的不平坦表面的顶部上排列成单层，而二氧化硅微粒以不均匀表面的底部相当于三层的厚度排列。玻璃板的不平坦表面的平均间隔Sm为至少0.4mm但不大于2.5mm，算术平均粗糙度Ra为0.5μm至5μm。对于从形成有减反射膜的一侧的入射光，玻璃罩在380nm〜780nm的整个波长范围内具有至少1.5％且不大于3％的反射率。

5. 发明授权

US08310626B2 Liquid crystal light control device and method for producing the same comprising a step of emulsion polymerization of monomers of a liquid crystal resin composite 有权
标题翻译：液晶光控制装置及其制造方法，包括液晶树脂复合体的单体的乳液聚合工序
公开(公告)号：US08310626B2
公开(公告)日：2012-11-13
申请号：US12744659
申请日：2008-11-13
申请人： Masaatsu Kido , Mitsuhiro Kawazu , Yuichi Yano , Daisuke Shiraishi , Hitoshi Shinike
发明人： Masaatsu Kido , Mitsuhiro Kawazu , Yuichi Yano , Daisuke Shiraishi , Hitoshi Shinike
IPC分类号： G02F1/1333 , H01L21/00
CPC分类号： C09K19/544 , G02F1/1334 , Y10T156/10
摘要： In the production method of the present invention, an emulsion including a copolymer with a glass transition temperature (Tg) of −50 to 20° C. is obtained by the emulsion polymerization of a monomer group including a monomer A that is a (meth)acrylic acid alkyl ester (where the alkyl group is an open chain group with 1 to 20 carbon atoms or a cyclic group with 5 to 20 carbon atoms) as the main monomer and a monomer B having a carbon-carbon double bond and a nonionic hydrophilic group such as a polyoxyalkylene group, an amide group, and a hydroxyl group. Liquid crystals are dispersed in this emulsion, which is applied onto a conductive film-coated substrate. Another conductive film-coated substrate is laminated thereto, and thus a liquid crystal light control device is obtained. A monomer C having a carboxyl group and/or an amino group and a carbon-carbon double bond may be used in combination with a crosslinking agent so that a crosslinked structure is introduced into the copolymer. The present invention provides a liquid crystal light control device in which the transparency with a voltage applied and the shielding property with no voltage applied are compatible at high level.
摘要翻译：在本发明的制造方法中，通过包含单体A（甲基）丙烯酸酯单体的乳液聚合，得到玻璃化转变温度（Tg）为-50〜20℃的共聚物的乳液，丙烯酸烷基酯（其中烷基是具有1至20个碳原子的开链基团或具有5至20个碳原子的环状基团）作为主要单体和具有碳 - 碳双键的单体B和非离子亲水性例如聚氧化烯基，酰胺基和羟基。将液晶分散在该乳液中，将其施加到导电膜涂覆的基底上。将另一个导电膜涂覆的基板层压，从而获得液晶光控制装置。具有羧基和/或氨基的单体C和碳 - 碳双键可以与交联剂组合使用，使得交联结构被引入到共聚物中。本发明提供了一种液晶光控制装置，其中施加电压的透明度和没有施加电压的屏蔽性能在高水平上是兼容的。

6. 发明申请

US20120148832A1 GLASS ARTICLE PROVIDED WITH PHOTOCATALYST FILM 有权
标题翻译：玻璃条提供光电膜
公开(公告)号：US20120148832A1
公开(公告)日：2012-06-14
申请号：US13390649
申请日：2010-08-17
申请人： Takeshi Yabuta , Fumiyoshi Kondo , Masaatsu Kido , Masahiro Hori , Mitsuhiro Kawazu , Kazutaka Kamitani
发明人： Takeshi Yabuta , Fumiyoshi Kondo , Masaatsu Kido , Masahiro Hori , Mitsuhiro Kawazu , Kazutaka Kamitani
IPC分类号： B32B5/16
CPC分类号： G02B1/11 , B01J21/063 , B01J35/002 , B01J35/004 , B01J35/006 , B01J37/0215 , C03C17/006 , C03C17/23 , C03C2217/42 , C03C2217/71 , C09D1/02 , C09D5/1618 , G02B27/0006 , Y10T428/259
摘要： Provided is a glass article that improves the film strength of a photocatalyst film while maintaining the photocatalytic function and the reflection suppressing function of the photocatalyst film. The photocatalyst film on the glass sheet is formed to contain, in mass %, 50 to 82% of silicon oxide particles, 8 to 40% of titanium oxide particles, and 7 to 20% of a binder component composed of silicon oxide. The average particle diameter of the silicon oxide particles is set to at least 5 times the average particle diameter of the titanium oxide particles. The photocatalyst film is formed to have a structure such that some of the silicon oxide particles in the film serve as protruding silicon oxide particles that are not in contact with the glass sheet and that have their top portions protruding from the surrounding titanium oxide particles and being exposed on the surface of the film, while some of the titanium oxide particles are interposed between the glass sheet and the protruding silicon oxide particles.
摘要翻译：提供一种玻璃制品，其在保持光催化剂功能和光催化剂膜的反射抑制功能的同时提高光催化剂膜的膜强度。形成玻璃板上的光催化剂膜，以质量％计含有50〜82％的氧化硅粒子，8〜40％的氧化钛粒子和7〜20％的由氧化硅构成的粘合剂成分。将氧化硅粒子的平均粒径设定为氧化钛粒子的平均粒径的5倍以上。光催化剂膜形成为具有这样的结构，使得该膜中的一些氧化硅颗粒用作与玻璃板不接触并且其顶部从周围的氧化钛颗粒突出的突出的氧化硅颗粒，并且是暴露在膜的表面上，而一些氧化钛颗粒介于玻璃板和突出的氧化硅颗粒之间。

7. 发明授权

US07006291B2 Optical device and method for fabricating the same 失效
标题翻译：光学装置及其制造方法
公开(公告)号：US07006291B2
公开(公告)日：2006-02-28
申请号：US10630925
申请日：2003-07-31
申请人： Masahiro Hori , Teruyuki Sasaki , Hiroaki Yamamoto , Kentaro Fukuda , Kenichi Yamada , Toshiaki Anzaki , Kenjiro Hamanaka , Koichiro Nakamura , Masaatsu Kido
发明人： Masahiro Hori , Teruyuki Sasaki , Hiroaki Yamamoto , Kentaro Fukuda , Kenichi Yamada , Toshiaki Anzaki , Kenjiro Hamanaka , Koichiro Nakamura , Masaatsu Kido
IPC分类号： G02B1/10
CPC分类号： G02B1/14 , G02B1/041 , G02B1/105 , G02B1/113 , G02B3/0006 , G02B3/0031 , G02B3/0056 , C08L63/00
摘要： The optical device having a predetermined surface profile of the invention is fabricated by forming a multi-layered dielectric film on the surface of a solid composition layer having a glass transition temperature of not lower than 100° C. The solid composition layer is formed by molding and curing a polymerizable organic group-having fluid composition. The curing may be effected through photopolymerization or thermal polymerization of the polymerizable organic group in the composition, and a predetermined surface profile is transferred onto the composition layer from the mold used. The cured composition is released from the mold, and this is coated with a multi-layered dielectric film.
摘要翻译：通过在玻璃化转变温度不低于100℃的固体组合物层的表面上形成多层电介质膜来制造具有本发明的预定表面轮廓的光学装置。固体组合物层通过模制并固化具有可聚合的含有机基团的流体组合物。可以通过组合物中的可聚合有机基团的光聚合或热聚合来实现固化，并且将预定的表面轮廓从所使用的模具转移到组合物层上。固化的组合物从模具中释放，并用多层电介质膜涂覆。

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